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Goethite

A valid IMA mineral species - grandfathered
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About GoethiteHide

02287060017271923643717.jpg
Johann Wolfgang von Goethe
Formula:
Fe3+O(OH)
Previously α-Fe#3+#O(OH)
Colour:
Brownish black, yellow-brown, reddish brown
Lustre:
Adamantine, Silky, Metallic, Dull
Hardness:
5 - 5½
Specific Gravity:
4.27 - 4.29
Crystal System:
Orthorhombic
Member of:
Name:
Named in 1806 by Johann Georg Lenz in honor of the German poet, novelist, playwrighter, philosopher, politician, and geoscientist Johann Wolfgang von Goethe [August 28, 1749, Frankfurt, Germany – March 22, 1832, Weimar, Germany]. Goethe was Chief Minister of State of Weimar.
The most common simple iron oxide mineral. A weathering product of numerous iron-bearing minerals.

Goethite may crystallize from a precursor - called 'proto-goethite' (not an approved mineral species). Can also form due to mineralization of lichen (Parmelia conspersa) thalli on metamorphics (e.g., gneisses), granites, feldspars.

Sulfidation of goethite into mackinawite and pyrrhotite is described by Wang et al. (2015); the process is inactive in the CH4 atmosphere but is triggered by the addition of CO2.




Unique IdentifiersHide

Mindat ID:
1719
Long-form identifier:
mindat:1:1:1719:6

Similar NamesHide

IMA Classification of GoethiteHide

Approved, 'Grandfathered' (first described prior to 1959)

Classification of GoethiteHide

4.FD.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
D : Hydroxides with OH, without H2O; chains of edge-sharing octahedra
6.1.1.2

6 : HYDROXIDES AND OXIDES CONTAINING HYDROXYL
1 : XO(OH)
7.20.5

7 : Oxides and Hydroxides
20 : Oxides of Fe

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
GthIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
GtKretz (1983)Kretz, R. (1983) Symbols of rock-forming minerals. American Mineralogist, 68, 277–279.
GtSiivolam & Schmid (2007)Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download
GthWhitney & Evans (2010)Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371
GtThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download
GthWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Pronunciation of GoethiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of GoethiteHide

Adamantine, Silky, Metallic, Dull
Transparency:
Opaque
Colour:
Brownish black, yellow-brown, reddish brown
Streak:
Yellowish brown, orange-yellow, ocher-yellow
Hardness:
5 - 5½ on Mohs scale
Hardness:
VHN100=667 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
Perfect
{010}; {100} less perfect.
Fracture:
Irregular/Uneven
Density:
4.27 - 4.29 g/cm3 (Measured)    4.18 g/cm3 (Calculated)

Optical Data of GoethiteHide

Type:
Biaxial (-)
RI values:
nα = 2.260 - 2.275 nβ = 2.393 - 2.409 nγ = 2.393 - 2.409
2V:
Calculated: 20°
Max. Birefringence:
δ = 0.133 - 0.134
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Anisotropism:
Distinct; in bluish grays
Dispersion:
relatively strong r>v
Optical Extinction:
X = b; Y = c; Z = a.
Reflectivity:
WavelengthR1 (%)R2 (%)
400nm17.5%19.2%
420nm16.7%18.3%
440nm15.9%17.4%
460nm15.2%16.7%
480nm14.6%16.0%
500nm14.1%15.5%
520nm13.7%15.0%
540nm13.3%14.6%
560nm13.0%14.3%
580nm12.8%14.0%
600nm12.5%13.7%
620nm12.4%13.5%
640nm12.2%13.4%
660nm12.0%13.2%
680nm12.0%13.1%
700nm11.9%13.0%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 19.2%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Gray with bluish tint
Internal Reflections:
Yellow, red, brown
Pleochroism:
Strong
Comments:
X = red b/yellow b = clear yellow
Y = red a/yellow c = brown-yellow
Z = red c/yellow a = orange-yellow
Comments:
Absorption: Z > Y > X.

Chemistry of GoethiteHide

Mindat Formula:
Fe3+O(OH)

Previously α-Fe#3+#O(OH)
Element Weights:
Element% weight
Fe62.852 %
O36.014 %
H1.134 %

Calculated from ideal end-member formula.
Fe
O
H
Common Impurities:
Mn

Crystallography of GoethiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnma
Cell Parameters:
a = 4.608 Å, b = 9.956 Å, c = 3.0215 Å
Ratio:
a:b:c = 0.463 : 1 : 0.303
Unit Cell V:
138.62 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Prismatic [001] and striated [001]; also flattened into tablets or scales on {010}. Velvety aggregates of capillary crystals to acicular [001] and long prismatic forms often radially grouped. Massive, reniform, botryoidal, stalactitic. Bladed or columnar. Compact or fibrous concretionary nodules. Oolitic.
Twinning:
Apparently none reported, but see https://www.mindat.org/mesg-631125.html and compare twinning in isostructural diaspore.
Comment:
Non-standard space-group setting Pbnm.

Crystallographic forms of GoethiteHide

Crystal Atlas:
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Goethite no.4 - {110} - Goldschmidt (1913-1926)
View 3D crystal model
Goethite no.29 - {110} - Goldschmidt (1913-1926)
3d models and HTML5 code kindly provided by www.smorf.nl.

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Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0004542GoethiteAlvarez M, Sileo E E, Rueda E H (2008) Structure and reactivity of synthetic Co-substituted goethites American Mineralogist 93 584-5902008synthetic0293
0004541GoethiteAlvarez M, Sileo E E, Rueda E H (2008) Structure and reactivity of synthetic Co-substituted goethites American Mineralogist 93 584-5902008synthetic0293
0004540GoethiteAlvarez M, Sileo E E, Rueda E H (2008) Structure and reactivity of synthetic Co-substituted goethites American Mineralogist 93 584-5902008synthetic0293
0004539GoethiteAlvarez M, Sileo E E, Rueda E H (2008) Structure and reactivity of synthetic Co-substituted goethites American Mineralogist 93 584-5902008synthetic0293
0004538GoethiteAlvarez M, Sileo E E, Rueda E H (2008) Structure and reactivity of synthetic Co-substituted goethites American Mineralogist 93 584-5902008synthetic0293
0010471GoethiteYang H, Lu R, Downs R T, Costin G (2006) Goethite, alpha-FeO(OH), from single-crystal data Acta Crystallographica E62 i250-i2522006Park County, Colorado, USA0293
0010571GoethiteHoppe W (1940) Uber die kristallstruktur von alpha-AlOOH (diaspore) und alpha-Fe OOH(nadeleisenerz) Zeitschrift fur Kristallographie 103 73-891940Synthetic0293
0002226GoethiteGualtieri A, Venturelli P (1999) In situ study of the goethite-hematite phase transformation by real time synchrotron powder diffraction American Mineralogist 84 895-90419990298
0003165GoethiteNagai T, Kagi H, Yamanaka T (2003) Variation of hydrogen bonded O...O distances in goethite at high pressure American Mineralogist 88 1423-142720030293
0016645GoethiteHazemann J, Berar J, Manceau A (1991) Rietveld studies of the aluminium-iron substitution in synthetic goethite _cod_database_code 1008768 Materials Science Forum 79 821-82619910293
0016644GoethiteHazemann J, Berar J, Manceau A (1991) Rietveld studies of the aluminium-iron substitution in synthetic goethite _cod_database_code 1008767 Materials Science Forum 79 821-82619910293
0016643GoethiteHazemann J, Berar J, Manceau A (1991) Rietveld studies of the aluminium-iron substitution in synthetic goethite _cod_database_code 1008766 Materials Science Forum 79 821-82619910293
0017983GoethiteGoldsztaub M (1935) Etude de quelques derives de l'oxyde ferrique (Fe O * O H, Fe O2 Na, Fe O Cl) determination de leurs structures. _cod_database_code 1011087 Bulletin de la Societe Francaise de Mineralogie 58 6-7619350293
0002227GoethiteGualtieri A, Venturelli P (1999) In situ study of the goethite-hematite phase transformation by real time synchrotron powder diffraction American Mineralogist 84 895-90419990429
0003166GoethiteNagai T, Kagi H, Yamanaka T (2003) Variation of hydrogen bonded O...O distances in goethite at high pressure American Mineralogist 88 1423-142720030.5293
0003167GoethiteNagai T, Kagi H, Yamanaka T (2003) Variation of hydrogen bonded O...O distances in goethite at high pressure American Mineralogist 88 1423-142720032.8293
0003168GoethiteNagai T, Kagi H, Yamanaka T (2003) Variation of hydrogen bonded O...O distances in goethite at high pressure American Mineralogist 88 1423-142720036.3293
0003169GoethiteNagai T, Kagi H, Yamanaka T (2003) Variation of hydrogen bonded O...O distances in goethite at high pressure American Mineralogist 88 1423-142720039293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Loading XRD data...
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
4.98 Å(12)
4.183 Å(100)
2.693 Å(35)
2.450 Å(50)
2.253 Å(14)
2.190 Å(18)
1.7192 Å(20)

Geological EnvironmentHide

Paragenetic Mode(s):
Geological Setting:
Common weathering product, primary hydrothermal mineral, bog and marine environments.

Type Occurrence of GoethiteHide

Synonyms of GoethiteHide

Other Language Names for GoethiteHide

Varieties of GoethiteHide

AlumogoethiteAl-bearing goethite.
EhrenwerthiteA name for goethite pseudomorphs after pyrite.
SammetblendeA fuzzy variety of goethite with a velvety luster created by carpets of microscopic acicular crystals forming crusts or balls. The name is derived from the German word for "velvet" and is often used for this variety in Germany and Bohemia. A more modern s...
SammtblendeA fuzzy variety of goethite with a velvety luster created by carpets of microscopic acicular crystals forming crusts or balls. The name is derived from the German word for "velvet" and is often used for this variety in Germany and Bohemia. A more modern s...
SamtblendeA fuzzy variety of goethite with a velvety luster created by carpets of microscopic acicular crystals forming crusts or balls. The name is derived from the German word for "velvet" and is often used for this variety in Germany and Bohemia.
Wood Iron (Goethite)Fibrous varieties of goethite.

See also Wood Iron (Siderite): fibrous siderite

Relationship of Goethite to other SpeciesHide

Member of:
Other Members of Diaspore Group:
BracewelliteCrO(OH)Orth. mmm(2/m2/m2/m)
DiasporeAlO(OH)Orth. mmm(2/m2/m2/m)
GroutiteMn3+O(OH)Orth. mmm(2/m2/m2/m) : Pnma
Montroseite(V3+,Fe3+)O(OH)Orth. mmm(2/m2/m2/m)
TsumgalliteGaO(OH)Orth. mmm(2/m2/m2/m)

Common AssociatesHide

Associations Based on Photo Data:
2,422 photos of Goethite associated with QuartzSiO2
1,311 photos of Goethite associated with CalciteCaCO3
998 photos of Goethite associated with HematiteFe2O3
742 photos of Goethite associated with MalachiteCu2(CO3)(OH)2
493 photos of Goethite associated with BaryteBaSO4
493 photos of Goethite associated with 'Limonite'
438 photos of Goethite associated with PyriteFeS2
325 photos of Goethite associated with ChalcopyriteCuFeS2
265 photos of Goethite associated with FluoriteCaF2
253 photos of Goethite associated with 'Smoky Quartz'SiO2

Related Minerals - Strunz-mindat GroupingHide

4.FD.05SpertiniiteCu(OH)2Orth. mm2 : Cmc21
4.FD.10DiasporeAlO(OH)Orth. mmm(2/m2/m2/m)
4.FD.10Montroseite(V3+,Fe3+)O(OH)Orth. mmm(2/m2/m2/m)
4.FD.10TsumgalliteGaO(OH)Orth. mmm(2/m2/m2/m)
4.FD.10GroutiteMn3+O(OH)Orth. mmm(2/m2/m2/m) : Pnma
4.FD.10BracewelliteCrO(OH)Orth. mmm(2/m2/m2/m)
4.FD.10GuyanaiteCrO(OH)Orth. mmm(2/m2/m2/m)
4.FD.15ManganiteMn3+O(OH)Mon. 2/m : P21/b
4.FD.20Yttrotungstite-(Y)YW2O7(OH) · H2OMon. 2/m : P21/m
4.FD.20Yttrotungstite-(Ce)CeW2O7(OH) · H2OMon. 2 : P21
4.FD.25FrankhawthorneiteCu2Te6+O4(OH)2Mon. 2/m
4.FD.30'Khinite-3T'Pb2+Cu2+3Te6+O6(OH)2Trig. 3 : P32
4.FD.30HousleyitePb6CuTe6+4O18(OH)2Mon. 2/m : P21/m
4.FD.30KhinitePb2+Cu2+3[Te6+O6](OH)2Orth. mm2 : Fdd2

Other InformationHide

Thermal Behaviour:
Heated in a closed tube, gives off water.
Notes:
Soluble in HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:
Iron ore

Goethite in petrologyHide

Internet Links for GoethiteHide

References for GoethiteHide

Reference List:

Significant localities for GoethiteHide

Showing 31 significant localities out of 10,014 recorded on mindat.org.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Ningxia
    • Zhongwei
      • Shapotou District
Zhaoxia Qiu (1989) +2 other references
Colombia
 
  • Cundinamarca Department
Moritz (n.d.)
France
 
  • Centre-Val de Loire
    • Indre
      • Le Blanc
        • Chaillac
Baillargeat (1981) +1 other reference
  • Provence-Alpes-Côte d'Azur
    • Var
      • Draguignan
        • Fréjus
MAURY (S)
Germany (TL)
 
  • Rhineland-Palatinate
    • Altenkirchen
      • Daaden-Herdorf
        • Herdorf
          • Dermbach
Overkott et al. (2007)
Hungary
 
  • Baranya County
    • Pécs District
      • Kővágótöttös
Szakáll et al. (1996)
Ireland
 
  • Leinster
    • Wicklow County
      • Blessington
        • Kilbride
  • Munster
    • Cork County
      • Glandore
Stephen Moreton Collection
Italy
 
  • Tuscany
    • Grosseto Province
      • Arcidosso
        • Bagnoli
Giannetti (1873) +1 other reference
      • Castel del Piano
Giannetti (1873) +1 other reference
    • Livorno Province
      • Rio
        • Rio Marina
          • Rio Mine
Norway
 
  • Innlandet
    • Gran
Goldschmidt (1911)
Portugal
 
  • Setúbal
    • Santiago do Cacém
      • Cercal do Alentejo
Betts (n.d.)
Slovakia
 
  • Banská Bystrica Region
    • Revúca District
      • Sirk
Grecula (1995)
South Africa
 
  • North West
    • Bojanala Platinum District Municipality
      • Madibeng Local Municipality
        • Brits
Robert O. Meyer collection +9 other references
Spain
 
  • Andalusia
    • Huelva
      • Alosno
        • Tharsis
          • Tharsis Mines
Calvo Rebollar (2009)
  • Basque Country
    • Biscay
      • Valle de Trápaga (Trapagaran)
Calvo Rebollar (2009) +1 other reference
  • Castile-La Mancha
    • Guadalajara
      • Tordelrábano
Calvo (1999) +1 other reference
USA
 
  • Arkansas
    • Garland County
      • Blue Springs
Benjamin Shacar Collection
  • Connecticut
    • Litchfield County
      • Kent
Shepard (1837)
      • Salisbury
Hobbs (1907) +1 other reference
    • New Haven County
      • East Haven
Powell (1987)
Moritz (n.d.)
        • Foxon
Mike Polletta specimen
Vener (1987)
  • New York
    • Dutchess County
      • Town of Beekman
        • Beekman
Newland (1919)
  • North Carolina
    • Davidson County
      • Cid Mining District
Steve Adams +1 other reference
  • Pennsylvania
    • Montgomery County
      • Springfield Township
The Mineralogy of Pennsylvania 1922 +1 other reference
  • Rhode Island
    • Providence County
      • Cumberland
        • Diamond Hill
  • Washington
    • King County
      • Snoqualmie Mining District
        • Hansen Creek area
Eric He's Collection +1 other reference
    • Skagit County
Mustoe et al. (1996)
 
and/or  
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