Metavivianite
A valid IMA mineral species
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About Metavivianite
Formula:
Fe2+Fe3+2(PO4)2(OH)2 · 6H2O
Colour:
Dark blue to blue-black; dark green to green-black
Lustre:
Sub-Vitreous, Resinous, Greasy, Dull
Hardness:
1½ - 2
Specific Gravity:
2.69 (Calculated)
Crystal System:
Triclinic
Name:
Named by C. Ritz, Eric J. Essene, and Donald R. Peacor in 1974 for its structural relationship to vivianite.
Type Locality:
Dimorph of:
Isostructural with:
Unique Identifiers
Mindat ID:
2695
Long-form identifier:
mindat:1:1:2695:2
IMA Classification of Metavivianite
Approved
IMA Formula:
Fe2+Fe3+2(PO4)2(OH)2·6H2O
Approval year:
1973
First published:
1974
Classification of Metavivianite
8.DC.25
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
40.11.9.4
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
11 :
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
11 :
19.13.12
19 : Phosphates
13 : Phosphates of Fe alone
19 : Phosphates
13 : Phosphates of Fe alone
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Mviv | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Pronunciation of Metavivianite
Pronunciation:
| Play | Recorded by | Country |
|---|---|---|
| Jolyon Ralph | United Kingdom |
Physical Properties of Metavivianite
Sub-Vitreous, Resinous, Greasy, Dull
Transparency:
Translucent
Colour:
Dark blue to blue-black; dark green to green-black
Streak:
Blue or greenish blue
Hardness:
1½ - 2 on Mohs scale
Tenacity:
Sectile
Cleavage:
Perfect
{110}
{110}
Density:
2.69 g/cm3 (Calculated)
Optical Data of Metavivianite
Type:
Biaxial (+)
RI values:
nα = 1.600 - 3 nβ = 1.640 - 3 nγ = 1.685 - 3
2V:
Measured: 85° (5), Calculated: 90°
Birefringence:
0.50
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
very weak
Optical Extinction:
X perpendicular to {010}, Y parallel {110}
Pleochroism:
Visible
Comments:
X blue to blue green, Y,Z yellow green
Chemistry of Metavivianite
Mindat Formula:
Fe2+Fe3+2(PO4)2(OH)2 · 6H2O
Element Weights:
Elements listed:
Crystallography of Metavivianite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Setting:
P1
Cell Parameters:
a = 7.989(1) Å, b = 9.321(2) Å, c = 4.629(1) Å
α = 97.34(1)°, β = 95.96(1)°, γ = 108.59(2)°
α = 97.34(1)°, β = 95.96(1)°, γ = 108.59(2)°
Ratio:
a:b:c = 0.857 : 1 : 0.497
Unit Cell V:
320.18 ų
Z:
1
Morphology:
Bladed crystals, often with irregular acute multiple terminations.
Twinning:
{110}
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0012078 | Metavivianite | Dormann J, Gasperin M, Poullen J F (1982) Etude structurale de la sequence d'oxydation de la vivianite Fe3(PO4)2*8(H2O) Bulletin de Mineralogie 105 147-160 | 1982 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 8.59 Å | (40) |
| 6.71 Å | (100) |
| 4.86 Å | (40) |
| 4.27 Å | (10) |
| 3.97 Å | (30) |
| 3.07 Å | (10) |
| 2.90 Å | (20) |
| 2.77 Å | (30) |
Comments:
ICDD 29-1137
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 24 : Authigenic minerals in terrestrial sediments (see also #17) | |
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47c : [Carbonates, phosphates, borates, nitrates] |
Geological Setting:
Phosphate veins in ironstone
Phosphatic sedimentary units
Phosphatic sedimentary units
Type Occurrence of Metavivianite
General Appearance of Type Material:
Blue black or green black bladed crystals
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 127100.
