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Paradamite

A valid IMA mineral species - grandfathered
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About ParadamiteHide

Formula:
Zn2(AsO4)(OH)
Colour:
Pale yellow
Lustre:
Vitreous, Sub-Vitreous, Resinous
Hardness:
Specific Gravity:
4.55
Crystal System:
Triclinic
Name:
Named in 1956 by George Switzer from the Greek παρα for "near", para-, and Adamite in allusion to its polymorphic relationship to that species.
Dimorph of:
Isostructural with:
Tarbuttite Group. The triclinic dimorph of Adamite.


Unique IdentifiersHide

Mindat ID:
3086
Long-form identifier:
mindat:1:1:3086:7

IMA Classification of ParadamiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Zn2+2As5+O4(OH)
First published:
1956

Classification of ParadamiteHide

8.BB.35

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
B : With only medium-sized cations, (OH, etc.):RO4 about 1:1
41.6.7.2

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
6 : A2(XO4)Zq
20.3.2

20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
PrdIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ParadamiteHide

Vitreous, Sub-Vitreous, Resinous
Transparency:
Transparent, Translucent
Colour:
Pale yellow
Streak:
White
Hardness:
3½ on Mohs scale
Hardness Data:
Estimated
Tenacity:
Brittle
Cleavage:
Perfect
{010}
Density:
4.55 g/cm3 (Measured)    4.595 g/cm3 (Calculated)

Optical Data of ParadamiteHide

Type:
Biaxial (-)
RI values:
nα = 1.726 nβ = 1.771 nγ = 1.780
2V:
Measured: 50° , Calculated: 46°
Birefringence:
0.054
Max. Birefringence:
δ = 0.054
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
relatively strong
Optical Extinction:
inclined
Pleochroism:
Non-pleochroic

Chemistry of ParadamiteHide

Mindat Formula:
Zn2(AsO4)(OH)
Element Weights:
Element% weight
Zn45.611 %
O27.904 %
As26.134 %
H0.352 %

Calculated from ideal end-member formula.
Zn
O
As
H

Crystallography of ParadamiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 5.638(3) Å, b = 5.827(3) Å, c = 6.692(2) Å
α = 103.25(4)°, β = 104.37(3)°, γ = 87.72(4)°
Ratio:
a:b:c = 0.968 : 1 : 1.148
Unit Cell V:
207.27 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Individual steeply angular, platy to prismatic, isolated crystals are usual, but may be rounded or occur in sheaf-like globular aggregates showing acute terminations. Crystals striated on {001} and {100}, but not on {010}. This mineral does not visually closely resemble its namesake, adamite.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020669ParadamiteJinnouchi S, Yoshiasa A, Sugiyama K, Shimura R, Arima H, Momma H, Miyawaki R (2016) Crystal structure refinements of legrandite, adamite, and paradamite: The complex structure and characteristic hydrogen bonding network of legrandite Journal of Mineralogical and Petrological Sciences 111 35-432016Ojuela Mine, Mapimi, Durango, Mexico0293
0019266ParadamiteHawthorne F C (1979) Paradamite Acta Crystallographica B35 720-7221979Mapimi, Mexico0293
0000780ParadamiteBennett T J (1980) Crystal structure of paradamite American Mineralogist 65 353-35419800293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Loading XRD data...
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
6.32 Å(70)
5.46 Å(50)
3.70 Å(100)
2.99 Å(100)
2.84 Å(100)
2.57 Å(50)
2.51 Å(50)
2.48 Å(70)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47d : [Arsenates, antimonates, selenates, bismuthinates]
Stage 10b: Anthropogenic minerals<10 Ka
56 : Slag and smelter minerals (see also #51 and #55)

Type Occurrence of ParadamiteHide

General Appearance of Type Material:
Sheaflike aggregates of crystals and as somewhat rounded and striated equant crystals up to 5 mm in size.
Place of Conservation of Type Material:
The Natural History Museum, London, England, number 1969,184.
Harvard University, Cambridge, Massachusetts, USA, number 106376.
National Museum of Natural History, Washington, D.C., USA, numbers R9492, 106378, 107443, 112518, 125506.
Geological Setting of Type Material:
Oxidized zone of a polymetallic ore deposit.
Associated Minerals at Type Locality:

Other Language Names for ParadamiteHide

Relationship of Paradamite to other SpeciesHide

Other Members of Tarbuttite Group:
TarbuttiteZn2(PO4)(OH)Tric. 1 : P1

Common AssociatesHide

Associations Based on Photo Data:
27 photos of Paradamite associated with LegranditeZn2(AsO4)(OH) · H2O
8 photos of Paradamite associated with AdamiteZn2(AsO4)(OH)
5 photos of Paradamite associated with SmithsoniteZnCO3
3 photos of Paradamite associated with HydrozinciteZn5(CO3)2(OH)6
3 photos of Paradamite associated with OjuelaiteZnFe3+2(AsO4)2(OH)2 · 4H2O
3 photos of Paradamite associated with AustiniteCaZn(AsO4)(OH)
2 photos of Paradamite associated with 'Limonite'
1 photo of Paradamite associated with GoethiteFe3+O(OH)
1 photo of Paradamite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

