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Kononovite

A valid IMA mineral species
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About KononoviteHide

09369320017272472455247.jpg
Oleg Vasilievich Kononov
Formula:
NaMg(SO4)F
Colour:
White
Lustre:
Vitreous
Hardness:
3
Specific Gravity:
2.91
Crystal System:
Monoclinic
Member of:
Name:
Named in honour of the Russian mineralogist Oleg V. Kononov (born 1932), Moscow State University.
Isostructural with phosphates and arsenates of the tilasite (durangite) group, and with silicates of the titanite group. The first sulphate member of the tilasite group. Chemically quite similar to krasheninnikovite.

Supergene alteration of kononovite may lead to the formation of uklonskovite.

Crystallographic data (space group) is set basing on similarity to the synthetic analogue, that has almost identical PXRD pattern.



Unique IdentifiersHide

Mindat ID:
46063
Long-form identifier:
mindat:1:1:46063:3

IMA Classification of KononoviteHide

Classification of KononoviteHide

8.BH.10

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KnvIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KononoviteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
White
Comment:
transparent in tiny grains but translucent in blocky crystals
Streak:
White
Hardness:
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
one direction of imperfect cleavage is observed.
Comment:
somewhat plastic
Density:
2.91 g/cm3 (Measured)    2.945 g/cm3 (Calculated)

Optical Data of KononoviteHide

Type:
Biaxial (+)
RI values:
nα = 1.488(2) nβ = 1.491(2) nγ = 1.496(2)
2V:
Measured: 75° (5)
Max. Birefringence:
δ = 0.008
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate

Chemistry of KononoviteHide

Mindat Formula:
NaMg(SO4)F
Element Weights:
Element% weight
O39.418 %
S19.750 %
Mg14.970 %
Na14.160 %
F11.702 %

Calculated from ideal end-member formula.

Crystallography of KononoviteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 6.662(2) Å, b = 8.584(3) Å, c = 7.035(2) Å
β = 114.06(3)°
Ratio:
a:b:c = 0.776 : 1 : 0.82
Unit Cell V:
367.4 ų
Z:
4
Morphology:
Prismatic to thick tabular crystals. Forming clusters or crusts.
Comment:
Space group by analogy to the synthetic analogue

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
45b : [Other oxidized fumarolic minerals]

Type Occurrence of KononoviteHide

General Appearance of Type Material:
As prismatic to thick tabular crystals up to 0.04 × 0.06 × 0.1 mm, forming clusters or interrupted crusts up to several cm2.
Place of Conservation of Type Material:
Type material is deposited in the collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, registration number 4452/1
Geological Setting of Type Material:
a fumarole
Associated Minerals at Type Locality:

Synonyms of KononoviteHide

Other Language Names for KononoviteHide

German:Kononovit

Relationship of Kononovite to other SpeciesHide

Member of:
Other Members of Tilasite Group:
ArsenatrotitaniteNaTi(AsO4)OMon. 2/m : B2/b
DurangiteNaAl(AsO4)FMon. 2/m : B2/b
IsokiteCaMg(PO4)FMon. 2/m : B2/b
LacroixiteNaAl(PO4)FMon. 2/m : B2/b
MaxwelliteNaFe3+(AsO4)FMon. 2/m : P2/m
PanasqueiraiteCaMg(PO4)(OH)Mon.
ReznitskyiteCaMg(VO4)FMon. 2/m : B2/b
TilasiteCaMg(AsO4)FMon.

