Scainiite
A valid IMA mineral species
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About Scainiite
Formula:
Pb14Sb30S54O5
Colour:
Black, bluish metallic with dark red tint
Lustre:
Metallic
Specific Gravity:
5.56 (Calculated)
Crystal System:
Monoclinic
Name:
For Dr. Giuseppe Scaini (1906-1988), engineer and skillful investigator of systematic and Italian mineralogy.
This page provides mineralogical data about Scainiite.
Unique Identifiers
Mindat ID:
7016
Long-form identifier:
mindat:1:1:7016:0
IMA Classification of Scainiite
Approved
IMA Formula:
Pb2+14Sb3+30S2-54O5
Approval year:
1997
First published:
1999
Type description reference:
Classification of Scainiite
2.JB.35b
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Scn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Scainiite
Metallic
Transparency:
Opaque
Colour:
Black, bluish metallic with dark red tint
Hardness:
VHN20=192 kg/mm2 - Vickers
Hardness Data:
Measured
Tenacity:
Brittle
Fracture:
Irregular/Uneven
Density:
5.56 g/cm3 (Calculated)
Optical Data of Scainiite
Anisotropism:
Weak
Bireflectance:
Weak
Reflectivity:
| Wavelength | R1 (%) |
|---|---|
| 400nm | 37.5% |
| 420nm | 38.0% |
| 400nm | 37.6% |
| 440nm | 37.6% |
| 460nm | 37.6% |
| 480nm | 37.0% |
| 500nm | 36.6% |
| 520nm | 36.2% |
| 540nm | 35.6% |
| 560nm | 35.4% |
| 580nm | 34.7% |
| 600nm | 34.1% |
| 620nm | 33.4% |
| 640nm | 32.8% |
| 660nm | 32.4% |
| 680nm | 32.0% |
| 700nm | 31.1% |
| 720nm | 30.9% |
| 740nm | 30.2% |
| 760nm | 29.8% |
| 780nm | 29.2% |
| 800nm | 29.8% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 38.0%.
Colour in reflected light:
Black
Internal Reflections:
Rare red internal reflections
Pleochroism:
Not Visible
Chemistry of Scainiite
Mindat Formula:
Pb14Sb30S54O5
Element Weights:
Elements listed:
Crystallography of Scainiite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 51.996(8) Å, b = 8.148(1) Å, c = 24.311(4) Å
β = 104.09(1)°
β = 104.09(1)°
Ratio:
a:b:c = 6.381 : 1 : 2.984
Unit Cell V:
9991 ų
Z:
4
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0006839 | Scainiite | Moelo Y, Meerschaut A, Orlandi P, Palvadeau P (2000) Lead-antimony sulfosalts from Tuscany (Italy): II - Crystal structure of scainiite, Pb14Sb30S54O5, an expanded monoclinic derivative of Ba12Bi24S48 hexagonal sub-type (zinkenite group) European Journal of Mineralogy 12 835-846 | 2000 | Tuscany, Italy | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.039 Å | (13) |
| 3.773 Å | (11) |
| 3.706 Å | (4) |
| 3.622 Å | (11) |
| 3.472 Å | (100) |
| 3.441 Å | (18) |
| 3.041 Å | (35) |
| 2.956 Å | (54) |
| 2.827 Å | (20) |
| 2.706 Å | (8) |
| 2.628 Å | (8) |
| 2.441 Å | (5) |
| 2.356 Å | (5) |
| 2.296 Å | (7) |
| 2.228 Å | (22) |
| 2.100 Å | (2) |
| 2.052 Å | (46) |
| 2.006 Å | (8) |
| 1.973 Å | (8) |
| 1.947 Å | (129 |
| 1.898 Å | (9) |
| 1.867 Å | (6) |
| 1.827 Å | (4) |
Reference:
Comments:
d and I observed. Gandolfi camera, diameter 114.6 mm.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Scainiite
General Appearance of Type Material:
Acicular crystals, elongated [010], black in colour with bluish metallic luster. The bluish colour apparently arises from a superficial very low hydrothermal alteration of the crystals. Up to 2 mm long and 0.2 mm thick
Place of Conservation of Type Material:
Museo di Storia Naturale e del Territorio, Pisa University, Italy Catalogue numbers: 15521, 15522, 15523.
Musée de l'Ecole des Mines de Paris, France.
Musée de l'Ecole des Mines de Paris, France.
Geological Setting of Type Material:
Late extensional calcite veins embedded in the dolomitic limestones.
