Plumboperloffite
A valid IMA mineral species
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Formula:
PbMn2+2Fe3+2(PO4)3(OH)3
Colour:
brownish orange
Lustre:
Vitreous
Hardness:
4
Specific Gravity:
4.416 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
The name is for the relationship to perloffite with Pb dominating the X site.
The Pb analogue of perloffite and strontioperloffite; the Mn2+-analogue of plumbojohntomaite; and the Mn2+Fe3+-analogue of nigelcookite. Unique combination of elements. The first member of the group with Pb dominant at the X site.
Unique Identifiers
Mindat ID:
54657
Long-form identifier:
mindat:1:1:54657:1
IMA Classification of Plumboperloffite
Approved
IMA Formula:
Pb2+Mn2+2Fe3+2(PO4)3(OH)3
Approval year:
2020
Classification of Plumboperloffite
8.BH.20
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Pplf | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Plumboperloffite
Vitreous
Colour:
Brownish orange
Streak:
Pale orange
Hardness:
4 on Mohs scale
Comment:
based on the hardness of other bjarebyite-group minerals.
Tenacity:
Brittle
Cleavage:
Perfect
excellent cleavage on {100}
excellent cleavage on {100}
Fracture:
Irregular/Uneven
Density:
4.416 g/cm3 (Calculated)
Optical Data of Plumboperloffite
Type:
Biaxial (+)
RI values:
nα = 1.87(1) nβ = 1.88(1) nγ = 1.89(1)
2V:
Measured: 88° (1), Calculated: 90.5°
Max. Birefringence:
δ = 0.020
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
Dispersion is apparently strong, based on extinction colours and the orientation is Y = b.
Pleochroism:
Visible
Comments:
The pleochroism in shades of yellow brown is X < Z < Y.
Chemistry of Plumboperloffite
Mindat Formula:
PbMn2+2Fe3+2(PO4)3(OH)3
Element Weights:
Chemical Analysis
Empirical formulas:
| Sample ID | Empirical Formula |
|---|---|
| 1 | (Pb0.92Ca0.04Ba0.01K0.01)0.98(Mn2+1.84Fe2+0.13)1.97(Fe3+1.97Al0.03)v2.00(P3.01O11.94)(OH)3.06 |
Sample references:
| ID | Locality | Reference | Notes |
|---|---|---|---|
| 1 | Wiperaminga Hill West Quarry, Boolcoomatta Reserve, Pastoral Unincorporated Area, South Australia, Australia | empirical formula basis: O=15 |
Crystallography of Plumboperloffite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Setting:
P21/m
Cell Parameters:
a = 9.176(2) Å, b = 12.340(3) Å, c = 5.009(1) Å
β = 101.01(3)°
β = 101.01(3)°
Ratio:
a:b:c = 0.744 : 1 : 0.406
Unit Cell V:
556.74 ų (Calculated from Unit Cell)
Z:
2
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 5.105 Å | (40) |
| 4.583 Å | (30) |
| 3.158 Å | (100) |
| 2.950 Å | (42) |
| 2.738 Å | (58) |
| 2.205 Å | (30) |
| 1.992 Å | (29) |
| 1.938 Å | (57) |
Reference:
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 22 : Hydration and low-? subsurface aqueous alteration (see also #23) | |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites | |
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47c : [Carbonates, phosphates, borates, nitrates] |
Type Occurrence of Plumboperloffite
General Appearance of Type Material:
The mineral forms intergrowths of subparallel, thin tabular to bladed crystals. Individual crystals are up to 40 µm in length.
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collections of the South Australian Museum, North Terrace, Adelaide, South Australia 5000, Australia, registration number G34868
Geological Setting of Type Material:
pegmatites belong to the beryl-columbite phosphate-rare element type in the classification of Černý
Associated Minerals at Type Locality:
Synonyms of Plumboperloffite
Other Language Names for Plumboperloffite
Dutch:Plumboperloffiet
German:Plumboperloffit
Relationship of Plumboperloffite to other Species
Member of:
Other Members of Bjarebyite Group:
| Bjarebyite | (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 | Mon. 2/m : P21/m |
| Johntomaite | BaFe2+2Fe3+2(PO4)3(OH)3 | Mon. 2/m : P21/m |
