Cuprozheshengite
A valid IMA mineral species
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About Cuprozheshengite
Formula:
Pb4CuZn2(AsO4)2(PO4)2(OH)2
Colour:
apple green to greenish blue
Lustre:
Vitreous
Hardness:
2½ - 3
Specific Gravity:
5.91 (Calculated)
Crystal System:
Triclinic
Member of:
Name:
The copper analogue of zheshengite
The Cu-, or rather CuZn-analogue of zheshengite. The (ordered?) As-enriched analogue of cuprodongchuanite. Unique combination of elements (at the upload time).
A rare example of As-P separation into different structural positions.
A rare example of As-P separation into different structural positions.
Unique Identifiers
Mindat ID:
56037
Long-form identifier:
mindat:1:1:56037:7
IMA Classification of Cuprozheshengite
Approved
IMA Formula:
Pb2+4Cu2+Zn2+2(As5+O4)2(PO4)2(OH)2
Approval year:
2021
Type description reference:
Sun, Ningyue, Grey, Ian E., Li, Guowu, Rewitzer, Christian, Xue, Yuan, Mumme, William G., Shen, Hongtao, Hao, Jinhua, MacRae, Colin M., Riboldi-Tunnicliffe, Alan, Boer, Stephanie, Williams, Tim, Kampf, Anthony R. (2024) The new mineral cuprozheshengite, Pb4CuZn2(AsO4)2(PO4)2(OH)2, from Yunnan, China, with site-selective As-P substitution. American Mineralogist, 109 (7) 1248-1257 doi:10.2138/am-2023-8942
Classification of Cuprozheshengite
8.BH.
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Czh | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Cuprozheshengite
Vitreous
Transparency:
Transparent
Colour:
Apple green to greenish blue
Streak:
White
Hardness:
2½ - 3 on Mohs scale
Hardness:
VHN10=129.2 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
Perfect
{011}
{011}
Fracture:
Irregular/Uneven
Density:
5.91 g/cm3 (Calculated)
Chemistry of Cuprozheshengite
Mindat Formula:
Pb4CuZn2(AsO4)2(PO4)2(OH)2
Element Weights:
Crystallography of Cuprozheshengite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 4.7977(8) Å, b = 8.5789(8) Å, c = 10.3855(9) Å
α = 97.270(8)°, β = 101.90(1)°, γ = 91.49(1)°
α = 97.270(8)°, β = 101.90(1)°, γ = 91.49(1)°
Ratio:
a:b:c = 0.559 : 1 : 1.211
Unit Cell V:
414.31 ų (Calculated from Unit Cell)
Z:
1
Morphology:
triclinic crystals are flattened on (011) and elongated along [100]
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 6.110 Å | (21) |
| 4.641 Å | (30) |
| 3.441 Å | (100) |
| 3.267 Å | (34) |
| 3.054 Å | (89) |
| 2.948 Å | (61) |
| 2.817 Å | (44) |
| 2.321 Å | (20) |
Reference:
Sun, Ningyue, Grey, Ian E., Li, Guowu, Rewitzer, Christian, Xue, Yuan, Mumme, William G., Shen, Hongtao, Hao, Jinhua, MacRae, Colin M., Riboldi-Tunnicliffe, Alan, Boer, Stephanie, Williams, Tim, Kampf, Anthony R. (2024) The new mineral cuprozheshengite, Pb4CuZn2(AsO4)2(PO4)2(OH)2, from Yunnan, China, with site-selective As-P substitution. American Mineralogist, 109 (7) 1248-1257 doi:10.2138/am-2023-8942
Type Occurrence of Cuprozheshengite
Co-Type Localities:
General Appearance of Type Material:
radial hemispheric aggregates with blade like crystals.
hemispheres are typically 0.3 to 1 mm in diameter and blades have lengths up to 0.1–0.2 mm but widths of only 10 to 50 μm.
hemispheres are typically 0.3 to 1 mm in diameter and blades have lengths up to 0.1–0.2 mm but widths of only 10 to 50 μm.
