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Ferroselite

A valid IMA mineral species - grandfathered
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About FerroseliteHide

Formula:
FeSe2
Colour:
Steel gray to tin white with rose tint, brass yellow
Lustre:
Metallic
Hardness:
6 - 6½
Specific Gravity:
7.20
Crystal System:
Orthorhombic
Member of:
Name:
For the chemical composition.
Dimorph of:

Unique IdentifiersHide

Mindat ID:
1527
Long-form identifier:
mindat:1:1:1527:7

Similar NamesHide

FerrosalitA synonym of 'Ferrosalite'
FerrosiliteA valid IMA mineral species - grandfatheredFe22+Si2O6

IMA Classification of FerroseliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
CoSe2
First published:
1955

Classification of FerroseliteHide

2.EB.10a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
E : Metal Sulfides, M: S <= 1:2
B : M:S = 1:2, with Fe, Co, Ni, PGE, etc.
2.12.2.2

2 : SULFIDES
12 : AmBnXp, with (m+n):p = 1:2
3.9.9

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
9 : Sulphides etc. of Fe

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
FseIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FerroseliteHide

Metallic
Transparency:
Opaque
Colour:
Steel gray to tin white with rose tint, brass yellow
Comment:
Tarnishes to brassy tone
Streak:
Black
Hardness:
6 - 6½ on Mohs scale
Hardness:
VHN25=858 - 933 kg/mm2 - Vickers
Tenacity:
Very brittle
Density:
7.20 g/cm3 (Measured)    7.139 g/cm3 (Calculated)

Optical Data of FerroseliteHide

Anisotropism:
Strong, from greenish gray to lilac gray
Reflectivity:
WavelengthR1 (%)R2 (%)
400nm42.3%44.1%
420nm42.5%44.3%
440nm43.0%44.5%
460nm43.5%45.1%
480nm43.9%45.9%
500nm44.4%47.0%
520nm44.9%48.2%
540nm45.3%49.5%
560nm46.0%50.9%
580nm46.8%52.3%
600nm47.6%53.7%
620nm48.2%54.9%
640nm48.7%55.9%
660nm49.1%56.3%
680nm49.3%56.5%
700nm49.5%56.7%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 56.7%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White with gray-brown hue
Pleochroism:
Visible

Chemistry of FerroseliteHide

Mindat Formula:
FeSe2
Element Weights:
Element% weight
Se73.876 %
Fe26.125 %

Calculated from ideal end-member formula.
Common Impurities:
Co

Crystallography of FerroseliteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnnm
Setting:
Pnnm
Cell Parameters:
a = 4.8007 Å, b = 5.776 Å, c = 3.5850 Å
Ratio:
a:b:c = 0.831 : 1 : 0.621
Unit Cell V:
99.41 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Slender prismatic crystals
Twinning:
Stellate and cruciform twins, twin lammellae in polished sections.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020709FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA0293
0013331FerroselitePickardt J, Reuter B, Riedel E, Sochtig J (1975) On the formation of FeSe2 single crystals by chemical transport reactions Journal of Solid State Chemistry 15 366-3681975synthetic0293
0011936FerroseliteKjekshus A, Rakke T, Andresen A (1974) Compounds of the marcasite type crystal structure. IX. Structural data for FeAs2, FeSe2, NiAs2, NiSb2, and CuSe2 Acta Chemica Scandinavica A28 996-10001974synthetic0293
0020717FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA0.0001198.2
0020718FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA0.0001148.4
0020719FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA0.000150.4
0020710FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA1.7293
0020721FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA3.64116
0020720FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA3.68197
0020711FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA3.83293
0020712FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA8.1293
0020713FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA17.3293
0020714FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA24.4293
0020715FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA32293
0020716FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA46293
0015754FerroseliteTengner S (1938) Uber diselenide und ditelluride von eisen, kobalt und nickel Zeitschrift fur Anorganische und Allgemeine Chemie 239 126-13219380293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.568 Å(100)
2.474 Å(100)
1.885 Å(70)
2.871 Å(50)
1.695 Å(40)
2.400 Å(35)
1.541 Å(35)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4
Geological Setting:
Red bed deposits of Colorado Plateau type.

