Alloclasite
A valid IMA mineral species - grandfathered
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About Alloclasite
Formula:
Co1-xFexAsS
(x ≈ 0-0.35)
Colour:
Steel gray to silver
Lustre:
Metallic
Hardness:
5
Specific Gravity:
5.95
Crystal System:
Monoclinic
Member of:
Name:
For the Greek άλλος ("allos") for "other" and κλάσις ("klasis"), "to break", because its cleavage was believed to be different from marcasite.
Type Locality:
See also the chemically very similar Cobaltite and Glaucodot. Compare 'UM1966-01-As:CoNiS'.
Fe content is distinctly higher than that of cobaltite, and the Fe usually occupies about 25% of the (Co,Fe) site (Kingston, 1971).
Fe content is distinctly higher than that of cobaltite, and the Fe usually occupies about 25% of the (Co,Fe) site (Kingston, 1971).
Unique Identifiers
Mindat ID:
134
Long-form identifier:
mindat:1:1:134:2
IMA Classification of Alloclasite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Co3+(AsS)3-
First published:
1866
Classification of Alloclasite
2.EB.10b
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
E : Metal Sulfides, M: S <= 1:2
B : M:S = 1:2, with Fe, Co, Ni, PGE, etc.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
E : Metal Sulfides, M: S <= 1:2
B : M:S = 1:2, with Fe, Co, Ni, PGE, etc.
2.12.6.2
2 : SULFIDES
12 : AmBnXp, with (m+n):p = 1:2
2 : SULFIDES
12 : AmBnXp, with (m+n):p = 1:2
3.10.16
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
10 : Sulphides etc. of Co
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
10 : Sulphides etc. of Co
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Acl | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Alo | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Alloclasite
Metallic
Transparency:
Opaque
Colour:
Steel gray to silver
Streak:
Nearly black
Hardness:
5 on Mohs scale
Hardness:
VHN100=818 - 940 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
Perfect
perfect on {101}
distinct on {010}
perfect on {101}
distinct on {010}
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
5.95 g/cm3 (Measured) 6.188 g/cm3 (Calculated)
Optical Data of Alloclasite
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 400nm | 49.5% | 48.2% |
| 420nm | 48.7% | 48.3% |
| 440nm | 48.2% | 48.6% |
| 460nm | 47.8% | 48.8% |
| 480nm | 47.6% | 49.2% |
| 500nm | 47.6% | 49.7% |
| 520nm | 47.8% | 50.1% |
| 540nm | 48.0% | 50.4% |
| 560nm | 48.1% | 50.5% |
| 580nm | 48.4% | 50.6% |
| 600nm | 48.6% | 50.7% |
| 620nm | 48.8% | 50.7% |
| 640nm | 49.0% | 50.5% |
| 660nm | 49.1% | 50.3% |
| 680nm | 49.1% | 50.1% |
| 700nm | 49.2% | 49.9% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 50.7%.
R1 shown in black, R2 shown in red
Chemistry of Alloclasite
Mindat Formula:
Co1-xFexAsS
(x ≈ 0-0.35)
(x ≈ 0-0.35)
Elements listed:
Common Impurities:
Ni
Chemical Analysis
wt%
| 1 | 2 | 3 | |
|---|---|---|---|
| Co | 25.4 % | 28.5 % | 23.3 % |
| Fe | 8.4 % | 4.0 % | 7.7 % |
| As | 44.3 % | 44.9 % | 47.3 % |
| S | 18.7 % | 17.8 % | 20.7 % |
| Total: | 96.8 % | 95.2 % | 99 % |
Empirical formulas:
| Sample ID | Empirical Formula |
|---|---|
| 1 | (Co0.74Fe0.26)1.00As1.01S1.00 |
| 2 | (Co0.87Fe0.13)1.00As1.02S10.95 |
| 3 | (Co0.74Fe0.26)1.00As1.20S1.23 |
Sample references:
| ID | Locality | Reference | Notes |
|---|---|---|---|
| 1 | Elizabeth Mine, Oraviţa, Caraş-Severin County, Romania | EMPA analysis of sample associated with calcite and a small intergrown gold wire. | |
| 2 | " " | EMPA analysis of Royal Ontario Museum sample | |
| 3 | Dohgatani mine, Totsukawa village, Yoshino district, Nara Prefecture, Japan | EMPA analysis. No details on the sample was given by Kingston. |
Crystallography of Alloclasite
Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
P21
Cell Parameters:
a = 4.661 Å, b = 5.602 Å, c = 3.411 Å
β = 90.03°
β = 90.03°
Ratio:
a:b:c = 0.832 : 1 : 0.609
Unit Cell V:
89.06 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals are prismatic parallel [010] , to 5 mm, in columnar to radiating aggregates; commonly massive.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0005134 | Alloclasite | Scott J D, Nowacki W (1976) The crystal structure of alloclasite, CoAsS, and the alloclasite-cobaltite transformation The Canadian Mineralogist 14 561-566 | ![]() | 1976 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.58 Å | (30) |
| 2.802 Å | (30) |
| 2.750 Å | (100) |
| 2.469 Å | (90) |
| 2.401 Å | (50) |
| 1.817 Å | (70) |
| 1.707 Å | (30) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47) | |
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Geological Setting:
In calcite or quartz veins of apparently low-temperature, late-stage hydrothermal origin. Also in silicified, recrystallized metamorphic rock.
