Sulvanite
A valid IMA mineral species - grandfathered
This page is currently not sponsored. Click here to sponsor this page.
About Sulvanite
Formula:
Cu3VS4
Colour:
Grey in visible light, but cream-gold, bronze gold-yellow in polished section
Lustre:
Metallic, Sub-Metallic
Hardness:
3½
Crystal System:
Isometric
Name:
The name reflects its sulfur and vanadium contents.
Member of Germanite Group?
According to Cressey et al. (1993), four metal valencies characterize sulvanite: Cu+, Cu2+, V2+ (!), and V5+. This could make sulvanite the first known mineral species with divalent vanadium (compare dellagiustaite).
According to Cressey et al. (1993), four metal valencies characterize sulvanite: Cu+, Cu2+, V2+ (!), and V5+. This could make sulvanite the first known mineral species with divalent vanadium (compare dellagiustaite).
Unique Identifiers
Mindat ID:
3827
Long-form identifier:
mindat:1:1:3827:6
Similar Names
| Sultanite | A synonym of Diaspore | |
| Sylvanite | A valid IMA mineral species - grandfathered | AgAuTe4 |
| Sylvanite (of Kirwan) | A synonym of Native Tellurium | |
| Sylvinite | A rock subtype | |
| Sylvite | A valid IMA mineral species - grandfathered | KCl |
IMA Classification of Sulvanite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Cu2+3V3+S2-4
First published:
1900
Type description reference:
Classification of Sulvanite
2.CB.70
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
3.2.3.1
3 : SULFOSALTS
2 : ø = 4
3 : SULFOSALTS
2 : ø = 4
6.4.1
6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
4 : Sulphovanadates
6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
4 : Sulphovanadates
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Sul | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Sulvanite
Metallic, Sub-Metallic
Transparency:
Opaque
Colour:
Grey in visible light, but cream-gold, bronze gold-yellow in polished section
Streak:
Black
Hardness:
3½ on Mohs scale
Optical Data of Sulvanite
Type:
Isotropic
Anisotropism:
Weak (rarely)
Reflectivity:
| Wavelength | R1 (%) |
|---|---|
| 400nm | 28.1% |
| 420nm | 26.4% |
| 440nm | 24.4% |
| 460nm | 24.1% |
| 480nm | 27.6% |
| 500nm | 31.4% |
| 520nm | 30.6% |
| 540nm | 28.4% |
| 560nm | 27.7% |
| 580nm | 29.4% |
| 600nm | 30.0% |
| 620nm | 30.8% |
| 640nm | 29.5% |
| 660nm | 27.0% |
| 680nm | 26.7% |
| 700nm | 25.9% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 31.4%.
Colour in reflected light:
Pale yellow
Chemistry of Sulvanite
Mindat Formula:
Cu3VS4
Element Weights:
Elements listed:
Common Impurities:
As,Cu,Zn
Crystallography of Sulvanite
Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
P43m
Cell Parameters:
a = 5.3912(7) Å
Unit Cell V:
156.70 ų (Calculated from Unit Cell)
Z:
1
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0000146 | Sulvanite | Trojer F J (1966) Refinement of the structure of sulvanite American Mineralogist 51 890-894 | ![]() | 1966 | 0 | 293 | |
| 0017516 | Sulvanite | Lundqvist D, Westgren A (1936) The crystal structure of CuVS4 _cod_database_code 1010634 Svensk Kemisk Tidskrift 48 241-243 | 1936 | 0 | 293 | ||
