Orlovite
A valid IMA mineral species
This page is currently not sponsored. Click here to sponsor this page.
About Orlovite
Yury L. Orlov
Formula:
KLi2Ti(Si4O10)OF
Colour:
Colourless to white
Lustre:
Vitreous
Hardness:
2 - 3
Specific Gravity:
2.91
Crystal System:
Monoclinic
Member of:
Name:
The mineral is named to honor the well-known Russian mineralogist, doctor of mineralogy Yury Leonidovich Orlov (Юрий Леонидович Орлов) (4 February 1926, Moscow, USSR – 30 August 1980, Moscow, USSR), Director (1976–1980) of the A.E. Fersman Mineralogical museum, RAS, specialist in the mineralogy of diamonds and gem stones, and author of more than 50 works including the classical monographs “Mineralogy of Diamond” and “Morphology of Diamond”.
This page provides mineralogical data about Orlovite.
Unique Identifiers
Mindat ID:
39557
Long-form identifier:
mindat:1:1:39557:9
IMA Classification of Orlovite
Approved
IMA Formula:
KLi2Ti4+(Si4O10)(OF)
Approval year:
2009
First published:
2011
Classification of Orlovite
9.EC.20
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.9.4
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Olv | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Orlovite
Vitreous
Transparency:
Transparent
Comment:
Glassy to pearl like
Colour:
Colourless to white
Streak:
White
Hardness:
2 - 3 on Mohs scale
Hardness:
VHN10=94 kg/mm2 - Vickers
Tenacity:
Flexible
Cleavage:
Perfect
on (001)
on (001)
Density:
2.91(1) g/cm3 (Measured) 2.014 g/cm3 (Calculated)
Optical Data of Orlovite
Type:
Biaxial (-)
RI values:
nα = 1.600(2) nβ = 1.620(2) nγ = 1.625(2)
2V:
Measured: 52.5° , Calculated: 52.6°
Max. Birefringence:
δ = 0.025
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Dispersion:
weak r
Chemistry of Orlovite
Mindat Formula:
KLi2Ti(Si4O10)OF
Element Weights:
Crystallography of Orlovite
Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
B2
Setting:
C2
Cell Parameters:
a = 5.199(3) Å, b = 9.068(7) Å, c = 10.070(4) Å
β = 99.35°
β = 99.35°
Ratio:
a:b:c = 0.573 : 1 : 1.11
Unit Cell V:
468.44 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Orlovite forms lamellar, colorless grains up to 2 mm in size.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 9.96 Å | (40) |
| 4.48 Å | (67) |
| 3.87 Å | (40) |
| 3.33 Å | (100) |
| 2.860 Å | (35) |
| 2.600 Å | (28) |
| 2.570 Å | (30) |
| 2.400 Å | (31) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Orlovite
Place of Conservation of Type Material:
Fersman Mineralogical Museum, RAS, Moscow (registration number 3824/1).
