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Césarferreiraite

A valid IMA mineral species
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About CésarferreiraiteHide

Formula:
Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O
Colour:
Pale to yellowish green
Lustre:
Vitreous, Sub-Vitreous
Specific Gravity:
2.934 (Calculated)
Crystal System:
Triclinic
Name:
Named in honor of César Mendonça Ferreira (b. 1942) mineralogist who established the Gemological Laboratory of the Federal University of Ouro Preto.
The Arsenate-analogue of ferrolaueite.
Related to stewartite and bendadaite.


Name EncodingHide

ASCII-7:
Cesarferreiraite

Unique IdentifiersHide

Mindat ID:
43865
Long-form identifier:
mindat:1:1:43865:2

Classification of CésarferreiraiteHide

05521570017685316117551.jpg
Laueite structure archetype

In césarferreiraite, the M1 site is occupied by Fe2+ and the M2 and M3 sites are occupied by Fe3+. The X site is an arsenate group.

IMA Classification of CésarferreiraiteHide

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CéfIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CésarferreiraiteHide

Vitreous, Sub-Vitreous
Transparency:
Transparent
Colour:
Pale to yellowish green
Streak:
Pale to yellowish green
Cleavage:
Distinct/Good
{010} {100}
Density:
2.934 g/cm3 (Calculated)

Optical Data of CésarferreiraiteHide

Type:
Biaxial (+)
Comments:
RI min=1.747 max=1.754

Chemistry of CésarferreiraiteHide

Mindat Formula:
Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O
Element Weights:
Element% weight
O46.188 %
Fe26.870 %
As24.032 %
H2.910 %

Calculated from ideal end-member formula.

Crystallography of CésarferreiraiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 5.383(2) Å, b = 6.878(2) Å, c = 10.364(3) Å
α = 96.43(4)°, β = 102.29(2)°, γ = 109.17(3)°
Ratio:
a:b:c = 0.783 : 1 : 1.507
Unit Cell V:
347.19 ų (Calculated from Unit Cell)
Z:
1
Morphology:
fibrous

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.85 Å(95)
6.35 Å(100)
4.963 Å(21)
4.534 Å(17)
3.997 Å(13)
3.671 Å(29)
3.158 Å(32)
2.960 Å(39)
2.884 Å(35)
2.680 Å(29)
2.540 Å(23)
2.475 Å(8)
1.9968 Å(8)*
1.9129 Å(5)
1.8798 Å(7)
1.6252 Å(7)
1.6153 Å(7)
Comments:
*1.9968 is in the XRD list twice, but with different calculated d values. Césarferreiraite, Fe2+Fe23+(AsO4)2(OH)2⋅8H2O, from Eduardo mine, Conselheiro Pena, Minas Gerais, Brazil: Second arsenate in the laueite mineral group: Ricardo Scholz, Nikita V. Chukanov, Luiz A.D. Menezes Filho, Daniel Atencio, Leonardo Lagoeiro, Fernanda M. Belotti, Mário I.S.c. Chaves, Antônio W. Romano, Paulo R. Brandão, Dmitriy I. Belakovskiy and Igor Pekov.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
Stage 7: Great Oxidation Event<2.4
46 : Near-surface hydrothermal alteration of minerals (see also #22)

Type Occurrence of CésarferreiraiteHide

General Appearance of Type Material:
Single crystals, up to 10 μm long with a thickness of about 1-2 μm, are elongated along [001] and flattened on (100).
Place of Conservation of Type Material:
Type material is deposited in the collections of the Museu de Ciência e Técnica da Escola de Minas, Universidade Federal de Ouro Preto, Praça Tiradentes, Ouro Preto, Brazil, registration number SAA-011
Geological Setting of Type Material:
pegmatite
Associated Minerals at Type Locality:

Synonyms of CésarferreiraiteHide

Other Language Names for CésarferreiraiteHide

Relationship of Césarferreiraite to other SpeciesHide

Other Members of Maghrebite Group:
MaghrebiteMgAl2(AsO4)2(OH)2 · 8H2OTric. 1 : P1