| 0018085 | Sulvanite | Pauling L, Hultgren R (1932) The crystal structure of sulvanite Cu3 V S4 _cod_database_code 1011219 Zeitschrift fur Kristallographie 84 204-212 | 1932 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 5.44 Å | (100) |
| 3.12 Å | (50) |
| 2.40 Å | (40) |
| 1.910 Å | (80) |
| 1.804 Å | (30) |
| 1.634 Å | (40) |
| 1.101 Å | (40) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Sulvanite
General Appearance of Type Material:
Massive
Associated Minerals at Type Locality:
Other Language Names for Sulvanite
Varieties of Sulvanite
| Ge-Sn-Sulvanite | A variety of sulvanite with significant contents of both germanium (up to 6 wt.-%) and tin (up to 3.6 wt.-%). |
Relationship of Sulvanite to other Species
Forms a series with:
Common Associates
Associations Based on Photo Data:
| 49 photos of Sulvanite associated with Calcite | CaCO3 |
| 34 photos of Sulvanite associated with Malachite | Cu2(CO3)(OH)2 |
| 25 photos of Sulvanite associated with Chalcocite | Cu2S |
| 20 photos of Sulvanite associated with Volborthite | Cu3(V2O7)(OH)2 · 2H2O |
| 18 photos of Sulvanite associated with Covellite | CuS |
| 16 photos of Sulvanite associated with Tangeite | CaCu(VO4)(OH) |
| 16 photos of Sulvanite associated with Goethite | Fe3+O(OH) |
| 12 photos of Sulvanite associated with Quartz | SiO2 |
| 7 photos of Sulvanite associated with Chrysocolla | Cu2-xAlx(H2-xSi2O5)(OH)4 · nH2O, x < 1 |
| 5 photos of Sulvanite associated with Vésigniéite | BaCu3(VO4)2(OH)2 |
Related Minerals - Strunz-mindat Grouping
| 2.CB. | Richardsite | Zn2CuGaS4 |
| 2.CB. | Okruginite | Cu2SnSe3 |
| 2.CB. | Hanswilkeite | KFeS2 |
| 2.CB. | Auroselenide | AuSe |
| 2.CB. | Ruizhongite | (Ag2◻)Pb3Ge2S8 |
| 2.CB. | Agmantinite | Ag2MnSnS4 |
| 2.CB. | Tolstykhite | Au3S4Te6 |
| 2.CB. | Gachingite | Au(Te1-xSex) |
| 2.CB.05a | Hawleyite | CdS |
| 2.CB.05 | 'UM1998-15-S:CuFeZn' | Cu2Fe3Zn5S10 |
| 2.CB.05a | Coloradoite | HgTe |
| 2.CB.05a | Metacinnabar | HgS |
| 2.CB.05a | Tiemannite | HgSe |
| 2.CB.05a | Sphalerite | ZnS |
| 2.CB.05b | Sakuraiite | (Cu,Zn,Fe)3(In,Sn)S4 |
| 2.CB.05c | Polhemusite | (Zn,Hg)S |
| 2.CB.05a | Rudashevskyite | (Fe,Zn)S |
| 2.CB.05a | Stilleite | ZnSe |
| 2.CB.05a | Ishiharaite | (Cu,Ga,Fe,In,Zn)S |
| 2.CB.07a | 'Unnamed (Cu-Mn-Sn Sulphide)' | Cu2MnSnS4 |
| 2.CB.07a | Shenzhuangite | NiFeS2 |
| 2.CB.10b | Talnakhite | Cu9(Fe,Ni)8S16 |
| 2.CB.10b | Haycockite | Cu4Fe5S8 |
| 2.CB.10a | Lenaite | AgFeS2 |
| 2.CB.10a | Gallite | CuGaS2 |
| 2.CB.10a | Roquesite | CuInS2 |
| 2.CB.10a | Eskebornite | CuFeSe2 |
| 2.CB.10a | 'UM1984-30-S:CuFeSn' | Cu2Fe2Sn3S7 |
| 2.CB.10c | Omariniite | Cu8Fe2ZnGe2S12 |
| 2.CB.10a | Chalcopyrite | CuFeS2 |
| 2.CB.10a | 'Unnamed (Cu-Zn-In Sulphide)' | CuZn2InS4 |
| 2.CB.10b | Mooihoekite | Cu9Fe9S16 |
| 2.CB.10a | Laforêtite | AgInS2 |
| 2.CB.10b | Putoranite | Cu1.1Fe1.2S2 |
| 2.CB.15a | Velikite | Cu2HgSnS4 |
| 2.CB.15c | 'UM2006-11-S:CuFeGeZn' | Cu8(Fe,Zn)3Ge2S12 (?) |
| 2.CB.15a | Hocartite | Ag2(Fe2+,Zn)SnS4 |
| 2.CB.15a | Kësterite | Cu2ZnSnS4 |
| 2.CB.15a | Pirquitasite | Ag2ZnSnS4 |
