Arthurite
A valid IMA mineral species
This page kindly sponsored by The Russell Society
About Arthurite
Formula:
CuFe3+2(AsO4)2(OH)2 · 4H2O
Colour:
Apple-green, emerald-green, pale olive-green.
Lustre:
Vitreous
Hardness:
3 - 4
Specific Gravity:
3.2
Crystal System:
Monoclinic
Member of:
Name:
Named in 1964 by Richard J. Davis and Max Hutchinson Hey in honor of Sir Arthur Edward Ian Montagu Russell [November 30, 1878 Folkestone, Kent, England, UK - February 23, 1964 UK], and Mr Arthur William Gerald Kingsbury [June 27, 1906 East Meon, Hampshire, England, UK - August 3, 1968 UK], both English mineralogists and collectors. Sir Arthur Edward Ian Montagu Russell (1878-1964) 6th Baronet, of Swallowfield Park, Reading, Berkshire, was perhaps the greatest British mineral collector of the 20th century. Sir Arthur Russell’s will directed that his collection should be given to the British Museum (Natural History) – now the Natural History Museum. The Russell Society, an organisation for amateur and professional mineralogists, dedicated to British topographical mineralogy, was named in his honor. Arthur Kingsbury, Russell's friend, was an indefatigable field collector and prolific author of mineralogical articles.
Unique Identifiers
Mindat ID:
376
Long-form identifier:
mindat:1:1:376:6
IMA Classification of Arthurite
Approved
IMA Formula:
Cu2+Fe3+2(As5+O4)2(OH)2·4H2O
Approval year:
1964
First published:
1964
Classification of Arthurite
8.DC.15
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
42.11.20.2
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
20.1.16
20 : Arsenates (also arsenates with phosphate, but without other anions)
1 : Arsenates of Cu
20 : Arsenates (also arsenates with phosphate, but without other anions)
1 : Arsenates of Cu
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Atu | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Arthurite
Vitreous
Transparency:
Transparent, Translucent
Colour:
Apple-green, emerald-green, pale olive-green.
Streak:
(not reported)
Hardness:
3 - 4 on Mohs scale
Density:
3.2 g/cm3 (Measured) 3.29 g/cm3 (Calculated)
Optical Data of Arthurite
Type:
Biaxial (+/-)
RI values:
nα = 1.736 nβ = 1.767 nγ = 1.796
2V:
Calculated: 86°
Max. Birefringence:
δ = 0.060
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v
Pleochroism:
Weak
Comments:
X = colorless to pale green; Y = gray-green; Z = olive-green.
Chemistry of Arthurite
Mindat Formula:
CuFe3+2(AsO4)2(OH)2 · 4H2O
Element Weights:
Common Impurities:
P,S
Crystallography of Arthurite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 10.09 Å, b = 9.62 Å, c = 5.55 Å
β = 92.2°
β = 92.2°
Ratio:
a:b:c = 1.049 : 1 : 0.577
Unit Cell V:
538.32 ų (Calculated from Unit Cell)
Z:
2
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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CIF File Best | x | y | z | a | b | c
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0014708 | Arthurite | Keller P, Hess H (1978) Die kristallstruktur von arthurit, CuFe2[(H2O)4|(OH)2|(AsO4)2] Neues Jahrbuch fur Mineralogie, Abhandlungen 133 291-302 | 1978 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.28 Å | (vvs) |
| 4.81 Å | (vvs) |
| 6.97 Å | (vvs) |
| 10.08 Å | (vs) |
| 2.801 Å | (vs) |
| 2.912 Å | (s) |
| 3.44 Å | (ms) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of Arthurite
General Appearance of Type Material:
Apple-green crusts
Place of Conservation of Type Material:
The Natural History Museum, London, England, 1964,74–75 and 1964,80.
Geological Setting of Type Material:
Formed by alteration of arsenopyrite or enargite.