Associated Minerals at Type Locality:
Synonyms of Scainiite
Other Language Names for Scainiite
Common Associates
Associations Based on Photo Data:
| 11 photos of Scainiite associated with Pyrite | FeS2 |
| 4 photos of Scainiite associated with Dolomite | CaMg(CO3)2 |
| 3 photos of Scainiite associated with Quartz | SiO2 |
| 2 photos of Scainiite associated with Calcite | CaCO3 |
| 1 photo of Scainiite associated with Pillaite | Pb9Sb10S23ClO0.5 |
| 1 photo of Scainiite associated with Cervantite | Sb3+Sb5+O4 |
Related Minerals - Strunz-mindat Grouping
| 2.JB. | Clino-oscarkempffite | Ag15Pb6Sb21Bi18S72 |
| 2.JB. | Arsenquatrandorite | Ag17.6Pb12.8Sb38.1As11.5S96 |
| 2.JB. | Ginelfite | Ag2(Ag0.5Fe)TlPb23.5(Sb,As)33.5S76 |
| 2.JB. | Andreadiniite | CuHgAg7Pb7Sb24S48 |
| 2.JB. | Chukotkaite | AgPb7Sb5S15 |
| 2.JB. | Selenojunoite | Cu2Pb3Bi8Se16 |
| 2.JB. | Lechnerite | Ag10Cu4HgPb33Sb58S128 |
| 2.JB. | Cuprosenandorite | Ag16Cu8Pb24Sb72S144 |
| 2.JB. | Morleyite | Ag2CuPb25Sb24As4S68.5 |
| 2.JB. | Lazerckerite | Ag3.75Pb4.50(Sb7.75Bi4)S24 |
| 2.JB. | Lasmanisite | Ag12Pb13Mn11Sb44S96 |
| 2.JB. | Montpelvouxite | AgPb16Sb27As18S84 |
| 2.JB. | Senandorite | AgPbSb3S6 |
| 2.JB. | Oscarkempffite | Ag10Pb4(Sb17Bi9)S48 |
| 2.JB.05 | Diaphorite | Ag3Pb2Sb3S8 |
| 2.JB.10 | Cosalite | Pb2Bi2S5 |
| 2.JB.15 | Marrite | AgPbAsS3 |
| 2.JB.15 | Freieslebenite | AgPbSbS3 |
| 2.JB.20 | Cannizzarite | Pb48Bi56S132 |
| 2.JB.20 | Wittite | Pb9Bi12(S,Se)27 |
| 2.JB.25j | Rouxelite | Cu2HgPb23Sb27S65.5 |
| 2.JB.25i | Neyite | Ag2Cu6Pb25Bi26S68 |
| 2.JB.25a | Junoite | Cu2Pb3Bi8(S,Se)16 |
| 2.JB.25f | Ángelaite | Cu2AgPbBiS4 |
| 2.JB.25e | Galenobismutite | PbBi2S4 |
| 2.JB.25c | Nordströmite | CuPb3Bi7(Se4S10) |
| 2.JB.25i | Cuproneyite | Cu7Pb27Bi25S68 |
| 2.JB.25g | Nuffieldite | Cu1.4Pb2.4Bi2.4Sb0.2S7 |
| 2.JB.25h | Weibullite | Pb5Bi8Se7S11 |
| 2.JB.25d | Proudite | CuPb7.5Bi9.33(S,Se)22 |
| 2.JB.25b | Felbertalite | Cu2Pb6Bi8S19 |
| 2.JB.30a | Jordanite | Pb14As6S23 |
| 2.JB.30a | Geocronite | Pb14Sb6S23 |
| 2.JB.30a | Arsenmarcobaldiite | Pb12(As3.2Sb2.8)Σ6S21 |
| 2.JB.30b | Kirkiite | Pb10Bi3As3S19 |
| 2.JB.30c | Tsugaruite | Pb28As15S50Cl |
| 2.JB.30a | Marcobaldiite | Pb12(Sb3As2Bi)Σ6S21 |
| 2.JB.35d | Pellouxite | (Cu,Ag)Pb10Sb12S27O(Cl,S)0.6 |
| 2.JB.35e | Chovanite | Pb15-2xSb14+2xS36Ox (x ~ 0.2) |
| 2.JB.35a | Zinkenite | Pb9Sb22S42 |
| 2.JB.35c | Pillaite | Pb9Sb10S23ClO0.5 |
| 2.JB.35f | Tubulite | Ag2Pb22Sb20S53 |
| 2.JB.40a | Fizélyite | Ag5Pb14Sb21S48 |
| 2.JB.40a | Ramdohrite | Pb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24 |
| 2.JB.40e | Ustarasite | Pb(Bi,Sb)6S10 (?) |
| 2.JB.40a | 'Bursaite' | Pb5Bi4S11 (?) |
| 2.JB.40 | 'UM1988-05-S:AgBiCuHgPb' | (Hg,Ag,Cu,Pb)5Pb5Bi11S27 |
| 2.JB.40 | 'UM1988-06-S:AgBiCuHgPb' | (Pb,Hg)12(Cu,Ag)3(Bi,Sb)10(S,Te)27 |
| 2.JB.40a | Terrywallaceite | AgPb(Sb,Bi)3S6 |
