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Megawite

A valid IMA mineral species
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About MegawiteHide

05920060017272471885169.jpg
Helen D. Megaw
Formula:
CaSnO3
Colour:
Pale yellowish brown, pale yellow to colourless
Lustre:
Vitreous
Specific Gravity:
5.06 (Calculated)
Crystal System:
Orthorhombic
Name:
It is named in honour of the British crystallographer Helen Dick Megaw (1 June 1907, Dublin, Ireland - 26 February 2002, Ballycastle, Northern Ireland) who made significant contributions to our understanding of the structure and properties of natural and synthetic perovskites. In 1989, Megaw became the first woman to receive the Roebling Medal of the Mineralogical Society of America.
Isostructural with:
Perovskite Group. The Sn analogue of perovskite and lakargiite.
Chemically related to burtite.


Unique IdentifiersHide

Mindat ID:
39893
Long-form identifier:
mindat:1:1:39893:8

IMA Classification of MegawiteHide

Approved
IMA Formula:
CaSn4+O3
Approval year:
2010
First published:
2011

Classification of MegawiteHide

4.CC.30

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MgwIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MegawiteHide

Vitreous
Transparency:
Transparent
Colour:
Pale yellowish brown, pale yellow to colourless
Streak:
White
Cleavage:
Distinct/Good
on {110} and {001}
Density:
5.06 g/cm3 (Calculated)

Optical Data of MegawiteHide

Type:
Biaxial
RI values:
n = 1.89
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Optical Extinction:
X = b; Y = a; Z = c.

Chemistry of MegawiteHide

Mindat Formula:
CaSnO3
Element Weights:
Element% weight
Sn57.407 %
O23.212 %
Ca19.381 %

Calculated from ideal end-member formula.
Sn
O
Ca

Crystallography of MegawiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pban
Cell Parameters:
a = 5.56(3) Å, b = 5.71(3) Å, c = 7.943(3) Å
Ratio:
a:b:c = 0.974 : 1 : 1.391
Unit Cell V:
252.17 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018605MegawiteZhao J, Ross N L, Angel R J (2004) Tilting and distortion of CaSnO3 perovskite to 7 GPa determined from single-crystal X-ray diffraction Physics and Chemistry of Minerals 31 299-3052004synthetic0293
0018625MegawiteVegas A, Vallet-Regi M, Gonzalez-Calbet J M, Alario-Franco M A (1986) The ASnO3 (A = Ca, Sr) perovskites Acta Crystallographica B42 167-1721986synthetic0293
0018606MegawiteZhao J, Ross N L, Angel R J (2004) Tilting and distortion of CaSnO3 perovskite to 7 GPa determined from single-crystal X-ray diffraction Physics and Chemistry of Minerals 31 299-3052004synthetic0.738293
0018607MegawiteZhao J, Ross N L, Angel R J (2004) Tilting and distortion of CaSnO3 perovskite to 7 GPa determined from single-crystal X-ray diffraction Physics and Chemistry of Minerals 31 299-3052004synthetic1.5293
0018608MegawiteZhao J, Ross N L, Angel R J (2004) Tilting and distortion of CaSnO3 perovskite to 7 GPa determined from single-crystal X-ray diffraction Physics and Chemistry of Minerals 31 299-3052004synthetic2.61293
0018609MegawiteZhao J, Ross N L, Angel R J (2004) Tilting and distortion of CaSnO3 perovskite to 7 GPa determined from single-crystal X-ray diffraction Physics and Chemistry of Minerals 31 299-3052004synthetic3.94293
0018610MegawiteZhao J, Ross N L, Angel R J (2004) Tilting and distortion of CaSnO3 perovskite to 7 GPa determined from single-crystal X-ray diffraction Physics and Chemistry of Minerals 31 299-3052004synthetic5.18293
0018611MegawiteZhao J, Ross N L, Angel R J (2004) Tilting and distortion of CaSnO3 perovskite to 7 GPa determined from single-crystal X-ray diffraction Physics and Chemistry of Minerals 31 299-3052004synthetic5.98293
0018612MegawiteZhao J, Ross N L, Angel R J (2004) Tilting and distortion of CaSnO3 perovskite to 7 GPa determined from single-crystal X-ray diffraction Physics and Chemistry of Minerals 31 299-3052004synthetic6.73293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.984 Å(52)
3.970 Å(19)
2.855 Å(43)
2.812 Å(100)
2.780 Å(19)
1.992 Å(13)
1.985 Å(13)
1.640 Å(13)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
9 : Lava/xenolith minerals (hornfels, sanidinite facies)