| Kulanite | Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 | Mon. 2/m : P21/m |
| Nigelcookite | PbFe2+2V3+2(PO4)3(OH)3 | Mon. 2/m : P21/m |
| Penikisite | Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3 | Mon. 2/m : P21/m |
| Perloffite | Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 | Mon. 2/m : P21/m |
| Plumbojohntomaite | PbFe2+2Fe3+2(PO4)3(OH)3 | Mon. 2/m : P21/m |
| Strontioperloffite | SrMn2+2Fe3+2(PO4)3(OH)3 | Mon. 2/m : P21/m |
Related Minerals - Strunz-mindat Grouping
| 8.BH. | Peterchinite | Zn3Zn2(OH)6As[O3(OH)3] |
| 8.BH. | Reznitskyite | CaMg(VO4)F |
| 8.BH. | Plumbogottlobite | PbMg(VO4)(OH) |
| 8.BH. | Cuprozheshengite | Pb4CuZn2(AsO4)2(PO4)2(OH)2 |
| 8.BH. | Zheshengite | Pb4ZnZn2(AsO4)2(PO4)2(OH)2 |
| 8.BH. | Crimsonite | PbFe3+2(PO4)2(OH)2 |
| 8.BH.05 | Thadeuite | Ca(Mg,Fe2+)3(PO4)2(OH,F)2 |
| 8.BH.10 | Panasqueiraite | CaMg(PO4)(OH) |
| 8.BH.10 | Isokite | CaMg(PO4)F |
| 8.BH.10 | Lacroixite | NaAl(PO4)F |
| 8.BH.10 | Arsenatrotitanite | NaTi(AsO4)O |
| 8.BH.10 | Maxwellite | NaFe3+(AsO4)F |
| 8.BH.10 | Durangite | NaAl(AsO4)F |
| 8.BH.10 | Kononovite | NaMg(SO4)F |
| 8.BH.15 | Drugmanite | Pb2Fe3+(PO4)(PO3OH)(OH)2 |
| 8.BH.20 | Nigelcookite | PbFe2+2V3+2(PO4)3(OH)3 |
| 8.BH.20 | Plumbojohntomaite | PbFe2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Cirrolite | Ca3Al2(PO4)3(OH)3 (?) |
| 8.BH.20 | Penikisite | Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3 |
| 8.BH.20 | Perloffite | Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Bjarebyite Group | |
| 8.BH.20 | Strontioperloffite | SrMn2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Johntomaite | BaFe2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Bjarebyite | (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 |
| 8.BH.20 | Kulanite | Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 |
| 8.BH.25 | Bertossaite | Li2CaAl4(PO4)4(OH)4 |
| 8.BH.25 | Natropalermoite | Na2SrAl4(PO4)4(OH)4 |
| 8.BH.25 | Palermoite | Li2SrAl4(PO4)4(OH)4 |
| 8.BH.30 | Sewardite | CaFe3+2(AsO4)2(OH)2 |
| 8.BH.30 | Carminite | PbFe3+2(AsO4)2(OH)2 |
| 8.BH.35 | Adelite | CaMg(AsO4)(OH) |
| 8.BH.35 | Duftite | PbCu(AsO4)(OH) |
| 8.BH.35 | Cobaltaustinite | CaCo(AsO4)(OH) |
| 8.BH.35 | Nickelaustinite | CaNi(AsO4)(OH) |
| 8.BH.35 | Gabrielsonite | PbFe3+(As3+O3)O |
| 8.BH.35 | Conichalcite | CaCu(AsO4)(OH) |
| 8.BH.35 | Arsendescloizite | PbZn(AsO4)(OH) |
| 8.BH.35 | 'Duftite-alpha' | PbCu(AsO4)(OH) |
| 8.BH.35 | Gottlobite | CaMg(VO4)(OH) |
| 8.BH.35 | Austinite | CaZn(AsO4)(OH) |
| 8.BH.35 | Hermannroseite | CaCu(PO4)(OH) |
| 8.BH.35 | Tangeite | CaCu(VO4)(OH) |
| 8.BH.40 | Čechite | PbFe2+(VO4)(OH) |
| 8.BH.40 | Khorixasite | (Bi0.67◻0.33)Cu(VO4)(OH) |
| 8.BH.40 | Mottramite | PbCu(VO4)(OH) |
| 8.BH.40 | Descloizite | PbZn(VO4)(OH) |
| 8.BH.40 | Pyrobelonite | PbMn2+(VO4)(OH) |
| 8.BH.45 | Bayldonite | PbCu3(AsO4)2(OH)2 |
| 8.BH.45 | Vésigniéite | BaCu3(VO4)2(OH)2 |
| 8.BH.50 | Paganoite | NiBi(AsO4)O |
| 8.BH.55 | Jagowerite | BaAl2(PO4)2(OH)2 |
| 8.BH.55 | Harrisonite | Ca(Fe2+,Mg)6(PO4)2(SiO4)2 |
| 8.BH.60 | Attakolite | CaMn2+Al4(SiO3OH)(PO4)3(OH)4 |
| 8.BH.65 | Leningradite | PbCu3(VO4)2Cl |
| 8.BH.70 | Katiarsite | KTiO(AsO4) |
| 8.BH.70 | Yurgensonite | K2SnTiO2(AsO4)2 |
| 8.BH.75 | Melanarsite | K3Cu7Fe3+O4(AsO4)4 |
| 8.BH.80 | Evseevite | Na2Mg(AsO4)F |
| 8.BH.80 | Moraskoite | Na2Mg(PO4)F |
| 8.BH.85 | Piccoliite | NaCaMn3+2(AsO4)2O(OH) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Plumboperloffite
mindat.org URL:
https://www.mindat.org/min-54657.html
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References for Plumboperloffite
Localities for Plumboperloffite
Showing 1 localities.
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The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia (TL) | |
| Miyawaki et al. (2020) +2 other references |
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