Kuramite
A valid IMA mineral species
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About Kuramite
Formula:
Cu3SnS4
Lustre:
Metallic
Hardness:
5
Specific Gravity:
4.56 (Calculated)
Crystal System:
Tetragonal
Member of:
Name:
Named in 1979 by V.A. Kovalenker, T.L. Evstigneeva, N.V. Troneva, and L.N. Vyal´sov for the Kuramin (Qurama) Mountains where the type locality is found.
Stannite group.
Compare also the varieties, stannoenargite and stannoluzonite, and other Cu-Sn sulphides: mohite, erazoite and 'UM1981-18-S:CuSn'.
Compare also the varieties, stannoenargite and stannoluzonite, and other Cu-Sn sulphides: mohite, erazoite and 'UM1981-18-S:CuSn'.
Unique Identifiers
Mindat ID:
2291
Long-form identifier:
mindat:1:1:2291:6
Similar Names
| Cromite | A synonym of Chromite | |
| Garmite | A valid IMA mineral species | CsLiMg2(Si4O10)F2 |
| Graemite | A valid IMA mineral species | Cu[TeO3] · H2O |
| Grammite | A synonym of Wollastonite | |
| Gurimite | A valid IMA mineral species | Ba3(VO4)2 |
| Keramite (of Hunt) | A variety of Kaolinite | |
| Keramite (of Mellor and Scott) | A synonym of Mullite | |
| Kulanite | A valid IMA mineral species | Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 |
| Kunatite | A valid IMA mineral species | CuFe23+(PO4)2(OH)2 · 4H2O |
| Kuratite | A valid IMA mineral species | Ca2(Fe52+Ti)O2[Si4Al2O18] |
IMA Classification of Kuramite
Approved
IMA Formula:
Cu1+2Cu2+Sn4+S2-4
Approval year:
1979
First published:
1979
Classification of Kuramite
2.CB.15a
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2.9.2.4
2 : SULFIDES
9 : AmBnXp, with (m+n):p = 1:1
2 : SULFIDES
9 : AmBnXp, with (m+n):p = 1:1
6.1.1
6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
1 : Sulphostannates and other sulfides containing Sn
6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
1 : Sulphostannates and other sulfides containing Sn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ku | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Ku | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Kuramite
Metallic
Transparency:
Opaque
Streak:
Metallic
Hardness:
5 on Mohs scale
Hardness:
VHN20=379 - 432 kg/mm2 - Vickers
Density:
4.56 g/cm3 (Calculated)
Optical Data of Kuramite
Anisotropism:
Distinct, brown shades
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 460nm | 25.3% | 25.2% |
| 540nm | 26.5% | 28.7% |
| 580nm | 26.7% | 29.5% |
| 640nm | 26.5% | 28.0% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 29.5%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Neutral gray
Chemistry of Kuramite
Mindat Formula:
Cu3SnS4
Element Weights:
Elements listed:
Common Impurities:
Fe,Zn,In
Crystallography of Kuramite
Crystal System:
Tetragonal
Class (H-M):
42m - Scalenohedral
Space Group:
I42m
Cell Parameters:
a = 5.545(5) Å, c = 10.75(2) Å
Ratio:
a:c = 1 : 1.939
Unit Cell V:
330.53 ų (Calculated from Unit Cell)
Z:
2
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0013950 | Kuramite | Chen X, Wada H, Sato A, Mieno M (1998) Synthesis, electrical conductivity, and crystal structure of Cu4Sn7S16 and structure refinement of Cu2SnS3 Journal of Solid State Chemistry 139 144-151 | 1998 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.13 Å | (10) |
| 1.914 Å | (8) |
| 1.640 Å | (6) |
| 1.108 Å | (4) |
| 1.244 Å | (3) |
| 2.70 Å | (2) |
| 1.044 Å | (2) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 3b: Earth’s earliest hydrosphere | >4.45 |
| 12 : Hadean hydrothermal subsurface sulfide deposits (see also #33) |
Type Occurrence of Kuramite
General Appearance of Type Material:
Inclusions, 5-80 microns in diameter within goldfieldite.
Place of Conservation of Type Material:
1) A. E. Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia.
2) Institute of Ore Deposits (IGEM), Moscow, Russia.
2) Institute of Ore Deposits (IGEM), Moscow, Russia.
Geological Setting of Type Material:
Gold-sulfide deposit.