Type Occurrence of FerroseliteHide

General Appearance of Type Material:
Prismatic crystals of the mineral are 0.2-0.5 mm long and up to 0.1 mm in cross-section.
Place of Conservation of Type Material:
Mining Museum, St. Petersburg Mining Institute, St. Petersburg, Russia, 46-2/1.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 69853.
Geological Setting of Type Material:
Cementing sandstones and pelites in Middle Devonian deposits.
Associated Minerals at Type Locality:

Synonyms of FerroseliteHide

Other Language Names for FerroseliteHide

Relationship of Ferroselite to other SpeciesHide

Member of:
Other Members of Marcasite Group:
FrohbergiteFeTe2Orth. mmm(2/m2/m2/m) : Pnnm
KulleruditeNiSe2Orth. mmm(2/m2/m2/m) : Pnnm
MarcasiteFeS2Orth. mmm(2/m2/m2/m) : Pnnm
MattagamiteCoTe2Orth. mmm(2/m2/m2/m) : Pnnm
PetříčekiteCuSe2Orth. mmm(2/m2/m2/m) : Pnnm

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Ferroselite associated with Native SeleniumSe
3 photos of Ferroselite associated with Haynesite(UO2)3(Se4+O3)2(OH)2 · 5H2O
3 photos of Ferroselite associated with Boltwoodite(K,Na)(UO2)(SiO3OH) · 1.5H2O
3 photos of Ferroselite associated with CobaltomeniteCoSeO3 · 2H2O
3 photos of Ferroselite associated with 'Sandstone'
2 photos of Ferroselite associated with 'Leucoxene'
2 photos of Ferroselite associated with CalciteCaCO3
1 photo of Ferroselite associated with K Feldspar
1 photo of Ferroselite associated with ClausthalitePbSe
1 photo of Ferroselite associated with BerzelianiteCu2-xSe (x ≈ 0.12)