| 2.CB.15a | Stannite | Cu2FeSnS4 |
| 2.CB.15c | Stannoidite | Cu+6Cu2+2(Fe2+,Zn)3Sn2S12 |
| 2.CB.15b | Mohite | Cu2SnS3 |
| 2.CB.15a | Černýite | Cu2CdSnS4 |
| 2.CB.15a | Idaite | Cu5FeS6 |
| 2.CB.15a | Ferrokësterite | Cu2FeSnS4 |
| 2.CB.15a | Kuramite | Cu3SnS4 |
| 2.CB.17a v | 'Arsenic-bearing Renierite' | Cu11GeAsFe4S16 |
| 2.CB.20 | Mawsonite | Cu6Fe2SnS8 |
| 2.CB.20 | Chatkalite | Cu6FeSn2S8 |
| 2.CB.30 | 'Frieseite' | Ag2Fe5S8 (?) |
| 2.CB.30 | Nekrasovite | Cu26V2(Sn,As,Sb)6S32 |
| 2.CB.30 | 'Argyropyrite' | near Ag2Fe7S11 |
| 2.CB.30 | Maikainite | Cu20(Fe,Cu)6Mo2Ge6S32 |
| 2.CB.30 | Colusite | Cu13VAs3S16 |
| 2.CB.30 | Germanite | Cu13Fe2Ge2S16 |
| 2.CB.30 | Germanocolusite | Cu26V2(Ge,As)6S32 |
| 2.CB.30 | Stibiocolusite | Cu13V(Sb,Sn,As)3S16 |
| 2.CB.30 | Ovamboite | Cu20(Fe,Cu,Zn)6W2Ge6S32 |
| 2.CB.35a | Morozeviczite | (Pb,Fe)3Ge1-xS4 |
| 2.CB.35a | Renierite | (Cu+,Zn)11Fe4(Ge4+,As5+)2S16 |
| 2.CB.35a | Hemusite | Cu6SnMoS8 |
| 2.CB.35b | Catamarcaite | Cu6GeWS8 |
| 2.CB.35a | Vinciennite | Cu+7Cu2+3Fe2+2Fe3+2Sn(As,Sb)S16 |
| 2.CB.35a | Kiddcreekite | Cu6SnWS8 |
| 2.CB.35a | Polkovicite | (Fe,Pb)3(Ge,Fe)1-xS4 |
| 2.CB.40 | Lautite | CuAsS |
| 2.CB.42 | Lingbaoite | AgTe3 |
| 2.CB.45 | Cadmoselite | CdSe |
| 2.CB.45 | Rambergite | MnS |
| 2.CB.45 | Buseckite | (Fe,Zn,Mn)S |
| 2.CB.45 | Maletoyvayamite | Au3Se4Te6 |
| 2.CB.45 | Greenockite | CdS |
| 2.CB.45 | Wurtzite | (Zn,Fe)S |
| 2.CB.47 | Murchisite | Cr5S6 |
| 2.CB.50 | 'Zincselenide' | ZnSe |
| 2.CB.50 | Wassonite | TiS |
| 2.CB.52 | 'Dzhezkazganite' | ReMoCu2PbS6 ? |
| 2.CB.55b | Isocubanite | CuFe2S3 |
| 2.CB.55a | Cubanite | CuFe2S3 |
| 2.CB.60 | Raguinite | TlFeS2 |
| 2.CB.60 | Picotpaulite | TlFe2S3 |
| 2.CB.65 | Argentopyrite | AgFe2S3 |
| 2.CB.65 | Sternbergite | AgFe2S3 |
| 2.CB.75 | Vulcanite | CuTe |
| 2.CB.80 | Empressite | AgTe |
| 2.CB.85 | Muthmannite | AuAgTe2 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Sulvanite
mindat.org URL:
https://www.mindat.org/min-3827.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Sulvanite
Reference List:
Jong, W. F. de (1928) Die Enargitgruppe. Struktur des Sulvanit, Cu3VS4. Zeitschrift für Kristallographie, 68 (1). 522-530 doi:10.1524/zkri.1928.68.1.522
Schempp, Christy A., Schaller, Waldemar T. (1931) Sulvanite from Utah. American Mineralogist, 16 (12) 557-562
Pauling, Linus, Hultgren, Ralph (1933) The Crystal Structure of Sulvanite, Cu3VS4. Zeitschrift für Kristallographie - Crystalline Materials, 84 (1) 204-212 doi:10.1524/zkri.1933.84.1.204
Pauling, Linus (1965) The nature of the chemical bonds in sulvanite, Cu3VS4. Tschermaks Mineralogische und Petrographische Mitteilungen, 10 (1). 379-384 doi:10.1007/bf01128641
Trojer, Felix J. (1966) Refinement of the structure of sulvanite. American Mineralogist, 51 (5-6) 890-894
Lévy, Claude, Caye, René, Cervelle, Bernard, Gouet, Geneviève (1981) Détermination par microspectrométrie en réflexion de bandes d'absorption sélective dans la sulvanite Cu3VS4. Bulletin de Minéralogie, 104 (2) 172-176 doi:10.3406/bulmi.1981.7452