Associated Minerals at Type Locality:
Synonyms of Arthurite
Other Language Names for Arthurite
Varieties of Arthurite
Relationship of Arthurite to other Species
Member of:
Other Members of Arthurite Group:
| Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
| Cobaltarthurite | CoFe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
| Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
| Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
| Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
| 'UKI-2006-(PO:AlCuFeH)' | Fe2+Al3+2(PO4)2(OH)2 · 4H2O | |
| 'UM2006-27-PO:FeHZn' | ZnFe3+2(PO4)2(OH)2 · 4H2O | Mon. |
| Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Common Associates
Associations Based on Photo Data:
| 65 photos of Arthurite associated with Pharmacosiderite | KFe3+4(AsO4)3(OH)4 · 6-7H2O |
| 50 photos of Arthurite associated with Scorodite | Fe3+AsO4 · 2H2O |
| 15 photos of Arthurite associated with Olivenite | Cu2(AsO4)(OH) |
| 11 photos of Arthurite associated with Quartz | SiO2 |
| 9 photos of Arthurite associated with Chenevixite | Cu2Fe3+2(AsO4)2(OH)4 |
| 6 photos of Arthurite associated with Bobierrite | Mg3(PO4)2 · 8H2O |
| 6 photos of Arthurite associated with Wavellite | Al3(PO4)2(OH)3 · 5H2O |
| 6 photos of Arthurite associated with Cuprite | Cu2O |
| 5 photos of Arthurite associated with Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O |
| 3 photos of Arthurite associated with Bariopharmacosiderite | Ba0.5Fe3+4(AsO4)3(OH)4 · 5H2O |
Related Minerals - Strunz-mindat Grouping
| 8.DC. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O |
| 8.DC. | Césarferreiraite | Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O |
| 8.DC. | Ferrivauxite | Fe3+Al2(PO4)2(OH)3 · 5H2O |
| 8.DC. | Ianbruceite | Zn2(AsO4)(OH) · 3H2O |
| 8.DC.05 | Nissonite | Cu2Mg2(PO4)2(OH)2 · 5H2O |
| 8.DC.07 | Euchroite | Cu2(AsO4)(OH) · 3H2O |
| 8.DC.10 | Legrandite | Zn2(AsO4)(OH) · H2O |
| 8.DC.12 | Strashimirite | Cu8(AsO4)4(OH)4 · 5H2O |
| 8.DC.15 | Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | 'UM2006-27-PO:FeHZn' | ZnFe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | 'UKI-2006-(PO:AlCuFeH)' | Fe2+Al3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Cobaltarthurite | CoFe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.15 | Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.15 | Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.17 | Kleemanite | ZnAl2(PO4)2(OH)2 · 3H2O |
| 8.DC.20 | Magnesiobermanite | MgMn3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.20 | Bermanite | Mn2+Mn3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.20 | Coralloite | Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.22 | Kovdorskite | Mg2(PO4)(OH) · 3H2O |
| 8.DC.25 | Zincostrunzite | ZnFe3+2(PO4)2(OH)2 · 6.5H2O |
| 8.DC.25 | Metavauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.25 | Metavivianite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
| 8.DC.25 | Ferristrunzite | Fe3+Fe3+2(PO4)2(OH)3 · 5H2O |
| 8.DC.25 | Strunzite | Mn2+Fe3+2(PO4)2(OH)2 · 6H2O |
| 8.DC.25 | Ferrostrunzite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
| 8.DC.27 | Beraunite | Fe3+6(PO4)4O(OH)4 · 6H2O |
| 8.DC.27 | Tvrdýite | Fe2+Fe3+2Al3(PO4)4(OH)5(H2O)4 · 2H2O |
| 8.DC.27 | Zincoberaunite | ZnFe3+5(PO4)4(OH)5 · 6H2O |
| 8.DC.30 | Maghrebite | MgAl2(AsO4)2(OH)2 · 8H2O |
| 8.DC.30 | Ferrolaueite | Fe2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Ushkovite | MgFe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Laueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Paravauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Sigloite | Fe3+Al2(PO4)2(OH)3 · 7H2O |
| 8.DC.30 | Nordgauite | MnAl2(PO4)2(F,OH)2 · 5H2O |
| 8.DC.30 | Kayrobertsonite | [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O |
| 8.DC.30 | Kummerite | Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Mangangordonite | Mn2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Stewartite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Gordonite | MgAl2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Kastningite | (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Pseudolaueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.32 | Kamarizaite | Fe3+3(AsO4)2(OH)3 · 3H2O |
| 8.DC.32 | Tinticite | Fe3+3(PO4)2(OH)3 · 3H2O |