Associated Minerals at Type Locality:
Synonyms of Orlovite
Other Language Names for Orlovite
Relationship of Orlovite to other Species
Member of:
Other Members of Trioctahedral mica:
| Aspidolite | NaMg3(AlSi3O10)(OH)2 | Mon. 2/m : B2/m |
| Balestraite | KLi2V5+Si4O12 | Mon. 2 : B2 |
| Biotite | K(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2 | |
| Ephesite | NaLiAl2(Al2Si2O10)(OH)2 | Tric. 1 : P1 |
| Garmite | CsLiMg2(Si4O10)F2 | Mon. |
| Hendricksite | KZn3(Si3Al)O10(OH)2 | Mon. 2/m : B2/m |
| Kreiterite | CsLi2Fe3+(Si4O10)F2 | Mon. |
| Lepidolite | A field name for the group of Li-rich micas in, or close to, the so-called Polylithionite-Trilithionite ... | |
| Masutomilite | K(LiAlMn2+)[AlSi3O10]F2 | Mon. 2 : B2 |
| Norrishite | KLiMn3+2(Si4O10)O2 | Mon. 2/m : B2/m |
| Preiswerkite | NaMg2Al(Al2Si2O10)(OH)2 | Mon. 2/m : B2/b |
| Shirokshinite | K(NaMg2)(Si4O10)F2 | Mon. 2/m : B2/m |
| Shirozulite | KMn2+3(Si3Al)O10(OH)2 | Mon. 2/m : B2/m |
| Sokolovaite | CsLi2Al(Si4O10)F2 | Mon. |
| Suhailite | (NH4)Fe2+3(AlSi3O10)(OH)2 | Mon. 2/m : B2/m |
| Tainiolite | KLiMg2(Si4O10)F2 | Mon. 2/m : B2/m |
| Wonesite | (Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4 | Mon. 2/m : B2/m |
| 'Zinnwaldite' | Mica Group. |
Common Associates
Associations Based on Photo Data:
| 1 photo of Orlovite associated with Fluorite | CaF2 |
| 1 photo of Orlovite associated with Baratovite | KCa7(Ti,Zr)2Li3Si12O36F2 |
| 1 photo of Orlovite associated with Pyrochlore Group | A2Nb2(O,OH)6Z |
Related Minerals - Strunz-mindat Grouping
| 9.EC. | Meifuite | KFe6(Si7Al)O19(OH)4Cl2 |
| 9.EC. | Balestraite | KLi2V5+Si4O12 |
| 9.EC.05 | Talc | Mg3Si4O10(OH)2 |
| 9.EC.05 | Minnesotaite | Fe2+3Si4O10(OH)2 |
| 9.EC.05 | Willemseite | Ni3Si4O10(OH)2 |
| 9.EC.9.EC. | Voloshinite | Rb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2 |
| 9.EC.10 | Fluorluanshiweiite | KLiAl1.5(Si3.5Al0.5)O10F2 |
| 9.EC.10 | Garmite | CsLiMg2(Si4O10)F2 |
| 9.EC.10 | Gorbunovite | CsLi2(Ti,Fe)Si4O10(F,OH,O)2 |
| 9.EC.10 | Ferripyrophyllite | Fe3+Si2O5(OH) |
| 9.EC.10 | Manganiceladonite | K(MgMn3+◻)(Si4O10)(OH)2 |
| 9.EC.10 | Luanshiweiite | KLiAl1.5(Si3.5Al0.5)O10(OH)2 |
| 9.EC.10 | Pyrophyllite | Al2Si4O10(OH)2 |
| 9.EC.15 | Paragonite | NaAl2(AlSi3O10)(OH)2 |
| 9.EC.15 | Ferroaluminoceladonite | K(Fe2+Al◻)(Si4O10)(OH)2 |
| 9.EC.15 | Nanpingite | CsAl2(AlSi3O10)(OH,F)2 |
| 9.EC.15 | Ferroceladonite | K(Fe2+Fe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Ganterite | Ba0.5(Na,K)0.5Al2(Si2.5Al1.5)O10(OH)2 |
| 9.EC.15 | Kreiterite | CsLi2Fe3+(Si4O10)F2 |
| 9.EC.15 | Roscoelite | KV3+2(AlSi3O10)(OH)2 |
| 9.EC.15 | Aluminoceladonite | K(MgAl◻)(Si4O10)(OH)2 |
| 9.EC.15 | Tobelite | (NH4)Al2(AlSi3O10)(OH)2 |
| 9.EC.15 | Tainiolite | KLiMg2(Si4O10)F2 |
| 9.EC.15 | Celadonite | K(MgFe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Chromceladonite | K(MgCr◻)(Si4O10)(OH)2 |
| 9.EC.15 | Montdorite | KFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2 |
| 9.EC.15 | Chromphyllite | KCr2(AlSi3O10)(OH)2 |
| 9.EC.15 | Boromuscovite | KAl2(BSi3O10)(OH)2 |
| 9.EC.15 | 'UM1988-22-SiO:AlCaFFeHKLiMg' | KLiMgAl2Si3O10F2 |
| 9.EC.15 | Chernykhite | (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2 |
| 9.EC.15 | Muscovite | KAl2(AlSi3O10)(OH)2 |
| 9.EC.20 | Masutomilite | K(LiAlMn2+)[AlSi3O10]F2 |
| 9.EC.20 | Oxyphlogopite | K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 |
| 9.EC.20 | 'Chloroferrokinoshitalite' | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2 |
| 9.EC.20 | Siderophyllite | KFe2+2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Sokolovaite | CsLi2Al(Si4O10)F2 |
