Volkonskoite
A valid IMA mineral species - grandfathered
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About Volkonskoite
Pyotr Mikhailovich Volkonsky
Formula:
Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O
Colour:
Blue-green, dark green, grass-green
Lustre:
Waxy, Dull
Hardness:
1 - 2
Specific Gravity:
2.11 - 2.36
Crystal System:
Monoclinic
Member of:
Name:
Named in 1831 by August Alexander Kämmerer in honour of Prince Pyotr Mikhailovich Volkonsky (25 April (6 May) 1776, Saint-Petersburg, Russian Empire - 27 August (8 September) 1852, Petergof, Petrodvortsovy District, Saint Petersburg, Russian Empire), Minister of the Russian Court, Russia.
Unique Identifiers
Mindat ID:
4201
Long-form identifier:
mindat:1:1:4201:3
IMA Classification of Volkonskoite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca0.3(Cr3+,Mg)2(Si,Al)4O10(OH)2·4H2O
First published:
1831
Classification of Volkonskoite
9.EC.40
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.3.1a.4
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
3 : Sheets of 6-membered rings with 2:1 clays
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
3 : Sheets of 6-membered rings with 2:1 clays
16.15.6
16 : Silicates Containing Aluminum and other Metals
15 : Aluminosilicates of V and Cr
16 : Silicates Containing Aluminum and other Metals
15 : Aluminosilicates of V and Cr
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Vkn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Vkn | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Volkonskoite
Waxy, Dull
Transparency:
Translucent
Colour:
Blue-green, dark green, grass-green
Hardness:
1 - 2 on Mohs scale
Tenacity:
Brittle
Fracture:
Conchoidal
Density:
2.11 - 2.36 g/cm3 (Measured)
Optical Data of Volkonskoite
Type:
Biaxial (-)
RI values:
nα = 1.551 - 1.560 nβ = 1.569 nγ = 1.564
2V:
Calculated: 62° to 84°
Max. Birefringence:
δ = 0.004 - 0.013
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
Surface Relief:
Moderate
Dispersion:
r > v strong
Chemistry of Volkonskoite
Mindat Formula:
Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O
Element Weights:
Common Impurities:
Ti,Mn,Na,K,C,P
Crystallography of Volkonskoite
Crystal System:
Monoclinic
Morphology:
Fine scaly to fibrous, massive.
Comment:
Point Group: n.d.; Space Group: n.d. Z = n.d
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| - Å | () |
Comments:
No published powder X-ray diffraction data.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 3b: Earth’s earliest hydrosphere | >4.45 |
| 13 : Hadean serpentinization | |
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47e : [Vanadates, chromates, manganates] | |
| Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere | <0.6 |
| 53 : Other minerals with taphonomic origins | <0.4 |
Geological Setting:
Weathering product of serpentine, epigenetic mineral in clastic sedimentary rocks.
Type Occurrence of Volkonskoite
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, R4820, 16308.
Synonyms of Volkonskoite
Other Language Names for Volkonskoite
Relationship of Volkonskoite to other Species
Member of:
Other Members of Smectite Group:
| Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O | Mon. 2/m : B2/m |
| Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O | Mon. |
| Hectorite | Na0.3(Mg,Li)3(Si4O10)(F,OH)2 | Mon. 2/m : B2/m |
| Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O | Mon. 2/m : B2/m |
| Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O | Mon. 2/m : B2/m |
| 'Pimelite' | Ni3Si4O10(OH)2 · 4H2O | Hex. |
| Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 | Mon. 2/m : B2/m |
| Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O | Mon. |
| Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O | Mon. |
| Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 | Mon. |
| Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O | Mon. 2/m : B2/m |
| Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O | Mon. |
| Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) | Mon. |
Common Associates
Associations Based on Photo Data:
| 8 photos of Volkonskoite associated with Descloizite | PbZn(VO4)(OH) |
| 5 photos of Volkonskoite associated with Melanophlogite | 46SiO2 · 6(N2,CO2) · 2(CH4,N2) |
| 4 photos of Volkonskoite associated with Vanadinite | Pb5(VO4)3Cl |
| 4 photos of Volkonskoite associated with Quartz | SiO2 |
| 3 photos of Volkonskoite associated with Baryte | BaSO4 |
| 3 photos of Volkonskoite associated with Ferrihollandite | Ba(Mn4+6Fe3+2)O16 |
