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Durangite

A valid IMA mineral species - grandfathered
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About DurangiteHide

04771900017271922686619.jpg
Flag of Durango, Mexico
Formula:
NaAl(AsO4)F
Colour:
Light to dark orange-red, red; green; orange-yellow in artificial light.
Lustre:
Vitreous
Hardness:
Specific Gravity:
3.94 - 4.07
Crystal System:
Monoclinic
Member of:
Name:
After the locality in the state of Durango, Mexico.
Isostructural with:

Unique IdentifiersHide

Mindat ID:
1332
Long-form identifier:
mindat:1:1:1332:7

IMA Classification of DurangiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
NaAlAs5+O4F
First published:
1869

Classification of DurangiteHide

8.BH.10

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1
41.5.5.2

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
5 : (AB)2(XO4)Zq
22.1.31

22 : Phosphates, Arsenates or Vanadates with other Anions
1 : Phosphates, arsenates or vanadates with fluoride

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
DurIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of DurangiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of DurangiteHide

Vitreous
Transparency:
Translucent
Colour:
Light to dark orange-red, red; green; orange-yellow in artificial light.
Comment:
Green colour exhibited by artificial material.
Streak:
Cream-yellow
Hardness:
5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
On {110}, distinct.
Fracture:
Irregular/Uneven
Density:
3.94 - 4.07 g/cm3 (Measured)    3.616 g/cm3 (Calculated)
Comment:
Highest in dark-coloured, ferrian material.

Optical Data of DurangiteHide

Type:
Biaxial (-)
RI values:
nα = 1.634 nβ = 1.673 nγ = 1.685
2V:
Measured: 45° , Calculated: 56°
Max. Birefringence:
δ = 0.051
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
strong
Pleochroism:
Visible
Comments:
X = ^c -25° = Orange-yellow
Y = Pale orange-yellow
Z = b = Nearly colourless

Chemistry of DurangiteHide

Mindat Formula:
NaAl(AsO4)F
Element Weights:
Element% weight
As36.039 %
O30.785 %
Al12.979 %
Na11.059 %
F9.139 %

Calculated from ideal end-member formula.
As
O
Al
Na
F

Crystallography of DurangiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 6.5789(5) Å, b = 8.5071(6) Å, c = 7.0212(5) Å
β = 115.447(4)°
Ratio:
a:b:c = 0.773 : 1 : 0.825
Unit Cell V:
354.83 ų
Z:
4
Morphology:
Crystal habit is oblique pyramidal with {111} and {110} dominant. Faces commonly dull and rough. Artificial crystals are prismatic [101], and rarely tabular.
Twinning:
On {001} common as interopenetration twins (artificial crystals).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019593DurangiteDowns G W, Yang B N, Thompson R M, Wenz M D, Andrade M B (2012) Redetermination of durangite, NaAl(AsO4)F Acta Crystallographica E68 i86-i872012the Barranca mine, Coneto de Comonfort, Durango, Mexico0293
0010570DurangiteKokkoros P (1938) Uber die struktur des durangit NaAlF[AsO4] Zeitschrift fur Kristallographie 99 38-491938Durango, Mexico0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.967 Å(100)
4.76 Å(80)
3.236 Å(80)
2.560 Å(60)
2.549 Å(57)
3.34 Å(50)
1.533 Å(41)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4a: Earth’s earliest continental crust>4.4-3.0
20 : Acidic volcanic rocks
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
Stage 7: Great Oxidation Event<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
45b : [Other oxidized fumarolic minerals]

Type Occurrence of DurangiteHide

General Appearance of Type Material:
Rhombic orange-red crystals.
Place of Conservation of Type Material:
Yale University, New Haven, Connecticut, USA, 3.586, 3.3036, 3.3037.
Associated Minerals at Type Locality:

Other Language Names for DurangiteHide

Dutch:Durangiet
German:Durangit
Spanish:Durangita

Relationship of Durangite to other SpeciesHide

Member of:
Other Members of Tilasite Group:
ArsenatrotitaniteNaTi(AsO4)OMon. 2/m : B2/b
IsokiteCaMg(PO4)FMon. 2/m : B2/b
KononoviteNaMg(SO4)FMon. 2/m : B2/b
LacroixiteNaAl(PO4)FMon. 2/m : B2/b
MaxwelliteNaFe3+(AsO4)FMon. 2/m : P2/m
PanasqueiraiteCaMg(PO4)(OH)Mon.
ReznitskyiteCaMg(VO4)FMon. 2/m : B2/b
TilasiteCaMg(AsO4)FMon.
Forms a series with:

Common AssociatesHide

Associations Based on Photo Data:
63 photos of Durangite associated with HematiteFe2O3
19 photos of Durangite associated with CassiteriteSnO2
4 photos of Durangite associated with TopazAl2(SiO4)(F,OH)2
2 photos of Durangite associated with 'Wood Tin'SnO2
2 photos of Durangite associated with SanidineK(AlSi3O8)
2 photos of Durangite associated with 'Rhyolite'

