Lazerckerite
A valid IMA mineral species
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About Lazerckerite
Formula:
Ag3.75Pb4.50(Sb7.75Bi4)S24
Colour:
lead grey
Lustre:
Metallic
Specific Gravity:
5.920 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
The mineral is named after Lazarus Ercker (1528 Annaberg-Buchholz, Germany – 1594 Prague, Czechia), the supreme Royal Bergmeister of the Kingdom of Bohemia (Minister of Mining) and the Master of Prague Mint, a renowned metallurgist, chemist, and mining specialist and the author of the Books on Assaying (original title Beschreibung Allerfürnemisten Mineralischen Ertzt und Berckwercksarten). This work – published in 1574 – was reissued 15 times, translated into four languages, and until the end of the 18th century was used as a principal textbook by all mining universities and Bergakademie in Europe.
Chemically similar to clino-oscarkempffite, izoklakeite, and staročeskéite. Co-described with also chemically (and stoichiometrically) similar holubite.
The structure of lazerckerite contains two Pb sites (Pb1 and Pb2) in bicapped trigonal prismatic coordination, 8 independent octahedral sites, and 13 distinct sulfur positions. Four of the octahedral sites are mixed (Sb,Bi) and (Bi,Sb) sites, one is a mixed (Ag,Bi) site, and one is a mixed (Sb,Pb) site. The new mineral belongs to the andorite branch of the lillianite homologous series with N=4 and is a new addition to the group of Sb–Bi mixed members of the series. Lazerckerite is defined as a lillianite homologue with the three following requirements: N=4, L (Ag (Bi3+, Sb3+) ↔ 2 Pb2+ substitution) ≈ 90 %–95 %, and approximately one-third of atom percentage of antimony is replaced by bismuth (Bi(Bi+Sb) ≈ 0.30–0.38).
The structure of lazerckerite contains two Pb sites (Pb1 and Pb2) in bicapped trigonal prismatic coordination, 8 independent octahedral sites, and 13 distinct sulfur positions. Four of the octahedral sites are mixed (Sb,Bi) and (Bi,Sb) sites, one is a mixed (Ag,Bi) site, and one is a mixed (Sb,Pb) site. The new mineral belongs to the andorite branch of the lillianite homologous series with N=4 and is a new addition to the group of Sb–Bi mixed members of the series. Lazerckerite is defined as a lillianite homologue with the three following requirements: N=4, L (Ag (Bi3+, Sb3+) ↔ 2 Pb2+ substitution) ≈ 90 %–95 %, and approximately one-third of atom percentage of antimony is replaced by bismuth (Bi(Bi+Sb) ≈ 0.30–0.38).
Unique Identifiers
Mindat ID:
470683
Long-form identifier:
mindat:1:1:470683:6
IMA Classification of Lazerckerite
Approved
IMA Formula:
Ag1+3.75Pb2+4.50(Sb3+7.75Bi3+4)S2-24
Approval year:
2023
First published:
2024
Approval history:
IMA No. 2022-113
Type description reference:
Pažout, R.; Dušek, M.; Sejkora, J.; Plášil, J.; Ilinca, G.; Dolnı́ček, Z. (2024) Lazerckerite, Ag3.75Pb4.5(Sb7.75Bi4)S24, from Kutná Hora, Czech Republic: a new Sb–Bi member of the andorite branch of the lillianite homologous series. European Journal of Mineralogy, 36 (4). p.641-656. doi:10.5194/ejm-36-641-2024
Classification of Lazerckerite
2.JB.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Lze | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Lazerckerite
Metallic
Transparency:
Opaque
Colour:
Lead grey
Streak:
Grey
Cleavage:
None Observed
Density:
5.920 g/cm3 (Calculated)
Optical Data of Lazerckerite
Anisotropism:
weak to moderate, with grey to bluish-grey rotation tints.
Bireflectance:
weak grey tints
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 470nm | 36.1% | 39.6% |
| 546nm | 34.1% | 38.6% |
| 589nm | 33.7% | 38.0% |
| 650nm | 33.1% | 37.7% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 39.6%.
R1 shown in black, R2 shown in red
Colour in reflected light:
greyish white
Internal Reflections:
none observed
Pleochroism:
Weak
Comments:
grey tints
Chemistry of Lazerckerite
Mindat Formula:
Ag3.75Pb4.50(Sb7.75Bi4)S24
Element Weights:
Crystallography of Lazerckerite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 13.2083(9) Å, b = 19.4595(8) Å, c = 8.405(1) Å
β = 90.032(7)°
β = 90.032(7)°
Ratio:
a:b:c = 0.679 : 1 : 0.432
Unit Cell V:
2,160.31 ų (Calculated from Unit Cell)
Z:
2
Twinning:
Twinned on (001).
