Tosudite
A valid IMA mineral species - grandfathered
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About Tosudite
Formula:
Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O
Colour:
White, light yellow, light green, deep blue to azure
Lustre:
Waxy, Dull
Hardness:
1 - 2
Specific Gravity:
2.83
Crystal System:
Monoclinic
Member of:
Name:
Named by V.A. Frank-Kamenetskii, N.V. Logvinenko, and V.A. Drits in 1963 in honour of Toshio Sudo (12 July 1911, Niigata Prefecture, Japan - 12 April 2000), professor of mineralogy, University of Tokyo, Japan. He was an expert in clay mineralogy, especially in the alteration processes by which clay minerals are formed.
Aliettite-Corrensite Group
A 1:1 regular interstratification of a chlorite group mineral and a smectite group mineral.
A 1:1 regular interstratification of a chlorite group mineral and a smectite group mineral.
Unique Identifiers
Mindat ID:
4001
Long-form identifier:
mindat:1:1:4001:9
IMA Classification of Tosudite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Na0.5(Al,Mg)6(Si,Al)8O18(OH)12·5H2O
First published:
1963
Classification of Tosudite
9.EC.60
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.4.2.4
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
4 : Sheets of 6-membered rings interlayered 1:1, 2:1, and octahedra
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
4 : Sheets of 6-membered rings interlayered 1:1, 2:1, and octahedra
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Tos | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Tos | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Tosudite
Waxy, Dull
Transparency:
Translucent
Colour:
White, light yellow, light green, deep blue to azure
Hardness:
1 - 2 on Mohs scale
Cleavage:
Perfect
{001}
{001}
Density:
2.83 g/cm3 (Measured)
Optical Data of Tosudite
Type:
Biaxial (-)
RI values:
nα = 1.542 - 1.564 nβ = 1.57 nγ = 1.548 - 1.574
2V:
Measured: 59°
Max. Birefringence:
δ = 0.006 - 0.010
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Low (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
none
Chemistry of Tosudite
Mindat Formula:
Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O
Element Weights:
Common Impurities:
Fe,Mg,Ca,Li
Crystallography of Tosudite
Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
B2
Cell Parameters:
a = 5.17 Å, b = 8.97 Å, c = 24.2 Å
β = 94°
β = 94°
Ratio:
a:b:c = 0.576 : 1 : 2.698
Unit Cell V:
1,119.54 ų (Calculated from Unit Cell)
Morphology:
Microscopically crystalline
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 30.4 Å | (100) |
| 15.2 Å | (75) |
| 4.480 Å | (30) |
| 5.006 Å | (20) |
| 2.562 Å | (12) |
| 1.493 Å | (12) |
| 3.30 Å | (8) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 3b: Earth’s earliest hydrosphere | >4.45 |
| 16 : Low-? aqueous alteration of Hadean subaerial lithologies (see also #23) |
Type Occurrence of Tosudite
General Appearance of Type Material:
Clay mineral.
Place of Conservation of Type Material:
Fersman MIneralogical Museum, Moscow, Russia, number 13545.
