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Hawthorneite

A valid IMA mineral species
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About HawthorneiteHide

00975520017271923662311.jpg
John B. Hawthorne
Formula:
BaMgTi3Cr4Fe2+2Fe3+2O19
Colour:
Black or brown
Lustre:
Metallic
Hardness:
5½ - 6
Specific Gravity:
5.02 (Calculated)
Crystal System:
Hexagonal
Name:
Named by I.E. Grey, I.C. Madsen, and S.E. Haggerty in 1987 in honor of John Barry Hawthorne (1934–2018), former Chief Geologist (Diamonds), DeBeers Consolidated Mines, South Africa, in honor of his contributions to studies of the upper mantle.
Unique combination of elements, although somewhat chemically similar to mathiasite and haggertyite.

The supposed Ti analogue (actually its Ti5Mg2Cr analogue) is IMA-coded as UM1994-07-O:BaCrFeMgTi.


Unique IdentifiersHide

Mindat ID:
1835
Long-form identifier:
mindat:1:1:1835:3

IMA Classification of HawthorneiteHide

Classification of HawthorneiteHide

4.CC.45

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
7.4.1.3

7 : MULTIPLE OXIDES
4 : AB12X19
7.14.9

7 : Oxides and Hydroxides
14 : Oxides of Cr

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
HwtIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of HawthorneiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of HawthorneiteHide

Metallic
Transparency:
Opaque
Colour:
Black or brown
Comment:
light gray in reflected light.
Hardness:
5½ - 6 on Mohs scale
Hardness:
VHN100=772 - 835 kg/mm2 - Vickers
Comment:
~5.8
Cleavage:
None Observed
Parting:
None observed
Density:
5.02 g/cm3 (Calculated)

Optical Data of HawthorneiteHide

Type:
Uniaxial (-)
Anisotropism:
Weak to moderate, brown to gray
Bireflectance:
Weakly to moderately bireflectant
Dispersion:
r < v
Reflectivity:
WavelengthR1 (%)R2 (%)imR1 (%)imR2 (%)
400nm18.1%19.5%6.08%7.00%
420nm17.8%19.1%5.79%6.66%
440nm17.5%18.8%5.55%6.36%
460nm17.2%18.4%5.33%6.12%
480nm16.95%18.1%5.18%5.95%
490nm16.9%18.0%5.11%5.87%
500nm16.8%17.9%5.06%5.80%
520nm16.6%17.7%4.98%5.70%
540nm16.5%17.6%4.90%5.61%
546nm16.4%17.5%4.88%5.58%
560nm16.4%17.4%4.83%5.51%
580nm16.3%17.3%4.78%5.45%
590nm16.3%17.3%4.76%5.42%
600nm16.2%17.2%4.75%5.40%
620nm16.15%17.2%4.72%5.37%
640nm16.1%17.1%4.69%5.35%
650nm16.0%17.05%4.68%5.34%
660nm16.0%17.0%4.66%5.32%
680nm15.95%16.95%4.62%5.29%
700nm15.9%16.9%4.58%5.26%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 19.5%.
R1 shown in black, R2 shown in red, imR1 shown in green, imR2 shown in blue
Colour in reflected light:
Light gray
Internal Reflections:
None
Pleochroism:
Non-pleochroic

Chemistry of HawthorneiteHide

Mindat Formula:
BaMgTi3Cr4Fe2+2Fe3+2O19
Element Weights:
Element% weight
O29.213 %
Fe21.467 %
Cr19.987 %
Ti13.800 %
Ba13.197 %
Mg2.336 %

Calculated from ideal end-member formula.

Crystallography of HawthorneiteHide

Crystal System:
Hexagonal
Class (H-M):
6/mmm(6/m2/m2/m) - Dihexagonal Dipyramidal
Space Group:
P63/mmc
Cell Parameters:
a = 5.871(2) Å, c = 23.06(2) Å
Ratio:
a:c = 1 : 3.928
Unit Cell V:
688.36 ų (Calculated from Unit Cell)
Z:
2
Morphology:
grains to 100 µm

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001094HawthorneiteGrey I E, Madsen I C, Haggerty S E (1987) Structure of a new upper-mantle, magnetoplumbite-type phase, Ba(Ti3Cr4Fe4Mg)O19 American Mineralogist 72 633-63619870293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.616 Å(100)
2.765 Å(85)
2.414 Å(49)
1.468 Å(45)
2.936 Å(42)
1.617 Å(42)
1.660 Å(38)
Comments:
calculated

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
36 : Carbonatites, kimberlites, and related igneous rocks