Associated Minerals at Type Locality:
Synonyms of Kuramite
Other Language Names for Kuramite
Relationship of Kuramite to other Species
Member of:
Other Members of Stannite Group:
| Briartite | Cu2FeGeS4 | Tet. |
| Černýite | Cu2CdSnS4 | Tet. 42m : I42m |
| Famatinite | Cu3SbS4 | Tet. 42m : I42m |
| Ferrokësterite | Cu2FeSnS4 | Tet. 4 : I4 |
| Hocartite | Ag2(Fe2+,Zn)SnS4 | Tet. 42m : I42m |
| Kësterite | Cu2ZnSnS4 | Tet. 4 : I4 |
| Keutschite | Cu2AgAsS4 | Tet. 42m : I42m |
| Luzonite | Cu3AsS4 | Tet. 42m : I42m |
| Omariniite | Cu8Fe2ZnGe2S12 | Orth. 222 : I222 |
| Permingeatite | Cu3SbSe4 | Tet. 42m : I42m |
| Petrukite | (Cu,Fe,Zn,Ag)3(Sn,In)S4 | Orth. mm2 : Pmn21 |
| Pirquitasite | Ag2ZnSnS4 | Tet. 4 : I4 |
| Richardsite | Zn2CuGaS4 | Tet. 42m : I42m |
| Stannite | Cu2FeSnS4 | Tet. 42m : I42m |
| Stannoidite | Cu+6Cu2+2(Fe2+,Zn)3Sn2S12 | Orth. 222 : I222 |
| 'UM1984-30-S:CuFeSn' | Cu2Fe2Sn3S7 | |
| 'Unnamed (Cu-Zn-In Sulphide)' | CuZn2InS4 | |
| Velikite | Cu2HgSnS4 | Tet. 4 : I4 |
| Zincobriartite | Cu2(Zn,Fe)(Ge,Ga)S4 | Tet. 42m : I42m |
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 2.CB. | Richardsite | Zn2CuGaS4 |
| 2.CB. | Okruginite | Cu2SnSe3 |
| 2.CB. | Hanswilkeite | KFeS2 |
| 2.CB. | Auroselenide | AuSe |
| 2.CB. | Ruizhongite | (Ag2◻)Pb3Ge2S8 |
| 2.CB. | Agmantinite | Ag2MnSnS4 |
| 2.CB. | Tolstykhite | Au3S4Te6 |
| 2.CB. | Gachingite | Au(Te1-xSex) |
| 2.CB.05a | Hawleyite | CdS |
| 2.CB.05 | 'UM1998-15-S:CuFeZn' | Cu2Fe3Zn5S10 |
| 2.CB.05a | Coloradoite | HgTe |
| 2.CB.05a | Metacinnabar | HgS |
| 2.CB.05a | Tiemannite | HgSe |
| 2.CB.05a | Sphalerite | ZnS |
| 2.CB.05b | Sakuraiite | (Cu,Zn,Fe)3(In,Sn)S4 |
| 2.CB.05c | Polhemusite | (Zn,Hg)S |
| 2.CB.05a | Rudashevskyite | (Fe,Zn)S |
| 2.CB.05a | Stilleite | ZnSe |
| 2.CB.05a | Ishiharaite | (Cu,Ga,Fe,In,Zn)S |
| 2.CB.07a | 'Unnamed (Cu-Mn-Sn Sulphide)' | Cu2MnSnS4 |
| 2.CB.07a | Shenzhuangite | NiFeS2 |
| 2.CB.10b | Talnakhite | Cu9(Fe,Ni)8S16 |
| 2.CB.10b | Haycockite | Cu4Fe5S8 |
| 2.CB.10a | Lenaite | AgFeS2 |
| 2.CB.10a | Gallite | CuGaS2 |
| 2.CB.10a | Roquesite | CuInS2 |
| 2.CB.10a | Eskebornite | CuFeSe2 |
| 2.CB.10a | 'UM1984-30-S:CuFeSn' | Cu2Fe2Sn3S7 |
| 2.CB.10c | Omariniite | Cu8Fe2ZnGe2S12 |
| 2.CB.10a | Chalcopyrite | CuFeS2 |
| 2.CB.10a | 'Unnamed (Cu-Zn-In Sulphide)' | CuZn2InS4 |
| 2.CB.10b | Mooihoekite | Cu9Fe9S16 |
| 2.CB.10a | Laforêtite | AgInS2 |
| 2.CB.10b | Putoranite | Cu1.1Fe1.2S2 |
| 2.CB.15a | Velikite | Cu2HgSnS4 |
| 2.CB.15c | 'UM2006-11-S:CuFeGeZn' | Cu8(Fe,Zn)3Ge2S12 (?) |
| 2.CB.15a | Hocartite | Ag2(Fe2+,Zn)SnS4 |
| 2.CB.15a | Kësterite | Cu2ZnSnS4 |
| 2.CB.15a | Pirquitasite | Ag2ZnSnS4 |
| 2.CB.15a | Stannite | Cu2FeSnS4 |
| 2.CB.15c | Stannoidite | Cu+6Cu2+2(Fe2+,Zn)3Sn2S12 |
| 2.CB.15b | Mohite | Cu2SnS3 |
| 2.CB.15a | Černýite | Cu2CdSnS4 |