Type Occurrence of MegawiteHide

General Appearance of Type Material:
Either pseudo-cubic or pseudo-cuboctahedral crystals <15 µm in size, usually as inclusions in spurrite (Xenolith No. 1). Also as rims on µm-sized lakargiite crystals in larnite-cuspidine zones in skarns which contain abundant hydrogarnet and hydrosilicates.
Place of Conservation of Type Material:
Mineralogical Museum of Wrocław University, Poland under accession number MMUWrII16 717 and the Fersman Mineralogical Museum, Moscow, Russia under accession number 4021/1.
Geological Setting of Type Material:
It was found in the spurrite zone of skarned xenolith no. 1
(20-25 m in size) in ignimbrite.
Associated Minerals at Type Locality:

Synonyms of MegawiteHide

Other Language Names for MegawiteHide

Dutch:Megawiet
German:Megawit

Relationship of Megawite to other SpeciesHide

Other Members of Perovskite Subgroup:
BarioperovskiteBaTiO3Orth. mm2 : Amm2
GoldschmidtiteKNbO3Iso. m3m(4/m32/m) : Pm3m
Isolueshite(Na,La)NbO3Iso. m3m(4/m32/m) : Pm3m
LakargiiteCa(Zr,Sn,Ti)O3Orth. mmm(2/m2/m2/m) : Pnma
Loparite(Na,REE)2Ti2O6Iso. m3m(4/m32/m)
LueshiteNaNbO3Orth. mmm(2/m2/m2/m)
MacedonitePbTiO3Tet. 4/mmm(4/m2/m2/m) : P4/nmm
PerovskiteCaTiO3Orth. mmm(2/m2/m2/m) : Pnma
TausoniteSrTiO3Iso. 43m

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Megawite associated with LarniteCa2SiO4
1 photo of Megawite associated with CuspidineCa8(Si2O7)2F4
1 photo of Megawite associated with EttringiteCa6Al2(SO4)3(OH)12 · 26H2O
1 photo of Megawite associated with PerovskiteCaTiO3