Cressey, G., Henderson, C. M. B., van der Laan, G. (1993) Use of L-edge X-ray absorption spectroscopy to characterize multiple valence states of 3d transition metals; a new probe for mineralogical and geochemical research. Physics and Chemistry of Minerals, 20 (2) 111-119 doi:10.1007/bf00207204
Localities for Sulvanite
Showing 71 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Gramaccioli |
Australia | |
| - (Erroneous attribution) +1 other reference |
| Gramaccioli |
| Ralph Bottrill (in prep) |
| Zaw et al. (1997) |
Bulgaria | |
| Cook et al. (2002) +1 other reference |
| Cook et al. (2002) +1 other reference |
| Straschimirov (1982) +3 other references | |
| Cook et al. (2002) |
Canada | |
| Scott et al. (1986) |
| Gill et al. (2016) |
| Deklerk et al. (compilers) +1 other reference |
China | |
| Coveney et al. (1993) |
| Wallis (2006) |
| Shenghua Wu et al. (2010) |
| [var: Ge-Sn-Sulvanite] Shihui Yang and Xiaoling Zhu (1991) |
| [var: Ge-Sn-Sulvanite] Shihui Yang et al. (1996) | |
| Li Chaoyang (1996) |
| Nansheng Chen (1996) |
Czech Republic | |
| Scharm et al. (2000) |
DR Congo | |
| ... |
| Deliens (1996) |
Finland | |
| Sergeeva et al. (2011, February) |
France | |
| Anthony et al. (1990) |
Germany | |
| Lorenz (1998) +1 other reference |
Greece | |
| Tombros et al. (2007) |
Italy | |
| Orlandi et al. (1996) +1 other reference |
| Orlandi (1974) +3 other references |
| Orlandi et al. (2009) |
| Biagioni et al. (2019) | |
| Matteo Chinellato collection | |
| Orlandi et al. (2009) +1 other reference | |
| Biagioni et al. (2019) |
| Orlandi et al. (1989) +3 other references | |
| Franzini et al. (1982) +1 other reference |
| - (n.d.) | |
| Orlandi et al. (2009) |
| Guelfi et al. (1987) +1 other reference | |
| D’Achiardi (1911 a) +5 other references | |
| Brizzi (1986) +5 other references | |
| Orlandi et al. (2009) | |
| Orlandi et al. (2000) +1 other reference |
| Orlandi et al. (2009) | |
| Orlandi et al. (2000) | |
Japan | |
| Matsubara et al. (2006) |
Kazakhstan | |
| United States Bureau of Mines (1982) |
| - (2005) |
| Evseev (1995) |
| Uranium One |
Kyrgyzstan | |
| Pautov L.A. |
Mongolia | |
| Economic Geology September 2001 v. 96 ... |
Namibia | |
| Gramaccioli |
Poland | |
| Chmielewski et al. (2016) |
Russia | |
| Parnell et al. (2001) |
| Korinevsky et al. (2022) |
| Pavel M. Kartashov (n.d.) |
| Am Min 59:307-313 | |
| Collection of Geological Museum in ... |
| Koval’chuk et al. (2008) |
| [World of Stones 12:49] | |
| Nenasheva et al. (2011) |
| Ayupova et al. (2021) |
| Gongalsky et al. (2019) |
Serbia | |
| RTB Bor |
| Anthony et al. (1990) | |
| Bosić et al. (2025) | |
USA | |
| Bart Cannon microprobe analysis +19 other references |
| Bullock (1981) | |
| Jackson (1986) |
Quick NavTopAbout SulvaniteUnique IdentifiersSimilar NamesIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence Other LanguagesVarietiesRelationshipsCommon AssociatesStrunz-MindatOther InformationInternet Links References Localities Locality List






symbol to view information about a locality.
The
Fantiscritti, Miseglie quarrying basin, Carrara, Massa-Carrara Province, Tuscany, Italy