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Deynekoite

A valid IMA mineral species - pending publication
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About DeynekoiteHide

Formula:
Ca9◻Fe3+(PO4)7
Colour:
light-yellow and light-brown
Hardness:
Specific Gravity:
3.09 (Calculated)
Crystal System:
Trigonal
Name:
The name deynekoite is given in honour of Dr Dina V. Deyneko (born 1988) for her valuable contribution to the investigation of synthetic analogues of merrillite group minerals
A member of the merrillite group of the cerite supergroup. The Fe3+ analogue of the other group members: merrillite, ferromerrillite, keplerite, and matyhite.

Deynekoite is the first mineral of the merrillite group whose composition includes Fe3+, and it has a synthetic analogue.


Unique IdentifiersHide

Mindat ID:
55965
Long-form identifier:
mindat:1:1:55965:4

IMA Classification of DeynekoiteHide

Approved, Pending publication
Approval year:
2022

Classification of DeynekoiteHide

8.AD.

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
D : With only large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
DnkIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DeynekoiteHide

Transparency:
Transparent
Colour:
Light-yellow and light-brown
Streak:
White with a yellowish tint
Hardness:
4½ on Mohs scale
Hardness:
VHN25=319(29) kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Conchoidal
Density:
3.09 g/cm3 (Calculated)

Optical Data of DeynekoiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.658(3) nε = 1.652(3)
Max. Birefringence:
δ = 0.006
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Pleochroism:
Non-pleochroic

Chemistry of DeynekoiteHide

Mindat Formula:
Ca9◻Fe3+(PO4)7
Element Weights:
Element% weight
O41.428 %
Ca33.357 %
P20.051 %
Fe5.164 %

Calculated from ideal end-member formula.

Chemical AnalysisHide

Crystallography of DeynekoiteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3c
Cell Parameters:
a = 10.3516(3) Å, c = 37.160(2) Å
Ratio:
a:c = 1 : 3.59
Unit Cell V:
3,448.43 ų (Calculated from Unit Cell)
Z:
6

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.451 Å(51)
3.433 Å(25)
3.183 Å(64)
2.861 Å(100)
2.737 Å(24)
2.588 Å(81)
1.919 Å(24)
1.716 Å(28)
Comments:
From Type Description.

Type Occurrence of DeynekoiteHide

General Appearance of Type Material:
aggregates with grains up to 30–40 µm in size
Place of Conservation of Type Material:
Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5791/1
Geological Setting of Type Material:
phosphide-bearing contact facies of diopside-anorthite-tridymite paralava of the Hatrurim Complex in Jordan. Where the phosphides are converting into phosphates.
Associated Minerals at Type Locality:

Synonyms of DeynekoiteHide

Other Language Names for DeynekoiteHide

German:Deynekoit

Relationship of Deynekoite to other SpeciesHide

Other Members of Merrillite Group:
Changesite-(Y)(Ca8Y)◻Fe2+(PO4)7Trig. 3m : R3c
Merrillite SubgroupA subgroup with the Merrillite group, which is itself within the greater Cerite Supergroup; new group ...
Whitlockite SubgroupGroup of structurally complex Ca-metal-phosphates.

Related Minerals - Strunz-mindat GroupingHide

8.AD.'Unnamed (Monoclinic polymorph of ximengite)'Bi(PO4)Mon. 2/m : P21/m
8.AD.KepleriteCa9(Ca0.50.5)Mg(PO4)7Trig. 3m : R3c
8.AD.MazoriteBa3(PO4)2Trig. 3m(32/m) : R3m
8.AD.Monazite-(Gd)Gd(PO4)Mon.
8.AD.05NahpoiteNa2(PO3OH)Mon. 2/m : P21/m
8.AD.10WeiliteCa(HAsO4)Tric. 1 : P1
8.AD.10ŠvenekiteCa(H2AsO4)2Tric. 1 : P1
8.AD.10MonetiteCa(PO3OH)Tric. 1
8.AD.15Archerite(K,NH4)(H2PO4)Tet. 42m : I42d
8.AD.15BiphosphammiteNH4(H2PO4)Tet. 422 : I4122
8.AD.20Phosphammite(NH4)2(PO3OH)Mon. 2/m : P21/b
8.AD.25BuchwalditeNaCa(PO4)Orth. mm2 : Pmn21
8.AD.30SchulténitePb(HAsO4)Mon. 2/m : P2/b
8.AD.35DreyeriteBi(VO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35Wakefieldite-(La)La(VO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35Anningite-(Ce)(Ca0.5Ce4+0.5)(VO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35PretuliteSc(PO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35Wakefieldite-(Ce)Ce(VO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35Wakefieldite-(Y)Y(VO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35Xenotime-(Yb)Yb(PO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35'Chernovite-(Ce)'(Ce,Y)(AsO4)Tet.
8.AD.35Xenotime-(Gd)Gd(PO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35Chernovite-(Y)Y(AsO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35Xenotime-(Y)Y(PO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.35Wakefieldite-(Nd)Nd(VO4)Tet. 4/mmm(4/m2/m2/m) : I41/amd
8.AD.40PucheriteBi(VO4)Orth. mmm(2/m2/m2/m)
8.AD.45XimengiteBi(PO4)Trig. 32 : P3121
8.AD.50'UM2005-35-VO:CaFePSiTh'(Th,Ca)(VO4,SiO4,PO4)
8.AD.50RooseveltiteBi(AsO4)Mon. 2/m
8.AD.50Gasparite-(Ce)Ce(AsO4)Mon. 2/m
8.AD.50Monazite-(Sm)Sm(PO4)Mon. 2/m
8.AD.50Monazite-(Ce)Ce(PO4)Mon. 2/m
8.AD.50Monazite-(La)La(PO4)Mon. 2/m
8.AD.50Monazite-(Nd)Nd(PO4)Mon. 2/m
8.AD.50Gasparite-(La)La(AsO4)Mon. 2/m
8.AD.50CheraliteCaTh(PO4)2Mon. 2/m
8.AD.55TetrarooseveltiteBi(AsO4)Tet. 4/m : I41/a
8.AD.60Chursinite[Hg2]2+Hg2+2[AsO4]2Mon. 2/m : P21/b
8.AD.65ClinobisvaniteBi(VO4)Mon. 2/m
8.AD.70GurimiteBa3(VO4)2Trig. 3m : R3m
8.AD.75PicaiteNaCa[AsO3OH][AsO2(OH)2]Mon. 2/m : P21/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DeynekoiteHide

References for DeynekoiteHide

Localities for DeynekoiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Jordan (TL)
 
  • Amman Governorate
    • Transjordan Plateau
      • Daba-Siwaqa complex
Miyawaki et al. (2022) +2 other references
 
and/or  
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