| 2.CB.15a | Idaite | Cu5FeS6 |
| 2.CB.15a | Ferrokësterite | Cu2FeSnS4 |
| 2.CB.17a v | 'Arsenic-bearing Renierite' | Cu11GeAsFe4S16 |
| 2.CB.20 | Mawsonite | Cu6Fe2SnS8 |
| 2.CB.20 | Chatkalite | Cu6FeSn2S8 |
| 2.CB.30 | 'Frieseite' | Ag2Fe5S8 (?) |
| 2.CB.30 | Nekrasovite | Cu26V2(Sn,As,Sb)6S32 |
| 2.CB.30 | 'Argyropyrite' | near Ag2Fe7S11 |
| 2.CB.30 | Maikainite | Cu20(Fe,Cu)6Mo2Ge6S32 |
| 2.CB.30 | Colusite | Cu13VAs3S16 |
| 2.CB.30 | Germanite | Cu13Fe2Ge2S16 |
| 2.CB.30 | Germanocolusite | Cu26V2(Ge,As)6S32 |
| 2.CB.30 | Stibiocolusite | Cu13V(Sb,Sn,As)3S16 |
| 2.CB.30 | Ovamboite | Cu20(Fe,Cu,Zn)6W2Ge6S32 |
| 2.CB.35a | Morozeviczite | (Pb,Fe)3Ge1-xS4 |
| 2.CB.35a | Renierite | (Cu+,Zn)11Fe4(Ge4+,As5+)2S16 |
| 2.CB.35a | Hemusite | Cu6SnMoS8 |
| 2.CB.35b | Catamarcaite | Cu6GeWS8 |
| 2.CB.35a | Vinciennite | Cu+7Cu2+3Fe2+2Fe3+2Sn(As,Sb)S16 |
| 2.CB.35a | Kiddcreekite | Cu6SnWS8 |
| 2.CB.35a | Polkovicite | (Fe,Pb)3(Ge,Fe)1-xS4 |
| 2.CB.40 | Lautite | CuAsS |
| 2.CB.42 | Lingbaoite | AgTe3 |
| 2.CB.45 | Cadmoselite | CdSe |
| 2.CB.45 | Rambergite | MnS |
| 2.CB.45 | Buseckite | (Fe,Zn,Mn)S |
| 2.CB.45 | Maletoyvayamite | Au3Se4Te6 |
| 2.CB.45 | Greenockite | CdS |
| 2.CB.45 | Wurtzite | (Zn,Fe)S |
| 2.CB.47 | Murchisite | Cr5S6 |
| 2.CB.50 | 'Zincselenide' | ZnSe |
| 2.CB.50 | Wassonite | TiS |
| 2.CB.52 | 'Dzhezkazganite' | ReMoCu2PbS6 ? |
| 2.CB.55b | Isocubanite | CuFe2S3 |
| 2.CB.55a | Cubanite | CuFe2S3 |
| 2.CB.60 | Raguinite | TlFeS2 |
| 2.CB.60 | Picotpaulite | TlFe2S3 |
| 2.CB.65 | Argentopyrite | AgFe2S3 |
| 2.CB.65 | Sternbergite | AgFe2S3 |
| 2.CB.70 | Sulvanite | Cu3VS4 |
| 2.CB.75 | Vulcanite | CuTe |
| 2.CB.80 | Empressite | AgTe |
| 2.CB.85 | Muthmannite | AuAgTe2 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Kuramite
mindat.org URL:
https://www.mindat.org/min-2291.html
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References for Kuramite
Reference List:
Fleischer, M., Cabri, L. J., Chao, G. Y., Pabst, A. (1980) New mineral names. American Mineralogist, 65 (9-10). 1065-1070
Kovalenker, V. A. (1981) Kuramite, Cu3SnS4, a new mineral of the stannite group. International Geology Review, 23 (3) 365-370 doi:10.1080/00206818109455070
Chen, Xue-an, Wada, Hiroaki, Sato, Akira, Mieno, Masahiro (1998) Synthesis, electrical conductivity, and crystal structure of Cu4Sn7S16 and structure refinement of Cu2SnS3. Journal of Solid State Chemistry, 139. 144-151 doi:10.1006/jssc.1998.7822
Di Benedetto, F., Evstigneeva, T., Borgheresi, M., Caneschi, A., Romanelli, M. (2009) The unusual magnetic properties of kuramite–stannite pseudobinary series: a SQUID and EPR survey. Physics and Chemistry of Minerals, 36 (6) 301-309 doi:10.1007/s00269-008-0278-7