Comment:
Pseudo-orthorhombic
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.408 Å | (32) |
| 3.407 Å | (34) |
| 3.353 Å | (100) |
| 3.004 Å | (22) |
| 3.003 Å | (25) |
| 2.902 Å | (39) |
| 2.901 Å | (37) |
| 2.101 Å | (29) |
Reference:
Pažout, R.; Dušek, M.; Sejkora, J.; Plášil, J.; Ilinca, G.; Dolnı́ček, Z. (2024) Lazerckerite, Ag3.75Pb4.5(Sb7.75Bi4)S24, from Kutná Hora, Czech Republic: a new Sb–Bi member of the andorite branch of the lillianite homologous series. European Journal of Mineralogy, 36 (4). p.641-656. doi:10.5194/ejm-36-641-2024
Type Occurrence of Lazerckerite
General Appearance of Type Material:
replacement rims of earlier Ag–Pb–Bi–Sb minerals and grain aggregates, growing together in aggregates up to 0.6×0.3 mm.
Place of Conservation of Type Material:
collections of the Department of Mineralogy and Petrology, National Museum, Cirkusová 1740, 19300 Prague 9, Czech Republic, catalogue number P1P 11/2022
Geological Setting of Type Material:
origin of the mineral is related to the later Bi mineralization, and we assume the mineral is a replacement product of earlier, Bi-richer lillianite homologues and galena that crystallized from originally low-temperature (ca. 100–250 °C) hydrothermal fluids in the tectonically opened fractures in yet earlier hydrothermal Fe–Cu–Zn–Sn–As base sulfide ore vein fillings
Associated Minerals at Type Locality:
Reference:
Pažout, R.; Dušek, M.; Sejkora, J.; Plášil, J.; Ilinca, G.; Dolnı́ček, Z. (2024) Lazerckerite, Ag3.75Pb4.5(Sb7.75Bi4)S24, from Kutná Hora, Czech Republic: a new Sb–Bi member of the andorite branch of the lillianite homologous series. European Journal of Mineralogy, 36 (4). p.641-656. doi:10.5194/ejm-36-641-2024
Synonyms of Lazerckerite
Other Language Names for Lazerckerite
Dutch:Lazerckeriet
German:Lazerckerit
Relationship of Lazerckerite to other Species
Member of:
Other Members of Lillianite Homologous Series:
| Andreadiniite | CuHgAg7Pb7Sb24S48 | Mon. 2/m : P21/b |
| Arsenquatrandorite | Ag17.6Pb12.8Sb38.1As11.5S96 | Mon. 2/m : P21/b |
| Aschamalmite | Pb6-3xBi2+xS9 | Mon. 2/m : B2/m |
| Baiamareite | Ag4Pb12Fe4Sb20S48 | Mon. 2/m |
| Brusnitsynite | Mn3CuPbAs3Sb2S12 | Mon. 2/m : P21/b |
| Clino-oscarkempffite | Ag15Pb6Sb21Bi18S72 | Mon. 2/m : P21/b |
| Erzwiesite | Ag8Pb12Bi16S40 | Orth. mmm(2/m2/m2/m) : Cmcm |
| Eskimoite | Ag7Pb10Bi15S36 | Mon. |
| Fizélyite | Ag5Pb14Sb21S48 | Mon. 2/m |
| Gustavite | AgPbBi3S6 | Orth. mmm(2/m2/m2/m) |
| Heyrovskýite | Pb6Bi2S9 | Orth. mmm(2/m2/m2/m) : Cccm |
| Holubite | Ag3Pb6(Sb8Bi3)S24 | Mon. 2/m |
| Jasrouxite | Ag16Pb4(Sb25As15)S72 | Tric. 1 : P1 |
| Lasmanisite | Ag12Pb13Mn11Sb44S96 | Orth. 222 : P212121 |
| Lillianite | Pb3-2xAgxBi2+xS6 | Orth. mmm(2/m2/m2/m) |
