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Trilithionite

A valid IMA mineral species
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About TrilithioniteHide

Formula:
K(Li1.5Al1.5)(AlSi3O10)(F,OH)2
Colour:
Pink-violet
Crystal System:
Monoclinic
Name:
When the formula above is doubled, so the subscripts are whole numbers, there are three ('tri') lithium atoms.
Mica Group.
Polylithionite-Trilithionite Series.
Also in a series with muscovite.

Several polytypes are known (see below).


Unique IdentifiersHide

Mindat ID:
7341
Long-form identifier:
mindat:1:1:7341:3

Similar NamesHide

IMA Classification of TrilithioniteHide

Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
KLi1.5Al1.5(Si3Al)O10F2
Approval history:
Redefined 1998 s.p.: Rieder et al. (1998).

Classification of TrilithioniteHide

9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
TlnIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
TlnThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download
TlnWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of TrilithioniteHide

Colour:
Pink-violet

Chemistry of TrilithioniteHide

Mindat Formula:
K(Li1.5Al1.5)(AlSi3O10)(F,OH)2
Element Weights:
Element% weight
O40.078 %
Si21.106 %
Al16.897 %
K9.794 %
F9.518 %
Li2.608 %

Calculated from ideal end-member formula.
O
Si
Al
K
F
Li

Crystallography of TrilithioniteHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Comment:
Trilithionite-2M2
K(Li1.5Al1.5)(AlSi3O10)(F,OH)2
Monoclinic 
2/m - Prismatic
B2/b
C2/c
a = 9.056 Å, b = 5.216 Å, c = 20.282 Å
β = 99.64°
a:b:c = 1.736 : 1 : 3.888
V 944.51 ų
(Calculated from Unit Cell)
 
 

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0007104TrilithioniteBrigatti M F, Caprilli E, Malferrari D, Medici L, Poppi L (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2 European Journal of Mineralogy 17 475-4812005Chedeville, France0293
0007103TrilithioniteBrigatti M F, Caprilli E, Malferrari D, Medici L, Poppi L (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2 European Journal of Mineralogy 17 475-4812005Chedeville, France0293
CIF Raw Data - click here to close

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Other Language Names for TrilithioniteHide

Varieties of TrilithioniteHide

Relationship of Trilithionite to other SpeciesHide

Other Members of Lepidolite:
FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
'Polylithionite-Trilithionite Series'
Forms a series with:

Common AssociatesHide

Associations Based on Photo Data:
8 photos of Trilithionite associated with QuartzSiO2
4 photos of Trilithionite associated with ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)
3 photos of Trilithionite associated with FluoriteCaF2
3 photos of Trilithionite associated with 'Aquamarine'
3 photos of Trilithionite associated with MicroclineK(AlSi3O8)
3 photos of Trilithionite associated with AlbiteNa(AlSi3O8)
2 photos of Trilithionite associated with MuscoviteKAl2(AlSi3O10)(OH)2
2 photos of Trilithionite associated with Lepidolite
2 photos of Trilithionite associated with PolylithioniteKLi2Al(Si4O10)(F,OH)2
1 photo of Trilithionite associated with TopazAl2(SiO4)(F,OH)2

Related Minerals - Strunz-mindat GroupingHide

9.EC.MeifuiteKFe6(Si7Al)O19(OH)4Cl2Tric. 1 : P1
9.EC.BalestraiteKLi2V5+Si4O12Mon. 2 : B2
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.9.EC.VoloshiniteRb(LiAl1.50.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.
9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon. 2/m
9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.
9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15GanteriteBa0.5(Na,K)0.5Al2(Si2.5Al1.5)O10(OH)2Mon. 2/m : B2/b
9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
9.EC.15RoscoeliteKV3+2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Tobelite(NH4)Al2(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 : B2
9.EC.15MontdoriteKFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2Mon. 2/m : B2/m
9.EC.15ChromphylliteKCr2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
9.EC.15'UM1988-22-SiO:AlCaFFeHKLiMg'KLiMgAl2Si3O10F2Mon.
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.20MasutomiliteK(LiAlMn2+)[AlSi3O10]F2Mon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.20'Chloroferrokinoshitalite'(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20TetraferriphlogopiteKMg3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.20FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4Mon. 2/m : B2/m
9.EC.20'UM2004-49-SiO:AlCsFHKLi'(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.22'Pimelite'Ni3Si4O10(OH)2 · 4H2OHex.
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon. 2/m : B2/m
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon. 2/m : B2/m
9.EC.35ClintoniteCaAlMg2(SiAl3O10)(OH)2Mon. 2/m : B2/m
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.35BityiteCaLiAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m : B2/m
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
9.EC.45ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.
9.EC.45HanjiangiteBa2CaV3+Al(H2AlSi3O12)(CO3)2FMon. 2 : B2
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.52'Tarasovite'near NaKAl11Si13O40(OH)9 · 3H2O
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55VakhrushevaiteMg5Cr(AlSi3O10)(OH)8Tric. 1
9.EC.55NimiteNi5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
9.EC.55GonyeriteMn2+5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55ChamositeFe2+5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55'Orthochamosite'(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55BaileychloreZn5Al(AlSi3O10)(OH)8Tric. 1
9.EC.55SudoiteMg2Al3(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55DonbassiteAl4.33(AlSi3O10)(OH)8Mon. 2 : B2
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon. 2/m : B2/m
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m(32/m) : P31m
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon. 2 : P21
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

