Stilleite
A valid IMA mineral species - grandfathered
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About Stilleite
Formula:
ZnSe
Colour:
Gray
Lustre:
Metallic
Hardness:
5
Specific Gravity:
5.42
Crystal System:
Isometric
Member of:
Name:
Named after Hans Wilhelm Stille (October 8, 1876, Hanover, Germany – December 26, 1966, Hanover, Germany), German geologist in the field of tectonics.
Unique Identifiers
Mindat ID:
3786
Long-form identifier:
mindat:1:1:3786:6
Similar Names
IMA Classification of Stilleite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Zn2+Se2-
First published:
1956
Classification of Stilleite
2.CB.05a
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2.8.2.2
2 : SULFIDES
8 : AmXp, with m:p = 1:1
2 : SULFIDES
8 : AmXp, with m:p = 1:1
3.4.6
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
4 : Sulphides etc. of Group II metals other than Hg (Mg, Ca, Zn, Cd)
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
4 : Sulphides etc. of Group II metals other than Hg (Mg, Ca, Zn, Cd)
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Sll | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Sll | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Stilleite
Metallic
Transparency:
Translucent, Opaque
Colour:
Gray
Hardness:
5 on Mohs scale
Density:
5.42 g/cm3 (Measured) 5.267 g/cm3 (Calculated)
Optical Data of Stilleite
Type:
Isotropic
RI values:
n = 2.5
Birefringence:
Isotropic minerals have no birefringence
Surface Relief:
Very High
Colour in reflected light:
Gray
Comments:
resembles tetrahedrite without the olive-brown or greenish blue hues.
Chemistry of Stilleite
Mindat Formula:
ZnSe
Elements listed:
Common Impurities:
Hg
Crystallography of Stilleite
Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
F43m
Cell Parameters:
a = 5.667 Å
Unit Cell V:
182.00 ų (Calculated from Unit Cell)
Z:
4
Twinning:
Twin lamellae noted in polished section.
Comment:
Synthetic
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0011535 | Stilleite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237 | 1963 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.273 Å | (100) |
| 2.003 Å | (70) |
| 1.707 Å | (44) |
| 1.1561 Å | (15) |
| 1.299 Å | (13) |
| 1.416 Å | (9) |
| 1.0901 Å | (8) |
Comments:
Synthetic
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Stilleite
General Appearance of Type Material:
Microscopic angular inclusions.
Place of Conservation of Type Material:
No designated type material.
Associated Minerals at Type Locality:
Other Language Names for Stilleite
Relationship of Stilleite to other Species
Member of:
Other Members of Sphalerite Group:
| Browneite | MnS | Iso. 43m : F43m |
| Coloradoite | HgTe | Iso. 43m : F43m |
| Hawleyite | CdS | Iso. 43m : F43m |
| Ishiharaite | (Cu,Ga,Fe,In,Zn)S | Iso. 43m : F43m |
| Metacinnabar | HgS | Iso. 43m : F43m |
| Rudashevskyite | (Fe,Zn)S | Iso. 43m : F43m |
| Sphalerite | ZnS | Iso. 43m : F43m |
| Tiemannite | HgSe | Iso. 43m : F43m |
Common Associates
Associations Based on Photo Data:
| 1 photo of Stilleite associated with Umangite | Cu3Se2 |
| 1 photo of Stilleite associated with Klockmannite | CuSe |
Related Minerals - Strunz-mindat Grouping
| 2.CB. | Richardsite | Zn2CuGaS4 |
| 2.CB. | Okruginite | Cu2SnSe3 |
| 2.CB. | Hanswilkeite | KFeS2 |
| 2.CB. | Auroselenide | AuSe |
| 2.CB. | Ruizhongite | (Ag2◻)Pb3Ge2S8 |
| 2.CB. | Agmantinite | Ag2MnSnS4 |
| 2.CB. | Tolstykhite | Au3S4Te6 |
| 2.CB. | Gachingite | Au(Te1-xSex) |
| 2.CB.05a | Hawleyite | CdS |
| 2.CB.05 | 'UM1998-15-S:CuFeZn' | Cu2Fe3Zn5S10 |
| 2.CB.05a | Coloradoite | HgTe |
| 2.CB.05a | Metacinnabar | HgS |
| 2.CB.05a | Tiemannite | HgSe |
| 2.CB.05a | Sphalerite | ZnS |
| 2.CB.05b | Sakuraiite | (Cu,Zn,Fe)3(In,Sn)S4 |
| 2.CB.05c | Polhemusite | (Zn,Hg)S |
| 2.CB.05a | Rudashevskyite | (Fe,Zn)S |
