Tinticite
A valid IMA mineral species - grandfathered
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About Tinticite
Formula:
Fe3+3(PO4)2(OH)3 · 3H2O
Colour:
Creamy white with yellowish or brownish tint, bright ocher-yellow
Lustre:
Dull
Hardness:
2½
Specific Gravity:
2.8 - 2.94
Crystal System:
Triclinic
Name:
Named after its discovery locality, a cave near the Tintic Standard Mine, East Tintic District, Dividend, Utah, USA.
Type Locality:
Isostructural with:
The phosphate analogue of kamarizaite.
Structurally related to afmite.
Chemically similar to allanpringite, santabarbaraite; further relation to mixed-valence Fe phosphates like beraunite, ferristrunzite, giniite, and others.
Structure details (Kolitsch et al., 2016): (1) 3 octahedrally coordinated (O) Fe(Al) sites, 2 tetrahedrally coordinated (T) As sites; (2) zigzag chains (along [1-10]) of dimers formed by 2 edge-sharing FeO6 octahedra, that corner-link to another octahedron; (3) mixed O-T framework formed by corner-linking of chains and tetrahedra; (4) layering || (001); (5) channels along [010].
Structurally related to afmite.
Chemically similar to allanpringite, santabarbaraite; further relation to mixed-valence Fe phosphates like beraunite, ferristrunzite, giniite, and others.
Structure details (Kolitsch et al., 2016): (1) 3 octahedrally coordinated (O) Fe(Al) sites, 2 tetrahedrally coordinated (T) As sites; (2) zigzag chains (along [1-10]) of dimers formed by 2 edge-sharing FeO6 octahedra, that corner-link to another octahedron; (3) mixed O-T framework formed by corner-linking of chains and tetrahedra; (4) layering || (001); (5) channels along [010].
Unique Identifiers
Mindat ID:
3970
Long-form identifier:
mindat:1:1:3970:9
IMA Classification of Tinticite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Fe3+3(PO4)2(OH)3·3H2O
Classification of Tinticite
8.DC.32
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
42.12.4.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
12 : (AB)4(XO4)3Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
12 : (AB)4(XO4)3Zq·xH2O
19.13.7
19 : Phosphates
13 : Phosphates of Fe alone
19 : Phosphates
13 : Phosphates of Fe alone
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ttc | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Tinticite
Dull
Transparency:
Translucent
Colour:
Creamy white with yellowish or brownish tint, bright ocher-yellow
Hardness:
2½ on Mohs scale
Density:
2.8 - 2.94 g/cm3 (Measured) 2.97 g/cm3 (Calculated)
Optical Data of Tinticite
Type:
Biaxial
RI values:
nα = 1.745 nγ = 1.7455
Max. Birefringence:
δ = 0.001
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Dispersion:
strong
Chemistry of Tinticite
Mindat Formula:
Fe3+3(PO4)2(OH)3 · 3H2O
Element Weights:
Elements listed:
Common Impurities:
V,S,As
Crystallography of Tinticite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.646(2) Å, b = 7.962(2) Å, c = 9.998(2) Å
α = 67.87(2)°, β = 76.06(2)°, γ = 64.06(2)°
α = 67.87(2)°, β = 76.06(2)°, γ = 64.06(2)°
Ratio:
a:b:c = 0.96 : 1 : 1.256
Unit Cell V:
504.9 ų
Morphology:
Thick clay-like coatings or fine-grained massive nodules composed of platy crystals to 1.5 μm.
Comment:
Originally assumed to have point group 2/m, m, or 2, with space group P2/m, Pm, or P2. Orthorhombic symmetry was also proposed.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0006835 | Tinticite | Rius J, Louer D, Louer M, Gali S, Melgarejo J C (2000) Structure solution from powder data of the phosphate hydrate tinticite European Journal of Mineralogy 12 581-588 | 2000 | Rocabruna mines, Bruguers, Barcelona, Catalonia, Spain | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.604 Å | (40) |
| 3.950 Å | (95) |
| 3.307 Å | (100) |
| 3.027 Å | (95) |
| 2.984 Å | (60) |
| 2.361 Å | (40) |
| 1.946 Å | (40) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47c : [Carbonates, phosphates, borates, nitrates] | |
| Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere | <0.6 |
| 52 : Guano- and urine-derived minerals | <0.4 |
Geological Setting:
Rocks containing apatite and jarosite
Type Occurrence of Tinticite
General Appearance of Type Material:
Dense, earthy to porcelainous masses.
