Vinciennite
A valid IMA mineral species
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About Vinciennite
Formula:
Cu+7Cu2+3Fe2+2Fe3+2Sn(As,Sb)S16
Colour:
Orange
Lustre:
Metallic
Hardness:
4½
Specific Gravity:
4.29 (Calculated)
Crystal System:
Tetragonal
Name:
Named in honor of Henri Vincienne (13 January 1898, Lizy sur Ourcq, Seine et Marne, France - 30 June 1965), professor of mineralogy, ENSMP, France.
This page provides mineralogical data about Vinciennite.
Unique Identifiers
Mindat ID:
4185
Long-form identifier:
mindat:1:1:4185:6
IMA Classification of Vinciennite
Approved
IMA Formula:
Cu10Fe4SnAsS16
Approval year:
1983
First published:
1985
Classification of Vinciennite
2.CB.35a
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
3.1.2.1
3 : SULFOSALTS
1 : ø > 4
3 : SULFOSALTS
1 : ø > 4
6.1.14
6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
1 : Sulphostannates and other sulfides containing Sn
6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
1 : Sulphostannates and other sulfides containing Sn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Vcn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Vinciennite
Metallic
Transparency:
Opaque
Colour:
Orange
Hardness:
4½ on Mohs scale
Hardness:
VHN25=280 kg/mm2 - Vickers
Tenacity:
Brittle
Fracture:
Conchoidal
Density:
4.29 g/cm3 (Calculated)
Optical Data of Vinciennite
Anisotropism:
Weak; purplish blue to greenish brown-yellow
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 420nm | 19.4% | 19.4% |
| 460nm | 21.8% | 20.6% |
| 500nm | 23.9% | 22.8% |
| 540nm | 27.7% | 26.5% |
| 580nm | 30.7% | 29.5% |
| 620nm | 33.6% | 32.1% |
| 660nm | 35.9% | 34.3% |
| 700nm | 37.8% | 36.0% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 37.8%.
R1 shown in black, R2 shown in red
Chemistry of Vinciennite
Mindat Formula:
Cu+7Cu2+3Fe2+2Fe3+2Sn(As,Sb)S16
Element Weights:
Common Impurities:
Zn
Crystallography of Vinciennite
Crystal System:
Tetragonal
Cell Parameters:
a = 10.697(6) Å, c = 10.697(6) Å
Ratio:
a:c = 1 : 1
Unit Cell V:
1,224.01 ų (Calculated from Unit Cell)
Z:
2
Twinning:
Simple and poor polysynthetic twins.
Comment:
Point Group: 4/m 2/m 2/m, 4mm, or 422.; Space Group: P4/mmm, P4mm, P422, or P4122.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.088 Å | (100) |
| 1.895 Å | (90) |
| 1.614 Å | (70) |
| 2.676 Å | (50) |
| 1.227 Å | (40) |
| 1.091 Å | (40) |
| 4.37 Å | (30) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Vinciennite
General Appearance of Type Material:
Grains up to 1 mm
Place of Conservation of Type Material:
National School of Mines, Paris, France.
