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Rondorfite

A valid IMA mineral species
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About RondorfiteHide

03040050017271948389900.jpg
From left to right Eugene Rondorf (rondorfite), Elsa Horváth (horváthite-(Y)), Alice Rondorf (rondorfite), Franz-Josef Emmerich (emmerichite) and Jochen Tschörtner (tschörtnerite).

Caspar quarry, Ettringen, Vordereifel, Mayen-Koblenz, Rhineland-Palatinate, Germany
Formula:
Ca8Mg(SiO4)4Cl2
Colour:
orange brown to amber, rarely green
Lustre:
Vitreous, Sub-Vitreous
Specific Gravity:
3.03 (Calculated)
Crystal System:
Isometric
Name:
Named in honour of Alice and Eugen Rondorf, of Neuwied, Germany, mineral collectors who discovered the mineral with Bernd Ternes in 1979. They also discovered the mineral almarudite.
Rondorfite grains are anhedral, < 0.3 mm in diameter, and show orange brown to amber color, vitreous luster, and a light amber streak. The color difference results from different O/Cl ratio. The orange color results from (1) Fe3+/Al substitution for Mg, (2) presence of atypical MgO4 tetrahedron, or (3) electronegativity. Non-equilibrium Cl positions and the presence of Ca-Cl bonds are confirmed (Dulski et al., 2015).

An Al-bearing, triclinic-pseudocubic variant was described by Rastsvetaeva et al. (2008).


Unique IdentifiersHide

Mindat ID:
25682
Long-form identifier:
mindat:1:1:25682:7

IMA Classification of RondorfiteHide

Classification of RondorfiteHide

9.AB.20

9 : SILICATES (Germanates)
A : Nesosilicates
B : Nesosilicates without additional anions; cations in [4] and greater coordination

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
RonIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of RondorfiteHide

Vitreous, Sub-Vitreous
Transparency:
Transparent, Translucent
Colour:
Orange brown to amber, rarely green
Streak:
Pale yellow
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Conchoidal
Density:
3.03 g/cm3 (Calculated)

Optical Data of RondorfiteHide

Type:
Isotropic
RI values:
n = 1.676
Birefringence:
0.0
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Pleochroism:
Non-pleochroic

Chemistry of RondorfiteHide

Mindat Formula:
Ca8Mg(SiO4)4Cl2
Element Weights:
Element% weight
Ca40.887 %
O32.645 %
Si14.326 %
Cl9.042 %
Mg3.100 %

Calculated from ideal end-member formula.
Ca
O
Si
Cl
Mg

Crystallography of RondorfiteHide

Crystal System:
Isometric
Class (H-M):
m3(2/m3) - Diploidal
Space Group:
Fd3
Setting:
F2/d3
Cell Parameters:
a = 15.0850(3) Å
Unit Cell V:
3,432.70 ų (Calculated from Unit Cell)
Z:
8
Comment:
Cubic or Triclinic. Point Group: 2/m 3 or 1.: Space Group: F2/d3 . a = 15.0850(3) Z = 8 or Space Group: P1 . a = 15.100(2) b = 15.110(2) c = 15.092(2) α = 90.06(1)° β = 90.01(1)° γ = 89.93(1)° Z = 8