| 2 photos of Volkonskoite associated with Cinnabar | HgS |
| 2 photos of Volkonskoite associated with Cerianite-(Ce) | Ce4+O2 |
| 1 photo of Volkonskoite associated with Bentorite | Ca6Cr2(SO4)3(OH)12 · 26H2O |
Related Minerals - Strunz-mindat Grouping
| 9.EC. | Meifuite | KFe6(Si7Al)O19(OH)4Cl2 |
| 9.EC. | Balestraite | KLi2V5+Si4O12 |
| 9.EC.05 | Talc | Mg3Si4O10(OH)2 |
| 9.EC.05 | Minnesotaite | Fe2+3Si4O10(OH)2 |
| 9.EC.05 | Willemseite | Ni3Si4O10(OH)2 |
| 9.EC.9.EC. | Voloshinite | Rb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2 |
| 9.EC.10 | Fluorluanshiweiite | KLiAl1.5(Si3.5Al0.5)O10F2 |
| 9.EC.10 | Garmite | CsLiMg2(Si4O10)F2 |
| 9.EC.10 | Gorbunovite | CsLi2(Ti,Fe)Si4O10(F,OH,O)2 |
| 9.EC.10 | Ferripyrophyllite | Fe3+Si2O5(OH) |
| 9.EC.10 | Manganiceladonite | K(MgMn3+◻)(Si4O10)(OH)2 |
| 9.EC.10 | Luanshiweiite | KLiAl1.5(Si3.5Al0.5)O10(OH)2 |
| 9.EC.10 | Pyrophyllite | Al2Si4O10(OH)2 |
| 9.EC.15 | Paragonite | NaAl2(AlSi3O10)(OH)2 |
| 9.EC.15 | Ferroaluminoceladonite | K(Fe2+Al◻)(Si4O10)(OH)2 |
| 9.EC.15 | Nanpingite | CsAl2(AlSi3O10)(OH,F)2 |
| 9.EC.15 | Ferroceladonite | K(Fe2+Fe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Ganterite | Ba0.5(Na,K)0.5Al2(Si2.5Al1.5)O10(OH)2 |
| 9.EC.15 | Kreiterite | CsLi2Fe3+(Si4O10)F2 |
| 9.EC.15 | Roscoelite | KV3+2(AlSi3O10)(OH)2 |
| 9.EC.15 | Aluminoceladonite | K(MgAl◻)(Si4O10)(OH)2 |
| 9.EC.15 | Tobelite | (NH4)Al2(AlSi3O10)(OH)2 |
| 9.EC.15 | Tainiolite | KLiMg2(Si4O10)F2 |
| 9.EC.15 | Celadonite | K(MgFe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Chromceladonite | K(MgCr◻)(Si4O10)(OH)2 |
| 9.EC.15 | Montdorite | KFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2 |
| 9.EC.15 | Chromphyllite | KCr2(AlSi3O10)(OH)2 |
| 9.EC.15 | Boromuscovite | KAl2(BSi3O10)(OH)2 |
| 9.EC.15 | 'UM1988-22-SiO:AlCaFFeHKLiMg' | KLiMgAl2Si3O10F2 |
| 9.EC.15 | Chernykhite | (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2 |
| 9.EC.15 | Muscovite | KAl2(AlSi3O10)(OH)2 |
| 9.EC.20 | Masutomilite | K(LiAlMn2+)[AlSi3O10]F2 |
| 9.EC.20 | Oxyphlogopite | K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 |
| 9.EC.20 | 'Chloroferrokinoshitalite' | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2 |
| 9.EC.20 | Siderophyllite | KFe2+2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Sokolovaite | CsLi2Al(Si4O10)F2 |
| 9.EC.20 | Hendricksite | KZn3(Si3Al)O10(OH)2 |
| 9.EC.20 | Tetraferriphlogopite | KMg3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Fluorannite | KFe2+3(Si3Al)O10F2 |
| 9.EC.20 | Aspidolite | NaMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Suhailite | (NH4)Fe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Ephesite | NaLiAl2(Al2Si2O10)(OH)2 |
| 9.EC.20 | Norrishite | KLiMn3+2(Si4O10)O2 |
| 9.EC.20 | Phlogopite | KMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Yangzhumingite | KMg2.5(Si4O10)F2 |
| 9.EC.20 | Orlovite | KLi2Ti(Si4O10)OF |
| 9.EC.20 | Tetraferriannite | KFe2+3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Shirokshinite | K(NaMg2)(Si4O10)F2 |
| 9.EC.20 | Trilithionite | K(Li1.5Al1.5)(AlSi3O10)(F,OH)2 |
| 9.EC.20 | Polylithionite | KLi2Al(Si4O10)(F,OH)2 |
| 9.EC.20 | Shirozulite | KMn2+3(Si3Al)O10(OH)2 |
| 9.EC.20 | Preiswerkite | NaMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Fluorophlogopite | KMg3(Si3Al)O10F2 |
| 9.EC.20 | Wonesite | (Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4 |
| 9.EC.20 | 'UM2004-49-SiO:AlCsFHKLi' | (Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2 |
| 9.EC.20 | Fluorotetraferriphlogopite | KMg3(Fe3+Si3O10)F2 |
| 9.EC.20 | Annite | KFe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Eastonite | KMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.22 | 'Pimelite' | Ni3Si4O10(OH)2 · 4H2O |
| 9.EC.30 | Margarite | CaAl2(Al2Si2O10)(OH)2 |
| 9.EC.35 | Kinoshitalite | (Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2 |
| 9.EC.35 | Ferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2 |
| 9.EC.35 | Clintonite | CaAlMg2(SiAl3O10)(OH)2 |
| 9.EC.35 | Oxykinoshitalite | (Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2 |
| 9.EC.35 | Fluorokinoshitalite | BaMg3(Al2Si2O10)F2 |
| 9.EC.35 | Bityite | CaLiAl2(AlBeSi2O10)(OH)2 |
| 9.EC.35 | Anandite | (Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2 |
| 9.EC.40 | Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O |
| 9.EC.40 | Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Kurumsakite | (Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?) |