Associated Minerals at Type Locality:
Synonyms of Vinciennite
Other Language Names for Vinciennite
Common Associates
Associations Based on Photo Data:
| 2 photos of Vinciennite associated with Bornite | Cu5FeS4 |
| 1 photo of Vinciennite associated with Pyrite | FeS2 |
| 1 photo of Vinciennite associated with Colusite | Cu13VAs3S16 |
| 1 photo of Vinciennite associated with Bohdanowiczite | AgBiSe2 |
| 1 photo of Vinciennite associated with Digenite | Cu9S5 |
| 1 photo of Vinciennite associated with Tennantite-(Cu) | Cu6(Cu4Cu2)As4S12S |
| 1 photo of Vinciennite associated with Chalcopyrite | CuFeS2 |
| 1 photo of Vinciennite associated with Enargite | Cu3AsS4 |
| 1 photo of Vinciennite associated with Covellite | CuS |
Related Minerals - Strunz-mindat Grouping
| 2.CB. | Richardsite | Zn2CuGaS4 |
| 2.CB. | Okruginite | Cu2SnSe3 |
| 2.CB. | Hanswilkeite | KFeS2 |
| 2.CB. | Auroselenide | AuSe |
| 2.CB. | Ruizhongite | (Ag2◻)Pb3Ge2S8 |
| 2.CB. | Agmantinite | Ag2MnSnS4 |
| 2.CB. | Tolstykhite | Au3S4Te6 |
| 2.CB. | Gachingite | Au(Te1-xSex) |
| 2.CB.05a | Hawleyite | CdS |
| 2.CB.05 | 'UM1998-15-S:CuFeZn' | Cu2Fe3Zn5S10 |
| 2.CB.05a | Coloradoite | HgTe |
| 2.CB.05a | Metacinnabar | HgS |
| 2.CB.05a | Tiemannite | HgSe |
| 2.CB.05a | Sphalerite | ZnS |
| 2.CB.05b | Sakuraiite | (Cu,Zn,Fe)3(In,Sn)S4 |
| 2.CB.05c | Polhemusite | (Zn,Hg)S |
| 2.CB.05a | Rudashevskyite | (Fe,Zn)S |
| 2.CB.05a | Stilleite | ZnSe |
| 2.CB.05a | Ishiharaite | (Cu,Ga,Fe,In,Zn)S |
| 2.CB.07a | 'Unnamed (Cu-Mn-Sn Sulphide)' | Cu2MnSnS4 |
| 2.CB.07a | Shenzhuangite | NiFeS2 |
| 2.CB.10b | Talnakhite | Cu9(Fe,Ni)8S16 |
| 2.CB.10b | Haycockite | Cu4Fe5S8 |
| 2.CB.10a | Lenaite | AgFeS2 |
| 2.CB.10a | Gallite | CuGaS2 |
| 2.CB.10a | Roquesite | CuInS2 |
| 2.CB.10a | Eskebornite | CuFeSe2 |
| 2.CB.10a | 'UM1984-30-S:CuFeSn' | Cu2Fe2Sn3S7 |
| 2.CB.10c | Omariniite | Cu8Fe2ZnGe2S12 |
| 2.CB.10a | Chalcopyrite | CuFeS2 |
| 2.CB.10a | 'Unnamed (Cu-Zn-In Sulphide)' | CuZn2InS4 |
| 2.CB.10b | Mooihoekite | Cu9Fe9S16 |
| 2.CB.10a | Laforêtite | AgInS2 |
| 2.CB.10b | Putoranite | Cu1.1Fe1.2S2 |
| 2.CB.15a | Velikite | Cu2HgSnS4 |
| 2.CB.15c | 'UM2006-11-S:CuFeGeZn' | Cu8(Fe,Zn)3Ge2S12 (?) |
| 2.CB.15a | Hocartite | Ag2(Fe2+,Zn)SnS4 |
| 2.CB.15a | Kësterite | Cu2ZnSnS4 |
| 2.CB.15a | Pirquitasite | Ag2ZnSnS4 |
| 2.CB.15a | Stannite | Cu2FeSnS4 |
| 2.CB.15c | Stannoidite | Cu+6Cu2+2(Fe2+,Zn)3Sn2S12 |
| 2.CB.15b | Mohite | Cu2SnS3 |
| 2.CB.15a | Černýite | Cu2CdSnS4 |
| 2.CB.15a | Idaite | Cu5FeS6 |
| 2.CB.15a | Ferrokësterite | Cu2FeSnS4 |
| 2.CB.15a | Kuramite | Cu3SnS4 |
| 2.CB.17a v | 'Arsenic-bearing Renierite' | Cu11GeAsFe4S16 |
| 2.CB.20 | Mawsonite | Cu6Fe2SnS8 |
| 2.CB.20 | Chatkalite | Cu6FeSn2S8 |
| 2.CB.30 | 'Frieseite' | Ag2Fe5S8 (?) |
| 2.CB.30 | Nekrasovite | Cu26V2(Sn,As,Sb)6S32 |
| 2.CB.30 | 'Argyropyrite' | near Ag2Fe7S11 |
| 2.CB.30 | Maikainite | Cu20(Fe,Cu)6Mo2Ge6S32 |
| 2.CB.30 | Colusite | Cu13VAs3S16 |
| 2.CB.30 | Germanite | Cu13Fe2Ge2S16 |
| 2.CB.30 | Germanocolusite | Cu26V2(Ge,As)6S32 |