Related Minerals - Strunz-mindat GroupingHide

8.BH.PeterchiniteZn3Zn2(OH)6As[O3(OH)3]Mon. 2/m : B2/m
8.BH.ReznitskyiteCaMg(VO4)FMon. 2/m : B2/b
8.BH.PlumbogottlobitePbMg(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.CuprozheshengitePb4CuZn2(AsO4)2(PO4)2(OH)2Tric. 1 : P1
8.BH.ZheshengitePb4ZnZn2(AsO4)2(PO4)2(OH)2Tric. 1 : P1
8.BH.CrimsonitePbFe3+2(PO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.05ThadeuiteCa(Mg,Fe2+)3(PO4)2(OH,F)2Orth. 222 : C2221
8.BH.10PanasqueiraiteCaMg(PO4)(OH)Mon.
8.BH.10IsokiteCaMg(PO4)FMon. 2/m : B2/b
8.BH.10LacroixiteNaAl(PO4)FMon. 2/m : B2/b
8.BH.10ArsenatrotitaniteNaTi(AsO4)OMon. 2/m : B2/b
8.BH.10MaxwelliteNaFe3+(AsO4)FMon. 2/m : P2/m
8.BH.10KononoviteNaMg(SO4)FMon. 2/m : B2/b
8.BH.15DrugmanitePb2Fe3+(PO4)(PO3OH)(OH)2Mon. 2/m : P21/b
8.BH.20Nigelcookite PbFe2+2V3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Plumbojohntomaite PbFe2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20CirroliteCa3Al2(PO4)3(OH)3 (?)
8.BH.20PenikisiteBa(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20PerloffiteBa(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Bjarebyite Group
8.BH.20StrontioperloffiteSrMn2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20PlumboperloffitePbMn2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20JohntomaiteBaFe2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Bjarebyite(Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20KulaniteBa(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.25BertossaiteLi2CaAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.25NatropalermoiteNa2SrAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.25PalermoiteLi2SrAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.30SewarditeCaFe3+2(AsO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.30CarminitePbFe3+2(AsO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.35AdeliteCaMg(AsO4)(OH)Orth. 222 : P212121
8.BH.35DuftitePbCu(AsO4)(OH)Orth. 222 : P212121
8.BH.35CobaltaustiniteCaCo(AsO4)(OH)Orth. 222 : P212121
8.BH.35NickelaustiniteCaNi(AsO4)(OH)Orth. 222 : P212121
8.BH.35GabrielsonitePbFe3+(As3+O3)OOrth. mm2 : Pmc21
8.BH.35ConichalciteCaCu(AsO4)(OH)Orth. 222 : P212121
8.BH.35ArsendescloizitePbZn(AsO4)(OH)Orth. 222 : P212121
8.BH.35'Duftite-alpha'PbCu(AsO4)(OH)
8.BH.35GottlobiteCaMg(VO4)(OH)Orth. 222 : P212121
8.BH.35AustiniteCaZn(AsO4)(OH)Orth. 222 : P212121
8.BH.35HermannroseiteCaCu(PO4)(OH)Orth. 222 : P212121
8.BH.35TangeiteCaCu(VO4)(OH)Orth. 222 : P212121
8.BH.40ČechitePbFe2+(VO4)(OH)Orth. mmm(2/m2/m2/m)
8.BH.40Khorixasite(Bi0.670.33)Cu(VO4)(OH)Mon. 2/m : P2/m
8.BH.40MottramitePbCu(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.40DescloizitePbZn(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.40PyrobelonitePbMn2+(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.45BayldonitePbCu3(AsO4)2(OH)2Mon. 2/m : B2/b
8.BH.45VésigniéiteBaCu3(VO4)2(OH)2Mon. 2/m : B2/m
8.BH.50PaganoiteNiBi(AsO4)OTric. 1 : P1
8.BH.55JagoweriteBaAl2(PO4)2(OH)2Tric.
8.BH.55HarrisoniteCa(Fe2+,Mg)6(PO4)2(SiO4)2Trig. 3m(32/m) : R3m
8.BH.60AttakoliteCaMn2+Al4(SiO3OH)(PO4)3(OH)4Mon. 2/m : B2/m
8.BH.65LeningraditePbCu3(VO4)2ClOrth. mmm(2/m2/m2/m) : Ibam
8.BH.70KatiarsiteKTiO(AsO4)Orth. mm2 : Pna21
8.BH.70YurgensoniteK2SnTiO2(AsO4)2Orth. mm2 : Pna21
8.BH.75MelanarsiteK3Cu7Fe3+O4(AsO4)4Mon. 2/m : B2/b
8.BH.80EvseeviteNa2Mg(AsO4)FOrth. mmm(2/m2/m2/m) : Pbcn
8.BH.80MoraskoiteNa2Mg(PO4)FOrth. mmm(2/m2/m2/m) : Pbcn
8.BH.85PiccoliiteNaCaMn3+2(AsO4)2O(OH)Orth. mmm(2/m2/m2/m) : Pbcm

Other InformationHide

Notes:
Soluble in H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DurangiteHide

References for DurangiteHide

Reference List:

Localities for DurangiteHide

Showing 14 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Nova Scotia
    • Lunenburg Co.
      • New Ross
Foord et al. (1985)
Faribault (1908)
Mexico (TL)
 
  • Durango
    • Coneto de Comonfort Municipality
      • Coneto de Comonfort
Brush G J (1869) +2 other references
  • Zacatecas
Megaw (2023)
Romania
 
  • Harghita County
    • Ditrău Complex
      • Jolotca (Orotva)
Hirtopanu et al. (2000)
UK
 
  • England
    • Cornwall
      • Linkinhorne
        • Minions
Embrey (1978) +1 other reference
USA
 
  • New Mexico
    • Catron County
      • Taylor Creek Mining District
        • Sawmill Creek
NMGS 37th Field Conference
    • Sierra County
NMGS 37th Field Conference
Maxwell et al. (1986)
geoinfo.nmt.edu (n.d.)
Northrop et al. (1996)
Northrop et al. (1996)
  • Utah
    • Juab County
Wilson (1986)
In the collection of Alex Earl
 
and/or  
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