Heamanite-(Ce)
A valid IMA mineral species
This page is currently not sponsored. Click here to sponsor this page.
Larry Heaman (b. 1955), Professor at the University of Alberta in Edmonton, Canada.
Formula:
(K0.5Ce0.5)TiO3
Colour:
brown
Lustre:
Adamantine
Hardness:
5½
Specific Gravity:
4.73 (Calculated)
Crystal System:
Isometric
Name:
In honour of Larry Heaman (b. 1955), who is a Distinguished University Professor at the University of Alberta in Edmonton, Canada, and his lifetime of work in the field of geology and geochemistry. He was the researcher who really developed perovskite age dating and made it an important tool in Earth Sciences research. Through his dating work, Larry Heaman has had an important impact on the field of kimberlite origins and provided a critical service to the emerging diamond exploration industry in North America since the early 1990s.
Anzolini et al. (2022) report the discovery and description of a new perovskite-group mineral, heamanite-(Ce), ideally (K0.5Ce0.5)TiO3, found as an inclusion in a diamond from the Gahcho Kue mine in the Northwest Territories, Canada.
Heamanite-(Ce) is the K-analog of loparite-(Ce), ideally (NaCe)Ti2O6. This finding not only represents the sixth perovskite-structured mineral to occur in Earth's mantle, along with perovskite sensu stricto, K-REE- Cr-rich tausonite, bridgmanite, CaSiO3-perovskite, and goldschmidtite, but also indicates that perovskite-structured oxides have the potential to be significant hosts for K and LREE in the mantle.
To precipitate a phase with such high concentrations of incompatible elements, we suggest that extreme levels of fractionation occurred in the fractionating metasomatic fluid. Moreover, the high concentration of radiogenic elements in heamanite-(Ce) may allow for future isotopic dating, making this discovery of interest to geochemists, kimberlite petrologists and mineralogists.
Heamanite-(Ce) is the K-analog of loparite-(Ce), ideally (NaCe)Ti2O6. This finding not only represents the sixth perovskite-structured mineral to occur in Earth's mantle, along with perovskite sensu stricto, K-REE- Cr-rich tausonite, bridgmanite, CaSiO3-perovskite, and goldschmidtite, but also indicates that perovskite-structured oxides have the potential to be significant hosts for K and LREE in the mantle.
To precipitate a phase with such high concentrations of incompatible elements, we suggest that extreme levels of fractionation occurred in the fractionating metasomatic fluid. Moreover, the high concentration of radiogenic elements in heamanite-(Ce) may allow for future isotopic dating, making this discovery of interest to geochemists, kimberlite petrologists and mineralogists.
Unique Identifiers
Mindat ID:
54647
Long-form identifier:
mindat:1:1:54647:4
Similar Names
| Hohmannite | A valid IMA mineral species - grandfathered | Fe23+(SO4)2O · 8H2O |
| Seamanite | A valid IMA mineral species - grandfathered | Mn32+[B(OH)4](PO4)(OH)2 |
IMA Classification of Heamanite-(Ce)
Classification of Heamanite-(Ce)
4.CC.
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Hea-Ce | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Heamanite-(Ce)
Adamantine
Transparency:
Translucent
Colour:
Brown
Hardness:
5½ on Mohs scale
Comment:
by comparison to loparite-(Ce)
Fracture:
Conchoidal
Density:
4.73(1) g/cm3 (Calculated)
Chemistry of Heamanite-(Ce)
Mindat Formula:
(K0.5Ce0.5)TiO3
Element Weights:
Elements listed:
Crystallography of Heamanite-(Ce)
Crystal System:
Isometric
Class (H-M):
m3m(4/m32/m) - Hexoctahedral
Cell Parameters:
a = 3.9129(9) Å
Unit Cell V:
59.91 ų (Calculated from Unit Cell)
Z:
1
Comment:
Spacegroup: Pm-3m
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.764 Å | (100) |
| 2.259 Å | (7) |
| 1.954 Å | (31) |
| 1.596 Å | (42) |
| 1.382 Å | (20) |
| 1.236 Å | (15) |
| 1.128 Å | (8) |
| 1.045 Å | (19) |
Comments:
From Type Description.
Type Occurrence of Heamanite-(Ce)
General Appearance of Type Material:
crystals to 80 microns.