Place of Conservation of Type Material:
Geological Museum of China, Xisi, Yangrou hutong no. 15, Xicheng District, Beijing, People's Republic of China, catalogue no. M16127 (holotype); the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue numbers 76191 and 76192; and the Crystal Structure Laboratory, China University of Geosciences, Beijing 100083, People's Republic of China, catalogue no. DC4 (cotype)
Geological Setting of Type Material:
Supergene mineral in fractures from copper sulfides along a regional redox boundary.
Associated Minerals at Type Locality:
Reference:
Sun, Ningyue, Grey, Ian E., Li, Guowu, Rewitzer, Christian, Xue, Yuan, Mumme, William G., Shen, Hongtao, Hao, Jinhua, MacRae, Colin M., Riboldi-Tunnicliffe, Alan, Boer, Stephanie, Williams, Tim, Kampf, Anthony R. (2024) The new mineral cuprozheshengite, Pb4CuZn2(AsO4)2(PO4)2(OH)2, from Yunnan, China, with site-selective As-P substitution. American Mineralogist, 109 (7) 1248-1257 doi:10.2138/am-2023-8942
Synonyms of Cuprozheshengite
Other Language Names for Cuprozheshengite
Dutch:Cuprozheshengiet
German:Cuprozheshengit
Relationship of Cuprozheshengite to other Species
Member of:
Other Members of Dongchuanite Group:
| Cuprodongchuanite | Pb4CuZn2(PO4)4(OH)2 | Tric. 1 : P1 |
| Dongchuanite | Pb4ZnZn2(PO4)4(OH)2 | Tric. 1 : P1 |
| Zheshengite | Pb4ZnZn2(AsO4)2(PO4)2(OH)2 | Tric. 1 : P1 |
Common Associates
Associations Based on Photo Data:
| 5 photos of Cuprozheshengite associated with Hemimorphite | Zn4Si2O7(OH)2 · H2O |
| 4 photos of Cuprozheshengite associated with Veszelyite | (Cu,Zn)2Zn(PO4)(OH)3 · 2H2O |
| 2 photos of Cuprozheshengite associated with Cuprodongchuanite | Pb4CuZn2(PO4)4(OH)2 |
| 1 photo of Cuprozheshengite associated with Arsenoveszelyite | Cu2Zn(AsO4)(OH)3 · 2H2O |
Related Minerals - Strunz-mindat Grouping
| 8.BH. | Peterchinite | Zn3Zn2(OH)6As[O3(OH)3] |
| 8.BH. | Reznitskyite | CaMg(VO4)F |
| 8.BH. | Plumbogottlobite | PbMg(VO4)(OH) |
| 8.BH. | Zheshengite | Pb4ZnZn2(AsO4)2(PO4)2(OH)2 |
| 8.BH. | Crimsonite | PbFe3+2(PO4)2(OH)2 |
| 8.BH.05 | Thadeuite | Ca(Mg,Fe2+)3(PO4)2(OH,F)2 |
| 8.BH.10 | Panasqueiraite | CaMg(PO4)(OH) |
| 8.BH.10 | Isokite | CaMg(PO4)F |
| 8.BH.10 | Lacroixite | NaAl(PO4)F |
| 8.BH.10 | Arsenatrotitanite | NaTi(AsO4)O |
| 8.BH.10 | Maxwellite | NaFe3+(AsO4)F |
| 8.BH.10 | Durangite | NaAl(AsO4)F |
| 8.BH.10 | Kononovite | NaMg(SO4)F |
| 8.BH.15 | Drugmanite | Pb2Fe3+(PO4)(PO3OH)(OH)2 |
| 8.BH.20 | Nigelcookite | PbFe2+2V3+2(PO4)3(OH)3 |
| 8.BH.20 | Plumbojohntomaite | PbFe2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Cirrolite | Ca3Al2(PO4)3(OH)3 (?) |
| 8.BH.20 | Penikisite | Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3 |
| 8.BH.20 | Perloffite | Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Bjarebyite Group | |