Other Language Names for Tosudite
Varieties of Tosudite
| Aluminum Tosudite | A clay mineral with a 1:1 regular interstratification of the dioctahedral Al chlorite donbassite and smectite. |
| Alushtite | A clay mineral with a 1:1 regular interstratification of di-trioctahedral Li-Mg chlorite of the Cookeite-Sudoite series (with cookeite:sudoite ratio close to 1:1) and dioctahedral smectite. Originally described in 1914 from Kuru-Uzen' village (now Solnec... |
| Lithium Tosudite | A clay mineral with a 1:1 regular interstratification of the trioctahedral Li chlorite cookeite and dioctahedral smectite. |
| Magnesium Tosudite | A clay mineral with a 1:1 regular interstratification of trioctahedral Mg chlorite Sudoite and dioctahedral Smectite. |
Relationship of Tosudite to other Species
Member of:
Other Members of Mixed-layer clay minerals:
| Aliettite | Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O | Mon. |
| Corrensite | (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O | Orth. |
| 'Glaucony' | The term glaucony was defined first by Odin and Létolle (1980) for green minerals in marine sediments formed by ... | |
| Rectorite | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O | Mon. |
Common Associates
Associations Based on Photo Data:
| 3 photos of Tosudite associated with 'Manganese Oxides' |
Related Minerals - Strunz-mindat Grouping
| 9.EC. | Meifuite | KFe6(Si7Al)O19(OH)4Cl2 |
| 9.EC. | Balestraite | KLi2V5+Si4O12 |
| 9.EC.05 | Talc | Mg3Si4O10(OH)2 |
| 9.EC.05 | Minnesotaite | Fe2+3Si4O10(OH)2 |
| 9.EC.05 | Willemseite | Ni3Si4O10(OH)2 |
| 9.EC.9.EC. | Voloshinite | Rb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2 |
| 9.EC.10 | Fluorluanshiweiite | KLiAl1.5(Si3.5Al0.5)O10F2 |
| 9.EC.10 | Garmite | CsLiMg2(Si4O10)F2 |
| 9.EC.10 | Gorbunovite | CsLi2(Ti,Fe)Si4O10(F,OH,O)2 |
| 9.EC.10 | Ferripyrophyllite | Fe3+Si2O5(OH) |
| 9.EC.10 | Manganiceladonite | K(MgMn3+◻)(Si4O10)(OH)2 |
| 9.EC.10 | Luanshiweiite | KLiAl1.5(Si3.5Al0.5)O10(OH)2 |
| 9.EC.10 | Pyrophyllite | Al2Si4O10(OH)2 |
| 9.EC.15 | Paragonite | NaAl2(AlSi3O10)(OH)2 |
| 9.EC.15 | Ferroaluminoceladonite | K(Fe2+Al◻)(Si4O10)(OH)2 |
| 9.EC.15 | Nanpingite | CsAl2(AlSi3O10)(OH,F)2 |
| 9.EC.15 | Ferroceladonite | K(Fe2+Fe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Ganterite | Ba0.5(Na,K)0.5Al2(Si2.5Al1.5)O10(OH)2 |
| 9.EC.15 | Kreiterite | CsLi2Fe3+(Si4O10)F2 |
| 9.EC.15 | Roscoelite | KV3+2(AlSi3O10)(OH)2 |
| 9.EC.15 | Aluminoceladonite | K(MgAl◻)(Si4O10)(OH)2 |
| 9.EC.15 | Tobelite | (NH4)Al2(AlSi3O10)(OH)2 |
| 9.EC.15 | Tainiolite | KLiMg2(Si4O10)F2 |
| 9.EC.15 | Celadonite | K(MgFe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Chromceladonite | K(MgCr◻)(Si4O10)(OH)2 |
| 9.EC.15 | Montdorite | KFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2 |
| 9.EC.15 | Chromphyllite | KCr2(AlSi3O10)(OH)2 |
| 9.EC.15 | Boromuscovite | KAl2(BSi3O10)(OH)2 |
| 9.EC.15 | 'UM1988-22-SiO:AlCaFFeHKLiMg' | KLiMgAl2Si3O10F2 |
| 9.EC.15 | Chernykhite | (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2 |
| 9.EC.15 | Muscovite | KAl2(AlSi3O10)(OH)2 |
| 9.EC.20 | Masutomilite | K(LiAlMn2+)[AlSi3O10]F2 |
| 9.EC.20 | Oxyphlogopite | K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 |
| 9.EC.20 | 'Chloroferrokinoshitalite' | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2 |
| 9.EC.20 | Siderophyllite | KFe2+2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Sokolovaite | CsLi2Al(Si4O10)F2 |
| 9.EC.20 | Hendricksite | KZn3(Si3Al)O10(OH)2 |
| 9.EC.20 | Tetraferriphlogopite | KMg3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Fluorannite | KFe2+3(Si3Al)O10F2 |