Type Occurrence of Alloclasite
General Appearance of Type Material:
Steel gray and fissile.
Place of Conservation of Type Material:
n.d.
Synonyms of Alloclasite
Other Language Names for Alloclasite
Dutch:Alloclasiet
French:Alloclasite
German:Alloclasit
Alloklas
Alloklas
Norwegian:Alloklasitt
Russian:Аллоклазит
Spanish:Alloclasita
Relationship of Alloclasite to other Species
Member of:
Other Members of Löllingite Group:
| Anduoite | RuAs2 | Orth. |
| Clinosafflorite | CoAs2 | Mon. 2/m : P21/m |
| Costibite | CoSbS | Orth. mm2 : Pmn21 |
| Löllingite | FeAs2 | Orth. mmm(2/m2/m2/m) : Pnnm |
| Nisbite | NiSb2 | Orth. mmm(2/m2/m2/m) : Pnnm |
| Oenite | CoSbAs | Orth. |
| Omeiite | OsAs2 | Orth. |
| Paracostibite | CoSbS | Orth. mmm(2/m2/m2/m) : Pbca |
| Pararammelsbergite | NiAs2 | Orth. mmm(2/m2/m2/m) : Pbca |
| Rammelsbergite | NiAs2 | Orth. mmm(2/m2/m2/m) : Pnnm |
| Safflorite | (Co,Ni,Fe)As2 | Orth. mmm(2/m2/m2/m) : Pnnm |
| 'UM1998-01-AsSb:CoFeNi' | (Fe,Ni)SbAs |
Common Associates
Associations Based on Photo Data:
| 8 photos of Alloclasite associated with Spherocobaltite | CoCO3 |
| 5 photos of Alloclasite associated with Quartz | SiO2 |
| 3 photos of Alloclasite associated with Chalcopyrite | CuFeS2 |
| 3 photos of Alloclasite associated with Erythrite | Co3(AsO4)2 · 8H2O |
| 2 photos of Alloclasite associated with Fukuchilite | Cu3FeS8 |
| 2 photos of Alloclasite associated with Scorodite | Fe3+AsO4 · 2H2O |
| 2 photos of Alloclasite associated with Chlorite Group | |
| 2 photos of Alloclasite associated with Native Silver | Ag |
| 2 photos of Alloclasite associated with Safflorite | (Co,Ni,Fe)As2 |
| 2 photos of Alloclasite associated with Arsenopyrite | FeAsS |
Related Minerals - Strunz-mindat Grouping
| 2.EB. | Selenolaurite | RuSe2 |
| 2.EB. | Andrieslombaardite | RhSbS |
| 2.EB. | Iridarsenite | (Ir,Ru)As2 |
| 2.EB. | Kanatzidisite | (SbBiS3)2Te2 |
| 2.EB.05a | Vaesite | NiS2 |
| 2.EB.05a | Hauerite | MnS2 |
| 2.EB.05a | Laurite | RuS2 |
| 2.EB.05a | Gaotaiite | Ir3Te8 |
| 2.EB.05a | Penroseite | (Ni,Co,Cu)Se2 |
| 2.EB.05a | Fukuchilite | Cu3FeS8 |
| 2.EB.05a | Villamanínite | (Cu,Ni,Co,Fe)S2 |
| 2.EB.05a | Erlichmanite | OsS2 |
| 2.EB.05a | Sperrylite | PtAs2 |
| 2.EB.05a | Geversite | PtSb2 |