Related Minerals - Strunz-mindat GroupingHide

8.DC.FerroberauniteFe2+Fe3+5(PO4)4(OH)5 · 6H2OMon. 2/m : B2/b
8.DC.FerrivauxiteFe3+Al2(PO4)2(OH)3 · 5H2OTric. 1 : P1
8.DC.IanbruceiteZn2(AsO4)(OH) · 3H2OMon. 2/m : P21/b
8.DC.05NissoniteCu2Mg2(PO4)2(OH)2 · 5H2OMon. 2/m : B2/b
8.DC.07EuchroiteCu2(AsO4)(OH) · 3H2OOrth. 222 : P212121
8.DC.10LegranditeZn2(AsO4)(OH) · H2OMon. 2/m : P21/b
8.DC.12StrashimiriteCu8(AsO4)4(OH)4 · 5H2OMon.
8.DC.15EarlshannoniteMn2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15KunatiteCuFe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15'UM2006-27-PO:FeHZn'ZnFe3+2(PO4)2(OH)2 · 4H2OMon.
8.DC.15'UKI-2006-(PO:AlCuFeH)'Fe2+Al3+2(PO4)2(OH)2 · 4H2O
8.DC.15CobaltarthuriteCoFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15ArthuriteCuFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15OjuelaiteZnFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15WhitmoreiteFe2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15BendadaiteFe2+Fe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.17KleemaniteZnAl2(PO4)2(OH)2 · 3H2OMon.
8.DC.20MagnesiobermaniteMgMn3+2(PO4)2(OH)2 · 4H2OMon. 2 : P21
8.DC.20BermaniteMn2+Mn3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P2/b
8.DC.20CoralloiteMn2+Mn3+2(AsO4)2(OH)2 · 4H2OTric. 1 : P1
8.DC.22KovdorskiteMg2(PO4)(OH) · 3H2OMon. 2/m : P21/b
8.DC.25ZincostrunziteZnFe3+2(PO4)2(OH)2 · 6.5H2OTric. 1 : P1
8.DC.25MetavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/b
8.DC.25MetavivianiteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.25FerristrunziteFe3+Fe3+2(PO4)2(OH)3 · 5H2OTric.
8.DC.25StrunziteMn2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.25FerrostrunziteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric.
8.DC.27BerauniteFe3+6(PO4)4O(OH)4 · 6H2OMon. m : Bb
8.DC.27TvrdýiteFe2+Fe3+2Al3(PO4)4(OH)5(H2O)4 · 2H2OMon. 2/m : B2/b
8.DC.27ZincoberauniteZnFe3+5(PO4)4(OH)5 · 6H2OMon. 2/m : B2/b
8.DC.30MaghrebiteMgAl2(AsO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30FerrolaueiteFe2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30UshkoviteMgFe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30LaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30ParavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30SigloiteFe3+Al2(PO4)2(OH)3 · 7H2OTric. 1 : P1
8.DC.30NordgauiteMnAl2(PO4)2(F,OH)2 · 5H2OTric. 1 : P1
8.DC.30Kayrobertsonite[MnAl2(PO4)2(OH)2(H2O)4] · 2H2OTric. 1 : P1
8.DC.30KummeriteMn2+Fe3+Al(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30MangangordoniteMn2+Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30StewartiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30GordoniteMgAl2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30Kastningite(Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30PseudolaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/b
8.DC.32KamarizaiteFe3+3(AsO4)2(OH)3 · 3H2OTric. 1 : P1
8.DC.32TinticiteFe3+3(PO4)2(OH)3 · 3H2OTric. 1 : P1
8.DC.35VauxiteFe2+Al2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.37VantasseliteAl4(PO4)3(OH)3 · 9H2OOrth.
8.DC.40CacoxeniteFe3+24AlO6(PO4)17(OH)12 · 75H2OHex. 6/m : P63/m
8.DC.45SouzaliteMg3Al4(PO4)4(OH)6 · 2H2OTric. 1
8.DC.45Gormanite(Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2OTric.
8.DC.47KingiteAl3(PO4)2F2(OH) · 7H2OTric.
8.DC.50AllanpringiteFe3+3(PO4)2(OH)3 · 5H2OMon. 2/m : P21/m
8.DC.50FluorwavelliteAl3(PO4)2(OH)2F · 5H2OOrth. mmm(2/m2/m2/m)
8.DC.50WavelliteAl3(PO4)2(OH)3 · 5H2OOrth. mmm(2/m2/m2/m)
8.DC.52KribergiteAl5(PO4)3(SO4)(OH)4 · 4H2OTric. 1 : P1
8.DC.55MapimiteZn2Fe3+3(AsO4)3(OH)4 · 10H2OMon. m : Bm
8.DC.57OgdensburgiteCa2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2OOrth. mmm(2/m2/m2/m) : Cmmm
8.DC.60CloncurryiteCu0.5(VO)0.5Al2(PO4)2F2 · 5H2OMon. 2/m : P21/b
8.DC.60Nevadaite(Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2OOrth. mmm(2/m2/m2/m)
8.DC.62KenngottiteMn2+3Fe3+4(PO4)4(OH)6(H2O)2 Mon. 2/m : P2/b
8.DC.67MolinelloiteCu(H2O)(OH)V4+O(V5+O4)Tric. 1 : P1
8.DC.70WhitecapsiteH16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2OHex. 6/m : P63/m
8.DC.75HeimitePbCu2(AsO4)(OH)3 · 2H2OMon. 2/m
8.DC.80LedneviteCu[PO3(OH)] · H2OMon. 2/m : P21/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CésarferreiraiteHide

References for CésarferreiraiteHide

Localities for CésarferreiraiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Minas Gerais
    • Conselheiro Pena
      • Barra do Cuieté
Bermanec et al. (2011)
Scholz et al. (2014)
 
and/or  
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