Place of Conservation of Type Material:
The Natural History Museum, London, England: #1986,61.
The U.S. National Museum of Natural History, Washington, D.C., USA: #105407, #105609.
The U.S. National Museum of Natural History, Washington, D.C., USA: #105407, #105609.
Geological Setting of Type Material:
Interaction of phosphatic solutions derived from bat guano reacting on oxidizing pyrite in a cave.
Associated Minerals at Type Locality:
Other Language Names for Tinticite
Common Associates
Associations Based on Photo Data:
| 10 photos of Tinticite associated with Variscite | AlPO4 · 2H2O |
| 7 photos of Tinticite associated with Quartz | SiO2 |
| 6 photos of Tinticite associated with Meurigite-K | KFe3+8(PO4)6(OH)7 · 6.5H2O |
| 6 photos of Tinticite associated with Calcioferrite | Ca4MgFe3+4(PO4)6(OH)4 · 12H2O |
| 5 photos of Tinticite associated with Montgomeryite | Ca4MgAl4(PO4)6(OH)4 · 12H2O |
| 3 photos of Tinticite associated with Fluorapatite | Ca5(PO4)3F |
| 3 photos of Tinticite associated with Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O |
| 3 photos of Tinticite associated with Goethite | Fe3+O(OH) |
| 2 photos of Tinticite associated with Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O |
| 2 photos of Tinticite associated with Jarosite | KFe3+3(SO4)2(OH)6 |
Related Minerals - Strunz-mindat Grouping
| 8.DC. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O |
| 8.DC. | Césarferreiraite | Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O |
| 8.DC. | Ferrivauxite | Fe3+Al2(PO4)2(OH)3 · 5H2O |
| 8.DC. | Ianbruceite | Zn2(AsO4)(OH) · 3H2O |
| 8.DC.05 | Nissonite | Cu2Mg2(PO4)2(OH)2 · 5H2O |
| 8.DC.07 | Euchroite | Cu2(AsO4)(OH) · 3H2O |
| 8.DC.10 | Legrandite | Zn2(AsO4)(OH) · H2O |
| 8.DC.12 | Strashimirite | Cu8(AsO4)4(OH)4 · 5H2O |
| 8.DC.15 | Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | 'UM2006-27-PO:FeHZn' | ZnFe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | 'UKI-2006-(PO:AlCuFeH)' | Fe2+Al3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Cobaltarthurite | CoFe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.15 | Arthurite | CuFe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.15 | Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.15 | Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.17 | Kleemanite | ZnAl2(PO4)2(OH)2 · 3H2O |
| 8.DC.20 | Magnesiobermanite | MgMn3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.20 | Bermanite | Mn2+Mn3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.20 | Coralloite | Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.22 | Kovdorskite | Mg2(PO4)(OH) · 3H2O |
| 8.DC.25 | Zincostrunzite | ZnFe3+2(PO4)2(OH)2 · 6.5H2O |
| 8.DC.25 | Metavauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.25 | Metavivianite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
| 8.DC.25 | Ferristrunzite | Fe3+Fe3+2(PO4)2(OH)3 · 5H2O |
| 8.DC.25 | Strunzite | Mn2+Fe3+2(PO4)2(OH)2 · 6H2O |
| 8.DC.25 | Ferrostrunzite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
| 8.DC.27 | Beraunite | Fe3+6(PO4)4O(OH)4 · 6H2O |
| 8.DC.27 | Tvrdýite | Fe2+Fe3+2Al3(PO4)4(OH)5(H2O)4 · 2H2O |
| 8.DC.27 | Zincoberaunite | ZnFe3+5(PO4)4(OH)5 · 6H2O |
| 8.DC.30 | Maghrebite | MgAl2(AsO4)2(OH)2 · 8H2O |
| 8.DC.30 | Ferrolaueite | Fe2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Ushkovite | MgFe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Laueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Paravauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Sigloite | Fe3+Al2(PO4)2(OH)3 · 7H2O |
| 8.DC.30 | Nordgauite | MnAl2(PO4)2(F,OH)2 · 5H2O |
| 8.DC.30 | Kayrobertsonite | [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O |