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collections of the Royal Ontario Museum, 100 Queen's Park, Toronto, ON M5S 2C6, Canada, catalogue number M59970
Geological Setting of Type Material:
Diamond mine
Associated Minerals at Type Locality:
Synonyms of Heamanite-(Ce)
Other Language Names for Heamanite-(Ce)
Dutch:Heamaniet-(Ce)
German:Heamanit-(Ce)
Related Minerals - Strunz-mindat Grouping
| 4.CC. | Bernwoodite | Ca5TiAl2Si2O14 |
| 4.CC. | Xuite | Ca3Fe3+2[(AlO3(OH)]3 |
| 4.CC. | Yttriaite-(Y) | Y2O3 |
| 4.CC. | Allendeite | Sc4Zr3O12 |
| 4.CC. | Chlorkyuygenite | Ca12Al14O32[(H2O)4Cl2] |
| 4.CC. | Oboniobite | Mg4Nb2O9 |
| 4.CC. | Botuobinskite | SrFe2+Mg2(Cr3+6Ti4+12)[O36(OH)2] |
| 4.CC. | Mirnyite | SrZr4+Mg2(Cr3+6Ti4+12)O38 |
| 4.CC. | Haitaite-(La) | LaU4+Fe3+2(Ti13Fe2+4Fe3+)O38 |
| 4.CC. | Shagamite | KFe11O17 |
| 4.CC. | Bitikleite | Ca3(Sb5+Sn4+)[AlO4]3 |
| 4.CC. | Anzaite-(Ce) | Ce3+ 4Fe2+Ti6O18 (OH)2 |
| 4.CC. | Priscillagrewite-(Y) | (Ca2Y)Zr2(AlO4)3 |
| 4.CC. | Strandite | Pb3Mn3+4Mn4+3O15 |
| 4.CC. | Saranovskite | SrCaFe2+2(Cr4Ti2)Ti12O38 |
| 4.CC.05 | Chrombismite | Bi3+16Cr6+O27 |
| 4.CC.10 | Freudenbergite | Na2(Ti,Fe)8O16 |
| 4.CC.10 | Fluormayenite | Ca12Al14O32F2 |
| 4.CC.10 | Fluorkyuygenite | Ca12Al14O32[(H2O)4F2] |
| 4.CC.15 | Grossite | CaAl4O7 |
| 4.CC.17 | Goldschmidtite | KNbO3 |
| 4.CC.20 | 'Unnamed (HBU UK-4)' | NaFe2+Zn2(Ti,Fe3+,Nb)6Ti12O38 |
| 4.CC.20 | Chlormayenite | Ca12Al14O32[◻4Cl2] |
| 4.CC.20 | Paseroite | PbMn2+(Mn2+,Fe3+)2(V5+,Ti,◻)18O38 |
| 4.CC.20 | Mianningite | (◻,Pb,Ce,Na)(U4+,Mn,U6+)Fe3+2 (Ti,Fe3+)18O38 |
| 4.CC.20 | 'UM1987-03-O:FePbTiU' | ~(U,Pb)(Ti,Fe3+,Fe2+,Mn)21O38 |
| 4.CC.22 | Gorerite | CaAlFe3+11O19 |
| 4.CC.22 | Kahlenbergite | KAl11O17 |
| 4.CC.25 | Hopmannite | Ba2(Ti5Fe)O13 |
| 4.CC.25 | Nixonite | Na2Ti6O13 |
| 4.CC.25 | Yafsoanite | Ca3Te6+2(ZnO4)3 |
| 4.CC.30 | Latrappite | Ca2NbFe3+O6 |
| 4.CC.30 | Natroniobite | NaNbO3 |
| 4.CC.30 | Perovskite | CaTiO3 |
| 4.CC.30 | Lueshite | NaNbO3 |
| 4.CC.30 | Bariolakargiite | BaZrO3 |
| 4.CC.30 | Barioperovskite | BaTiO3 |
| 4.CC.30 | Megawite | CaSnO3 |
| 4.CC.30 | Lakargiite | Ca(Zr,Sn,Ti)O3 |
| 4.CC.32 | Usturite | Ca3(Sb5+Zr)[Fe3+O4]3 |
| 4.CC.32 | Elbrusite | Ca3(U6+0.5Zr1.5)[Fe3+O4]3 |
| 4.CC.32 | Monteneveite | Ca3Sb5+2(Fe3+2Fe2+)O12 |
| 4.CC.32 | Dzhuluite | Ca3(Sb5+Sn4+)[Fe3+O4]3 |
| 4.CC.35 | Tausonite | SrTiO3 |
| 4.CC.35 | Loparite | (Na,REE)2Ti2O6 |
| 4.CC.35 | Panguite | (Ti,Al,Sc,Mg,Zr,Ca)1.8O3 |
| 4.CC.35 | Isolueshite | (Na,La)NbO3 |
| 4.CC.35 | Macedonite | PbTiO3 |
| 4.CC.37 | Pauloabibite | NaNbO3 |
| 4.CC.40 | Landauite | NaMnZn2(Ti,Fe)6Ti12O38 |
| 4.CC.40 | Mathiasite | (Mg,Cr,Fe,Ca,K)2(Ti,Zr,Cr,Fe)5O12 |