| Menchettiite | AgPb2.40Mn1.60Sb3As2S12 | Mon. 2/m : P21/b |
| Oscarkempffite | Ag10Pb4(Sb17Bi9)S48 | Orth. mm2 |
| Ourayite | Ag3Pb4Bi5S13 | Orth. |
| Oyonite | Ag3Mn2Pb4Sb7As4S24 | Mon. 2/m |
| Quatrandorite | AgPbSb3S6 | Mon. 2/m : P21/b |
| Ramdohrite | Pb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24 | Mon. 2/m |
| Roshchinite | Ag19Pb10Sb51S96 | Orth. mmm(2/m2/m2/m) : Pnma |
| 'Schirmerite' | PbAgBi3S6 - Pb3Ag1.5Bi3.5S9 | Orth. |
| Senandorite | AgPbSb3S6 | Orth. mm2 : Pmn21 |
| Staročeskéite | Ag0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6 | Orth. mmm(2/m2/m2/m) : Cmcm |
| Tarutinoite | Ag3Pb7Bi7S19 | Mon. 2/m : B2/m |
| Terrywallaceite | AgPb(Sb,Bi)3S6 | Mon. 2/m : P21/b |
| Treasurite | Ag7Pb6Bi15S32 | Mon. |
| Uchucchacuaite | AgMnPb3Sb5S12 | Orth. mmm(2/m2/m2/m) : Pmmm |
| Ustarasite | Pb(Bi,Sb)6S10 (?) | |
| Vikingite | Ag5Pb8Bi13S30 | Mon. 2/m : B2/m |
| Xilingolite | Pb3Bi2S6 | Mon. |
Related Minerals - Strunz-mindat Grouping
| 2.JB. | Clino-oscarkempffite | Ag15Pb6Sb21Bi18S72 |
| 2.JB. | Arsenquatrandorite | Ag17.6Pb12.8Sb38.1As11.5S96 |
| 2.JB. | Ginelfite | Ag2(Ag0.5Fe)TlPb23.5(Sb,As)33.5S76 |
| 2.JB. | Andreadiniite | CuHgAg7Pb7Sb24S48 |
| 2.JB. | Chukotkaite | AgPb7Sb5S15 |
| 2.JB. | Selenojunoite | Cu2Pb3Bi8Se16 |
| 2.JB. | Lechnerite | Ag10Cu4HgPb33Sb58S128 |
| 2.JB. | Cuprosenandorite | Ag16Cu8Pb24Sb72S144 |
| 2.JB. | Morleyite | Ag2CuPb25Sb24As4S68.5 |
| 2.JB. | Lasmanisite | Ag12Pb13Mn11Sb44S96 |
| 2.JB. | Montpelvouxite | AgPb16Sb27As18S84 |
| 2.JB. | Senandorite | AgPbSb3S6 |
| 2.JB. | Oscarkempffite | Ag10Pb4(Sb17Bi9)S48 |
| 2.JB.05 | Diaphorite | Ag3Pb2Sb3S8 |
| 2.JB.10 | Cosalite | Pb2Bi2S5 |
| 2.JB.15 | Marrite | AgPbAsS3 |
| 2.JB.15 | Freieslebenite | AgPbSbS3 |
| 2.JB.20 | Cannizzarite | Pb48Bi56S132 |
| 2.JB.20 | Wittite | Pb9Bi12(S,Se)27 |
| 2.JB.25j | Rouxelite | Cu2HgPb23Sb27S65.5 |
| 2.JB.25i | Neyite | Ag2Cu6Pb25Bi26S68 |
| 2.JB.25a | Junoite | Cu2Pb3Bi8(S,Se)16 |
| 2.JB.25f | Ángelaite | Cu2AgPbBiS4 |
| 2.JB.25e | Galenobismutite | PbBi2S4 |
| 2.JB.25c | Nordströmite | CuPb3Bi7(Se4S10) |
| 2.JB.25i | Cuproneyite | Cu7Pb27Bi25S68 |
| 2.JB.25g | Nuffieldite | Cu1.4Pb2.4Bi2.4Sb0.2S7 |
| 2.JB.25h | Weibullite | Pb5Bi8Se7S11 |
| 2.JB.25d | Proudite | CuPb7.5Bi9.33(S,Se)22 |
| 2.JB.25b | Felbertalite | Cu2Pb6Bi8S19 |
| 2.JB.30a | Jordanite | Pb14As6S23 |
| 2.JB.30a | Geocronite | Pb14Sb6S23 |
| 2.JB.30a | Arsenmarcobaldiite | Pb12(As3.2Sb2.8)Σ6S21 |
| 2.JB.30b | Kirkiite | Pb10Bi3As3S19 |
| 2.JB.30c | Tsugaruite | Pb28As15S50Cl |
| 2.JB.30a | Marcobaldiite | Pb12(Sb3As2Bi)Σ6S21 |
| 2.JB.35d | Pellouxite | (Cu,Ag)Pb10Sb12S27O(Cl,S)0.6 |
| 2.JB.35e | Chovanite | Pb15-2xSb14+2xS36Ox (x ~ 0.2) |
| 2.JB.35a | Zinkenite | Pb9Sb22S42 |
| 2.JB.35c | Pillaite | Pb9Sb10S23ClO0.5 |