| 8.DC.30 | Kummerite | Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Mangangordonite | Mn2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Stewartite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Gordonite | MgAl2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Kastningite | (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Pseudolaueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.32 | Kamarizaite | Fe3+3(AsO4)2(OH)3 · 3H2O |
| 8.DC.35 | Vauxite | Fe2+Al2(PO4)2(OH)2 · 6H2O |
| 8.DC.37 | Vantasselite | Al4(PO4)3(OH)3 · 9H2O |
| 8.DC.40 | Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O |
| 8.DC.45 | Souzalite | Mg3Al4(PO4)4(OH)6 · 2H2O |
| 8.DC.45 | Gormanite | (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O |
| 8.DC.47 | Kingite | Al3(PO4)2F2(OH) · 7H2O |
| 8.DC.50 | Allanpringite | Fe3+3(PO4)2(OH)3 · 5H2O |
| 8.DC.50 | Fluorwavellite | Al3(PO4)2(OH)2F · 5H2O |
| 8.DC.50 | Wavellite | Al3(PO4)2(OH)3 · 5H2O |
| 8.DC.52 | Kribergite | Al5(PO4)3(SO4)(OH)4 · 4H2O |
| 8.DC.55 | Mapimite | Zn2Fe3+3(AsO4)3(OH)4 · 10H2O |
| 8.DC.57 | Ogdensburgite | Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O |
| 8.DC.60 | Cloncurryite | Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O |
| 8.DC.60 | Nevadaite | (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O |
| 8.DC.62 | Kenngottite | Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 |
| 8.DC.67 | Molinelloite | Cu(H2O)(OH)V4+O(V5+O4) |
| 8.DC.70 | Whitecapsite | H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O |
| 8.DC.75 | Heimite | PbCu2(AsO4)(OH)3 · 2H2O |
| 8.DC.80 | Lednevite | Cu[PO3(OH)] · H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tinticite
mindat.org URL:
https://www.mindat.org/min-3970.html
Please feel free to link to this page.
Please feel free to link to this page.
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Mineral Dealers:
References for Tinticite
Reference List:
Stringham, Bronson (1946) Tinticite, a new mineral from Utah. American Mineralogist, 31 (7-8) 395-400
Melgarejo, J.C., Galí, S. and Ayora, C. (1988): Tinticite: new structural and chemical data. Neues Jahrbuch für Mineralogie, Monatshefte 1988, 446-453.[Abs. in American Mineralogist (1989): 74: 1404]
Rius, Jordi, Louër, Daniel, Louër, Michèle, Galí, Salvador, Melgarejo, Joan Carles (2000) Structure solution from powder data of the phosphate hydrate tinticite. European Journal of Mineralogy, 12 (3) 581-588 doi:10.1127/0935-1221/2000/0012-0581
Localities for Tinticite
Showing 25 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| Peter Elliott |
| Peter Elliott |
Germany | |
| Walenta (1999) |
| Klaus Arnold Collection. Identified by ... |
| Blaß (2002) |
| Pestel et al. (2007) +1 other reference |
Japan | |
| Suo et al. (2004) |
| SAKURAI et al. (1991) |
Spain | |
| Camprubí et al. (Catalunya) |
| Kolitsch et al. (2014) +2 other references | |
| Sigurd Stordal collection +2 other references | |
| Col. Agustin Agudo Espinosa. |
| Mineralogistes de Catalunya (1997) |
| Joan Abella i Creus (Joanabellacreus@gmail.com) |
Sweden | |
| Thorin (1989) +3 other references |
USA | |
| Henry Barwood - confirmed by Tony Kampf ... |
| Newmont Mining Corporation |
| Jensen et al. (1995) |
| Silver Coin Mine. Compact Disc. Paul ... |
| A Listing of North Carolina Minerals | |
| Anthony et al. (2000) |
| Bullock (1981) |
| Stringham (1946) +2 other references |
| Dietrich (1990) |
Uzbekistan | |
| Mineraly Uzbekistana (Minerals of the Uzbekistan) |
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The
Elvira Mine, Bruguers, Gavà, Baix Llobregat, Barcelona, Catalonia, Spain