Zalewski, W., Bacewicz, R., Antonowicz, J., Pietnoczka, A., Evstigneeva, T.L., Schorr, S. (2010) XAFS study of kesterite, kuramite and stannite type alloys. Journal of Alloys and Compounds, 492. 35-38 doi:10.1016/j.jallcom.2009.11.158
Benedetto, Francesco Di, Borrini, Daniele, Caneschi, Andrea, Fornaciai, Gabriele, Innocenti, Massimo, Lavacchi, Alessandro, Massa, Carlo Andrea, Montegrossi, Giordano, Oberhauser, Werner, Pardi, Luca A., Romanelli, Maurizio (2011) Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4. Physics and Chemistry of Minerals, 38 (6) 483-490 doi:10.1007/s00269-011-0421-8
Lin, Xianzhong, Steigert, Alexander, Lux-Steiner, Martha Ch., Ennaoui, Ahmed (2012) One-step solution-based synthesis and characterization of kuramite Cu3SnS4 nanocrystals. RSC Advances, 2 (26). 9798pp. doi:10.1039/c2ra21777e
Goto, Yosuke; Naito, Fumihiko; Sato, Rina; Yoshiyasu, Keigo; Itoh, Takanori; Kamihara, Yoichi; Matoba, Masanori (2013) Enhanced Thermoelectric Figure of Merit in Stannite–Kuramite Solid Solutions Cu2+xFe1–xSnS4–y (x = 0–1) with Anisotropy Lowering. Inorganic Chemistry, 52 (17). 9861-9866 doi:10.1021/ic401310c
Shibuya, Taizo; Goto, Yosuke; Kamihara, Yoichi; Matoba, Masanori; Yasuoka, Kenji; Burton, Lee A.; Walsh, Aron (2014) From kesterite to stannite photovoltaics: Stability and band gaps of the Cu2(Zn,Fe)SnS4 alloy. Applied Physics Letters, 104 (2). 21912 doi:10.1063/1.4862030
Goto, Yosuke, Sakai, Yuki, Kamihara, Yoichi, Matoba, Masanori (2015) Electronic structure and transport properties of Cu-deficient kuramite Cu3−xSnS4. Japanese Journal of Applied Physics, 54 (2) 21801 doi:10.7567/jjap.54.021801
Di Benedetto, Francesco, Bencistà, Ilaria, D’Acapito, Francesco, Frizzera, Silvia, Caneschi, Andrea, Innocenti, Massimo, Lavacchi, Alessandro, Montegrossi, Giordano, Oberhauser, Werner, Romanelli, Maurizio, Dittrich, Herbert, Pardi, Luca A., Tippelt, Gerold, Amthauer, Georg (2016) Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite, Cu3SnS4. Physics and Chemistry of Minerals, 43 (8) 535-544 doi:10.1007/s00269-016-0814-9
Localities for Kuramite
Showing 18 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Arctic Ocean | |
| Olsen (2016) |
Argentina | |
| FRANCHINI (27º26'S-66º16'O) |
| Brodtkorb (2002) +2 other references |
Bosnia and Herzegovina | |
| Vokić (2024) |
Chile | |
| HENLEY et al. (2011) |
DR Congo | |
| ... |
Greece | |
| Voudouris et al. (2011) |
Hungary | |
| |
Japan | |
| CHIMIZU (1993) |
Russia | |
| Kozlov et al. (n.d.) |
UK | |
| Golley et al. (1995) +1 other reference |
USA | |
| Graeme (1993) |
| Anthony et al. (1995) | |
| Rocks & Minerals 71:2 pp94-101 |
| Castor et al. (2004) |
| Castor et al. (2004) |
| Castor et al. (2004) |
Uzbekistan (TL) | |
| Kovalenker et al. (1979) +3 other references |
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Campbell Mine, Bisbee, Cochise County, Arizona, USA