| 2.CB.30 | Stibiocolusite | Cu13V(Sb,Sn,As)3S16 |
| 2.CB.30 | Ovamboite | Cu20(Fe,Cu,Zn)6W2Ge6S32 |
| 2.CB.35a | Morozeviczite | (Pb,Fe)3Ge1-xS4 |
| 2.CB.35a | Renierite | (Cu+,Zn)11Fe4(Ge4+,As5+)2S16 |
| 2.CB.35a | Hemusite | Cu6SnMoS8 |
| 2.CB.35b | Catamarcaite | Cu6GeWS8 |
| 2.CB.35a | Kiddcreekite | Cu6SnWS8 |
| 2.CB.35a | Polkovicite | (Fe,Pb)3(Ge,Fe)1-xS4 |
| 2.CB.40 | Lautite | CuAsS |
| 2.CB.42 | Lingbaoite | AgTe3 |
| 2.CB.45 | Cadmoselite | CdSe |
| 2.CB.45 | Rambergite | MnS |
| 2.CB.45 | Buseckite | (Fe,Zn,Mn)S |
| 2.CB.45 | Maletoyvayamite | Au3Se4Te6 |
| 2.CB.45 | Greenockite | CdS |
| 2.CB.45 | Wurtzite | (Zn,Fe)S |
| 2.CB.47 | Murchisite | Cr5S6 |
| 2.CB.50 | 'Zincselenide' | ZnSe |
| 2.CB.50 | Wassonite | TiS |
| 2.CB.52 | 'Dzhezkazganite' | ReMoCu2PbS6 ? |
| 2.CB.55b | Isocubanite | CuFe2S3 |
| 2.CB.55a | Cubanite | CuFe2S3 |
| 2.CB.60 | Raguinite | TlFeS2 |
| 2.CB.60 | Picotpaulite | TlFe2S3 |
| 2.CB.65 | Argentopyrite | AgFe2S3 |
| 2.CB.65 | Sternbergite | AgFe2S3 |
| 2.CB.70 | Sulvanite | Cu3VS4 |
| 2.CB.75 | Vulcanite | CuTe |
| 2.CB.80 | Empressite | AgTe |
| 2.CB.85 | Muthmannite | AuAgTe2 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Vinciennite
mindat.org URL:
https://www.mindat.org/min-4185.html
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References for Vinciennite
Reference List:
Cesbron, Fabien, Giraud, Roger, Picot, Paul, Pillard, François (1985) La vinciennite, Cu10Fe4Sn(As,Sb)S16, une nouvelle espèce minérale. Etude paragénétique du gîte type de Chizeuil, Saône-et-Loire. Bulletin de Minéralogie, 108 (3) 447-456 doi:10.3406/bulmi.1985.7841
Marcoux, E.; Milési, J. P.; Moëlo, Y. (1994) Vinciennite and Cu-excess tennantite from the Layo (Cu, Sn, As, Au) epithermal deposit (Southern Peru). Mineralogy and Petrology, 51 (1). p.21-36. doi:10.1007/bf01164912
Kouzmanov, K., Ramboz, C., Bailly, L., Bogdanov, K. (2004) Genesis of high sulfidation vinciennite-bearing Cu-As-Sn (±Au) assemblage from the Radka epithermal copper deposit, Bulgaria: Evidence from mineralogy and infrared microthermometry of enargite. The Canadian Mineralogist, 42 (5) 1501-1521 doi:10.2113/gscanmin.42.5.1501
Localities for Vinciennite
Showing 18 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Putz et al. (2009) |
| Brodtkorb (2002) +2 other references |
Bulgaria | |
| Cook et al. (2002) |
| Cook et al. (2002) +3 other references |
Canada | |
| Jambor et al. (1987) +1 other reference |
| Kidd Operations |
China | |
| Liu Wenyuan et al. (2014) |
| Long et al. (2025) | |
| Long et al. (2025) | |
| Long et al. (2025) | |
| Zijin Mining Group Company Limited | |
France (TL) | |
| Cesbron et al. (1985) +1 other reference |
Peru | |
| Marcoux et al. (1994) +1 other reference |
| Catchpole et al. (2012) |
| Anthony et al. (1990) |
Portugal | |
| Lundin Mining |
Russia | |
| Plotinskaya et al. (2014) |
| O.Yu. Plotinskaya data |
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The
Chizeuil Mine, Chalmoux, Charolles, Saône-et-Loire, Bourgogne-Franche-Comté, France