Geological Setting of Type Material:
Late stage oxidation of vivianite in a granite pegmatite
Associated Minerals at Type Locality:
Synonyms of Metavivianite
Other Language Names for Metavivianite
Dutch:Metavivianiet
German:Metavivianit
Russian:Метавивианит
Simplified Chinese:三斜蓝铁矿
Spanish:Metavivianita
Traditional Chinese:三斜藍鐵礦
Common Associates
Associations Based on Photo Data:
| 19 photos of Metavivianite associated with Santabarbaraite | Fe3+3(PO4)2(OH)3 · 5H2O |
| 11 photos of Metavivianite associated with Vivianite | Fe2+Fe2+2(PO4)2 · 8H2O |
| 6 photos of Metavivianite associated with Siderite | FeCO3 |
| 3 photos of Metavivianite associated with Baryte | BaSO4 |
| 3 photos of Metavivianite associated with 'Limonite' | |
| 2 photos of Metavivianite associated with Berthierine | (Fe2+,Fe3+,Al)3(Si,Al)2O5(OH)4 |
| 1 photo of Metavivianite associated with Triplite | Mn2+2(PO4)F |
| 1 photo of Metavivianite associated with Anglesite | PbSO4 |
| 1 photo of Metavivianite associated with 'Kertschenite' | |
| 1 photo of Metavivianite associated with Kryzhanovskite | (Fe3+,Mn2+)3(PO4)2(OH,H2O)3 |
Related Minerals - Strunz-mindat Grouping
| 8.DC. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O |
| 8.DC. | Césarferreiraite | Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O |
| 8.DC. | Ferrivauxite | Fe3+Al2(PO4)2(OH)3 · 5H2O |
| 8.DC. | Ianbruceite | Zn2(AsO4)(OH) · 3H2O |
| 8.DC.05 | Nissonite | Cu2Mg2(PO4)2(OH)2 · 5H2O |
| 8.DC.07 | Euchroite | Cu2(AsO4)(OH) · 3H2O |
| 8.DC.10 | Legrandite | Zn2(AsO4)(OH) · H2O |
| 8.DC.12 | Strashimirite | Cu8(AsO4)4(OH)4 · 5H2O |
| 8.DC.15 | Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | 'UM2006-27-PO:FeHZn' | ZnFe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | 'UKI-2006-(PO:AlCuFeH)' | Fe2+Al3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Cobaltarthurite | CoFe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.15 | Arthurite | CuFe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.15 | Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.15 | Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.15 | Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.17 | Kleemanite | ZnAl2(PO4)2(OH)2 · 3H2O |
| 8.DC.20 | Magnesiobermanite | MgMn3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.20 | Bermanite | Mn2+Mn3+2(PO4)2(OH)2 · 4H2O |
| 8.DC.20 | Coralloite | Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O |
| 8.DC.22 | Kovdorskite | Mg2(PO4)(OH) · 3H2O |
| 8.DC.25 | Zincostrunzite | ZnFe3+2(PO4)2(OH)2 · 6.5H2O |
| 8.DC.25 | Metavauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.25 | Ferristrunzite | Fe3+Fe3+2(PO4)2(OH)3 · 5H2O |
| 8.DC.25 | Strunzite | Mn2+Fe3+2(PO4)2(OH)2 · 6H2O |
| 8.DC.25 | Ferrostrunzite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
| 8.DC.27 | Beraunite | Fe3+6(PO4)4O(OH)4 · 6H2O |
| 8.DC.27 | Tvrdýite | Fe2+Fe3+2Al3(PO4)4(OH)5(H2O)4 · 2H2O |
| 8.DC.27 | Zincoberaunite | ZnFe3+5(PO4)4(OH)5 · 6H2O |
| 8.DC.30 | Maghrebite | MgAl2(AsO4)2(OH)2 · 8H2O |
| 8.DC.30 | Ferrolaueite | Fe2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Ushkovite | MgFe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Laueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Paravauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Sigloite | Fe3+Al2(PO4)2(OH)3 · 7H2O |
| 8.DC.30 | Nordgauite | MnAl2(PO4)2(F,OH)2 · 5H2O |
| 8.DC.30 | Kayrobertsonite | [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O |
| 8.DC.30 | Kummerite | Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Mangangordonite | Mn2+Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Stewartite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Gordonite | MgAl2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Kastningite | (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O |
| 8.DC.30 | Pseudolaueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
| 8.DC.32 | Kamarizaite | Fe3+3(AsO4)2(OH)3 · 3H2O |
| 8.DC.32 | Tinticite | Fe3+3(PO4)2(OH)3 · 3H2O |
| 8.DC.35 | Vauxite | Fe2+Al2(PO4)2(OH)2 · 6H2O |
| 8.DC.37 | Vantasselite | Al4(PO4)3(OH)3 · 9H2O |
| 8.DC.40 | Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O |
| 8.DC.45 | Souzalite | Mg3Al4(PO4)4(OH)6 · 2H2O |
| 8.DC.45 | Gormanite | (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O |
| 8.DC.47 | Kingite | Al3(PO4)2F2(OH) · 7H2O |
| 8.DC.50 | Allanpringite | Fe3+3(PO4)2(OH)3 · 5H2O |
| 8.DC.50 | Fluorwavellite | Al3(PO4)2(OH)2F · 5H2O |
| 8.DC.50 | Wavellite | Al3(PO4)2(OH)3 · 5H2O |
| 8.DC.52 | Kribergite | Al5(PO4)3(SO4)(OH)4 · 4H2O |
| 8.DC.55 | Mapimite | Zn2Fe3+3(AsO4)3(OH)4 · 10H2O |
| 8.DC.57 | Ogdensburgite | Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O |
| 8.DC.60 | Cloncurryite | Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O |
| 8.DC.60 | Nevadaite | (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O |
| 8.DC.62 | Kenngottite | Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 |
| 8.DC.67 | Molinelloite | Cu(H2O)(OH)V4+O(V5+O4) |
| 8.DC.70 | Whitecapsite | H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O |
| 8.DC.75 | Heimite | PbCu2(AsO4)(OH)3 · 2H2O |
| 8.DC.80 | Lednevite | Cu[PO3(OH)] · H2O |
Fluorescence of Metavivianite
Not fluorescent
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Metavivianite
mindat.org URL:
https://www.mindat.org/min-2695.html
Please feel free to link to this page.