| 9.EC.40 | Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O |
| 9.EC.45 | Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O |
| 9.EC.45 | Hectorite | Na0.3(Mg,Li)3(Si4O10)(F,OH)2 |
| 9.EC.45 | Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) |
| 9.EC.45 | Hanjiangite | Ba2CaV3+Al(H2AlSi3O12)(CO3)2F |
| 9.EC.45 | Spadaite | MgSiO2(OH)2 · H2O (?) |
| 9.EC.45 | Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.45 | Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 |
| 9.EC.45 | Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.45 | Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.50 | Vermiculite | Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O |
| 9.EC.52 | 'Tarasovite' | near NaKAl11Si13O40(OH)9 · 3H2O |
| 9.EC.55 | Clinochlore | Mg5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Borocookeite | (LiAl4◻)[BSi3O10](OH)8 |
| 9.EC.55 | Franklinfurnaceite | Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8 |
| 9.EC.55 | Pennantite | Mn2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Vakhrushevaite | Mg5Cr(AlSi3O10)(OH)8 |
| 9.EC.55 | Nimite | Ni5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Cookeite | (LiAl4◻)[AlSi3O10](OH)8 |
| 9.EC.55 | Gonyerite | Mn2+5Fe3+(Fe3+Si3O10)(OH)8 |
| 9.EC.55 | Chamosite | Fe2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | 'Orthochamosite' | (Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Baileychlore | Zn5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Sudoite | Mg2Al3(AlSi3O10)(OH)8 |
| 9.EC.55 | Glagolevite | Na(Mg,Al)6(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Donbassite | Al4.33(AlSi3O10)(OH)8 |
| 9.EC.60 | Dozyite | Mg7Al2(Al2Si4O15)(OH)12 |
| 9.EC.60 | Rectorite | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O |
| 9.EC.60 | Corrensite | (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O |
| 9.EC.60 | Aliettite | Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O |
| 9.EC.60 | Karpinskite | (Ni,Mg)2Si2O5(OH)2 (?) |
| 9.EC.60 | Lunijianlaite | Li0.7Al6.2(AlSi7O20)(OH,O)10 |
| 9.EC.60 | Tosudite | Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O |
| 9.EC.60 | Hydrobiotite | K(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O |
| 9.EC.60 | Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 |
| 9.EC.60 | Kulkeite | Mg8Al(AlSi7O20)(OH)10 |
| 9.EC.60 | Brinrobertsite | Na0.3Al4(Si4O10)2(OH)4 · 3.5 H2O |
| 9.EC.65 | Macaulayite | (Fe,Al)24Si4O43(OH)2 |
| 9.EC.70 | Burckhardtite | Pb2(Fe3+Te6+)[AlSi3O8]O6 |
| 9.EC.75 | Niksergievite | (Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O |
| 9.EC.75 | Ferrisurite | (Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2O |
| 9.EC.75 | Surite | (Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2 |
| 9.EC.80 | Kegelite | Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Volkonskoite
mindat.org URL:
https://www.mindat.org/min-4201.html
Please feel free to link to this page.
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References for Volkonskoite
Reference List:
Foord, Eugene E. (1987) Reassessment of the Volkonskoite-Chromian Smectite Nomenclature Problem. Clays and Clay Minerals, 35 (2) 139-149 doi:10.1346/ccmn.1987.0350206
Localities for Volkonskoite
Showing 33 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Bolivia | |
| PXRD by John Attard |
Brazil | |
| F. Zaccarini (2006) |
China | |
| Jianhong Zhang et al. (1989) |
Germany | |
| www.senckenberg.de (n.d.) |
| Witzke (2018) |
Greece | |
| Rieck et al. (2022) |
Israel | |
| collected May 2025 by Michael J. Feldman |
| collected Oct. 2024 by Michael J. ... +1 other reference | |
Italy | |
| Bonifazi (2020) |
| Sartori F. (1967) |
| Antonio Borrelli collection +1 other reference | |
| Orlandi (2005) |
Jordan | |
| Dill et al. (2009) |
| Fourcade et al. (2007) | |
| Pitty et al. (2010) |
| Sokol +9 other references |
| Khoury et al. (1985) |
Middle East | |
| Gross (1977) | |
Norway | |
| Nilssen et al. (1973) +1 other reference |
| Nilssen et al. (1973) |
Palestine | |
| Sokol et al. (2011) |
| Färber (n.d.) |
Russia | |
| Gorshkov A.I. et al. (1991) |
| Kosantin's data |
| MINERALOGICAL MAGAZINE +1 other reference |
USA | |
| Graeme (1993) |
| Graeme (1993) +1 other reference | |
| Walstrom (n.d.) |
| Eckel et al. (1941) +2 other references | |
| Bullock (1981) |
| Bullock (1981) |
| Ransom (1974) |
| Ransom (1974) |
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Efimyatskaya Mt, Efimyata Village, Chastinsky District, Perm Krai, Russia