| 2.JB.35b | Scainiite | Pb14Sb30S54O5 |
| 2.JB.35f | Tubulite | Ag2Pb22Sb20S53 |
| 2.JB.40a | Fizélyite | Ag5Pb14Sb21S48 |
| 2.JB.40a | Ramdohrite | Pb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24 |
| 2.JB.40e | Ustarasite | Pb(Bi,Sb)6S10 (?) |
| 2.JB.40a | 'Bursaite' | Pb5Bi4S11 (?) |
| 2.JB.40 | 'UM1988-05-S:AgBiCuHgPb' | (Hg,Ag,Cu,Pb)5Pb5Bi11S27 |
| 2.JB.40 | 'UM1988-06-S:AgBiCuHgPb' | (Pb,Hg)12(Cu,Ag)3(Bi,Sb)10(S,Te)27 |
| 2.JB.40a | Terrywallaceite | AgPb(Sb,Bi)3S6 |
| 2.JB.40a | Jasrouxite | Ag16Pb4(Sb25As15)S72 |
| 2.JB.40a | Tarutinoite | Ag3Pb7Bi7S19 |
| 2.JB.40a | Oyonite | Ag3Mn2Pb4Sb7As4S24 |
| 2.JB.40b | Heyrovskýite | Pb6Bi2S9 |
| 2.JB.40a | Quatrandorite | AgPbSb3S6 |
| 2.JB.40a | Erzwiesite | Ag8Pb12Bi16S40 |
| 2.JB.40a | Vikingite | Ag5Pb8Bi13S30 |
| 2.JB.40a | Lillianite | Pb3-2xAgxBi2+xS6 |
| 2.JB.40b | Baiamareite | Ag4Pb12Fe4Sb20S48 |
| 2.JB.40a | Staročeskéite | Ag0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6 |
| 2.JB.40a | Roshchinite | Ag19Pb10Sb51S96 |
| 2.JB.40b | Aschamalmite | Pb6-3xBi2+xS9 |
| 2.JB.40b | Eskimoite | Ag7Pb10Bi15S36 |
| 2.JB.40a | Menchettiite | AgPb2.40Mn1.60Sb3As2S12 |
| 2.JB.40a | Holubite | Ag3Pb6(Sb8Bi3)S24 |
| 2.JB.40a | Brusnitsynite | Mn3CuPbAs3Sb2S12 |
| 2.JB.40a | Treasurite | Ag7Pb6Bi15S32 |
| 2.JB.40c | Ourayite | Ag3Pb4Bi5S13 |
| 2.JB.40a | Uchucchacuaite | AgMnPb3Sb5S12 |
| 2.JB.40d | 'Schirmerite' | PbAgBi3S6 - Pb3Ag1.5Bi3.5S9 |
| 2.JB.40a | Xilingolite | Pb3Bi2S6 |
| 2.JB.40a | Gustavite | AgPbBi3S6 |
| 2.JB.55 | Gratonite | Pb9As4S15 |
| 2.JB.60 | Marrucciite | Hg3Pb16Sb18S46 |
| 2.JB.65 | Vurroite | Pb20Sn2(Bi,As)22S54Cl6 |
| 2.JB.65 | Tazieffite | Pb20Cd2(As,Bi)22S50Cl10 |
| 2.JB.70 | Daliranite | PbHgAs2S5 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Lazerckerite
mindat.org URL:
https://www.mindat.org/min-470683.html
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References for Lazerckerite
Reference List:
Bosi, Ferdinando, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2023) Newsletter 72. Mineralogical Magazine, 87 (3) 512-518 doi:10.1180/mgm.2023.21
Pažout, R.; Dušek, M.; Sejkora, J.; Plášil, J.; Ilinca, G.; Dolnı́ček, Z. (2024) Lazerckerite, Ag3.75Pb4.5(Sb7.75Bi4)S24, from Kutná Hora, Czech Republic: a new Sb–Bi member of the andorite branch of the lillianite homologous series. European Journal of Mineralogy, 36 (4). p.641-656. doi:10.5194/ejm-36-641-2024
Localities for Lazerckerite
Showing 2 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Bolivia | |
| Pažout et al. (2024) |
Czech Republic (TL) | |
| Bosi et al. (2023) +1 other reference |
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The
Staročeské Lode, Kutná Hora, Kutná Hora District, Central Bohemian Region, Czech Republic