| 2.CB.05a | Ishiharaite | (Cu,Ga,Fe,In,Zn)S |
| 2.CB.07a | 'Unnamed (Cu-Mn-Sn Sulphide)' | Cu2MnSnS4 |
| 2.CB.07a | Shenzhuangite | NiFeS2 |
| 2.CB.10b | Talnakhite | Cu9(Fe,Ni)8S16 |
| 2.CB.10b | Haycockite | Cu4Fe5S8 |
| 2.CB.10a | Lenaite | AgFeS2 |
| 2.CB.10a | Gallite | CuGaS2 |
| 2.CB.10a | Roquesite | CuInS2 |
| 2.CB.10a | Eskebornite | CuFeSe2 |
| 2.CB.10a | 'UM1984-30-S:CuFeSn' | Cu2Fe2Sn3S7 |
| 2.CB.10c | Omariniite | Cu8Fe2ZnGe2S12 |
| 2.CB.10a | Chalcopyrite | CuFeS2 |
| 2.CB.10a | 'Unnamed (Cu-Zn-In Sulphide)' | CuZn2InS4 |
| 2.CB.10b | Mooihoekite | Cu9Fe9S16 |
| 2.CB.10a | Laforêtite | AgInS2 |
| 2.CB.10b | Putoranite | Cu1.1Fe1.2S2 |
| 2.CB.15a | Velikite | Cu2HgSnS4 |
| 2.CB.15c | 'UM2006-11-S:CuFeGeZn' | Cu8(Fe,Zn)3Ge2S12 (?) |
| 2.CB.15a | Hocartite | Ag2(Fe2+,Zn)SnS4 |
| 2.CB.15a | Kësterite | Cu2ZnSnS4 |
| 2.CB.15a | Pirquitasite | Ag2ZnSnS4 |
| 2.CB.15a | Stannite | Cu2FeSnS4 |
| 2.CB.15c | Stannoidite | Cu+6Cu2+2(Fe2+,Zn)3Sn2S12 |
| 2.CB.15b | Mohite | Cu2SnS3 |
| 2.CB.15a | Černýite | Cu2CdSnS4 |
| 2.CB.15a | Idaite | Cu5FeS6 |
| 2.CB.15a | Ferrokësterite | Cu2FeSnS4 |
| 2.CB.15a | Kuramite | Cu3SnS4 |
| 2.CB.17a v | 'Arsenic-bearing Renierite' | Cu11GeAsFe4S16 |
| 2.CB.20 | Mawsonite | Cu6Fe2SnS8 |
| 2.CB.20 | Chatkalite | Cu6FeSn2S8 |
| 2.CB.30 | 'Frieseite' | Ag2Fe5S8 (?) |
| 2.CB.30 | Nekrasovite | Cu26V2(Sn,As,Sb)6S32 |
| 2.CB.30 | 'Argyropyrite' | near Ag2Fe7S11 |
| 2.CB.30 | Maikainite | Cu20(Fe,Cu)6Mo2Ge6S32 |
| 2.CB.30 | Colusite | Cu13VAs3S16 |
| 2.CB.30 | Germanite | Cu13Fe2Ge2S16 |
| 2.CB.30 | Germanocolusite | Cu26V2(Ge,As)6S32 |
| 2.CB.30 | Stibiocolusite | Cu13V(Sb,Sn,As)3S16 |
| 2.CB.30 | Ovamboite | Cu20(Fe,Cu,Zn)6W2Ge6S32 |
| 2.CB.35a | Morozeviczite | (Pb,Fe)3Ge1-xS4 |
| 2.CB.35a | Renierite | (Cu+,Zn)11Fe4(Ge4+,As5+)2S16 |
| 2.CB.35a | Hemusite | Cu6SnMoS8 |
| 2.CB.35b | Catamarcaite | Cu6GeWS8 |
| 2.CB.35a | Vinciennite | Cu+7Cu2+3Fe2+2Fe3+2Sn(As,Sb)S16 |
| 2.CB.35a | Kiddcreekite | Cu6SnWS8 |
| 2.CB.35a | Polkovicite | (Fe,Pb)3(Ge,Fe)1-xS4 |
| 2.CB.40 | Lautite | CuAsS |
| 2.CB.42 | Lingbaoite | AgTe3 |
| 2.CB.45 | Cadmoselite | CdSe |
| 2.CB.45 | Rambergite | MnS |
| 2.CB.45 | Buseckite | (Fe,Zn,Mn)S |
| 2.CB.45 | Maletoyvayamite | Au3Se4Te6 |
| 2.CB.45 | Greenockite | CdS |
| 2.CB.45 | Wurtzite | (Zn,Fe)S |
| 2.CB.47 | Murchisite | Cr5S6 |
| 2.CB.50 | 'Zincselenide' | ZnSe |
| 2.CB.50 | Wassonite | TiS |
| 2.CB.52 | 'Dzhezkazganite' | ReMoCu2PbS6 ? |
| 2.CB.55b | Isocubanite | CuFe2S3 |
| 2.CB.55a | Cubanite | CuFe2S3 |
| 2.CB.60 | Raguinite | TlFeS2 |
| 2.CB.60 | Picotpaulite | TlFe2S3 |
| 2.CB.65 | Argentopyrite | AgFe2S3 |
| 2.CB.65 | Sternbergite | AgFe2S3 |
| 2.CB.70 | Sulvanite | Cu3VS4 |
| 2.CB.75 | Vulcanite | CuTe |
| 2.CB.80 | Empressite | AgTe |
| 2.CB.85 | Muthmannite | AuAgTe2 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Stilleite
mindat.org URL:
https://www.mindat.org/min-3786.html
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References for Stilleite
Reference List:
Zacharissen, William (1926) Über die Kristallstrukturen der Selenide von Beryllium, Zink, Cadmium und Quecksilber. Zeitschrift für Physikalische Chemie, 124 (1). 436-448 doi:10.1515/zpch-1926-12434
Localities for Stilleite
Showing 10 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Anthony et al. (1990) |
| Simon et al. (1997) |
| Simon et al. (1997) | |
| de Brodtkorb +4 other references | |
Canada | |
| Bamburak et al. (parts of NTS 62N1, 16, 63C1) +1 other reference |
DR Congo (TL) | |
| Ramdohr (1956) +2 other references |
Germany | |
| Weiß (1990) |
| Wittern (2001) |
Jordan | |
| Fleurance et al. (2013) |
Mongolia | |
| Areva Mines SA |
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The
Shinkolobwe Mine, Shinkolobwe, Kambove Territory, Haut-Katanga, DR Congo