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Holtedahlite

A valid IMA mineral species
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About HoltedahliteHide

03160640017271923974271.jpg
Olaf Holtedahl
Formula:
Mg2(PO4)(OH)
Colour:
Colorless
Lustre:
Vitreous
Hardness:
4½ - 5
Specific Gravity:
2.94
Crystal System:
Trigonal
Name:
First mentioned in Raade & Tysseland (1975) as "an unidentified Ca-Mg-phosphate". First described by Raade & Mladeck (1979).

Named in honor of Olaf Holtedahl (24 June 1885, Oslo, Norway - 28 August 1975), professor of geology at the University of Oslo. He was the recipient of the Wollastone Medal of the Geological Society of London and the Leopold von Buch Medal from Deutsche Geologische Gesellschaft.
Occurs as irregular masses and patches. It's difficult to visually distinguish between holtedahlite and the associated apatite. It typically contains inclusions of small magnetite grains which may impart a greyish color to it (Raade & Mladeck 1979)


Unique IdentifiersHide

Mindat ID:
1924
Long-form identifier:
mindat:1:1:1924:4

IMA Classification of HoltedahliteHide

Approved
IMA Formula:
Mg12(PO3OH,CO3)(PO4)5(OH,O)6
Approval year:
1976
First published:
1979

Classification of HoltedahliteHide

8.BB.20

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
B : With only medium-sized cations, (OH, etc.):RO4 about 1:1
41.6.4.2

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
6 : A2(XO4)Zq
19.3.15

19 : Phosphates
3 : Phosphates of Be and Mg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
HtdIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HoltedahliteHide

Vitreous
Transparency:
Transparent
Colour:
Colorless
Streak:
White
Hardness:
4½ - 5 on Mohs scale
Cleavage:
None Observed
Shows no cleavage
Fracture:
Irregular/Uneven
Density:
2.94 g/cm3 (Measured)    2.936 g/cm3 (Calculated)

Optical Data of HoltedahliteHide

Type:
Uniaxial (-)
RI values:
nω = 1.599 nε = 1.597
Max. Birefringence:
δ = 0.002
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of HoltedahliteHide

Mindat Formula:
Mg2(PO4)(OH)
Element Weights:
Element% weight
O49.815 %
Mg30.270 %
P19.288 %
H0.628 %

Calculated from ideal end-member formula.
O
Mg
P
H

Crystallography of HoltedahliteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
P31m
Cell Parameters:
a = 11.203(3) Å, c = 4.977(1) Å
Ratio:
a:c = 1 : 0.444
Unit Cell V:
540.96 ų (Calculated from Unit Cell)
Z:
6
Morphology:
Occurred as masses and irregular patches, no external form has been observed.
Comment:
Rømming & Raade (1989).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014622HoltedahliteRomming C, Raade G (1989) The crystal structure of natural and synthetic holtedahlite Mineralogy and Petrology 40 91-1001989synthetic0293
0014621HoltedahliteRomming C, Raade G (1989) The crystal structure of natural and synthetic holtedahlite Mineralogy and Petrology 40 91-1001989Tingelstadtjern serpentine-magnesium deposit, Modum, Norway0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.722 Å(90)
3.475 Å(50)
3.234 Å(30)
2.796 Å(30)
2.438 Å(100)
2.177 Å(30)
1.859 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3b: Earth’s earliest hydrosphere>4.45
13 : Hadean serpentinization
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Stage 7: Great Oxidation Event<2.4
45b : [Other oxidized fumarolic minerals]

Type Occurrence of HoltedahliteHide

General Appearance of Type Material:
Colorless masses and patches intimately associated with althausite and apatite.
Place of Conservation of Type Material:
The Natural History Museum in Oslo
Geological Setting of Type Material:
Serpentinite-magnesite deposit.
Associated Minerals at Type Locality:

Synonyms of HoltedahliteHide

Other Language Names for HoltedahliteHide

Common AssociatesHide

Associations Based on Photo Data:
11 photos of Holtedahlite associated with AlthausiteMg4(PO4)2(OH,O)(F,◻)
6 photos of Holtedahlite associated with LizarditeMg3(Si2O5)(OH)4
5 photos of Holtedahlite associated with 'Apatite'Ca5(PO4)3A
3 photos of Holtedahlite associated with ChlorapatiteCa5(PO4)3Cl
1 photo of Holtedahlite associated with HydroxylapatiteCa5(PO4)3(OH)
1 photo of Holtedahlite associated with Phosphoellenbergerite(Mg,◻)2Mg12(PO4,PO3OH)6(PO3OH,CO3)2(OH)6
1 photo of Holtedahlite associated with HeneuiteCaMg5(CO3)(PO4)3(OH)
1 photo of Holtedahlite associated with RaadeiteMg7(PO4)2(OH)8
1 photo of Holtedahlite associated with HematiteFe2O3

Related Minerals - Strunz-mindat GroupingHide

8.BB.MoabiteNiFe3+(PO4)OOrth. mmm(2/m2/m2/m) : Pnma
8.BB.TilasiteCaMg(AsO4)FMon.
8.BB.PaulgrothiteCu9Fe3+O4(PO4)4Cl3Orth. mm2 : Cmc21
8.BB.KarlditmariteCu9O4(PO4)2(SO4)2Tric. 1 : P1
8.BB.MilkovoiteCu4O(PO4)(AsO4)Orth. mmm(2/m2/m2/m) : Pnma
8.BB.XArsenowagneriteMg2(AsO4)FMon. 2/m : P21/b
8.BB.05TavoriteLiFe3+(PO4)(OH)Tric. 1 : P1
8.BB.05AmblygoniteLiAl(PO4)FTric. 1 : P1
8.BB.05MontebrasiteLiAl(PO4)(OH)Tric. 1 : P1
8.BB.10ZwieseliteFe2+2(PO4)FMon. 2/m : P21/b
8.BB.10TripliteMn2+2(PO4)FMon. 2/m
8.BB.15'Unnamed (Sb-analogue of Auriacusite)'Fe3+Cu2+[(Sb,As)O4]O
8.BB.15JoosteiteMn2+(Mn3+,Fe3+)(PO4)OMon. 2/m
8.BB.15HydroxylwagneriteMg2(PO4)(OH)Mon. 2/m : P21/b
8.BB.15WagneriteMg2(PO4)FMon. 2/m : P21/b
8.BB.15Stanĕkite(Mn2+,Fe2+,Mg)Fe3+(PO4)OMon. 2/m : P21/b
8.BB.15TriploiditeMn2+2(PO4)(OH)Mon. 2/m : P2/b
8.BB.15SarkiniteMn2+2(AsO4)(OH)Mon. 2/m : P21/b
8.BB.15WolfeiteFe2+2(PO4)(OH)Mon. 2/m : P21/b
8.BB.20Satterlyite(Fe2+,Mg,Fe)12(PO4)5(PO3OH)(OH,O)6Trig. 3m(32/m) : P31m
8.BB.25AlthausiteMg4(PO4)2(OH,O)(F,◻)Orth. mmm(2/m2/m2/m) : Pnma
8.BB.30ZincoliveniteCuZn(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30AdamiteZn2(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30LibetheniteCu2(PO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30ZincolibetheniteCuZn(PO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30EveiteMn2+2(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30OliveniteCu2(AsO4)(OH)Mon. 2/m : P21/m
8.BB.30AuriacusiteFe3+Cu2+(AsO4)OOrth. mmm(2/m2/m2/m) : Pnnm
8.BB.35ParadamiteZn2(AsO4)(OH)Tric. 1 : P1
8.BB.35TarbuttiteZn2(PO4)(OH)Tric. 1 : P1
8.BB.40BarbosaliteFe2+Fe3+2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40ScorzaliteFe2+Al2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40LazuliteMgAl2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40MeizhouiteFe2+V3+2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40HentscheliteCuFe3+2(PO4)2(OH)2Mon. 2/m : P21/m
8.BB.40WilhelmkleiniteZnFe3+2(AsO4)2(OH)2Mon. 2/m : P21/m
8.BB.45DokuchaeviteCu8O2(VO4)3Cl3Tric. 1 : P1
8.BB.45TrolleiteAl4(PO4)3(OH)3Mon. 2/m : B2/b
8.BB.45YaroshevskiteCu9O2(VO4)4Cl2 Tric. 1 : P1
8.BB.50NamibiteCu(BiO)2(VO4)(OH)Tric. 1 : P1
8.BB.50Aleutite[Cu5O2](AsO4)(VO4) · (Cu,K,Pb,Rb,Cs,)ClMon. 2/m : B2/m
8.BB.52aEriclaxmaniteCu4O(AsO4)2Tric. 1 : P1
8.BB.52bKozyrevskiteCu4O(AsO4)2Orth. mmm(2/m2/m2/m) : Pnma
8.BB.55Phosphoellenbergerite(Mg,◻)2Mg12(PO4,PO3OH)6(PO3OH,CO3)2(OH)6Hex. 6mm : P63mc
8.BB.55PopoviteCu5O2(AsO4)2Tric. 1 : P1
8.BB.60UrusoviteCuAl(AsO4)OMon. 2/m : P21/b
8.BB.65TheoparacelsiteCu3(As2O7)(OH)2Orth. mmm(2/m2/m2/m) : Pmma
8.BB.70TuraniteCu5(VO4)2(OH)4Tric. 1 : P1
8.BB.75StoiberiteCu5(VO4)2O2Mon. 2/m
8.BB.80FingeriteCu11(VO4)6O2Tric. 1 : P1
8.BB.85AverieviteCu6(VO4)2O2Cl2Trig. 3 : P3
8.BB.90RichelliteCaFe3+2(PO4)2(OH,F)2Amor.
8.BB.90LipscombiteFe2+Fe3+2(PO4)2(OH)2Tet. 422 : P41212
8.BB.90ZinclipscombiteZnFe3+2(PO4)2(OH)2Tet. 422 : P43212

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HoltedahliteHide

References for HoltedahliteHide

Localities for HoltedahliteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Norway (TL)
 
  • Buskerud
    • Modum
Raade et al. (1979)
 
and/or  
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