Related Minerals - Strunz-mindat GroupingHide

2.EB.SelenolauriteRuSe2Iso. m3(2/m3) : Pa3
2.EB.AndrieslombaarditeRhSbSIso. 23 : P213
2.EB.Iridarsenite(Ir,Ru)As2Mon. 2/m : P21/b
2.EB.Kanatzidisite(SbBiS3)2Te2Mon. 2/m : P21/m
2.EB.05aVaesiteNiS2Iso. m3(2/m3) : Pa3
2.EB.05aHaueriteMnS2Iso. m3(2/m3) : Pa3
2.EB.05aLauriteRuS2Iso. m3(2/m3) : Pa3
2.EB.05aGaotaiiteIr3Te8Iso. m3(2/m3) : Pa3
2.EB.05aPenroseite(Ni,Co,Cu)Se2Iso. m3(2/m3) : Pa3
2.EB.05aFukuchiliteCu3FeS8Iso. m3(2/m3) : Pa3
2.EB.05aVillamanínite(Cu,Ni,Co,Fe)S2Tric.
2.EB.05aErlichmaniteOsS2Iso. m3(2/m3) : Pa3
2.EB.05aSperrylitePtAs2Iso. m3(2/m3) : Pa3
2.EB.05aGeversitePtSb2Iso. m3(2/m3) : Pa3
2.EB.05aCattieriteCoS2Iso. m3(2/m3) : Pa3
2.EB.05aAurostibiteAuSb2Iso. m3(2/m3) : Pa3
2.EB.05aTrogtaliteCoSe2Iso. m3(2/m3) : Pa3
2.EB.05a v'Cayeuxite'
2.EB.05aKruťaiteCuSe2Iso. m3(2/m3) : Pa3
2.EB.05aPyriteFeS2Iso. m3(2/m3) : Pa3
2.EB.05aInsizwaitePtBi2Iso. m3(2/m3) : Pa3
2.EB.05bBambollaiteCu(Se,Te)2Tet.
2.EB.05aDzharkeniteFeSe2Iso. m3(2/m3) : Pa3
2.EB.10aMarcasiteFeS2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10eParacostibiteCoSbSOrth. mmm(2/m2/m2/m) : Pbca
2.EB.10fOeniteCoSbAsOrth.
2.EB.10ePararammelsbergiteNiAs2Orth. mmm(2/m2/m2/m) : Pbca
2.EB.10aMattagamiteCoTe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10aFrohbergiteFeTe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10dCostibiteCoSbSOrth. mm2 : Pmn21
2.EB.10bAlloclasiteCo1-xFexAsSMon. 2 : P21
2.EB.10cGlaucodot(Co0.50Fe0.50)AsSOrth. mm2 : Pmn21
2.EB.10aPetříčekiteCuSe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10aKulleruditeNiSe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15bSeinäjokiteFeSb2Orth.
2.EB.15aRammelsbergiteNiAs2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15aClinosaffloriteCoAs2Mon. 2/m : P21/m
2.EB.15cPaxiteCuAs2Mon. 2/m : P21/b
2.EB.15aNisbiteNiSb2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15aLöllingiteFeAs2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15aSafflorite(Co,Ni,Fe)As2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15aOmeiiteOsAs2Orth.
2.EB.15aAnduoiteRuAs2Orth.
2.EB.20ArsenopyriteFeAsSMon. 2/m : P21/b
2.EB.20Ruarsite(Ru,Os)AsSMon.
2.EB.20Osarsite(Os,Ru)AsSMon.
2.EB.20GudmunditeFeSbSMon. 2/m : P21/b
2.EB.25MayingiteIrBiTeIso. m3(2/m3) : Pa3
2.EB.25MaslovitePtBiTeIso. 23 : P213
2.EB.25ParagersdorffiteNi(As,S)2Iso. m3(2/m3) : Pa3
2.EB.25OrthogersdorffiteNiAsSOrth. mm2 : Pca21
2.EB.25SulfopadmaitePdBiSIso. 23 : P213
2.EB.25JolliffeiteNiAsSeIso. m3(2/m3) : Pa3
2.EB.25CobaltiteCoAsSOrth. mm2 : Pca21
2.EB.25GuixiangiteNiBiSIso. 23 : P213
2.EB.25TestibiopalladitePdSbTeIso.
2.EB.25 va'Antimony-bearing Gersdorffite'Ni(As,Sb)S
2.EB.25KalungaitePdAsSeIso. m3(2/m3) : Pa3
2.EB.25Hollingworthite(Rh,Pt,Pd)AsSIso. m3(2/m3) : Pa3
2.EB.25MicheneritePdBiTeIso. 23 : P213
2.EB.25GersdorffiteNiAsSIso. 23 : P213
2.EB.25MilotaitePdSbSeIso. 23 : P213
2.EB.25TolovkiteIrSbSIso.
2.EB.25'Platarsite'Pt(As,S)2Iso. m3(2/m3) : Pa3
2.EB.25WillyamiteCoSbS
2.EB.25ChangchengiteIrBiSIso. 23 : P213
2.EB.25KvačekiteNiSbSeIso. 23 : P213
2.EB.25KrutoviteNiAs2Iso. 23 : P213
2.EB.25PadmaitePdBiSeIso. 432
2.EB.25UllmanniteNiSbSIso. 23 : P213
2.EB.25Irarsite(Ir,Ru,Rh,Pt)AsSIso. m3(2/m3) : Pa3
2.EB.30UrvantsevitePd(Bi,Pb)2Tet. 4/mmm(4/m2/m2/m) : I4/mmm
2.EB.35RheniiteReS2Tric. 1 : P1

Other InformationHide

Thermal Behaviour:
Heated in a closed tube, it gives a dark-red sublimate and the characteristic selenium odor.
Notes:
On heating becomes magnetic.
Dissolved by HNO3, only slightly by HCl and H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FerroseliteHide

References for FerroseliteHide

Reference List:

Localities for FerroseliteHide

Showing 72 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • La Rioja Province
    • Capital Department
      • Puerto Alegre
Zappettini et al. (2014) +1 other reference
    • General Lamadrid Department
      • Villa Castelli
        • Sierra de Cacho
Grundmann et al. (2018)
Brodtkorb (2002) +3 other references
Zappettini et al. (2014) +1 other reference
  • Mendoza Province
    • Luján de Cuyo department
      • Cacheuta District
Grundmann et al. (2018)
          • Cerro de Cacheuta
Grundmann et al. (2018)
Brazil
 
  • Goiás
    • Cavalcante
Menez +3 other references
China
 
  • Gansu
    • Gannan
      • Luqu Co.
Hanjie Wen et al. (2003)
  • Guizhou
    • Guiyang
      • Kaiyang County
        • Baimacun
Chen Luming et al. (1993) +1 other reference
  • Inner Mongolia
    • Alxa League (Alashan Prefecture)
      • Alxa Right Banner (Alashan Youqi)
Jiayong Pan et al. (2009)
    • Tongliao City (Tongliao Prefecture)
      • Horqin Left Middle Banner
Yang et al. (2026)
Hu et al. (2024) +1 other reference
Shenyun Wu et al. (1982)
  • Xinjiang
    • Ili Kazakh Autonomous Prefecture
      • Chabucha'er Xibo Co. (Qapqal Xibe Co.; Chapchal Shibe Co.)
Dai et al. (2015)
Czech Republic
 