Type Occurrence of HawthorneiteHide

Synonyms of HawthorneiteHide

Other Language Names for HawthorneiteHide

Relationship of Hawthorneite to other SpeciesHide

Other Members of Hawthorneite Subgroup:
BarioferriteBaFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
BatiferriteBaTi2Fe3+8Fe2+2O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
HaggertyiteBaFe2+4Fe3+2Ti5MgO19Hex. 6/mmm(6/m2/m2/m) : P63/mmc

Common AssociatesHide

Associations Based on Photo Data:
8 photos of Hawthorneite associated with PargasiteNaCa2(Mg4Al)(Si6Al2)O22(OH)2
8 photos of Hawthorneite associated with 'Fayalite-Forsterite Series'

Related Minerals - Strunz-mindat GroupingHide

4.CC.XuiteCa3Fe3+2[(AlO3(OH)]3Iso. m3m(4/m32/m)
4.CC.Yttriaite-(Y)Y2O3Iso. m3(2/m3)
4.CC.AllendeiteSc4Zr3O12Trig. 3 : R3
4.CC.ChlorkyuygeniteCa12Al14O32[(H2O)4Cl2]Iso. 43m : I43d
4.CC.OboniobiteMg4Nb2O9Trig. 3m(32/m) : P3c1
4.CC.BotuobinskiteSrFe2+Mg2(Cr3+6Ti4+12)[O36(OH)2]Trig. 3 : R3
4.CC.MirnyiteSrZr4+Mg2(Cr3+6Ti4+12)O38Trig. 3 : R3
4.CC.Haitaite-(La)LaU4+Fe3+2(Ti13Fe2+4Fe3+)O38Trig. 3 : R3
4.CC.ShagamiteKFe11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.BitikleiteCa3(Sb5+Sn4+)[AlO4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.Anzaite-(Ce)Ce3+ 4Fe2+Ti6O18 (OH)2Mon. 2/m : B2/m
4.CC.Heamanite-(Ce)(K0.5Ce0.5)TiO3Iso. m3m(4/m32/m)
4.CC.Priscillagrewite-(Y)(Ca2Y)Zr2(AlO4)3Iso.
4.CC.StranditePb3Mn3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) : P63/mcm
4.CC.SaranovskiteSrCaFe2+2(Cr4Ti2)Ti12O38Trig. 3 : R3
4.CC.05ChrombismiteBi3+16Cr6+O27Iso. m3m(4/m32/m)
4.CC.10FreudenbergiteNa2(Ti,Fe)8O16Mon.
4.CC.10FluormayeniteCa12Al14O32F2Iso. 43m : I43d
4.CC.10FluorkyuygeniteCa12Al14O32[(H2O)4F2]Iso. 43m : I43d
4.CC.15GrossiteCaAl4O7Mon. 2/m : B2/b
4.CC.17GoldschmidtiteKNbO3Iso. m3m(4/m32/m) : Pm3m
4.CC.20'Unnamed (HBU UK-4)'NaFe2+Zn2(Ti,Fe3+,Nb)6Ti12O38Trig. 3 : R3
4.CC.20ChlormayeniteCa12Al14O32[◻4Cl2]Iso. 43m : I43d
4.CC.20PaseroitePbMn2+(Mn2+,Fe3+)2(V5+,Ti,◻)18O38 Trig. 3 : R3
4.CC.20Mianningite(◻,Pb,Ce,Na)(U4+,Mn,U6+)Fe3+2 (Ti,Fe3+)18O38Trig. 3 : R3
4.CC.20'UM1987-03-O:FePbTiU'~(U,Pb)(Ti,Fe3+,Fe2+,Mn)21O38Trig. 3 : R3
4.CC.22GoreriteCaAlFe3+11O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.22KahlenbergiteKAl11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.25HopmanniteBa2(Ti5Fe)O13Mon. 2/m : B2/m
4.CC.25NixoniteNa2Ti6O13Mon. 2/m : B2/m
4.CC.25YafsoaniteCa3Te6+2(ZnO4)3Iso. m3m(4/m32/m) : Ia3d
4.CC.30LatrappiteCa2NbFe3+O6Orth. mmm(2/m2/m2/m) : Pnma
4.CC.30NatroniobiteNaNbO3Mon.
4.CC.30PerovskiteCaTiO3Orth. mmm(2/m2/m2/m) : Pnma
4.CC.30LueshiteNaNbO3Orth. mmm(2/m2/m2/m)
4.CC.30BariolakargiiteBaZrO3Iso. m3m(4/m32/m) : Pm3m
4.CC.30BarioperovskiteBaTiO3Orth. mm2 : Amm2
4.CC.30MegawiteCaSnO3Orth. mmm(2/m2/m2/m) : Pban
4.CC.30LakargiiteCa(Zr,Sn,Ti)O3Orth. mmm(2/m2/m2/m) : Pnma
4.CC.32UsturiteCa3(Sb5+Zr)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.32ElbrusiteCa3(U6+0.5Zr1.5)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.32MonteneveiteCa3Sb5+2(Fe3+2Fe2+)O12Iso. m3m(4/m32/m) : Ia3d
4.CC.32DzhuluiteCa3(Sb5+Sn4+)[Fe3+O4]3Iso. m3m(4/m32/m) : Ia3d
4.CC.35TausoniteSrTiO3Iso. 43m