Related Minerals - Strunz-mindat GroupingHide

8.BH.PeterchiniteZn3Zn2(OH)6As[O3(OH)3]Mon. 2/m : B2/m
8.BH.ReznitskyiteCaMg(VO4)FMon. 2/m : B2/b
8.BH.PlumbogottlobitePbMg(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.CuprozheshengitePb4CuZn2(AsO4)2(PO4)2(OH)2Tric. 1 : P1
8.BH.ZheshengitePb4ZnZn2(AsO4)2(PO4)2(OH)2Tric. 1 : P1
8.BH.CrimsonitePbFe3+2(PO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.05ThadeuiteCa(Mg,Fe2+)3(PO4)2(OH,F)2Orth. 222 : C2221
8.BH.10PanasqueiraiteCaMg(PO4)(OH)Mon.
8.BH.10IsokiteCaMg(PO4)FMon. 2/m : B2/b
8.BH.10LacroixiteNaAl(PO4)FMon. 2/m : B2/b
8.BH.10ArsenatrotitaniteNaTi(AsO4)OMon. 2/m : B2/b
8.BH.10MaxwelliteNaFe3+(AsO4)FMon. 2/m : P2/m
8.BH.10DurangiteNaAl(AsO4)FMon. 2/m : B2/b
8.BH.15DrugmanitePb2Fe3+(PO4)(PO3OH)(OH)2Mon. 2/m : P21/b
8.BH.20Nigelcookite PbFe2+2V3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Plumbojohntomaite PbFe2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20CirroliteCa3Al2(PO4)3(OH)3 (?)
8.BH.20PenikisiteBa(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20PerloffiteBa(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Bjarebyite Group
8.BH.20StrontioperloffiteSrMn2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20PlumboperloffitePbMn2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20JohntomaiteBaFe2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Bjarebyite(Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20KulaniteBa(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.25BertossaiteLi2CaAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.25NatropalermoiteNa2SrAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.25PalermoiteLi2SrAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.30SewarditeCaFe3+2(AsO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.30CarminitePbFe3+2(AsO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.35AdeliteCaMg(AsO4)(OH)Orth. 222 : P212121
8.BH.35DuftitePbCu(AsO4)(OH)Orth. 222 : P212121
8.BH.35CobaltaustiniteCaCo(AsO4)(OH)Orth. 222 : P212121
8.BH.35NickelaustiniteCaNi(AsO4)(OH)Orth. 222 : P212121
8.BH.35GabrielsonitePbFe3+(As3+O3)OOrth. mm2 : Pmc21
8.BH.35ConichalciteCaCu(AsO4)(OH)Orth. 222 : P212121
8.BH.35ArsendescloizitePbZn(AsO4)(OH)Orth. 222 : P212121
8.BH.35'Duftite-alpha'PbCu(AsO4)(OH)
8.BH.35GottlobiteCaMg(VO4)(OH)Orth. 222 : P212121
8.BH.35AustiniteCaZn(AsO4)(OH)Orth. 222 : P212121
8.BH.35HermannroseiteCaCu(PO4)(OH)Orth. 222 : P212121
8.BH.35TangeiteCaCu(VO4)(OH)Orth. 222 : P212121
8.BH.40ČechitePbFe2+(VO4)(OH)Orth. mmm(2/m2/m2/m)
8.BH.40Khorixasite(Bi0.670.33)Cu(VO4)(OH)Mon. 2/m : P2/m
8.BH.40MottramitePbCu(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.40DescloizitePbZn(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.40PyrobelonitePbMn2+(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.45BayldonitePbCu3(AsO4)2(OH)2Mon. 2/m : B2/b
8.BH.45VésigniéiteBaCu3(VO4)2(OH)2Mon. 2/m : B2/m
8.BH.50PaganoiteNiBi(AsO4)OTric. 1 : P1
8.BH.55JagoweriteBaAl2(PO4)2(OH)2Tric.
8.BH.55HarrisoniteCa(Fe2+,Mg)6(PO4)2(SiO4)2Trig. 3m(32/m) : R3m
8.BH.60AttakoliteCaMn2+Al4(SiO3OH)(PO4)3(OH)4Mon. 2/m : B2/m
8.BH.65LeningraditePbCu3(VO4)2ClOrth. mmm(2/m2/m2/m) : Ibam
8.BH.70KatiarsiteKTiO(AsO4)Orth. mm2 : Pna21
8.BH.70YurgensoniteK2SnTiO2(AsO4)2Orth. mm2 : Pna21
8.BH.75MelanarsiteK3Cu7Fe3+O4(AsO4)4Mon. 2/m : B2/b
8.BH.80EvseeviteNa2Mg(AsO4)FOrth. mmm(2/m2/m2/m) : Pbcn
8.BH.80MoraskoiteNa2Mg(PO4)FOrth. mmm(2/m2/m2/m) : Pbcn
8.BH.85PiccoliiteNaCaMn3+2(AsO4)2O(OH)Orth. mmm(2/m2/m2/m) : Pbcm

Other InformationHide

Notes:
Decomposes and partially dissolves in H2O at room temperature during several hours. In humid air the mineral slowly alters with the formation of uklonskovite NaMg(SO4)F·2H2O.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KononoviteHide

References for KononoviteHide

Localities for KononoviteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Kamchatka Krai
    • Milkovsky District
      • Tolbachik Volcanic field
        • Great Fissure eruption (Main Fracture)
          • Northern Breakthrough (North Breach)
            • Second scoria cone
Williams et al. (2014) +2 other references
 
and/or  
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