| 2.EB.05a | Cattierite | CoS2 |
| 2.EB.05a | Aurostibite | AuSb2 |
| 2.EB.05a | Trogtalite | CoSe2 |
| 2.EB.05a v | 'Cayeuxite' | |
| 2.EB.05a | Kruťaite | CuSe2 |
| 2.EB.05a | Pyrite | FeS2 |
| 2.EB.05a | Insizwaite | PtBi2 |
| 2.EB.05b | Bambollaite | Cu(Se,Te)2 |
| 2.EB.05a | Dzharkenite | FeSe2 |
| 2.EB.10a | Marcasite | FeS2 |
| 2.EB.10e | Paracostibite | CoSbS |
| 2.EB.10f | Oenite | CoSbAs |
| 2.EB.10e | Pararammelsbergite | NiAs2 |
| 2.EB.10a | Mattagamite | CoTe2 |
| 2.EB.10a | Frohbergite | FeTe2 |
| 2.EB.10d | Costibite | CoSbS |
| 2.EB.10c | Glaucodot | (Co0.50Fe0.50)AsS |
| 2.EB.10a | Petříčekite | CuSe2 |
| 2.EB.10a | Kullerudite | NiSe2 |
| 2.EB.10a | Ferroselite | FeSe2 |
| 2.EB.15b | Seinäjokite | FeSb2 |
| 2.EB.15a | Rammelsbergite | NiAs2 |
| 2.EB.15a | Clinosafflorite | CoAs2 |
| 2.EB.15c | Paxite | CuAs2 |
| 2.EB.15a | Nisbite | NiSb2 |
| 2.EB.15a | Löllingite | FeAs2 |
| 2.EB.15a | Safflorite | (Co,Ni,Fe)As2 |
| 2.EB.15a | Omeiite | OsAs2 |
| 2.EB.15a | Anduoite | RuAs2 |
| 2.EB.20 | Arsenopyrite | FeAsS |
| 2.EB.20 | Ruarsite | (Ru,Os)AsS |
| 2.EB.20 | Osarsite | (Os,Ru)AsS |
| 2.EB.20 | Gudmundite | FeSbS |
| 2.EB.25 | Mayingite | IrBiTe |
| 2.EB.25 | Maslovite | PtBiTe |
| 2.EB.25 | Paragersdorffite | Ni(As,S)2 |
| 2.EB.25 | Orthogersdorffite | NiAsS |
| 2.EB.25 | Sulfopadmaite | PdBiS |
| 2.EB.25 | Jolliffeite | NiAsSe |
| 2.EB.25 | Cobaltite | CoAsS |
| 2.EB.25 | Guixiangite | NiBiS |
| 2.EB.25 | Testibiopalladite | PdSbTe |
| 2.EB.25 va | 'Antimony-bearing Gersdorffite' | Ni(As,Sb)S |
| 2.EB.25 | Kalungaite | PdAsSe |
| 2.EB.25 | Hollingworthite | (Rh,Pt,Pd)AsS |
| 2.EB.25 | Michenerite | PdBiTe |
| 2.EB.25 | Gersdorffite | NiAsS |
| 2.EB.25 | Milotaite | PdSbSe |
| 2.EB.25 | Tolovkite | IrSbS |
| 2.EB.25 | 'Platarsite' | Pt(As,S)2 |
| 2.EB.25 | Willyamite | CoSbS |
| 2.EB.25 | Changchengite | IrBiS |
| 2.EB.25 | Kvačekite | NiSbSe |
| 2.EB.25 | Krutovite | NiAs2 |
| 2.EB.25 | Padmaite | PdBiSe |
| 2.EB.25 | Ullmannite | NiSbS |
| 2.EB.25 | Irarsite | (Ir,Ru,Rh,Pt)AsS |
| 2.EB.30 | Urvantsevite | Pd(Bi,Pb)2 |
| 2.EB.35 | Rheniite | ReS2 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Alloclasite
mindat.org URL:
https://www.mindat.org/min-134.html
Please feel free to link to this page.
