Hectorite
A valid IMA mineral species - grandfathered - questionable
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About Hectorite
Formula:
Na0.3(Mg,Li)3(Si4O10)(F,OH)2
Colour:
White, cream, pale brown, mottled
Lustre:
Waxy, Dull, Earthy
Hardness:
1 - 2
Specific Gravity:
2.3
Crystal System:
Monoclinic
Member of:
Unique Identifiers
Mindat ID:
1841
Long-form identifier:
mindat:1:1:1841:4
Similar Names
| Hectorite (of Cox) | (Mg,Fe)2Si3O8 · 0.5H2O | |
| Rectorite | A valid IMA mineral species - grandfathered | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O |
IMA Classification of Hectorite
Approved, 'Grandfathered' (first described prior to 1959), Questionable
IMA Formula:
Na0.3(Mg,Li)3Si4O10(F,OH)2·nH2O
Classification of Hectorite
9.EC.45
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.3.1b.4
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
3 : Sheets of 6-membered rings with 2:1 clays
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
3 : Sheets of 6-membered rings with 2:1 clays
17.1.1
17 : Silicates Containing other Anions
1 : Silicates with fluoride (not containing Al)
17 : Silicates Containing other Anions
1 : Silicates with fluoride (not containing Al)
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Htr | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Htr | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Hectorite
Waxy, Dull, Earthy
Transparency:
Translucent
Colour:
White, cream, pale brown, mottled
Hardness:
1 - 2 on Mohs scale
Cleavage:
Perfect
{001}
{001}
Fracture:
Irregular/Uneven
Density:
2.3 g/cm3 (Measured)
Optical Data of Hectorite
Type:
Biaxial (-)
RI values:
nα = 1.49 nβ = 1.50 nγ = 1.52
Max. Birefringence:
δ = 0.030
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Dispersion:
none
Comments:
2V(meas.) = Small
Chemistry of Hectorite
Mindat Formula:
Na0.3(Mg,Li)3(Si4O10)(F,OH)2
Element Weights:
Common Impurities:
Ti,Al,Fe,Ca,K,Cl
Crystallography of Hectorite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 5.25 Å, b = 9.18 Å, c = 16.0 Å
β = 99°
β = 99°
Ratio:
a:b:c = 0.572 : 1 : 1.743
Unit Cell V:
761.63 ų (Calculated from Unit Cell)
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0015819 | Hectorite | Breu J, Seidl W, Stoll A (2003) Fehlordnung bei smectiten in abhangigkeit vom zwischenschichtkation Zeitschrift fur Anorganische und Allgemeine Chemie 629 503-515 | 2003 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Loading XRD data...
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.58 Å | (100) |
| 1.53 Å | (100) |
| 15.8 Å | (80) |
| 2.66 Å | (80) |
| 1.32 Å | (80) |
| 1.30 Å | (80) |
| 2.48 Å | (60) |
Comments:
spacings variable by humidity, intensities variable by orientation
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 3b: Earth’s earliest hydrosphere | >4.45 |
| 14 : Hot springs, geysers, and other subaerial geothermal minerals | |
| 16 : Low-? aqueous alteration of Hadean subaerial lithologies (see also #23) |
Type Occurrence of Hectorite
Geological Setting of Type Material:
bentonite deposit,
Associated Minerals at Type Locality:
Synonyms of Hectorite
Other Language Names for Hectorite
Dutch:Hectoriet
German:Hectorit
Ghassoulit
Ghassoulit
Italian:Hectorite
Japanese:ヘクトライト
Spanish:Ghassoulita
Hectorita
Hectorita
Relationship of Hectorite to other Species
Member of:
Other Members of Smectite Group:
| Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O | Mon. 2/m : B2/m |
| Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O | Mon. |
| Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O | Mon. 2/m : B2/m |
| Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O | Mon. 2/m : B2/m |
| 'Pimelite' | Ni3Si4O10(OH)2 · 4H2O | Hex. |
| Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 | Mon. 2/m : B2/m |
| Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O | Mon. |
| Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O | Mon. |
| Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 | Mon. |
| Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O | Mon. 2/m : B2/m |
| Volkonskoite | Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O | Mon. |
| Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O | Mon. |
| Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) | Mon. |
Common Associates
Associations Based on Photo Data:
| 16 photos of Hectorite associated with Pyrrhotite | Fe1-xS |
| 15 photos of Hectorite associated with Gmelinite-Na | Na4(Si8Al4)O24 · 11H2O |
| 9 photos of Hectorite associated with Analcime | Na(AlSi2O6) · H2O |
| 8 photos of Hectorite associated with Clinoptilolite-Na | Na6(Si30Al6)O72 · 20H2O |
| 6 photos of Hectorite associated with Rhodochrosite | MnCO3 |
| 6 photos of Hectorite associated with Searlesite | Na(H2BSi2O7) |
| 6 photos of Hectorite associated with Chabazite-Na | (Na2,K2,Ca,Sr,Mg)2[Al2Si4O12]2 · 12H2O |
| 5 photos of Hectorite associated with Greigite | Fe2+Fe3+2S4 |
| 1 photo of Hectorite associated with 'Basalt' |
Related Minerals - Strunz-mindat Grouping
| 9.EC. | Meifuite | KFe6(Si7Al)O19(OH)4Cl2 |
| 9.EC. | Balestraite | KLi2V5+Si4O12 |
| 9.EC.05 | Talc | Mg3Si4O10(OH)2 |
| 9.EC.05 | Minnesotaite | Fe2+3Si4O10(OH)2 |
| 9.EC.05 | Willemseite | Ni3Si4O10(OH)2 |
| 9.EC.9.EC. | Voloshinite | Rb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2 |
| 9.EC.10 | Fluorluanshiweiite | KLiAl1.5(Si3.5Al0.5)O10F2 |
| 9.EC.10 | Garmite | CsLiMg2(Si4O10)F2 |
| 9.EC.10 | Gorbunovite | CsLi2(Ti,Fe)Si4O10(F,OH,O)2 |
| 9.EC.10 | Ferripyrophyllite | Fe3+Si2O5(OH) |
| 9.EC.10 | Manganiceladonite | K(MgMn3+◻)(Si4O10)(OH)2 |
| 9.EC.10 | Luanshiweiite | KLiAl1.5(Si3.5Al0.5)O10(OH)2 |
| 9.EC.10 | Pyrophyllite | Al2Si4O10(OH)2 |
| 9.EC.15 | Paragonite | NaAl2(AlSi3O10)(OH)2 |
| 9.EC.15 | Ferroaluminoceladonite | K(Fe2+Al◻)(Si4O10)(OH)2 |
| 9.EC.15 | Nanpingite | CsAl2(AlSi3O10)(OH,F)2 |
| 9.EC.15 | Ferroceladonite | K(Fe2+Fe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Ganterite | Ba0.5(Na,K)0.5Al2(Si2.5Al1.5)O10(OH)2 |
| 9.EC.15 | Kreiterite | CsLi2Fe3+(Si4O10)F2 |
| 9.EC.15 | Roscoelite | KV3+2(AlSi3O10)(OH)2 |
| 9.EC.15 | Aluminoceladonite | K(MgAl◻)(Si4O10)(OH)2 |
| 9.EC.15 | Tobelite | (NH4)Al2(AlSi3O10)(OH)2 |
| 9.EC.15 | Tainiolite | KLiMg2(Si4O10)F2 |
| 9.EC.15 | Celadonite | K(MgFe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Chromceladonite | K(MgCr◻)(Si4O10)(OH)2 |
| 9.EC.15 | Montdorite | KFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2 |
| 9.EC.15 | Chromphyllite | KCr2(AlSi3O10)(OH)2 |
| 9.EC.15 | Boromuscovite | KAl2(BSi3O10)(OH)2 |
| 9.EC.15 | 'UM1988-22-SiO:AlCaFFeHKLiMg' | KLiMgAl2Si3O10F2 |
| 9.EC.15 | Chernykhite | (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2 |
| 9.EC.15 | Muscovite | KAl2(AlSi3O10)(OH)2 |
| 9.EC.20 | Masutomilite | K(LiAlMn2+)[AlSi3O10]F2 |
| 9.EC.20 | Oxyphlogopite | K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 |
