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Latrappite

A valid IMA mineral species
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About LatrappiteHide

03852540017271924691298.jpg
La Trappe Monastery
Formula:
Ca2NbFe3+O6
Hardness:
Crystal System:
Orthorhombic
Name:
Named introduced by Nickel (1964) after the Trappist (an order of the Cistercians) monastery of La Trappe, near the type locality. The material was first described as a Nb-rich variety of perovskite from the Oka carbonatite complex, Quebec, Canada and named as a niobian perovskite. The Nb content showed to be greater than the Ti content in perovskite (CaTiO3), so it was defined and approved as a new mineral.
The status of latrappite has been questioned. Following Mitchell et al. 2016, the significant Fe3+ content was not considered by Nickel (1964) and the material investigated by Nickel (1964) and Nickel and McAdam (1963) was found to be a complex quaternary solid solution involving the components Ca2Nb2O7, Ca2Fe3+NbO6, CaTiO3 and NaNbO3.

Mitchell et al. 2016 suggested that the potential end-member latrappite be considered as analogous to synthetic 1:1 ordered Ca2Fe3+NbO6. They also recommended that only Ca-rich, Nb and Fe-rich perovskites [(Ca,Na)2(Nb,Fe3+,Ti)2O6] whose compositions are such that: (1) divalent cations prevail in the A-site with Ca dominant; and (2) pentavalent cations prevail in the B -site(s) with Nb dominant be termed latrappite.

It was thus redefined by IMA in 2016 as Ca2NbFe3+O6.


Note: it is not sure if latrappite belongs to the above-given subgroup of perovskites.


Unique IdentifiersHide

Mindat ID:
2337
Long-form identifier:
mindat:1:1:2337:1

IMA Classification of LatrappiteHide

Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
Ca2Fe3+Nb5+O6
Approval year:
1964
First published:
1963
Approval history:
Redefined, special procedure 2016.

Classification of LatrappiteHide

4.CC.30

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
4.3.3.2

4 : SIMPLE OXIDES
3 : A2X3
18.1.13

18 : Niobates and Tantalates
1 : Niobates and tantalates containing neither rare earths nor U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
LtpIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
LtpThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of LatrappiteHide

Hardness:
5½ on Mohs scale

Chemistry of LatrappiteHide

Mindat Formula:
Ca2NbFe3+O6
Element Weights:
Element% weight
O29.546 %
Nb28.595 %
Ca24.671 %
Fe17.188 %

Calculated from ideal end-member formula.
O
Nb
Ca
Fe

Crystallography of LatrappiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnma
Cell Parameters:
a = 5.44 Å, b = 7.77 Å, c = 5.55 Å
Ratio:
a:b:c = 0.7 : 1 : 0.714
Unit Cell V:
234.59 ų (Calculated from Unit Cell)
Comment:
Spacegroup: P21/n (Mitchell et al. 2016)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005539LatrappiteMitchell R H, Choi J B, Hawthorne F C, McCammon C A, Burns P C (1998) Latrappite: A re-investigation The Canadian Mineralogist 36 107-11619980293
CIF Raw Data - click here to close

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
36 : Carbonatites, kimberlites, and related igneous rocks

Type Occurrence of LatrappiteHide

Synonyms of LatrappiteHide

Other Language Names for LatrappiteHide

Relationship of Latrappite to other SpeciesHide

Other Members of Vapnikite Subgroup:
VapnikiteCa2CaUO6Mon. 2/m

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Latrappite associated with CalciteCaCO3
4 photos of Latrappite associated with FluorapatiteCa5(PO4)3F
3 photos of Latrappite associated with Pyrochlore GroupA2Nb2(O,OH)6Z
3 photos of Latrappite associated with Hydroxykenopyrochlore(◻,Ce,Ba)2(Nb,Ti)2O6(OH,F)
1 photo of Latrappite associated with MagnetiteFe2+Fe3+2O4
1 photo of Latrappite associated with Niocalite(Ca,Nb)4(Si2O7)(O,OH,F)2
1 photo of Latrappite associated with PhlogopiteKMg3(AlSi3O10)(OH)2