| 8.DC.35 | Vauxite | Fe2+Al2(PO4)2(OH)2 · 6H2O |
| 8.DC.37 | Vantasselite | Al4(PO4)3(OH)3 · 9H2O |
| 8.DC.40 | Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O |
| 8.DC.45 | Souzalite | Mg3Al4(PO4)4(OH)6 · 2H2O |
| 8.DC.45 | Gormanite | (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O |
| 8.DC.47 | Kingite | Al3(PO4)2F2(OH) · 7H2O |
| 8.DC.50 | Allanpringite | Fe3+3(PO4)2(OH)3 · 5H2O |
| 8.DC.50 | Fluorwavellite | Al3(PO4)2(OH)2F · 5H2O |
| 8.DC.50 | Wavellite | Al3(PO4)2(OH)3 · 5H2O |
| 8.DC.52 | Kribergite | Al5(PO4)3(SO4)(OH)4 · 4H2O |
| 8.DC.55 | Mapimite | Zn2Fe3+3(AsO4)3(OH)4 · 10H2O |
| 8.DC.57 | Ogdensburgite | Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O |
| 8.DC.60 | Cloncurryite | Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O |
| 8.DC.60 | Nevadaite | (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O |
| 8.DC.62 | Kenngottite | Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 |
| 8.DC.67 | Molinelloite | Cu(H2O)(OH)V4+O(V5+O4) |
| 8.DC.70 | Whitecapsite | H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O |
| 8.DC.75 | Heimite | PbCu2(AsO4)(OH)3 · 2H2O |
| 8.DC.80 | Lednevite | Cu[PO3(OH)] · H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Arthurite
mindat.org URL:
https://www.mindat.org/min-376.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Arthurite
Reference List:
Davis, R. J., Hey, M. H. (1964) Arthurite, a new copper—iron arsenate from Cornwall. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (266) 937-941 doi:10.1180/minmag.1964.033.266.01
Clark, A.H., Sillitoe, R.H. (1969) Arthurite from Potrerillos, Atacama Province, Chile. Mineralogical Magazine, 37 (288) 519-520 doi:10.1180/minmag.1969.037.288.14
Davis, R. J., Hey, M. H. (1969) The cell-contents of arthurite redetermined. Mineralogical Magazine, 37 (288) 520-521 doi:10.1180/minmag.1969.037.288.15
Fleischer, M.; Nickel, E.H. (1970) New Minerals Names. American Mineralogist, 55 (9-10). p.1810-1818.
Frost, Ray L., Duong, L., Martens, W. (2003) Molecular assembly in secondary minerals – Raman spectroscopy of the arthurite group species arthurite and whitmoreite. Neues Jahrbuch für Mineralogie - Monatshefte, 2003 (5) 223-240 doi:10.1127/0028-3649/2003/2003-0223
Palmer, Sara J., Frost, Ray L. (2011) The structure of the mineral arthurite (AsO4,PO4,SO4)2(O,OH)2·4H2O – A Raman spectroscopic study. Journal of Molecular Structure, 994 (1) 283-288 doi:10.1016/j.molstruc.2011.03.034
Localities for Arthurite
Showing 48 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| Anthony et al. (2000) +1 other reference |
Austria | |
| Hackenberg (2003) |
Chile | |
| SEM-EDS by Joy Desor |
| Samples analysed by Dr. Jochen Schlüter (Hamburg University) |
| Anthony et al. (2000) |
| maurizio dini collection - analysed ... |
Czech Republic | |
| www.researchgate.net (n.d.) +2 other references |
France | |
| Lebocey et al. (2010) |
| Queneau (n.d.) |
| Henderson (1994) +1 other reference |
Germany | |
| Walenta (1992) |
| Wittern (2001) |
| Wittern (2001) +1 other reference |
Greece | |
| Rieck (n.d.) |
| |
| Rieck (1999) | |
| |
Hungary | |
| HOM Collection-Szakáll S.-2010 |
Italy | |
| Fernando Caboni et al. (2024) |
| Fernando Caboni et al. (2024) | |
| Orlandi et al. (2005) |
| Ferretti et al. (2018) |
| Ferretti et al. (2019) |
| Domenico Saccardo (2019) |
Namibia | |
| von Bezing et al. (2016) |
Portugal | |
| Schnorrer-Köhler et al. (1991) |
Russia | |
| Kostin (2021) |
| Pavel M. Kartashov (n.d.) |
Spain | |
| Sintes et al. (2025) |
| Calvo (2015) | |
| García Guirado (2016) |
| Ko Jansen collection |
| Borja Sainz de Baranda et al. (2003) |
| Viñals et al. (2007) |
UK (TL) | |
| Davis et al. (1964) +1 other reference |
| Golley et al. (1995) +2 other references | |
| U. Kolitsch (X-ray powder diffraction) +2 other references |
| Golley et al. (1995) +1 other reference |
USA | |
| Waisman (1992) +1 other reference |
| The Minerals of Rhyolite Pass |
| Wise (1978) +2 other references |
| - (n.d.) +1 other reference | |
| Roberts et al. (1965) |
| Thorne (n.d.) |
| Thorne (n.d.) | |
| SEM-EDS analyzed by Kerry Day | |
| Collected by and in the collection of ... | |
| Anthony et al. (2000) |
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Majuba Hill Mine, Antelope Mining District, Pershing County, Nevada, USA