| 9.EC.20 | Aspidolite | NaMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Suhailite | (NH4)Fe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Ephesite | NaLiAl2(Al2Si2O10)(OH)2 |
| 9.EC.20 | Norrishite | KLiMn3+2(Si4O10)O2 |
| 9.EC.20 | Phlogopite | KMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Yangzhumingite | KMg2.5(Si4O10)F2 |
| 9.EC.20 | Orlovite | KLi2Ti(Si4O10)OF |
| 9.EC.20 | Tetraferriannite | KFe2+3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Shirokshinite | K(NaMg2)(Si4O10)F2 |
| 9.EC.20 | Trilithionite | K(Li1.5Al1.5)(AlSi3O10)(F,OH)2 |
| 9.EC.20 | Polylithionite | KLi2Al(Si4O10)(F,OH)2 |
| 9.EC.20 | Shirozulite | KMn2+3(Si3Al)O10(OH)2 |
| 9.EC.20 | Preiswerkite | NaMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Fluorophlogopite | KMg3(Si3Al)O10F2 |
| 9.EC.20 | Wonesite | (Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4 |
| 9.EC.20 | 'UM2004-49-SiO:AlCsFHKLi' | (Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2 |
| 9.EC.20 | Fluorotetraferriphlogopite | KMg3(Fe3+Si3O10)F2 |
| 9.EC.20 | Annite | KFe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Eastonite | KMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.22 | 'Pimelite' | Ni3Si4O10(OH)2 · 4H2O |
| 9.EC.30 | Margarite | CaAl2(Al2Si2O10)(OH)2 |
| 9.EC.35 | Kinoshitalite | (Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2 |
| 9.EC.35 | Ferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2 |
| 9.EC.35 | Clintonite | CaAlMg2(SiAl3O10)(OH)2 |
| 9.EC.35 | Oxykinoshitalite | (Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2 |
| 9.EC.35 | Fluorokinoshitalite | BaMg3(Al2Si2O10)F2 |
| 9.EC.35 | Bityite | CaLiAl2(AlBeSi2O10)(OH)2 |
| 9.EC.35 | Anandite | (Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2 |
| 9.EC.40 | Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O |
| 9.EC.40 | Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Volkonskoite | Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.40 | Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Kurumsakite | (Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?) |
| 9.EC.40 | Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O |
| 9.EC.45 | Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O |
| 9.EC.45 | Hectorite | Na0.3(Mg,Li)3(Si4O10)(F,OH)2 |
| 9.EC.45 | Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) |
| 9.EC.45 | Hanjiangite | Ba2CaV3+Al(H2AlSi3O12)(CO3)2F |
| 9.EC.45 | Spadaite | MgSiO2(OH)2 · H2O (?) |
| 9.EC.45 | Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.45 | Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 |
| 9.EC.45 | Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.45 | Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.50 | Vermiculite | Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O |
| 9.EC.52 | 'Tarasovite' | near NaKAl11Si13O40(OH)9 · 3H2O |
| 9.EC.55 | Clinochlore | Mg5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Borocookeite | (LiAl4◻)[BSi3O10](OH)8 |
| 9.EC.55 | Franklinfurnaceite | Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8 |
| 9.EC.55 | Pennantite | Mn2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Vakhrushevaite | Mg5Cr(AlSi3O10)(OH)8 |
| 9.EC.55 | Nimite | Ni5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Cookeite | (LiAl4◻)[AlSi3O10](OH)8 |
| 9.EC.55 | Gonyerite | Mn2+5Fe3+(Fe3+Si3O10)(OH)8 |
| 9.EC.55 | Chamosite | Fe2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | 'Orthochamosite' | (Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Baileychlore | Zn5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Sudoite | Mg2Al3(AlSi3O10)(OH)8 |