| 9.EC.20 | Hendricksite | KZn3(Si3Al)O10(OH)2 |
| 9.EC.20 | Tetraferriphlogopite | KMg3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Fluorannite | KFe2+3(Si3Al)O10F2 |
| 9.EC.20 | Aspidolite | NaMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Suhailite | (NH4)Fe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Ephesite | NaLiAl2(Al2Si2O10)(OH)2 |
| 9.EC.20 | Norrishite | KLiMn3+2(Si4O10)O2 |
| 9.EC.20 | Phlogopite | KMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Yangzhumingite | KMg2.5(Si4O10)F2 |
| 9.EC.20 | Tetraferriannite | KFe2+3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Shirokshinite | K(NaMg2)(Si4O10)F2 |
| 9.EC.20 | Trilithionite | K(Li1.5Al1.5)(AlSi3O10)(F,OH)2 |
| 9.EC.20 | Polylithionite | KLi2Al(Si4O10)(F,OH)2 |
| 9.EC.20 | Shirozulite | KMn2+3(Si3Al)O10(OH)2 |
| 9.EC.20 | Preiswerkite | NaMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Fluorophlogopite | KMg3(Si3Al)O10F2 |
| 9.EC.20 | Wonesite | (Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4 |
| 9.EC.20 | 'UM2004-49-SiO:AlCsFHKLi' | (Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2 |
| 9.EC.20 | Fluorotetraferriphlogopite | KMg3(Fe3+Si3O10)F2 |
| 9.EC.20 | Annite | KFe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Eastonite | KMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.22 | 'Pimelite' | Ni3Si4O10(OH)2 · 4H2O |
| 9.EC.30 | Margarite | CaAl2(Al2Si2O10)(OH)2 |
| 9.EC.35 | Kinoshitalite | (Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2 |
| 9.EC.35 | Ferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2 |
| 9.EC.35 | Clintonite | CaAlMg2(SiAl3O10)(OH)2 |
| 9.EC.35 | Oxykinoshitalite | (Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2 |
| 9.EC.35 | Fluorokinoshitalite | BaMg3(Al2Si2O10)F2 |
| 9.EC.35 | Bityite | CaLiAl2(AlBeSi2O10)(OH)2 |
| 9.EC.35 | Anandite | (Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2 |
| 9.EC.40 | Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O |
| 9.EC.40 | Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Volkonskoite | Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.40 | Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Kurumsakite | (Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?) |
| 9.EC.40 | Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O |
| 9.EC.45 | Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O |
| 9.EC.45 | Hectorite | Na0.3(Mg,Li)3(Si4O10)(F,OH)2 |
| 9.EC.45 | Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) |
| 9.EC.45 | Hanjiangite | Ba2CaV3+Al(H2AlSi3O12)(CO3)2F |
| 9.EC.45 | Spadaite | MgSiO2(OH)2 · H2O (?) |
| 9.EC.45 | Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.45 | Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 |
| 9.EC.45 | Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.45 | Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.50 | Vermiculite | Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O |
| 9.EC.52 | 'Tarasovite' | near NaKAl11Si13O40(OH)9 · 3H2O |
| 9.EC.55 | Clinochlore | Mg5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Borocookeite | (LiAl4◻)[BSi3O10](OH)8 |
| 9.EC.55 | Franklinfurnaceite | Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8 |
| 9.EC.55 | Pennantite | Mn2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Vakhrushevaite | Mg5Cr(AlSi3O10)(OH)8 |
| 9.EC.55 | Nimite | Ni5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Cookeite | (LiAl4◻)[AlSi3O10](OH)8 |
| 9.EC.55 | Gonyerite | Mn2+5Fe3+(Fe3+Si3O10)(OH)8 |