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012395RondorfiteRastsvetaeva R K, Zadov A E, Chukanov N V (2008) Crystal structure of low-symmetry rondorfite Crystallography Reports 53 199-2052008Kabardino-Balkarian Republic, Northern Caucasus Region, Russia0293
0014723RondorfiteMihajlovic T, Lengauer C L, Ntaflos T, Lolitsch U, Tillmanns E (2004) Two new minerals, rondorfite, Ca8Mg[SiO4]4Cl2, and almarudite, K(box,Na)2(Mn,Fe,Mg)2(Be,Al)3[Si12O30], and a study of iron-rich wadalite, Ca12[(Al8Si4Fe2)O32]C16, from the Bellerberg (Bellberg) volcano, Eifel, Germany Eastern Eifel volcanic area, Eifel, Germany Neues Jahrbuch fur Mineralogie, Abhandlungen 179 265-2942004Bellerberg volcano lava field, 2 km N of Mayen,0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.669 Å(20)
5.323 Å(15)
4.545 Å(20)
4.365 Å(5)
3.767 Å(5)
3.074 Å(15)
2.901 Å(40)
2.666 Å(100)
2.549 Å(30)
2.383 Å(10)
2.302 Å(15)
2.272 Å(15)
2.111. Å(20)
1.964 Å(30)
1.885 Å(30)
1.844 Å(5)
1.777 Å(30)
1.742 Å(20)
1.688 Å(5)
1.580 Å(5)
1.540 Å(50)
1.459 Å(30)
1.333 Å(15)
1.224 Å(10)
1.193 Å(20)
1.154 Å(20)
1.020 Å(10)
1.008 Å(10)
Comments:
Mihajlović, T., C. L. Lengauer, T. Ntaflos, U. Kolitsch and E. Tillmanns (2004) Two new minerals rondorfite, Ca8Mg[SiO4]4Cl2, and almarudite, K(ٱ,Na)2(Mn,Fe,Mg)2(Be,Al)3[Si12O30], and a study of iron-rich wadalite, Ca12[(Al8Si4Fe2)O32]Cl6, from the Bellerberg (Bellberg) volcano, Eifel, Germany. Neues Jahrbuch für Mineralogie, Abhandlungen: 179: 265-294.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45b : [Other oxidized fumarolic minerals]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36
Stage 10b: Anthropogenic minerals<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)

Type Occurrence of RondorfiteHide

Synonyms of RondorfiteHide

Other Language Names for RondorfiteHide

German:Rondorfit
Simplified Chinese:罗道尔夫石
Traditional Chinese:羅道爾夫石

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Rondorfite associated with 'Ellestadite'
3 photos of Rondorfite associated with LarniteCa2SiO4
1 photo of Rondorfite associated with EltyubyuiteCa12Fe3+10Si4O32Cl6
1 photo of Rondorfite associated with 'Hibschite'Ca3Al2(SiO4)3-x(OH)4x
1 photo of Rondorfite associated with ChegemiteCa7(SiO4)3(OH)2
1 photo of Rondorfite associated with 'Hydrogarnet'
1 photo of Rondorfite associated with ChlorellestaditeCa5(SiO4)1.5(SO4)1.5Cl
1 photo of Rondorfite associated with SpurriteCa5(SiO4)2(CO3)
1 photo of Rondorfite associated with HydrocalumiteCa4Al2(OH)12(Cl,CO3,OH)2 · 4H2O

Related Minerals - Strunz-mindat GroupingHide

9.AB.05TrimeriteCaMn2+2Be3(SiO4)3Mon. 2/m : P21/m
9.AB.10LarsenitePbZnSiO4Orth. mm2 : Pna21
9.AB.15EsperitePbCa2Zn3(SiO4)3Mon. 2/m : P21/b

Fluorescence of RondorfiteHide

Not fluorescent in Ultraviolet

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for RondorfiteHide

References for RondorfiteHide

Localities for RondorfiteHide

Showing 10 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Czech Republic
 
  • South Moravian Region
    • Brno-Country District
      • Oslavany
Hršelová et al. (2013)
Georgia
 
  • South Ossetia
    • Kel’ volcanic area
      • Shadil-Khokh volcano
Galuskina et al. (2015) +1 other reference
Germany (TL)
 
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Vordereifel
        • Ettringen
T. Mihajlović +1 other reference
in the collection of Christof Schäfer
in the collection of Christof Schäfer
Russia
 
  • Chelyabinsk Oblast
Sharygin (2015)
  • Kabardino-Balkaria
    • Chegemsky District
Bailau +1 other reference
        • Lakargi Mountain
Galuskina et al. (2015)
Galuskin et al. (2011)
Galuskin +10 other references
 
and/or  
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