| 9.EC.55 | Glagolevite | Na(Mg,Al)6(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Donbassite | Al4.33(AlSi3O10)(OH)8 |
| 9.EC.60 | Dozyite | Mg7Al2(Al2Si4O15)(OH)12 |
| 9.EC.60 | Rectorite | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O |
| 9.EC.60 | Corrensite | (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O |
| 9.EC.60 | Aliettite | Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O |
| 9.EC.60 | Karpinskite | (Ni,Mg)2Si2O5(OH)2 (?) |
| 9.EC.60 | Lunijianlaite | Li0.7Al6.2(AlSi7O20)(OH,O)10 |
| 9.EC.60 | Hydrobiotite | K(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O |
| 9.EC.60 | Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 |
| 9.EC.60 | Kulkeite | Mg8Al(AlSi7O20)(OH)10 |
| 9.EC.60 | Brinrobertsite | Na0.3Al4(Si4O10)2(OH)4 · 3.5 H2O |
| 9.EC.65 | Macaulayite | (Fe,Al)24Si4O43(OH)2 |
| 9.EC.70 | Burckhardtite | Pb2(Fe3+Te6+)[AlSi3O8]O6 |
| 9.EC.75 | Niksergievite | (Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O |
| 9.EC.75 | Ferrisurite | (Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2O |
| 9.EC.75 | Surite | (Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2 |
| 9.EC.80 | Kegelite | Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tosudite
mindat.org URL:
https://www.mindat.org/min-4001.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Tosudite
Localities for Tosudite
Showing 69 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Bouhier et al. (2023) |
Belgium | |
| Mélon et al. (1976) |
| [var: Alushtite, var: Lithium Tosudite] Brown G. et al. (1974) | |
Bosnia and Herzegovina | |
| ... |
Chile | |
| Lohmeier et al. (2025) |
France | |
| [var: Lithium Tosudite] Merceron (1988) |
| Econ Geol (1994) |
Germany | |
| [var: Aluminum Tosudite] Starke R. et al. (1984) |
India | |
| A.G. Dessai |
Indonesia | |
| Al Hakim et al. (2017) |
Iran | |
| Ahmadi et al. (2025) |
Italy | |
| Ciriotti et al. (2006) |
Japan | |
| [var: Magnesium Tosudite] Kimbara K. (1974) |
| [var: Magnesium Tosudite] Sudo T. (1957) |
| Professor Seiichiro Uehara |
| [var: Lithium Tosudite] Shimoda (1969) +1 other reference |
| [var: Aluminum Tosudite, var: Lithium Tosudite] Ichikawa A. (1976) |
| 米田哲朗. (1989) |
| [var: Aluminum Tosudite] Gaines et al. (1997) |
| Kawano et al. (1991) |
| [var: Aluminum Tosudite] IMAI et al. (1972) +1 other reference |
| Marumo et al. (2008) |
Mexico | |
| Anisimov et al. (2001) |
Mozambique | |
| [var: Aluminum Tosudite] Gomes Figueiredo C.S. (1967) |
New Zealand | |
| Singh (2015) |
Niger | |
| Billon et al. (2016) |
Russia | |
| Nikolaev et al. (2013) |
| Kalko et al. (2014) | |
| [var: Lithium Tosudite] Fin'ko V.I. et al. (1977) |
| Kol'tsov A.B. e.a. (1988) | |
South Korea | |
| Cho et al. (1994) | |
Spain | |
| Cruz et al. (1997) |
UK | |
| Diederik Visser List #39 |
Ukraine | |
| [var: Alushtite] Dvoichenko P.A. (1914) |
| Alexander I. Tischenko (1996) | |
| [var: Alushtite] Kartashov P.M. (1989) | |
| [var: Alushtite] Pekov (1998) | |
| [var: Alushtite] Kartashov P.M. (1989) |
| [var: Alushtite] Geologiya SSSR (The geology of USSR) |
| Kovalenko A.P. (1976) |
USA | |
| [var: Lithium Tosudite] Foord et al. (1986) +1 other reference |
| [var: Lithium Tosudite] Gaines et al. (1997) |
| [var: Lithium Tosudite] King et al. (1994) +1 other reference |
| [var: Lithium Tosudite] King (n.d.) |
| [var: Lithium Tosudite] Pavel M. Kartashov (n.d.) |
| Castor et al. (2004) |
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Takatama mine, Koriyama City, Fukushima Prefecture, Japan