| 9.EC.20 | 'Chloroferrokinoshitalite' | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2 |
| 9.EC.20 | Siderophyllite | KFe2+2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Sokolovaite | CsLi2Al(Si4O10)F2 |
| 9.EC.20 | Hendricksite | KZn3(Si3Al)O10(OH)2 |
| 9.EC.20 | Tetraferriphlogopite | KMg3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Fluorannite | KFe2+3(Si3Al)O10F2 |
| 9.EC.20 | Aspidolite | NaMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Suhailite | (NH4)Fe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Ephesite | NaLiAl2(Al2Si2O10)(OH)2 |
| 9.EC.20 | Norrishite | KLiMn3+2(Si4O10)O2 |
| 9.EC.20 | Phlogopite | KMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Yangzhumingite | KMg2.5(Si4O10)F2 |
| 9.EC.20 | Orlovite | KLi2Ti(Si4O10)OF |
| 9.EC.20 | Tetraferriannite | KFe2+3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Shirokshinite | K(NaMg2)(Si4O10)F2 |
| 9.EC.20 | Trilithionite | K(Li1.5Al1.5)(AlSi3O10)(F,OH)2 |
| 9.EC.20 | Polylithionite | KLi2Al(Si4O10)(F,OH)2 |
| 9.EC.20 | Shirozulite | KMn2+3(Si3Al)O10(OH)2 |
| 9.EC.20 | Preiswerkite | NaMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Fluorophlogopite | KMg3(Si3Al)O10F2 |
| 9.EC.20 | Wonesite | (Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4 |
| 9.EC.20 | 'UM2004-49-SiO:AlCsFHKLi' | (Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2 |
| 9.EC.20 | Fluorotetraferriphlogopite | KMg3(Fe3+Si3O10)F2 |
| 9.EC.20 | Annite | KFe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Eastonite | KMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.22 | 'Pimelite' | Ni3Si4O10(OH)2 · 4H2O |
| 9.EC.30 | Margarite | CaAl2(Al2Si2O10)(OH)2 |
| 9.EC.35 | Kinoshitalite | (Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2 |
| 9.EC.35 | Ferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2 |
| 9.EC.35 | Clintonite | CaAlMg2(SiAl3O10)(OH)2 |
| 9.EC.35 | Oxykinoshitalite | (Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2 |
| 9.EC.35 | Fluorokinoshitalite | BaMg3(Al2Si2O10)F2 |
| 9.EC.35 | Bityite | CaLiAl2(AlBeSi2O10)(OH)2 |
| 9.EC.35 | Anandite | (Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2 |
| 9.EC.40 | Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O |
| 9.EC.40 | Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Volkonskoite | Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.40 | Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Kurumsakite | (Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?) |
| 9.EC.40 | Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O |
| 9.EC.45 | Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O |
| 9.EC.45 | Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) |
| 9.EC.45 | Hanjiangite | Ba2CaV3+Al(H2AlSi3O12)(CO3)2F |
| 9.EC.45 | Spadaite | MgSiO2(OH)2 · H2O (?) |
| 9.EC.45 | Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.45 | Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 |
| 9.EC.45 | Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.45 | Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.50 | Vermiculite | Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O |
| 9.EC.52 | 'Tarasovite' | near NaKAl11Si13O40(OH)9 · 3H2O |
| 9.EC.55 | Clinochlore | Mg5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Borocookeite | (LiAl4◻)[BSi3O10](OH)8 |
| 9.EC.55 | Franklinfurnaceite | Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8 |