| 2.JB.40a | Jasrouxite | Ag16Pb4(Sb25As15)S72 |
| 2.JB.40a | Tarutinoite | Ag3Pb7Bi7S19 |
| 2.JB.40a | Oyonite | Ag3Mn2Pb4Sb7As4S24 |
| 2.JB.40b | Heyrovskýite | Pb6Bi2S9 |
| 2.JB.40a | Quatrandorite | AgPbSb3S6 |
| 2.JB.40a | Erzwiesite | Ag8Pb12Bi16S40 |
| 2.JB.40a | Vikingite | Ag5Pb8Bi13S30 |
| 2.JB.40a | Lillianite | Pb3-2xAgxBi2+xS6 |
| 2.JB.40b | Baiamareite | Ag4Pb12Fe4Sb20S48 |
| 2.JB.40a | Staročeskéite | Ag0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6 |
| 2.JB.40a | Roshchinite | Ag19Pb10Sb51S96 |
| 2.JB.40b | Aschamalmite | Pb6-3xBi2+xS9 |
| 2.JB.40b | Eskimoite | Ag7Pb10Bi15S36 |
| 2.JB.40a | Menchettiite | AgPb2.40Mn1.60Sb3As2S12 |
| 2.JB.40a | Holubite | Ag3Pb6(Sb8Bi3)S24 |
| 2.JB.40a | Brusnitsynite | Mn3CuPbAs3Sb2S12 |
| 2.JB.40a | Treasurite | Ag7Pb6Bi15S32 |
| 2.JB.40c | Ourayite | Ag3Pb4Bi5S13 |
| 2.JB.40a | Uchucchacuaite | AgMnPb3Sb5S12 |
| 2.JB.40d | 'Schirmerite' | PbAgBi3S6 - Pb3Ag1.5Bi3.5S9 |
| 2.JB.40a | Xilingolite | Pb3Bi2S6 |
| 2.JB.40a | Gustavite | AgPbBi3S6 |
| 2.JB.55 | Gratonite | Pb9As4S15 |
| 2.JB.60 | Marrucciite | Hg3Pb16Sb18S46 |
| 2.JB.65 | Vurroite | Pb20Sn2(Bi,As)22S54Cl6 |
| 2.JB.65 | Tazieffite | Pb20Cd2(As,Bi)22S50Cl10 |
| 2.JB.70 | Daliranite | PbHgAs2S5 |
Fluorescence of Scainiite
Not fluorescent
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Scainiite
mindat.org URL:
https://www.mindat.org/min-7016.html
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References for Scainiite
Reference List:
Makovicky, Emil (1985) Cyclically twinned sulphosalt structures and their approximate analogues. Zeitschrift für Kristallographie - Crystalline Materials, 173 (1-2). 1-23 doi:10.1524/zkri.1985.173.1-2.1
Orlandi, Paolo, Moëlo, Yves, Meerschaut, Alain, Palvadeau, Pierre (1999) Lead-antimony sulfosalts from Tuscany (Italy) I. Scainiite, Pb14Sb30S54O5, the first Pb-Sb oxy-sulfosalt, from Buca della Vena mine. European Journal of Mineralogy, 11 (6) 949-954 doi:10.1127/ejm/11/6/0949
Jambor, John L., Pertsev, Nikolai N., Roberts, Andrew C. (2000) New Mineral Names. American Mineralogist, 85. 1321-1325
Moëlo, Yves, Meerschaut, Alain, Orlandi, Paolo, Palvadeau, Pierre (2000) Lead-antimony sulfosalts from Tuscany (Italy): II - Crystal structure of scainiite, Pb14Sb30S54O5, an expanded monoclinic derivative of Ba12Bi24S48 hexagonal sub-type (zinkenite group) European Journal of Mineralogy, 12 (4) 835-846 doi:10.1127/0935-1221/2000/0012-0835
Localities for Scainiite
Showing 7 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Italy (TL) | |
| Orlandi et al. (1999) |
Slovakia | |
| Števko et al. (2018) |
| Sejkora et al. (2011) |
| Chovan et al. (1998) +1 other reference |
| Števko M. (2021) |
| Sejkora et al. (2021) |
| Topa et al. (2012) |
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The
Dimitrij vein, Ľudovít adit, Dúbrava Sb deposit, Dúbrava, Liptovský Mikuláš District, Žilina Region, Slovakia