| 8.BH.20 | Strontioperloffite | SrMn2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Plumboperloffite | PbMn2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Johntomaite | BaFe2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Bjarebyite | (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 |
| 8.BH.20 | Kulanite | Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 |
| 8.BH.25 | Bertossaite | Li2CaAl4(PO4)4(OH)4 |
| 8.BH.25 | Natropalermoite | Na2SrAl4(PO4)4(OH)4 |
| 8.BH.25 | Palermoite | Li2SrAl4(PO4)4(OH)4 |
| 8.BH.30 | Sewardite | CaFe3+2(AsO4)2(OH)2 |
| 8.BH.30 | Carminite | PbFe3+2(AsO4)2(OH)2 |
| 8.BH.35 | Adelite | CaMg(AsO4)(OH) |
| 8.BH.35 | Duftite | PbCu(AsO4)(OH) |
| 8.BH.35 | Cobaltaustinite | CaCo(AsO4)(OH) |
| 8.BH.35 | Nickelaustinite | CaNi(AsO4)(OH) |
| 8.BH.35 | Gabrielsonite | PbFe3+(As3+O3)O |
| 8.BH.35 | Conichalcite | CaCu(AsO4)(OH) |
| 8.BH.35 | Arsendescloizite | PbZn(AsO4)(OH) |
| 8.BH.35 | 'Duftite-alpha' | PbCu(AsO4)(OH) |
| 8.BH.35 | Gottlobite | CaMg(VO4)(OH) |
| 8.BH.35 | Austinite | CaZn(AsO4)(OH) |
| 8.BH.35 | Hermannroseite | CaCu(PO4)(OH) |
| 8.BH.35 | Tangeite | CaCu(VO4)(OH) |
| 8.BH.40 | Čechite | PbFe2+(VO4)(OH) |
| 8.BH.40 | Khorixasite | (Bi0.67◻0.33)Cu(VO4)(OH) |
| 8.BH.40 | Mottramite | PbCu(VO4)(OH) |
| 8.BH.40 | Descloizite | PbZn(VO4)(OH) |
| 8.BH.40 | Pyrobelonite | PbMn2+(VO4)(OH) |
| 8.BH.45 | Bayldonite | PbCu3(AsO4)2(OH)2 |
| 8.BH.45 | Vésigniéite | BaCu3(VO4)2(OH)2 |
| 8.BH.50 | Paganoite | NiBi(AsO4)O |
| 8.BH.55 | Jagowerite | BaAl2(PO4)2(OH)2 |
| 8.BH.55 | Harrisonite | Ca(Fe2+,Mg)6(PO4)2(SiO4)2 |
| 8.BH.60 | Attakolite | CaMn2+Al4(SiO3OH)(PO4)3(OH)4 |
| 8.BH.65 | Leningradite | PbCu3(VO4)2Cl |
| 8.BH.70 | Katiarsite | KTiO(AsO4) |
| 8.BH.70 | Yurgensonite | K2SnTiO2(AsO4)2 |
| 8.BH.75 | Melanarsite | K3Cu7Fe3+O4(AsO4)4 |
| 8.BH.80 | Evseevite | Na2Mg(AsO4)F |
| 8.BH.80 | Moraskoite | Na2Mg(PO4)F |
| 8.BH.85 | Piccoliite | NaCaMn3+2(AsO4)2O(OH) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Cuprozheshengite
mindat.org URL:
https://www.mindat.org/min-56037.html
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References for Cuprozheshengite
Reference List:
Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 67. European Journal of Mineralogy, 34 (3) 359-364 doi:10.5194/ejm-34-359-2022
Sun, Ningyue, Grey, Ian E., Li, Guowu, Rewitzer, Christian, Xue, Yuan, Mumme, William G., Shen, Hongtao, Hao, Jinhua, MacRae, Colin M., Riboldi-Tunnicliffe, Alan, Boer, Stephanie, Williams, Tim, Kampf, Anthony R. (2024) The new mineral cuprozheshengite, Pb4CuZn2(AsO4)2(PO4)2(OH)2, from Yunnan, China, with site-selective As-P substitution. American Mineralogist, 109 (7) 1248-1257 doi:10.2138/am-2023-8942
Localities for Cuprozheshengite
Showing 2 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
China (TL) | |
| Miyawaki et al. (2022) |
| Miyawaki et al. (2022) |
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The
Sanguozhuang, Shizhuang Village, Tangdan Town, Dongchuan District, Kunming, Yunnan, China