8.BB.MoabiteNiFe3+(PO4)OOrth. mmm(2/m2/m2/m) : Pnma
8.BB.TilasiteCaMg(AsO4)FMon.
8.BB.PaulgrothiteCu9Fe3+O4(PO4)4Cl3Orth. mm2 : Cmc21
8.BB.KarlditmariteCu9O4(PO4)2(SO4)2Tric. 1 : P1
8.BB.MilkovoiteCu4O(PO4)(AsO4)Orth. mmm(2/m2/m2/m) : Pnma
8.BB.XArsenowagneriteMg2(AsO4)FMon. 2/m : P21/b
8.BB.05TavoriteLiFe3+(PO4)(OH)Tric. 1 : P1
8.BB.05AmblygoniteLiAl(PO4)FTric. 1 : P1
8.BB.05MontebrasiteLiAl(PO4)(OH)Tric. 1 : P1
8.BB.10ZwieseliteFe2+2(PO4)FMon. 2/m : P21/b
8.BB.10TripliteMn2+2(PO4)FMon. 2/m
8.BB.15'Unnamed (Sb-analogue of Auriacusite)'Fe3+Cu2+[(Sb,As)O4]O
8.BB.15JoosteiteMn2+(Mn3+,Fe3+)(PO4)OMon. 2/m
8.BB.15HydroxylwagneriteMg2(PO4)(OH)Mon. 2/m : P21/b
8.BB.15WagneriteMg2(PO4)FMon. 2/m : P21/b
8.BB.15Stanĕkite(Mn2+,Fe2+,Mg)Fe3+(PO4)OMon. 2/m : P21/b
8.BB.15TriploiditeMn2+2(PO4)(OH)Mon. 2/m : P2/b
8.BB.15SarkiniteMn2+2(AsO4)(OH)Mon. 2/m : P21/b
8.BB.15WolfeiteFe2+2(PO4)(OH)Mon. 2/m : P21/b
8.BB.20HoltedahliteMg2(PO4)(OH)Trig. 3m : P31m
8.BB.20Satterlyite(Fe2+,Mg,Fe)12(PO4)5(PO3OH)(OH,O)6Trig. 3m(32/m) : P31m
8.BB.25AlthausiteMg4(PO4)2(OH,O)(F,◻)Orth. mmm(2/m2/m2/m) : Pnma
8.BB.30ZincoliveniteCuZn(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30AdamiteZn2(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30LibetheniteCu2(PO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30ZincolibetheniteCuZn(PO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30EveiteMn2+2(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30OliveniteCu2(AsO4)(OH)Mon. 2/m : P21/m
8.BB.30AuriacusiteFe3+Cu2+(AsO4)OOrth. mmm(2/m2/m2/m) : Pnnm
8.BB.35TarbuttiteZn2(PO4)(OH)Tric. 1 : P1
8.BB.40BarbosaliteFe2+Fe3+2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40ScorzaliteFe2+Al2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40LazuliteMgAl2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40MeizhouiteFe2+V3+2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40HentscheliteCuFe3+2(PO4)2(OH)2Mon. 2/m : P21/m
8.BB.40WilhelmkleiniteZnFe3+2(AsO4)2(OH)2Mon. 2/m : P21/m
8.BB.45DokuchaeviteCu8O2(VO4)3Cl3Tric. 1 : P1
8.BB.45TrolleiteAl4(PO4)3(OH)3Mon. 2/m : B2/b
8.BB.45YaroshevskiteCu9O2(VO4)4Cl2 Tric. 1 : P1
8.BB.50NamibiteCu(BiO)2(VO4)(OH)Tric. 1 : P1
8.BB.50Aleutite[Cu5O2](AsO4)(VO4) · (Cu,K,Pb,Rb,Cs,)ClMon. 2/m : B2/m
8.BB.52aEriclaxmaniteCu4O(AsO4)2Tric. 1 : P1
8.BB.52bKozyrevskiteCu4O(AsO4)2Orth. mmm(2/m2/m2/m) : Pnma
8.BB.55Phosphoellenbergerite(Mg,◻)2Mg12(PO4,PO3OH)6(PO3OH,CO3)2(OH)6Hex. 6mm : P63mc
8.BB.55PopoviteCu5O2(AsO4)2Tric. 1 : P1
8.BB.60UrusoviteCuAl(AsO4)OMon. 2/m : P21/b
8.BB.65TheoparacelsiteCu3(As2O7)(OH)2Orth. mmm(2/m2/m2/m) : Pmma
8.BB.70TuraniteCu5(VO4)2(OH)4Tric. 1 : P1
8.BB.75StoiberiteCu5(VO4)2O2Mon. 2/m
8.BB.80FingeriteCu11(VO4)6O2Tric. 1 : P1
8.BB.85AverieviteCu6(VO4)2O2Cl2Trig. 3 : P3
8.BB.90RichelliteCaFe3+2(PO4)2(OH,F)2Amor.
8.BB.90LipscombiteFe2+Fe3+2(PO4)2(OH)2Tet. 422 : P41212
8.BB.90ZinclipscombiteZnFe3+2(PO4)2(OH)2Tet. 422 : P43212

Fluorescence of ParadamiteHide

Not fluorescent from Ojuela Mine, Mapimi, Durango, Mexico.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ParadamiteHide

References for ParadamiteHide

Localities for ParadamiteHide

Showing 9 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany
 
  • North Rhine-Westphalia
    • Arnsberg
      • Märkischer Kreis
        • Iserlohn
          • Letmathe
            • Helmke quarry nature reserve
Bender et al. (1994)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Agios Konstantinos (Kamariza)
          • Mercati mines
Mineralienwelt 5/2018 p.75 +1 other reference
Mexico (TL)
 
  • Durango
    • Mapimí Municipality
      • Mapimí
Switzer (1956) +2 other references
Moore (2008)
Moore (2018)
  • Nuevo León
    • Lampazos de Naranjo Municipality
      • Lampazos de Naranjo (Lampazos)
Mike Shannon
Namibia
 
  • Oshikoto Region
    • Tsumeb
Gebhard (1999)
Spain
 
  • Andalusia
    • Córdoba
      • Belalcázar
        • La Ventosilla farmhouse
Rewitzer et al. (2018)
 
and/or  
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