RadioactivityHide

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TrilithioniteHide

References for TrilithioniteHide

Localities for TrilithioniteHide

Showing 51 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Algeria
 
  • Djanet Province
    • Djanet District
Oulebsir et al. (2021)
Argentina
 
  • Salta Province
    • La Poma Department
      • El Quemado mining district
López de Azarevich et al. (2021)
  • San Luis Province
    • Sierra de Comechingones
      • Comechingones Pegmatitic field
Demartis et al. (2011)
Australia
 
  • Western Australia
    • Coolgardie Shire
      • Nepean
Peter Keller Collection
    • East Pilbara Shire
      • Pilgangoora
Aylmore et al. (2018)
    • Upper Gascoyne Shire
      • Yinnietharra
R. Bottrill
Austria
 
  • Salzburg
    • Zell am See District
      • Bramberg am Wildkogel
        • Nasenkopf mountain
          • Leckbachgraben
Nikopoulou et al. (2024)
Brazil
 
Queiroz et al. (2018)
  • Minas Gerais
    • Conselheiro Pena
Wilson (2012)
  • Tocantins
Coelho et al. (2025)
    • São Salvador do Tocantins
Queiroz et al. (2018)
Canada
 
  • British Columbia
    • Revelstoke Mining Division
      • Boulder Mountain Pegmatite Group
Breasley et al. (2024)
      • Revelstoke
RRUFF Database Specimen No. RO60004 +1 other reference
  • Manitoba
    • Lac-du-Bonnet area
      • Bernic Lake
Van Lichterveld et al. (2008) +1 other reference
    • Red Cross Lake
Cerny et al. 2012 +1 other reference
  • Newfoundland and Labrador
    • Newfoundland
Malay et al. (2026)
China
 
  • Henan
    • Sanmenxia
      • Lushi County
        • Guanpo
          • Guanpo pegmatite field
Fan G. et al. (2013)
Qu et al. (2023)
Qu et al. (2023)
  • Jiangxi
    • Yichun
      • Yifeng Co.
Ganfu Shen and Jinsha Xu (2006)
      • Yuanzhou District
Ma et al. (2026)
  • Sichuan
    • Garzê Autonomous Prefecture (Ganzi Autonomous Prefecture)
      • Yajiang County
Lei et al. (2025)
  • Xinjiang
    • Bayin'gholin Autonomous Prefecture
      • Ruoqiang Co. (Qakilik Co.; Chaqiliq Co.)
Qin et al. (2025)
    • Ili Kazakh Autonomous Prefecture
      • Altay Prefecture (Aletai Prefecture)
        • Fuyun Co. (Koktokay Co.)
          • Koktokay pegmatite field (Keketuohai pegmatite field)
            • Altay Mine
Wang et al. (2007)
Czech Republic
 
  • South Bohemian Region
    • Český Krumlov District
      • Nová Ves
Welser +1 other reference
  • Ústí nad Labem Region
    • Teplice District
      • Krupka
        • Knöttel area
Rieder et al. (1970)
  • Vysočina Region
    • Třebíč District
Rieder et al. (1970)
    • Žďár nad Sázavou District
Novák et al. (1999)
      • Rožná
Novák +2 other references
P. Pauliš (2001)
P. Pauliš (2001)
Egypt
 
  • Red Sea Governorate
    • Wadi Sikait
Elsagheer et al. (2025)
Europe
 
  • Ore Mountains
Rieder et al. (1970)
Finland
 
  • Pirkanmaa
    • Orivesi
      • Eräjärvi area
Sandström et al. (2009)
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Limoges
        • Ambazac
Brigatti et al. (2005)
Germany
 
  • Saxony
    • Görlitz District
      • Vierkirchen
        • Döbschütz
          • Arnsdorf-Melaune Quarry
Witzke et al. (2001)
Italy
 
  • Trentino-Alto Adige/Südtirol
    • Trento Province
      • Canal San Bovo
        • Vanoi Valley
          • Pralongo
Venzo et al. (2017)
Japan
 
  • Fukuoka Prefecture
    • Fukuoka City
...
  • Ibaraki Prefecture
    • Hitachiota City
Kataoka & Uehara (2000)
Madagascar
 
  • Anosy
    • Taolagnaro District
Vandall King
Mozambique
 
University of Arizona Mineral Museum ...
Norway
 
  • Telemark
    • Drangedal
      • Tørdal
Rosing-Schow et al. (2017)
Portugal
 
  • Castelo Branco
    • Covilhã
      • Barco e Coutada
Charoy et al. (1995)
Russia
 
  • Sakha
    • Ust-Yansky District
      • Omchikandya Ore Field
Trunilina et al. (2024)
    • Verkhoyansk District
      • Yana River Basin
        • Yana-Adycha Region
Trunilina et al. (2024)
Spain
 
  • Community of Madrid
    • La Cabrera
Tánago et al. (2012)
Sweden
 
  • Norrbotten County
    • Gällivare
      • Leipojärvi
Analysis by the Swedish Museum of ...
Ukraine
 
  • Zhytomyr Oblast
    • Zhytomyr Raion
Lyckberg et al. (2009)
USA
 
  • Colorado
    • Fremont County
      • Cotopaxi Mining District
RRUFF Database Specimen No. RO50486
    • Gunnison County
      • Quartz Creek Pegmatite Mining District
University of Arizona Mineral Museum ...
  • Massachusetts
    • Essex County
Foster et al. (1962) +1 other reference
 
and/or  
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