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Krutovite

A valid IMA mineral species
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About KrutoviteHide

04593510017271924534791.jpg
Georgy A. Krutov and Oleg V. Kononov
Formula:
NiAs2
Colour:
Greyish-white
Lustre:
Metallic
Hardness:
Specific Gravity:
7.10 (Calculated)
Crystal System:
Isometric
Name:
Named in honor of Georgy Alekseevich Krutov (Георгий Алексеевич Крутов) (24 April 1902, Lytinko, Solnechnogorsk, Moscow, Russian Empire - 11 December 1989, USSR), Professor, Department of Mineralogy, Moscow State University. He specialized in the field of geology, mineralogy, and geochemistry of nickel-cobalt. He was awarded the 1961 A.E. Fersman prize.
Probably a member of the Pyrite Group (Strunz and Nickel, 2001). Synthetic NiAs2 has a pyrite-type structure (Munson, 1968).


Unique IdentifiersHide

Mindat ID:
2280
Long-form identifier:
mindat:1:1:2280:0

IMA Classification of KrutoviteHide

Classification of KrutoviteHide

2.EB.25

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
E : Metal Sulfides, M: S <= 1:2
B : M:S = 1:2, with Fe, Co, Ni, PGE, etc.
2.12.1.12

2 : SULFIDES
12 : AmBnXp, with (m+n):p = 1:2

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KruIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KrutoviteHide

Metallic
Transparency:
Opaque
Colour:
Greyish-white
Hardness:
5½ on Mohs scale
Hardness:
VHN100=719 - Vickers
Density:
7.10(2) g/cm3 (Calculated)

Optical Data of KrutoviteHide

Type:
Isotropic
Reflectivity:
WavelengthR1 (%)R2 (%)
440nm64.0%66.2%
460nm64.7%65.4%
500nm63.8%64.0%
540nm64.7%65.0%
580nm65.7%65.8%
620nm66.2%66.7%
660nm66.3%66.8%
700nm66.2%66.8%
740nm66.2%66.8%
780nm66.0%66.8%
820nm66.0%66.8%
860nm66.3%67.1%
900nm66.6%67.5%
940nm67.2%68.0%
980nm68.0%68.8%
1020nm69.7%70.3%
1060nm71.3%72.1%
1100nm73.4%74.0%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 74.0%.
R1 shown in black, R2 shown in red
Colour in reflected light:
bright white with rose tint, compared to nickel skutterudite

Chemistry of KrutoviteHide

Mindat Formula:
NiAs2
Element Weights:
Element% weight
As71.855 %
Ni28.145 %

Calculated from ideal end-member formula.
Common Impurities:
Co,Fe,Cu,Sb,S

Crystallography of KrutoviteHide

Crystal System:
Isometric
Class (H-M):
23 - Tetartoidal
Space Group:
P213
Cell Parameters:
a = 5.79 Å
Unit Cell V:
194.10 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012675KrutoviteMunson R A (1968) The synthesis of iridium disulfide and nickel diarsenide having the pyrite structure Inorganic Chemistry 7 389-3901968synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.593 Å(10)
2.365 Å(8)
1.746 Å(8)
2.897 Å(6)
1.548 Å(6)
1.0242 Å(6)
2.051 Å(5)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of KrutoviteHide

General Appearance of Type Material:
grains intergrown with ore
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Academy of Science, Moscow, Russia.
Mining Institute, St. Petersburg, Russia.
National Museum, Prague, Czech Republic, 61625.
Associated Minerals at Type Locality:

Synonyms of KrutoviteHide

Other Language Names for KrutoviteHide

Dutch:Krutoviet
German:Krutovit
Spanish:Krutovita

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Krutovite associated with StephaniteAg5SbS4
2 photos of Krutovite associated with AnnabergiteNi3(AsO4)2 · 8H2O
2 photos of Krutovite associated with DickiteAl2(Si2O5)(OH)4
2 photos of Krutovite associated with ProustiteAg3AsS3
2 photos of Krutovite associated with QuartzSiO2
2 photos of Krutovite associated with SymplesiteFe2+3(AsO4)2 · 8H2O
2 photos of Krutovite associated with ParasymplesiteFe2+3(AsO4)2 · 8H2O
2 photos of Krutovite associated with JarositeKFe3+3(SO4)2(OH)6
1 photo of Krutovite associated with CalciteCaCO3
1 photo of Krutovite associated with Tennantite SubgroupCu6(Cu4C2+2)As4S12S