Related Minerals - Strunz-mindat GroupingHide

4.CC.XuiteCa3Fe3+2[(AlO3(OH)]3Iso. m3m(4/m32/m)
4.CC.Yttriaite-(Y)Y2O3Iso. m3(2/m3)
4.CC.AllendeiteSc4Zr3O12Trig. 3 : R3
4.CC.ChlorkyuygeniteCa12Al14O32[(H2O)4Cl2]Iso. 43m : I43d
4.CC.OboniobiteMg4Nb2O9Trig. 3m(32/m) : P3c1
4.CC.BotuobinskiteSrFe2+Mg2(Cr3+6Ti4+12)[O36(OH)2]Trig. 3 : R3
4.CC.MirnyiteSrZr4+Mg2(Cr3+6Ti4+12)O38Trig. 3 : R3
4.CC.Haitaite-(La)LaU4+Fe3+2(Ti13Fe2+4Fe3+)O38Trig. 3 : R3
4.CC.ShagamiteKFe11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.BitikleiteCa3(Sb5+Sn4+)[AlO4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.Anzaite-(Ce)Ce3+ 4Fe2+Ti6O18 (OH)2Mon. 2/m : B2/m
4.CC.Heamanite-(Ce)(K0.5Ce0.5)TiO3Iso. m3m(4/m32/m)
4.CC.Priscillagrewite-(Y)(Ca2Y)Zr2(AlO4)3Iso.
4.CC.StranditePb3Mn3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) : P63/mcm
4.CC.SaranovskiteSrCaFe2+2(Cr4Ti2)Ti12O38Trig. 3 : R3
4.CC.05ChrombismiteBi3+16Cr6+O27Iso. m3m(4/m32/m)
4.CC.10FreudenbergiteNa2(Ti,Fe)8O16Mon.
4.CC.10FluormayeniteCa12Al14O32F2Iso. 43m : I43d
4.CC.10FluorkyuygeniteCa12Al14O32[(H2O)4F2]Iso. 43m : I43d
4.CC.15GrossiteCaAl4O7Mon. 2/m : B2/b
4.CC.17GoldschmidtiteKNbO3Iso. m3m(4/m32/m) : Pm3m
4.CC.20'Unnamed (HBU UK-4)'NaFe2+Zn2(Ti,Fe3+,Nb)6Ti12O38Trig. 3 : R3
4.CC.20ChlormayeniteCa12Al14O32[◻4Cl2]Iso. 43m : I43d
4.CC.20PaseroitePbMn2+(Mn2+,Fe3+)2(V5+,Ti,◻)18O38 Trig. 3 : R3
4.CC.20Mianningite(◻,Pb,Ce,Na)(U4+,Mn,U6+)Fe3+2 (Ti,Fe3+)18O38Trig. 3 : R3
4.CC.20'UM1987-03-O:FePbTiU'~(U,Pb)(Ti,Fe3+,Fe2+,Mn)21O38Trig. 3 : R3
4.CC.22GoreriteCaAlFe3+11O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.22KahlenbergiteKAl11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.25HopmanniteBa2(Ti5Fe)O13Mon. 2/m : B2/m
4.CC.25NixoniteNa2Ti6O13Mon. 2/m : B2/m
4.CC.25YafsoaniteCa3Te6+2(ZnO4)3Iso. m3m(4/m32/m) : Ia3d
4.CC.30NatroniobiteNaNbO3Mon.
4.CC.30PerovskiteCaTiO3Orth. mmm(2/m2/m2/m) : Pnma
4.CC.30LueshiteNaNbO3Orth. mmm(2/m2/m2/m)
4.CC.30BariolakargiiteBaZrO3Iso. m3m(4/m32/m) : Pm3m
4.CC.30BarioperovskiteBaTiO3Orth. mm2 : Amm2
4.CC.30MegawiteCaSnO3Orth. mmm(2/m2/m2/m) : Pban
4.CC.30LakargiiteCa(Zr,Sn,Ti)O3Orth. mmm(2/m2/m2/m) : Pnma
4.CC.32UsturiteCa3(Sb5+Zr)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.32ElbrusiteCa3(U6+0.5Zr1.5)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.32MonteneveiteCa3Sb5+2(Fe3+2Fe2+)O12Iso. m3m(4/m32/m) : Ia3d
4.CC.32DzhuluiteCa3(Sb5+Sn4+)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.35TausoniteSrTiO3Iso. 43m
4.CC.35Loparite(Na,REE)2Ti2O6Iso. m3m(4/m32/m)
4.CC.35Panguite(Ti,Al,Sc,Mg,Zr,Ca)1.8O3Orth. mmm(2/m2/m2/m) : Pbca
4.CC.35Isolueshite(Na,La)NbO3Iso. m3m(4/m32/m) : Pm3m
4.CC.35MacedonitePbTiO3Tet. 4/mmm(4/m2/m2/m) : P4/nmm
4.CC.37PauloabibiteNaNbO3Trig. 3 : R3
4.CC.40LandauiteNaMnZn2(Ti,Fe)6Ti12O38Trig. 3 : R3
4.CC.40Mathiasite(Mg,Cr,Fe,Ca,K)2(Ti,Zr,Cr,Fe)5O12Trig. 3 : R3