Please feel free to link to this page.
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Mineral Dealers:
References for Metavivianite
Reference List:
Ritz, Charles, Essene, Eric J., Peacor, and Donald R. (1974) Metavivianite, Fe3(PO4)2·8H2O, a new mineral. American Mineralogist, 59 (9-10) 896-899
Cabri, Louis J., Fleischer, Michael, Pabst, Adolf (1981) New Mineral Names. American Mineralogist, 66 (9-10) 1099-1103 p.1103
Dormann, Jean-Louis, Gasperin, Madeleine, Poullen, Jean-François (1982) Étude structurale de la séquence d'oxydation de la vivianite Fe3(PO4)2 • 8 H2O. Bulletin de Minéralogie, 105 (2) 147-160 doi:10.3406/bulmi.1982.7597
Sameshima, T., Henderson, G. S., Black, P. M., Rodgers, K. A. (1985) X-ray diffraction studies of vivianite, metavivianite, and barićite. Mineralogical Magazine, 49 (350) 81-85 doi:10.1180/minmag.1985.049.350.11
Rodgers, K. A. (1986) Metavivianite and kerchenite: a review. Mineralogical Magazine, 50 (358) 687-691 doi:10.1180/minmag.1986.050.358.16
Rodgers, K.A.; Henderson, G.S. (1986) The thermochemistry of some iron phosphate minerals: vivianite, metavivianite, baraćite [sic], ludlamite and vivianite/metavivianite admixtures. Thermochimica Acta, 104. 1-12 doi:10.1016/0040-6031(86)85179-6
Frost, Ray L., Weier, Matt, Lyon, William G. (2004) Metavivianite an intermediate mineral phase between vivianite, and ferro/ferristrunzite – a Raman spectroscopic study. Neues Jahrbuch für Mineralogie - Monatshefte, 2004 (5) 228-240 doi:10.1127/0028-3649/2004/2004-0228
Chukanov, N. V., Scholz, R., Aksenov, S. M., Rastsvetaeva, R. K., Pekov, I. V., Belakovskiy, D. I., Krambrock, K., Paniago, R. M., Righi, A., Martins, R. F., Belotti, F. M., Bermanec, V. (2012) Metavivianite, Fe2+Fe3+2(PO4)2(OH)2·6H2O: new data and formula revision. Mineralogical Magazine, 76 (3) 725-741 doi:10.1180/minmag.2012.076.3.20
Localities for Metavivianite
Showing 37 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Bolivia | |
| Petrov (n.d.) |
| XRD confirmation by Dr. Anthony Kampf. |
Brazil | |
| Baijot et al. (2012) |
Cameroon | |
| Fransolet et al. (1984) |
Canada | |
| Robinson et al. (1992) |
| 150-152. +2 other references | |
Finland | |
| Lahti (1981) |
| Sandström et al. (2009) | |
Germany | |
| XRD and Wet Chemical by Gerhard Möhn |
| Schnorrer-Köhler (1991) |
| Schnorrer (1993) +1 other reference |
| Wittern (2001) |
Italy | |
| Pratesi (1993) +2 other references |
| Pratesi (1993) +2 other references | |
Japan | |
| S. Matsubara (2000) |
Netherlands | |
| T.G. Nijland |
Portugal | |
| Alves (n.d.) |
| DOI: ... +1 other reference |
Russia | |
| Shen et al. (2021) |
Sweden | |
| Gustafsson et al. (1991) |
UK | |
| Cooper et al. (1990) |
| Alysson Rowan collection |
| Alysson Rowan collection |
Ukraine | |
| Geologiya SSSR (The geology of USSR) +1 other reference |
| Abramov (1989) | |
| |
| Arbuzov V.A. et al. (1967) | |
| Popov S.P. (1938) +1 other reference | |
USA | |
| Denicourt +1 other reference |
| Bob Wilken collection |
| |
| Whitmore et al. (2004) | |
| Luetcke (n.d.) |
| Smith et al. (2000) |
| Ritz et al. (1974) +1 other reference |
| Cordua (1998) |
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Kerchenskoe deposit, Kerchenskyi iron ore basin, Kerch Peninsula, Crimea, Ukraine