Related Minerals - Strunz-mindat GroupingHide

2.EB.SelenolauriteRuSe2Iso. m3(2/m3) : Pa3
2.EB.AndrieslombaarditeRhSbSIso. 23 : P213
2.EB.Iridarsenite(Ir,Ru)As2Mon. 2/m : P21/b
2.EB.Kanatzidisite(SbBiS3)2Te2Mon. 2/m : P21/m
2.EB.05aVaesiteNiS2Iso. m3(2/m3) : Pa3
2.EB.05aHaueriteMnS2Iso. m3(2/m3) : Pa3
2.EB.05aLauriteRuS2Iso. m3(2/m3) : Pa3
2.EB.05aGaotaiiteIr3Te8Iso. m3(2/m3) : Pa3
2.EB.05aPenroseite(Ni,Co,Cu)Se2Iso. m3(2/m3) : Pa3
2.EB.05aFukuchiliteCu3FeS8Iso. m3(2/m3) : Pa3
2.EB.05aVillamanínite(Cu,Ni,Co,Fe)S2Tric.
2.EB.05aErlichmaniteOsS2Iso. m3(2/m3) : Pa3
2.EB.05aSperrylitePtAs2Iso. m3(2/m3) : Pa3
2.EB.05aGeversitePtSb2Iso. m3(2/m3) : Pa3
2.EB.05aCattieriteCoS2Iso. m3(2/m3) : Pa3
2.EB.05aAurostibiteAuSb2Iso. m3(2/m3) : Pa3
2.EB.05aTrogtaliteCoSe2Iso. m3(2/m3) : Pa3
2.EB.05a v'Cayeuxite'
2.EB.05aKruťaiteCuSe2Iso. m3(2/m3) : Pa3
2.EB.05aPyriteFeS2Iso. m3(2/m3) : Pa3
2.EB.05aInsizwaitePtBi2Iso. m3(2/m3) : Pa3
2.EB.05bBambollaiteCu(Se,Te)2Tet.
2.EB.05aDzharkeniteFeSe2Iso. m3(2/m3) : Pa3
2.EB.10aMarcasiteFeS2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10eParacostibiteCoSbSOrth. mmm(2/m2/m2/m) : Pbca
2.EB.10fOeniteCoSbAsOrth.
2.EB.10ePararammelsbergiteNiAs2Orth. mmm(2/m2/m2/m) : Pbca
2.EB.10aMattagamiteCoTe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10aFrohbergiteFeTe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10dCostibiteCoSbSOrth. mm2 : Pmn21
2.EB.10bAlloclasiteCo1-xFexAsSMon. 2 : P21
2.EB.10cGlaucodot(Co0.50Fe0.50)AsSOrth. mm2 : Pmn21
2.EB.10aPetříčekiteCuSe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10aKulleruditeNiSe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.10aFerroseliteFeSe2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15bSeinäjokiteFeSb2Orth.
2.EB.15aRammelsbergiteNiAs2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15aClinosaffloriteCoAs2Mon. 2/m : P21/m
2.EB.15cPaxiteCuAs2Mon. 2/m : P21/b
2.EB.15aNisbiteNiSb2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15aLöllingiteFeAs2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15aSafflorite(Co,Ni,Fe)As2Orth. mmm(2/m2/m2/m) : Pnnm
2.EB.15aOmeiiteOsAs2Orth.
2.EB.15aAnduoiteRuAs2Orth.
2.EB.20ArsenopyriteFeAsSMon. 2/m : P21/b
2.EB.20Ruarsite(Ru,Os)AsSMon.
2.EB.20Osarsite(Os,Ru)AsSMon.
2.EB.20GudmunditeFeSbSMon. 2/m : P21/b
2.EB.25MayingiteIrBiTeIso. m3(2/m3) : Pa3
2.EB.25MaslovitePtBiTeIso. 23 : P213
2.EB.25ParagersdorffiteNi(As,S)2Iso. m3(2/m3) : Pa3
2.EB.25OrthogersdorffiteNiAsSOrth. mm2 : Pca21
2.EB.25SulfopadmaitePdBiSIso. 23 : P213
2.EB.25JolliffeiteNiAsSeIso. m3(2/m3) : Pa3
2.EB.25CobaltiteCoAsSOrth. mm2 : Pca21
2.EB.25GuixiangiteNiBiSIso. 23 : P213
2.EB.25TestibiopalladitePdSbTeIso.
2.EB.25 va'Antimony-bearing Gersdorffite'Ni(As,Sb)S
2.EB.25KalungaitePdAsSeIso. m3(2/m3) : Pa3
2.EB.25Hollingworthite(Rh,Pt,Pd)AsSIso. m3(2/m3) : Pa3
2.EB.25MicheneritePdBiTeIso. 23 : P213
2.EB.25GersdorffiteNiAsSIso. 23 : P213
2.EB.25MilotaitePdSbSeIso. 23 : P213
2.EB.25TolovkiteIrSbSIso.
2.EB.25'Platarsite'Pt(As,S)2Iso. m3(2/m3) : Pa3
2.EB.25WillyamiteCoSbS
2.EB.25ChangchengiteIrBiSIso. 23 : P213
2.EB.25KvačekiteNiSbSeIso. 23 : P213
2.EB.25PadmaitePdBiSeIso. 432
2.EB.25UllmanniteNiSbSIso. 23 : P213
2.EB.25Irarsite(Ir,Ru,Rh,Pt)AsSIso. m3(2/m3) : Pa3
2.EB.30UrvantsevitePd(Bi,Pb)2Tet. 4/mmm(4/m2/m2/m) : I4/mmm
2.EB.35RheniiteReS2Tric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KrutoviteHide

References for KrutoviteHide

Reference List:

Localities for KrutoviteHide

Showing 24 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Bahia
    • Maracás
      • Rio Jacaré layered complex
Campbell (2012)
Czech Republic
 
  • Karlovy Vary Region
    • Karlovy Vary District
Hloušek et al. (2002)
86. +1 other reference
      • Potůčky
Nickel & Nichols +1 other reference
Germany
 
  • Hesse
    • Darmstadt
      • Darmstadt-Dieburg
        • Mühltal
          • Nieder-Ramstadt
PETITJEAN collection
Poland
 
  • Lower Silesian Voivodeship
    • Jawor County
      • Gmina Męcinka
        • Chełmiec
Muszyński et al. (2023)
Muszyński et al. (2023)
Romania
 
  • Bihor County
    • Nucet
Săbău et al. (2023)
Russia
 
  • Adygea (Republic of Adygea)
    • Maykopsky District
Pavel M. Kartashov (n.d.) +1 other reference
  • Orenburg Oblast
    • Gaysky District
Zaikov et al. (2006)
  • Tuva
    • Chedi-Kholsky District
Anthony et al. (1990)
    • Ovyursky District
Sejkora et al. (2021)
Serbia
 
  • Central Serbia
    • Raška District
      • Novi Pazar
Budinov et al. (2015)
Slovakia
 
  • Banská Bystrica Region
    • Banská Bystrica District
      • Ľubietová
Majzlan J. et al. (2022) +1 other reference
  • Košice Region
    • Rožňava District
Chovan M. & Ozdín D. et al. (Slovakia)
Kiefer et al. (2020)
Martin Števko-unpublished
Števko M. et al. (Slovenská republika)
  • Trenčín Region
    • Bánovce nad Bebravou District
      • Čierna Lehota
Majzlan et al. (2022)
  • Žilina Region
    • Liptovský Mikuláš District
Ozdín et al. (1999)
Ozdín et al. (1999)
Spain
 
  • Aragon
    • Huesca
      • San Juan de Plan
Fanlo et al. (2004)
Switzerland
 
  • Valais
    • Leuk
      • Turtmann-Unterems
        • Turtmann Valley
          • Pipjitälli
Ansermet et al. (2021)
    • Sierre
      • Anniviers
        • Ayer
Ansermet (2012)
 
and/or  
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