4.CC.40SenaitePb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38Trig. 3 : R3
4.CC.40Gramaccioliite-(Y)(Pb,Sr)(Y,Mn)Fe3+2(Ti,Fe3+)18O38Trig. 3 : R3
4.CC.40Lindsleyite(Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38Trig.
4.CC.40CrichtoniteSr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38Trig. 3 : R3
4.CC.40Loveringite(Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38Trig. 3 : R3
4.CC.40Cleusonite(Pb,Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38Trig. 3 : R3
4.CC.40Davidite-(Ce)Ce(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig. 3 : R3
4.CC.40Davidite-(La)La(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig. 3 : R3
4.CC.40'Davidite-(Y)'(La,Ce,Na,Ca,Pb)(Y,Fe2+,◻)(Fe2+,Mn2+)2(Ti,Fe3+,Nb,Zr)18O38 (hypothetical)Trig.
4.CC.40'Uhligite'Ca3(Ti,Al,Zr)9O20 ?Iso.
4.CC.40Dessauite-(Y)(Sr,Pb)(Y,U)(Ti,Fe3+)20O38Trig. 3 : R3
4.CC.45DiaoyudaoiteNaAl11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45YimengiteK(Cr,Ti,Fe,Mg)12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45NežilovitePbZn2Mn4+2Fe3+8O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HawthorneiteBaMgTi3Cr4Fe2+2Fe3+2O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45Mizraite-(Ce)Ce(Al11Mg)O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HaggertyiteBaFe2+4Fe3+2Ti5MgO19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45LindqvistitePb2Mn2+Fe16O27Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HiboniteCaAl12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45Kangite(Sc,Ti,Al,Zr,Mg,Ca,◻)2O3 Iso. m3(2/m3)
4.CC.45ChihuahuaiteFeAl12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45BarioferriteBaFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45PlumboferritePb[Fe3+10.67Mn2+0.33Pb]O18.33Trig. 32 : P312
4.CC.45BatiferriteBaTi2Fe3+8Fe2+2O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45MagnetoplumbitePbFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.50JeppeiteK2Ti6O13Mon. 2/m : B2/m
4.CC.55ZenzénitePb3Fe3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) : P63/mcm
4.CC.60'Mengxianminite (of Huang et al.)'(Ca,Na)3(Fe,Mn)2Mg2(Sn,Zn)5Al8O29

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LatrappiteHide

References for LatrappiteHide

Reference List:

Localities for LatrappiteHide

Showing 9 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Québec
    • Laurentides
      • Deux-Montagnes RCM
        • Oka
Nickel et al. (1963) +2 other references
GOLD (1972)
Sabina (1967)
Romania
 
  • Harghita County
Hirtopanu (2006)
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
Dill et al. (2023)
        • Arico
Dill et al. (2023)
        • Arona
Dill et al. (2023)
Dill et al. (2023)
Tanzania
 
  • Arusha Region
    • Monduli District
      • Kerimasi volcano
Mitchell et al. (2021)
 
and/or  
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