  • Central Bohemian Region
Škácha et al. (2017)
      • Háje
Škácha et al. (2017) +1 other reference
  • Plzeň Region
    • Klatovy District
      • Nalžovské Hory
        • Ústaleč
Sejkora et al. (2022) +1 other reference
    • Tachov District
      • Zadní Chodov
Scharmová (1998)
  • South Bohemian Region
    • Písek District
      • Kovářov
        • Předbořice
Anthony et al. (1990) +2 other references
  • Vysočina Region
    • Žďár nad Sázavou District
      • Nové Město na Moravě
Kvaček (1979) +1 other reference
Kvaček (1979) +1 other reference
      • Rožná
        • Rožná deposit
Anthony et al. (1990)
Egypt
 
  • Red Sea Governorate
    • Wadi Abu Rasheid
Shalan (2021)
Finland
 
  • Lapland
    • Savukoski
      • Tulppio
        • Sokli carbonatite complex
Ani et al. (2013)
  • North Ostrobothnia
Vuorelainen et al. (1964) +1 other reference
Vuorelainen et al. (1964) +1 other reference
Germany
 
  • Bavaria
    • Upper Palatinate
Seeliger et al. (1965) +1 other reference
  • Lower Saxony
    • Goslar District
      • Braunlage
        • St Andreasberg
Wittern (2001)
      • Harz (Landkreis Goslar)
Frank Keutsch analysis +3 other references
  • Saxony-Anhalt
    • Mansfeld-Südharz
      • Mansfeld
Wittern (2001)
  • Saxony
    • Erzgebirgskreis
      • Aue-Bad Schlema
        • Alberoda
          • Shaft 366
Forster et al. (2004)
    • Görlitz District
      • Quitzdorf am See
        • Horscha
86. +1 other reference
India
 
  • Meghalaya
    • South West Khasi Hills District
Babu et al. (2002)
Babu et al. (2002)
Kazakhstan
 
  • Almaty Region
    • Middle Ili River
      • Dzharkenskaya Depression
Pavel M. Kartashov (n.d.)
Pekov (1998)
Russia
 
  • Kemerovo Oblast
Wanlie Ding (2005)
  • Tuva
    • Turan District
DAN-SSSR (1955) +1 other reference
Sweden
 
  • Östergötland County
    • Valdemarsvik
Sandström (2007)
USA
 
  • Colorado
    • Montrose County
Eckel et al. (1997)
Eckel et al. (1997)
Eckel et al. (1997)
Eckel et al. (1997)
      • Paradox Valley
Eckel et al. (1997)
Am Min 53:2075-2077 +3 other references
Carnegie Museum of Natural History ... +1 other reference
Eckel et al. (1997)
Eckel et al. (1997)
    • San Juan County
Eckel et al. (1997)
    • San Miguel County
      • King Mine
Shawe et al. (2011)
Eckel et al. (1997)
  • New Mexico
Northrop et al. (1996)
    • McKinley County
Northrop et al. (1996)
Austin et al. (83)
NMBMMR Memoir 15 Geology and Technology ...
NMBMMR Memoir 15 Geology and Technology ...
      • Nose Rock
NMBMMR Memoir 38 Geology and Technology ...
Am Min 53:2075-2077 +1 other reference
USGS Prof Paper 550C ppC133-C137
Simon et al. (1997)
  • Utah
    • Emery County
Bullock (1981)
Geochimica et Cosmochimica Acta Volume ...
    • Grand County
      • Thompsons Mining District
Kampf et al. (2025)
        • The Poison Strip
SEM-EDS and PXRD analyzed by Tony Kampf.
        • Yellow Cat Mesa
Thorne (n.d.) +2 other references
King (n.d.)
    • San Juan County
      • Montezuma Canyon Mining District
King et al. (1993)
  • Wyoming
    • Carbon County
USGS Prof Paper 550C ppC133-C137 +1 other reference
    • Converse County
      • Southern Powder River Basin Mining District
USGS Prof Paper 550C ppC133-C137
Harshman (1972)
 
and/or  
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