Related Minerals - Strunz-mindat GroupingHide

4.CC.BernwooditeCa5TiAl2Si2O14Mon. 2/m : B2/b
4.CC.XuiteCa3Fe3+2[(AlO3(OH)]3Iso. m3m(4/m32/m)
4.CC.Yttriaite-(Y)Y2O3Iso. m3(2/m3)
4.CC.AllendeiteSc4Zr3O12Trig. 3 : R3
4.CC.ChlorkyuygeniteCa12Al14O32[(H2O)4Cl2]Iso. 43m : I43d
4.CC.OboniobiteMg4Nb2O9Trig. 3m(32/m) : P3c1
4.CC.BotuobinskiteSrFe2+Mg2(Cr3+6Ti4+12)[O36(OH)2]Trig. 3 : R3
4.CC.MirnyiteSrZr4+Mg2(Cr3+6Ti4+12)O38Trig. 3 : R3
4.CC.Haitaite-(La)LaU4+Fe3+2(Ti13Fe2+4Fe3+)O38Trig. 3 : R3
4.CC.ShagamiteKFe11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.BitikleiteCa3(Sb5+Sn4+)[AlO4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.Anzaite-(Ce)Ce3+ 4Fe2+Ti6O18 (OH)2Mon. 2/m : B2/m
4.CC.Heamanite-(Ce)(K0.5Ce0.5)TiO3Iso. m3m(4/m32/m)
4.CC.Priscillagrewite-(Y)(Ca2Y)Zr2(AlO4)3Iso.
4.CC.StranditePb3Mn3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) : P63/mcm
4.CC.SaranovskiteSrCaFe2+2(Cr4Ti2)Ti12O38Trig. 3 : R3
4.CC.05ChrombismiteBi3+16Cr6+O27Iso. m3m(4/m32/m)
4.CC.10FreudenbergiteNa2(Ti,Fe)8O16Mon.
4.CC.10FluormayeniteCa12Al14O32F2Iso. 43m : I43d
4.CC.10FluorkyuygeniteCa12Al14O32[(H2O)4F2]Iso. 43m : I43d
4.CC.15GrossiteCaAl4O7Mon. 2/m : B2/b
4.CC.17GoldschmidtiteKNbO3Iso. m3m(4/m32/m) : Pm3m
4.CC.20'Unnamed (HBU UK-4)'NaFe2+Zn2(Ti,Fe3+,Nb)6Ti12O38Trig. 3 : R3
4.CC.20ChlormayeniteCa12Al14O32[◻4Cl2]Iso. 43m : I43d
4.CC.20PaseroitePbMn2+(Mn2+,Fe3+)2(V5+,Ti,◻)18O38 Trig. 3 : R3
4.CC.20Mianningite(◻,Pb,Ce,Na)(U4+,Mn,U6+)Fe3+2 (Ti,Fe3+)18O38Trig. 3 : R3
4.CC.20'UM1987-03-O:FePbTiU'~(U,Pb)(Ti,Fe3+,Fe2+,Mn)21O38Trig. 3 : R3
4.CC.22GoreriteCaAlFe3+11O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.22KahlenbergiteKAl11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.25HopmanniteBa2(Ti5Fe)O13Mon. 2/m : B2/m
4.CC.25NixoniteNa2Ti6O13Mon. 2/m : B2/m
4.CC.25YafsoaniteCa3Te6+2(ZnO4)3Iso. m3m(4/m32/m) : Ia3d
4.CC.30LatrappiteCa2NbFe3+O6Orth. mmm(2/m2/m2/m) : Pnma
4.CC.30NatroniobiteNaNbO3Mon.
4.CC.30PerovskiteCaTiO3Orth. mmm(2/m2/m2/m) : Pnma
4.CC.30LueshiteNaNbO3Orth. mmm(2/m2/m2/m)
4.CC.30BariolakargiiteBaZrO3Iso. m3m(4/m32/m) : Pm3m
4.CC.30BarioperovskiteBaTiO3Orth. mm2 : Amm2
4.CC.30LakargiiteCa(Zr,Sn,Ti)O3Orth. mmm(2/m2/m2/m) : Pnma
4.CC.32UsturiteCa3(Sb5+Zr)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.32ElbrusiteCa3(U6+0.5Zr1.5)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.32MonteneveiteCa3Sb5+2(Fe3+2Fe2+)O12Iso. m3m(4/m32/m) : Ia3d
4.CC.32DzhuluiteCa3(Sb5+Sn4+)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.35TausoniteSrTiO3Iso. 43m
4.CC.35Loparite(Na,REE)2Ti2O6Iso. m3m(4/m32/m)
4.CC.35Panguite(Ti,Al,Sc,Mg,Zr,Ca)1.8O3Orth. mmm(2/m2/m2/m) : Pbca
4.CC.35Isolueshite(Na,La)NbO3Iso. m3m(4/m32/m) : Pm3m
4.CC.35MacedonitePbTiO3Tet. 4/mmm(4/m2/m2/m) : P4/nmm
4.CC.37PauloabibiteNaNbO3Trig. 3 : R3
4.CC.40LandauiteNaMnZn2(Ti,Fe)6Ti12O38Trig. 3 : R3
4.CC.40Mathiasite(Mg,Cr,Fe,Ca,K)2(Ti,Zr,Cr,Fe)5O12Trig. 3 : R3
4.CC.40SenaitePb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38Trig. 3 : R3
4.CC.40Gramaccioliite-(Y)(Pb,Sr)(Y,Mn)Fe3+2(Ti,Fe3+)18O38Trig. 3 : R3
4.CC.40Lindsleyite(Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38Trig.
4.CC.40CrichtoniteSr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38Trig. 3 : R3
4.CC.40Loveringite(Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38Trig. 3 : R3
4.CC.40Cleusonite(Pb,Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38Trig. 3 : R3
4.CC.40Davidite-(Ce)Ce(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig. 3 : R3
4.CC.40Davidite-(La)La(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig. 3 : R3
4.CC.40'Davidite-(Y)'(La,Ce,Na,Ca,Pb)(Y,Fe2+,◻)(Fe2+,Mn2+)2(Ti,Fe3+,Nb,Zr)18O38 (hypothetical)Trig.
4.CC.40'Uhligite'Ca3(Ti,Al,Zr)9O20 ?Iso.
4.CC.40Dessauite-(Y)(Sr,Pb)(Y,U)(Ti,Fe3+)20O38Trig. 3 : R3
4.CC.45DiaoyudaoiteNaAl11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45YimengiteK(Cr,Ti,Fe,Mg)12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45NežilovitePbZn2Mn4+2Fe3+8O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HawthorneiteBaMgTi3Cr4Fe2+2Fe3+2O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45Mizraite-(Ce)Ce(Al11Mg)O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HaggertyiteBaFe2+4Fe3+2Ti5MgO19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45LindqvistitePb2Mn2+Fe16O27Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HiboniteCaAl12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45Kangite(Sc,Ti,Al,Zr,Mg,Ca,◻)2O3 Iso. m3(2/m3)
4.CC.45ChihuahuaiteFeAl12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45BarioferriteBaFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45PlumboferritePb[Fe3+10.67Mn2+0.33Pb]O18.33Trig. 32 : P312
4.CC.45BatiferriteBaTi2Fe3+8Fe2+2O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45MagnetoplumbitePbFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.50JeppeiteK2Ti6O13Mon. 2/m : B2/m
4.CC.55ZenzénitePb3Fe3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) : P63/mcm
4.CC.60'Mengxianminite (of Huang et al.)'(Ca,Na)3(Fe,Mn)2Mg2(Sn,Zn)5Al8O29

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MegawiteHide

References for MegawiteHide

Localities for MegawiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Kabardino-Balkaria
    • Chegemsky District
      • Upper Chegem volcanic caldera (Verkhnechegemskaya caldera)
        • Lakargi Mountain
Galuskin et al. (2011)
 
and/or  
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