4.CC.35Loparite(Na,REE)2Ti2O6Iso. m3m(4/m32/m)
4.CC.35Panguite(Ti,Al,Sc,Mg,Zr,Ca)1.8O3Orth. mmm(2/m2/m2/m) : Pbca
4.CC.35Isolueshite(Na,La)NbO3Iso. m3m(4/m32/m) : Pm3m
4.CC.35MacedonitePbTiO3Tet. 4/mmm(4/m2/m2/m) : P4/nmm
4.CC.37PauloabibiteNaNbO3Trig. 3 : R3
4.CC.40LandauiteNaMnZn2(Ti,Fe)6Ti12O38Trig. 3 : R3
4.CC.40Mathiasite(Mg,Cr,Fe,Ca,K)2(Ti,Zr,Cr,Fe)5O12Trig. 3 : R3
4.CC.40SenaitePb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38Trig. 3 : R3
4.CC.40Gramaccioliite-(Y)(Pb,Sr)(Y,Mn)Fe3+2(Ti,Fe3+)18O38Trig. 3 : R3
4.CC.40Lindsleyite(Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38Trig.
4.CC.40CrichtoniteSr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38Trig. 3 : R3
4.CC.40Loveringite(Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38Trig. 3 : R3
4.CC.40Cleusonite(Pb,Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38Trig. 3 : R3
4.CC.40Davidite-(Ce)Ce(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig. 3 : R3
4.CC.40Davidite-(La)La(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig. 3 : R3
4.CC.40'Davidite-(Y)'(La,Ce,Na,Ca,Pb)(Y,Fe2+,◻)(Fe2+,Mn2+)2(Ti,Fe3+,Nb,Zr)18O38 (hypothetical)Trig.
4.CC.40'Uhligite'Ca3(Ti,Al,Zr)9O20 ?Iso.
4.CC.40Dessauite-(Y)(Sr,Pb)(Y,U)(Ti,Fe3+)20O38Trig. 3 : R3
4.CC.45DiaoyudaoiteNaAl11O17Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45YimengiteK(Cr,Ti,Fe,Mg)12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45NežilovitePbZn2Mn4+2Fe3+8O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45Mizraite-(Ce)Ce(Al11Mg)O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HaggertyiteBaFe2+4Fe3+2Ti5MgO19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45LindqvistitePb2Mn2+Fe16O27Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45HiboniteCaAl12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45Kangite(Sc,Ti,Al,Zr,Mg,Ca,◻)2O3 Iso. m3(2/m3)
4.CC.45ChihuahuaiteFeAl12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45BarioferriteBaFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45PlumboferritePb[Fe3+10.67Mn2+0.33Pb]O18.33Trig. 32 : P312
4.CC.45BatiferriteBaTi2Fe3+8Fe2+2O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.45MagnetoplumbitePbFe3+12O19Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CC.50JeppeiteK2Ti6O13Mon. 2/m : B2/m
4.CC.55ZenzénitePb3Fe3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) : P63/mcm
4.CC.60'Mengxianminite (of Huang et al.)'(Ca,Na)3(Fe,Mn)2Mg2(Sn,Zn)5Al8O29

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HawthorneiteHide

References for HawthorneiteHide

Localities for HawthorneiteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Shandong
    • Linyi
      • Mengyin County
Qi Lu et al. (2007)
Russia
 
  • Sakha
    • Mirninsky District
      • Daldyn
Rezvukhin +3 other references
South Africa (TL)
 
  • Northern Cape
    • Frances Baard District Municipality
      • Sol Plaatje Local Municipality
        • Kimberley
          • KEM JV Mine (Kimberley Ekapa Mining Joint Venture mine; Kimberley Underground mine)
Amer.Min. (1989) +1 other reference
 
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