| 9.EC.55 | Pennantite | Mn2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Vakhrushevaite | Mg5Cr(AlSi3O10)(OH)8 |
| 9.EC.55 | Nimite | Ni5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Cookeite | (LiAl4◻)[AlSi3O10](OH)8 |
| 9.EC.55 | Gonyerite | Mn2+5Fe3+(Fe3+Si3O10)(OH)8 |
| 9.EC.55 | Chamosite | Fe2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | 'Orthochamosite' | (Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Baileychlore | Zn5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Sudoite | Mg2Al3(AlSi3O10)(OH)8 |
| 9.EC.55 | Glagolevite | Na(Mg,Al)6(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Donbassite | Al4.33(AlSi3O10)(OH)8 |
| 9.EC.60 | Dozyite | Mg7Al2(Al2Si4O15)(OH)12 |
| 9.EC.60 | Rectorite | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O |
| 9.EC.60 | Corrensite | (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O |
| 9.EC.60 | Aliettite | Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O |
| 9.EC.60 | Karpinskite | (Ni,Mg)2Si2O5(OH)2 (?) |
| 9.EC.60 | Lunijianlaite | Li0.7Al6.2(AlSi7O20)(OH,O)10 |
| 9.EC.60 | Tosudite | Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O |
| 9.EC.60 | Hydrobiotite | K(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O |
| 9.EC.60 | Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 |
| 9.EC.60 | Kulkeite | Mg8Al(AlSi7O20)(OH)10 |
| 9.EC.60 | Brinrobertsite | Na0.3Al4(Si4O10)2(OH)4 · 3.5 H2O |
| 9.EC.65 | Macaulayite | (Fe,Al)24Si4O43(OH)2 |
| 9.EC.70 | Burckhardtite | Pb2(Fe3+Te6+)[AlSi3O8]O6 |
| 9.EC.75 | Niksergievite | (Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O |
| 9.EC.75 | Ferrisurite | (Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2O |
| 9.EC.75 | Surite | (Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2 |
| 9.EC.80 | Kegelite | Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 |
Other Information
Notes:
Swells on addition of H2O
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Hectorite in petrology
An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.
Internet Links for Hectorite
mindat.org URL:
https://www.mindat.org/min-1841.html
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References for Hectorite
Localities for Hectorite
Showing 35 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Brazil | |
| Robinson et al. (1998) |
China | |
| 何晗晗; 艾尔肯; 吐尔孙; 王登红; 王瑞江; 陈振宇 (2020) |
France | |
| Chauris (2014) |
Mexico | |
| Gazquez et al. (1) |
Namibia | |
| Fuchsloch et al. (2018) |
| Ashworth (2014) |
| Bezing et al. (2007) +1 other reference | |
Romania | |
| Ianovici et al. (1983) |
Serbia | |
| Putzolu et al. (2025) |
South America Plate | |
| Schrank et al. (2024) |
USA | |
| azminerals.com |
| Eyde (1986) +1 other reference |
| - (2005) |
| U.S. Borax |
| Wise et al. (1988) | |
| - (2005) |
| Foshag et al. (1936) +3 other references | |
| Wright et al. (1953) +2 other references | |
| Wright et al. (1953) +2 other references | |
| Ames et al. (1958) +3 other references | |
| Castor et al. (2004) |
| - (2005) |
| - (2005) |
| - (2005) | |
| Albemarle Corporation | |
| Castor et al. (2004) |
| - (2005) |
| Castor et al. (2004) | |
| - (2005) | |
| - (2005) | |
| Castor et al. (2004) | |
| - (2005) |
| Asadzadeh et al. (2025) |
| Bullock (1981) |
| Bullock (1981) |
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Lyles Hectorite Mine, Hillside, Thompson Valley, Yavapai County, Arizona, USA