| 9.EC.55 | Chamosite | Fe2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | 'Orthochamosite' | (Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Baileychlore | Zn5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Sudoite | Mg2Al3(AlSi3O10)(OH)8 |
| 9.EC.55 | Glagolevite | Na(Mg,Al)6(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Donbassite | Al4.33(AlSi3O10)(OH)8 |
| 9.EC.60 | Dozyite | Mg7Al2(Al2Si4O15)(OH)12 |
| 9.EC.60 | Rectorite | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O |
| 9.EC.60 | Corrensite | (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O |
| 9.EC.60 | Aliettite | Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O |
| 9.EC.60 | Karpinskite | (Ni,Mg)2Si2O5(OH)2 (?) |
| 9.EC.60 | Lunijianlaite | Li0.7Al6.2(AlSi7O20)(OH,O)10 |
| 9.EC.60 | Tosudite | Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O |
| 9.EC.60 | Hydrobiotite | K(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O |
| 9.EC.60 | Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 |
| 9.EC.60 | Kulkeite | Mg8Al(AlSi7O20)(OH)10 |
| 9.EC.60 | Brinrobertsite | Na0.3Al4(Si4O10)2(OH)4 · 3.5 H2O |
| 9.EC.65 | Macaulayite | (Fe,Al)24Si4O43(OH)2 |
| 9.EC.70 | Burckhardtite | Pb2(Fe3+Te6+)[AlSi3O8]O6 |
| 9.EC.75 | Niksergievite | (Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O |
| 9.EC.75 | Ferrisurite | (Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2O |
| 9.EC.75 | Surite | (Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2 |
| 9.EC.80 | Kegelite | Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 |
Radioactivity
Radioactivity:
| Element | % Content | Activity (Bq/kg) | Radiation Type |
|---|---|---|---|
| Uranium (U) | 0.0000% | 0 | α, β, γ |
| Thorium (Th) | 0.0000% | 0 | α, β, γ |
| Potassium (K) | 9.5787% | 2,969 | β, γ |
For comparison:
- Banana: ~15 Bq per fruit
- Granite: 1,000–3,000 Bq/kg
- EU exemption limit: 10,000 Bq/kg
Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.
Interactive Simulator:
Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!
Activity: –
| Distance | Dose rate | Risk |
|---|---|---|
| 1 cm | ||
| 10 cm | ||
| 1 m |
The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).
D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield
Fluorescence of Orlovite
Short wave - bright yellow
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Orlovite
mindat.org URL:
https://www.mindat.org/min-39557.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Orlovite
Reference List:
Agakhanov, A. A., Pautov, L. A., Karpenko, V. Yu., Bekenova, G. K., Uvarova, Y. A. (2011) Orlovite, KLi2TiSi4O11F, a new mineral of the mica group. New Data on Minerals, 46. Moscow. 13-19
Gatta, G. D., Camara, F., Tait, K. T., Belakovskiy, D. (2012) New Mineral Names. American Mineralogist, 97 (11) 2064-2072 doi:10.2138/am.2012.603
Sokolova, Elena, Hawthorne, Frank C., Agakhanov, Atali A., Pautov, Leonid A., Karpenko, Vladimir Yu. (2018) The crystal structure of orlovite, KLi2Ti(Si4O10)(OF): the first example of the short-range order of Ti in true trioctahedral micas. European Journal of Mineralogy, 30 (2) 399-402 doi:10.1127/ejm/1988/0030-2724
Localities for Orlovite
Showing 1 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Tajikistan (TL) | |
| Agakhanov et al. (2011) +4 other references |
Quick NavTopAbout OrloviteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography X-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesRelationshipsCommon AssociatesStrunz-MindatRadioactivityFluorescence Other InformationInternet Links References Localities Locality List
Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan