Heyrovskýite
A valid IMA mineral species
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About Heyrovskýite
Formula:
Pb6Bi2S9
May contain minor Ag (substitution scheme 2Pb <-> Ag + Bi).
Colour:
Tin white
Lustre:
Metallic
Hardness:
4 - 5
Specific Gravity:
7.17
Crystal System:
Orthorhombic
Member of:
Name:
Named in 1971 J, Klominsky, M. Rieder, C. Kieft, and L. Mraz in honor of Jaroslav Heyrovský [1890-1967], professor of chemistry at Charles University, Prague, Czech Republic.
Closely related to aschamalmite, but always contains minor Ag (Mumme et al., 1983).
May exsolve/decompose to a mixture of galena and cosalite (Klomínský et al., 1971).
Bi may be substituted by Sb (Ertl et al., 1994).
A heyrovskýite with a doubled c-axis (2x 4.08 A) is decribed by Ertl et al. (1994).
May exsolve/decompose to a mixture of galena and cosalite (Klomínský et al., 1971).
Bi may be substituted by Sb (Ertl et al., 1994).
A heyrovskýite with a doubled c-axis (2x 4.08 A) is decribed by Ertl et al. (1994).
Name Encoding
ASCII-7:
Heyrovskyite
Unique Identifiers
Mindat ID:
6993
Long-form identifier:
mindat:1:1:6993:5
IMA Classification of Heyrovskýite
Approved
IMA Formula:
Pb2+6Bi3+2S2-9
Approval year:
1970
First published:
1971
Classification of Heyrovskýite
2.JB.40b
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb
3.3.3.1
3 : SULFOSALTS
3 : 3 <ø < 4
3 : SULFOSALTS
3 : 3 <ø < 4
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Hyv | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Heyrovskýite
Metallic
Transparency:
Opaque
Colour:
Tin white
Streak:
Greyish black
Hardness:
4 - 5 on Mohs scale
Hardness:
VHN50=166 - 234 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
Poor/Indistinct
Density:
7.17 g/cm3 (Measured) 7.18 g/cm3 (Calculated)
Optical Data of Heyrovskýite
Anisotropism:
Strong, dark gray to white in air, grayish-white to brownish in oil.
Bireflectance:
Weak in air with color white to light gray, distinct bireflectance in oil, white, to grayish white.
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 470nm | 43.3% | 47.3% |
| 546nm | 40.6% | 44.6% |
| 589nm | 39.8% | 43.9% |
| 650nm | 39.6% | 43.7% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 47.3%.
R1 shown in black, R2 shown in red
Chemistry of Heyrovskýite
Mindat Formula:
Pb6Bi2S9
May contain minor Ag (substitution scheme 2Pb <-> Ag + Bi).
May contain minor Ag (substitution scheme 2Pb <-> Ag + Bi).
Element Weights:
Elements listed:
Crystallography of Heyrovskýite
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Cccm
Setting:
Cccm
Cell Parameters:
a = 4.1457(3) Å, b = 13.7421(5) Å, c = 31.5005(12) Å
Ratio:
a:b:c = 0.302 : 1 : 2.292
Unit Cell V:
1794.6 ų
Z:
4
Comment:
Cell parameters from Pervukhina et al. (2012).
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.435 Å | (100) |
| 2.962 Å | (80) |
| 2.098 Å | (35) |
| 1.790 Å | (22) |
| 3.343 Å | (20) |
| 3.006 Å | (15) |
| 2.067 Å | (15) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 3a: Earth’s earliest Hadean crust | >4.50 |
| 11 : Volcanic fumarole minerals; reduced phases (see also #45) | |
| Stage 3b: Earth’s earliest hydrosphere | >4.45 |
| 12 : Hadean hydrothermal subsurface sulfide deposits (see also #33) | |
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Heyrovskýite
General Appearance of Type Material:
Acicular crystals less than 20 mm long and 0.1 to 0.5 mm thick, and in masses to 2 mm.
Place of Conservation of Type Material:
Charles University, Prague, Czech Republic, 14265.
Geological Setting of Type Material:
Hydrothermal; high-temperature quartz veins.
Associated Minerals at Type Locality:
Synonyms of Heyrovskýite
Other Language Names for Heyrovskýite
Dutch:Heyrovskýiet
German:Heyrovskýit
Heyrovskit
Heyrovskit
Russian:Хейровскит
Simplified Chinese:富硫铋铅矿
Spanish:Heyrovskita
Heyrovskýita
Heyrovskýita
Traditional Chinese:富硫鉍鉛礦
Varieties of Heyrovskýite
| Argentogoongarrite | Unnecessary name for an argentian variety of heyrovskýite. |
Relationship of Heyrovskýite to other Species
Member of:
Other Members of Lillianite Homologous Series:
| Andreadiniite | CuHgAg7Pb7Sb24S48 | Mon. 2/m : P21/b |
| Arsenquatrandorite | Ag17.6Pb12.8Sb38.1As11.5S96 | Mon. 2/m : P21/b |
| Aschamalmite | Pb6-3xBi2+xS9 | Mon. 2/m : B2/m |
| Baiamareite | Ag4Pb12Fe4Sb20S48 | Mon. 2/m |
| Brusnitsynite | Mn3CuPbAs3Sb2S12 | Mon. 2/m : P21/b |
| Clino-oscarkempffite | Ag15Pb6Sb21Bi18S72 | Mon. 2/m : P21/b |
| Erzwiesite | Ag8Pb12Bi16S40 | Orth. mmm(2/m2/m2/m) : Cmcm |
| Eskimoite | Ag7Pb10Bi15S36 | Mon. |
| Fizélyite | Ag5Pb14Sb21S48 | Mon. 2/m |
| Gustavite | AgPbBi3S6 | Orth. mmm(2/m2/m2/m) |
| Holubite | Ag3Pb6(Sb8Bi3)S24 | Mon. 2/m |
| Jasrouxite | Ag16Pb4(Sb25As15)S72 | Tric. 1 : P1 |
| Lasmanisite | Ag12Pb13Mn11Sb44S96 | Orth. 222 : P212121 |
| Lazerckerite | Ag3.75Pb4.50(Sb7.75Bi4)S24 | Mon. 2/m : P21/b |
| Lillianite | Pb3-2xAgxBi2+xS6 | Orth. mmm(2/m2/m2/m) |
| Menchettiite | AgPb2.40Mn1.60Sb3As2S12 | Mon. 2/m : P21/b |
| Oscarkempffite | Ag10Pb4(Sb17Bi9)S48 | Orth. mm2 |
| Ourayite | Ag3Pb4Bi5S13 | Orth. |
| Oyonite | Ag3Mn2Pb4Sb7As4S24 | Mon. 2/m |
| Quatrandorite | AgPbSb3S6 | Mon. 2/m : P21/b |
| Ramdohrite | Pb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24 | Mon. 2/m |
| Roshchinite | Ag19Pb10Sb51S96 | Orth. mmm(2/m2/m2/m) : Pnma |
| 'Schirmerite' | PbAgBi3S6 - Pb3Ag1.5Bi3.5S9 | Orth. |
| Senandorite | AgPbSb3S6 | Orth. mm2 : Pmn21 |
| Staročeskéite | Ag0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6 | Orth. mmm(2/m2/m2/m) : Cmcm |
| Tarutinoite | Ag3Pb7Bi7S19 | Mon. 2/m : B2/m |
| Terrywallaceite | AgPb(Sb,Bi)3S6 | Mon. 2/m : P21/b |
| Treasurite | Ag7Pb6Bi15S32 | Mon. |
| Uchucchacuaite | AgMnPb3Sb5S12 | Orth. mmm(2/m2/m2/m) : Pmmm |
| Ustarasite | Pb(Bi,Sb)6S10 (?) | |
| Vikingite | Ag5Pb8Bi13S30 | Mon. 2/m : B2/m |
| Xilingolite | Pb3Bi2S6 | Mon. |
Common Associates
Associations Based on Photo Data:
| 5 photos of Heyrovskýite associated with Quartz | SiO2 |
| 3 photos of Heyrovskýite associated with Pyrite | FeS2 |
| 1 photo of Heyrovskýite associated with Galena | PbS |
| 1 photo of Heyrovskýite associated with Lillianite | Pb3-2xAgxBi2+xS6 |
| 1 photo of Heyrovskýite associated with Chalcopyrite | CuFeS2 |
Related Minerals - Strunz-mindat Grouping
| 2.JB. | Clino-oscarkempffite | Ag15Pb6Sb21Bi18S72 |
| 2.JB. | Arsenquatrandorite | Ag17.6Pb12.8Sb38.1As11.5S96 |
| 2.JB. | Ginelfite | Ag2(Ag0.5Fe)TlPb23.5(Sb,As)33.5S76 |
| 2.JB. | Andreadiniite | CuHgAg7Pb7Sb24S48 |
| 2.JB. | Chukotkaite | AgPb7Sb5S15 |
| 2.JB. | Selenojunoite | Cu2Pb3Bi8Se16 |
| 2.JB. | Lechnerite | Ag10Cu4HgPb33Sb58S128 |
| 2.JB. | Cuprosenandorite | Ag16Cu8Pb24Sb72S144 |
| 2.JB. | Morleyite | Ag2CuPb25Sb24As4S68.5 |
| 2.JB. | Lazerckerite | Ag3.75Pb4.50(Sb7.75Bi4)S24 |
| 2.JB. | Lasmanisite | Ag12Pb13Mn11Sb44S96 |
| 2.JB. | Montpelvouxite | AgPb16Sb27As18S84 |
| 2.JB. | Senandorite | AgPbSb3S6 |
| 2.JB. | Oscarkempffite | Ag10Pb4(Sb17Bi9)S48 |
| 2.JB.05 | Diaphorite | Ag3Pb2Sb3S8 |
| 2.JB.10 | Cosalite | Pb2Bi2S5 |
| 2.JB.15 | Marrite | AgPbAsS3 |
| 2.JB.15 | Freieslebenite | AgPbSbS3 |
| 2.JB.20 | Cannizzarite | Pb48Bi56S132 |
| 2.JB.20 | Wittite | Pb9Bi12(S,Se)27 |
| 2.JB.25j | Rouxelite | Cu2HgPb23Sb27S65.5 |
| 2.JB.25i | Neyite | Ag2Cu6Pb25Bi26S68 |
| 2.JB.25a | Junoite | Cu2Pb3Bi8(S,Se)16 |
| 2.JB.25f | Ángelaite | Cu2AgPbBiS4 |
| 2.JB.25e | Galenobismutite | PbBi2S4 |
| 2.JB.25c | Nordströmite | CuPb3Bi7(Se4S10) |
| 2.JB.25i | Cuproneyite | Cu7Pb27Bi25S68 |
| 2.JB.25g | Nuffieldite | Cu1.4Pb2.4Bi2.4Sb0.2S7 |
| 2.JB.25h | Weibullite | Pb5Bi8Se7S11 |
| 2.JB.25d | Proudite | CuPb7.5Bi9.33(S,Se)22 |
| 2.JB.25b | Felbertalite | Cu2Pb6Bi8S19 |
| 2.JB.30a | Jordanite | Pb14As6S23 |
| 2.JB.30a | Geocronite | Pb14Sb6S23 |
| 2.JB.30a | Arsenmarcobaldiite | Pb12(As3.2Sb2.8)Σ6S21 |
| 2.JB.30b | Kirkiite | Pb10Bi3As3S19 |
| 2.JB.30c | Tsugaruite | Pb28As15S50Cl |
| 2.JB.30a | Marcobaldiite | Pb12(Sb3As2Bi)Σ6S21 |
| 2.JB.35d | Pellouxite | (Cu,Ag)Pb10Sb12S27O(Cl,S)0.6 |
| 2.JB.35e | Chovanite | Pb15-2xSb14+2xS36Ox (x ~ 0.2) |
| 2.JB.35a | Zinkenite | Pb9Sb22S42 |
| 2.JB.35c | Pillaite | Pb9Sb10S23ClO0.5 |
| 2.JB.35b | Scainiite | Pb14Sb30S54O5 |
| 2.JB.35f | Tubulite | Ag2Pb22Sb20S53 |
| 2.JB.40a | Fizélyite | Ag5Pb14Sb21S48 |
| 2.JB.40a | Ramdohrite | Pb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24 |
| 2.JB.40e | Ustarasite | Pb(Bi,Sb)6S10 (?) |
| 2.JB.40a | 'Bursaite' | Pb5Bi4S11 (?) |
| 2.JB.40 | 'UM1988-05-S:AgBiCuHgPb' | (Hg,Ag,Cu,Pb)5Pb5Bi11S27 |
| 2.JB.40 | 'UM1988-06-S:AgBiCuHgPb' | (Pb,Hg)12(Cu,Ag)3(Bi,Sb)10(S,Te)27 |
| 2.JB.40a | Terrywallaceite | AgPb(Sb,Bi)3S6 |
| 2.JB.40a | Jasrouxite | Ag16Pb4(Sb25As15)S72 |
| 2.JB.40a | Tarutinoite | Ag3Pb7Bi7S19 |
| 2.JB.40a | Oyonite | Ag3Mn2Pb4Sb7As4S24 |
| 2.JB.40a | Quatrandorite | AgPbSb3S6 |
| 2.JB.40a | Erzwiesite | Ag8Pb12Bi16S40 |
| 2.JB.40a | Vikingite | Ag5Pb8Bi13S30 |
| 2.JB.40a | Lillianite | Pb3-2xAgxBi2+xS6 |
| 2.JB.40b | Baiamareite | Ag4Pb12Fe4Sb20S48 |
| 2.JB.40a | Staročeskéite | Ag0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6 |
| 2.JB.40a | Roshchinite | Ag19Pb10Sb51S96 |
| 2.JB.40b | Aschamalmite | Pb6-3xBi2+xS9 |
| 2.JB.40b | Eskimoite | Ag7Pb10Bi15S36 |
| 2.JB.40a | Menchettiite | AgPb2.40Mn1.60Sb3As2S12 |
| 2.JB.40a | Holubite | Ag3Pb6(Sb8Bi3)S24 |
| 2.JB.40a | Brusnitsynite | Mn3CuPbAs3Sb2S12 |
| 2.JB.40a | Treasurite | Ag7Pb6Bi15S32 |
| 2.JB.40c | Ourayite | Ag3Pb4Bi5S13 |
| 2.JB.40a | Uchucchacuaite | AgMnPb3Sb5S12 |
| 2.JB.40d | 'Schirmerite' | PbAgBi3S6 - Pb3Ag1.5Bi3.5S9 |
| 2.JB.40a | Xilingolite | Pb3Bi2S6 |
| 2.JB.40a | Gustavite | AgPbBi3S6 |
| 2.JB.55 | Gratonite | Pb9As4S15 |
| 2.JB.60 | Marrucciite | Hg3Pb16Sb18S46 |
| 2.JB.65 | Vurroite | Pb20Sn2(Bi,As)22S54Cl6 |
| 2.JB.65 | Tazieffite | Pb20Cd2(As,Bi)22S50Cl10 |
| 2.JB.70 | Daliranite | PbHgAs2S5 |
Other Information
Notes:
HNO3 (1:1) stains variegated, brown after 1 minute.
HCl (1:1) stains weakly brown, easily rubs clean.
FeCl3 (20%), HgCl2 (5%), KCN (20%), KOH (40%) do not react.
HCl (1:1) stains weakly brown, easily rubs clean.
FeCl3 (20%), HgCl2 (5%), KCN (20%), KOH (40%) do not react.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Heyrovskýite
mindat.org URL:
https://www.mindat.org/min-6993.html
Please feel free to link to this page.
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References for Heyrovskýite
Reference List:
Craig, James R. (1967) Phase relations and mineral assemblages in the Ag-Bi-Pb-S system. Mineralium Deposita, 1 (4). 278-306 doi:10.1007/bf00205202
Klomínský, J.; Rieder, M.; Kieft, C.; Mráz, L. (1971) Heyrovskýite, 6(Pb0.86Bi0.08(Ag,Cu)0.04)S. Bi2S3 from Hůrky, Czechoslovakia, a new mineral of genetic interest. Mineralium Deposita, 6 (2). p.133-147. doi:10.1007/bf00206625
Takéuchi, Yoshio; Takagi, Junkou (1974) The structure of heyrovskyite (6PbS·Bi2S3). Proceedings of the Japan Academy, 50 (1). p.76-79. doi:10.2183/pjab1945.50.76
Moëlo, Yves; Marcoux, Eric; Makovicky, Emil; Karup-Møller, Sven; Legendre, Olivier (1987) Homologues de la lillianite (gustavite, vikingite, heyrovskyite riche en Ag et Bi.) de l'indice à W-As-(Pb,Bi,Ag) de La Roche-Balue (Loire Atlantique, France). Bulletin de Minéralogie, 110 (1). p.43-64. doi:10.3406/bulmi.1987.8025
Chang, Luke L. Y., Daqing Wu, , Knowles, Charles R. (1988) Phase relations in the system Ag2S-Cu2S-PbS-Bi2S3. Economic Geology, 83 (2) 405-418 doi:10.2113/gsecongeo.83.2.405
Makovicky, E.; Mumme, W. G.; Hoskins, B. F. (1991) The crystal structure of Ag-Bi-bearing heyrovskyite. The Canadian Mineralogist, 29 (3). p.553-559.
Mitolo, D., Capitani, G. C., Garavelli, A., Pinto, D. (2011) Transmission electron microscopy investigation of Ag-free lillianite and heyrovskýite from Vulcano, Aeolian Islands, Italy. American Mineralogist, 96 (2) 288-300 doi:10.2138/am.2011.3530
Pinto, D., Balic-Zunic, T., Garavelli, A., Vurro, F. (2011) Structure refinement of Ag-free heyrovskyite from Vulcano (Aeolian Islands, Italy) American Mineralogist, 96 (7) 1120-1128 doi:10.2138/am.2011.3635
Localities for Heyrovskýite
Showing 87 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| Simon et al. (1997) |
| R Bottrill |
| Bottrill et al. (2025) | |
Austria | |
| Pichler (2009) |
| PUTZ (2010) |
| Makovicky et al. (2010) |
| Topa et al. (2026) | |
| Paar (1979) |
| Strasser (1989) | |
| Chris Auer collection |
| Kolitsch (2010) | |
| Ertl et al. (1994) |
| Niedermayr (2007) |
Canada | |
| Makovicky et al. (1991) |
| Montgomery (n.d.) | |
| Moëlo et al. (1987) |
| Grant (2009) |
Chile | |
| Zentilli (2018) |
China | |
| Huan Hu et al. (2001) |
| Dianhao Huang et al. (1991) |
| Yingchen Ren (1999) |
| Yingchen Ren (1999) |
| Yingchen Ren et al. (1986) +4 other references |
| Yingchen Ren (1999) |
| Dianfen Chen and Wenmao Zhou (1995) |
Czech Republic | |
| Pažout (2017) |
| Klomínský et al. (1971) |
France | |
| Moëlo et al. (1987) |
Germany | |
| Anthony et al. (1990) +2 other references |
| Gröbner et al. (2011) |
| Schramm et al. (2023) | |
Greece | |
| Voudouris et al. (2003) |
Hungary | |
| Zajzon et al (2014) |
Italy | |
| Bruno Marello et al. (2023) |
| Piccoli et al. (2007) |
| Boscardin M. et al. (2013) |
| Borodaev et al. (2003) |
Japan | |
| Alfredo Petrov collection (obtained from Dr. Ryuji Marumoto) +2 other references |
| Shimizu et al. (1993) | |
| Sadanaga et al. (1974) |
| Uehara et al. (2014) |
Kosovo | |
| Kołodziejczyk et al. (2015) |
Mexico | |
| Sid Williams |
Papua New Guinea | |
| Noku et al. (2011) |
Peru | |
| Yáñez et al. (2014, May) |
Portugal | |
| Fuertes-Fuente et al. (2016) |
Romania | |
| Cook et al. (2002) +1 other reference |
| Cook et al. (2002) |
| Szakáll (2002) | |
| Szakáll et al. (2010) |
| Cook et al. (2004) |
| Buzatu et al. (2015) |
| Damian +7 other references | |
| Cook +1 other reference |
| Cook (1997) +1 other reference |
Russia | |
| Simanenko (2007) |
| Gonevchuk et al. (2005) |
| Gamyanin et al. (1998) |
| Pervukhina et al. (2012) |
| Mineralogical Society of America - ... |
| Эпова et al. (2025) |
| Yurgenson et al. (2023) | |
Slovakia | |
| Ďuďa R. et al. (1993) |
| Mikuš et al. (2026) |
| Pršek J. (Kandid. Diz.práca) |
| Koděra et al. (1986) | |
| Bálintová T. (2006) +1 other reference |
| Koděra et al. (1986) |
| Pršek J. (Kandid. dizert. práca) |
| Ozdín D. & Pršek J. (2004) |
| Ozdín D. & Pršek J. | |
Spain | |
| Moëlo et al. (1987) |
Switzerland | |
| Nowacki et al. (1976) +1 other reference |
| Schad (1989) |
| Schweizer strahler | |
Turkey | |
| Yigit (2012) +1 other reference |
UK | |
| Moëlo et al. (1987) |
USA | |
| Foord et al. (1989) |
| Mineral News: 16 (9) +2 other references | |
| Dunning et al. (2000) | |
| Hanson et al. (Rusty) |
| Mark Coolbaugh |
| Foord et al. (1989) +1 other reference |
| Moëlo et al. (1987) |
| John Lindell Collection |
| Castor et al. (2004) |
Uzbekistan | |
| Ashirov et al. (2023) |
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Hůrky, Čistá ring, Čistá, Rakovník District, Central Bohemian Region, Czech Republic