| 4.CC.40 | Senaite | Pb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38 |
| 4.CC.40 | Gramaccioliite-(Y) | (Pb,Sr)(Y,Mn)Fe3+2(Ti,Fe3+)18O38 |
| 4.CC.40 | Lindsleyite | (Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38 |
| 4.CC.40 | Crichtonite | Sr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38 |
| 4.CC.40 | Loveringite | (Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38 |
| 4.CC.40 | Cleusonite | (Pb,Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38 |
| 4.CC.40 | Davidite-(Ce) | Ce(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38 |
| 4.CC.40 | Davidite-(La) | La(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38 |
| 4.CC.40 | 'Davidite-(Y)' | (La,Ce,Na,Ca,Pb)(Y,Fe2+,◻)(Fe2+,Mn2+)2(Ti,Fe3+,Nb,Zr)18O38 (hypothetical) |
| 4.CC.40 | 'Uhligite' | Ca3(Ti,Al,Zr)9O20 ? |
| 4.CC.40 | Dessauite-(Y) | (Sr,Pb)(Y,U)(Ti,Fe3+)20O38 |
| 4.CC.45 | Diaoyudaoite | NaAl11O17 |
| 4.CC.45 | Yimengite | K(Cr,Ti,Fe,Mg)12O19 |
| 4.CC.45 | Nežilovite | PbZn2Mn4+2Fe3+8O19 |
| 4.CC.45 | Hawthorneite | BaMgTi3Cr4Fe2+2Fe3+2O19 |
| 4.CC.45 | Mizraite-(Ce) | Ce(Al11Mg)O19 |
| 4.CC.45 | Haggertyite | BaFe2+4Fe3+2Ti5MgO19 |
| 4.CC.45 | Lindqvistite | Pb2Mn2+Fe16O27 |
| 4.CC.45 | Hibonite | CaAl12O19 |
| 4.CC.45 | Kangite | (Sc,Ti,Al,Zr,Mg,Ca,◻)2O3 |
| 4.CC.45 | Chihuahuaite | FeAl12O19 |
| 4.CC.45 | Barioferrite | BaFe3+12O19 |
| 4.CC.45 | Plumboferrite | Pb[Fe3+10.67Mn2+0.33Pb]O18.33 |
| 4.CC.45 | Batiferrite | BaTi2Fe3+8Fe2+2O19 |
| 4.CC.45 | Magnetoplumbite | PbFe3+12O19 |
| 4.CC.50 | Jeppeite | K2Ti6O13 |
| 4.CC.55 | Zenzénite | Pb3Fe3+4Mn4+3O15 |
| 4.CC.60 | 'Mengxianminite (of Huang et al.)' | (Ca,Na)3(Fe,Mn)2Mg2(Sn,Zn)5Al8O29 |
Radioactivity
Radioactivity:
| Element | % Content | Activity (Bq/kg) | Radiation Type |
|---|---|---|---|
| Uranium (U) | 0.0000% | 0 | α, β, γ |
| Thorium (Th) | 0.0000% | 0 | α, β, γ |
| Potassium (K) | 10.5402% | 3,267 | β, γ |
For comparison:
- Banana: ~15 Bq per fruit
- Granite: 1,000–3,000 Bq/kg
- EU exemption limit: 10,000 Bq/kg
Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.
Interactive Simulator:
Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!
Activity: –
| Distance | Dose rate | Risk |
|---|---|---|
| 1 cm | ||
| 10 cm | ||
| 1 m |
The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).
D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield
Other Information
Notes:
Raman bands[cm-1]: 560b, 787b
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Heamanite-(Ce)
mindat.org URL:
https://www.mindat.org/min-54647.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Heamanite-(Ce)
Localities for Heamanite-(Ce)
Showing 1 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Canada (TL) | |
| Miyawaki et al. (2020) +1 other reference |