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References for Alloclasite
Reference List:
Maurel, Colette, Picot, Paul (1973) Sur le mécanisme de la transformation de l'alloclasite en cobaltite : cas du gisement du Lautaret. Bulletin de Minéralogie, 96 (4) 292-297 doi:10.3406/bulmi.1973.6831
Hem, S. R., Makovicky, E., Gervilla, F. (2001) Compositional trends in Fe, Co and Ni sulfarsenides and their crystal-chemical implications: Results from the Arroyo de La Cueva deposits, Ronda Peridotite, Southern Spain. The Canadian Mineralogist, 39 (3). 831-853 doi:10.2113/gscanmin.39.3.831
Localities for Alloclasite
Showing 100 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Brodtkorb (2002) |
Australia | |
| Braize et al. (2026) |
| Croxford (1974) |
| Sielecki (1988) | |
| Jeff Steadman |
| Williams et al 2015 +1 other reference | |
| Lawrence et al. (1998) |
| Croxford (1974) |
| Mineralogical Society of America - ... |
| Bottrill |
Austria | |
| Leitner (2013) |
| Raith et al. (2015) | |
| Raith et al. (2015) |
| Tropper et al. (2011) |
Brazil | |
| Campbell (2012) |
Bulgaria | |
| Kerestedjian (1984) |
Canada | |
| Montgomery (n.d.) |
| Brueckner et al. (2016) |
| Caglioti (2023) |
| [www.ontariominerals.com] +2 other references |
| |
| Mielke (n.d.) |
| Reiner Mielke 2009 | |
| Mineralogical Society of America - ... +1 other reference | |
| Sabina (2000) |
| Mineralogical Society of America - ... |
Chile | |
| Lohmeier et al. (2025) |
China | |
| Xiong et al. (2022) |
| Wang et al. (2022) |
| Zhaolong Li et al. (1981) |
| Gao et al. (2026) |
| Yuanren Chen (1976) |
Czech Republic | |
| Hloušek et al. (2002) |
| Ondruš et al. (2003) | |
Finland | |
| Pere Tuomas (2009) |
France | |
| Mineralogical Society of America - ... |
| R. Pierrot | |
Germany | |
| Kolitsch (1996) |
| |
| Joachim et al. (1993) |
| Wagner et al. (2002) |
| Gröbner et al. (2019) |
| Wittern (2001) |
| Mills et al. (2020) | |
| Henrich (2009) |
| Golze +3 other references | |
| Wittern (2001) |
| www.mineralienatlas.de (2025) |
| Schnorrer et al. (1997) |
| Blass et al. (1998) +1 other reference | |
| Rolf Golze +3 other references |
| Golze +3 other references |
| Sandmann et al. (2015) |
Greece | |
| Rieck et al. (2022) |
India | |
| Goldschmidt Conference Abstracts (2011) |
Indonesia | |
| Dana et al. (2022) |
Iran | |
| Goudarzi et al. (2024) |
| Rezazadeh et al. (2020) |
Ireland | |
| S. MORETON et al. (1999) |
Italy | |
| Vergani et al. (2024) |
| Vergani F. et al. (2019) | |
| Ciriotti et al. (2010) |
| Scano (2023) |
| Sabelli (2000) |
| Scano (2023) | |
Japan | |
| Kingston (1971) |
| Ohnishi et al (2004) |
Kazakhstan | |
| Kovalev et al. (2018) |
Mongolia | |
| Khishgee et al. (2015) |
Morocco | |
| Weiß (2006) |
| ONA |
| Favreau (n.d.) |
| Joachim Esche collection (specimen obtained from Jean-Pierre Barral) |
| Richard Gunter Collection |
Norway | |
| Kullerud et al. (2016) |
Papua New Guinea | |
| Noku et al. (2012) |
Portugal | |
| Marques de Sá et al. (2010) |
| Lundin Mining |
Romania | |
| Szakáll (2002) |
| Tschermak (1866) +3 other references |
Russia | |
| Melekestseva (2005) |
| Izvekova et al. (2021) |
| AA et al. (2021) |
| Bazai et al. (2009) |
| Azovskova et al. (2013, January) |
| Vinogradova +2 other references |
| Gas’kov (2008) |
South Africa | |
| Rudnick et al. (2013) |
Spain | |
| Tornos et al. (1998) |
| Bocamina (4) |
| Fanlo et al. (2004) +2 other references |
UK | |
| Embrey et al. (1987) |
| Betterton (2000) |
| Mineralogical Society of America - ... +2 other references |
| Solferino et al. (2021) |
USA | |
| - (2008) |
| Anthony et al. (1995) |
| Sandfire Resources America Inc. |
| Mineralogical Society of America - ... |
| Bart Cannon Collection |
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Bou Azzer mining district, Drâa-Tafilalet Region, Morocco