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Shcherbakovite

A valid IMA mineral species - grandfathered
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About ShcherbakoviteHide

04709410017271926648574.jpg
Dmitri Ivanovich Shcherbakov (1893-1966)
Formula:
(K,Ba)KNa(Ti,Nb)2(Si4O12)O2
Colour:
Dark brown
Lustre:
Vitreous, Greasy
Hardness:
Specific Gravity:
2.968
Crystal System:
Orthorhombic
Member of:
Name:
Named by E.M. Es'kova and M.E. Kazakova in 1954 in honor of Dmitri Ivanovich Shcherbakov (13 January 1893 - 25 May 1966, Moscow, Russia) geochemist and mineralogist.
Batisite Group.
Easily confused with batisite.

Note: the "shcherbakovite" described by Mitchell (1990) is in fact noonkanbahite.


Unique IdentifiersHide

Mindat ID:
3635
Long-form identifier:
mindat:1:1:3635:7

IMA Classification of ShcherbakoviteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
K2NaTi4+2(Si4O12)O(OH)
First published:
1954

Classification of ShcherbakoviteHide

9.DH.20

9 : SILICATES (Germanates)
D : Inosilicates
H : Inosilicates with 4-periodic single chains, Si4O12
65.3.4.2

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
3 : Single-Width Unbranched Chains, W=1 with chains P=4
17.8.13

17 : Silicates Containing other Anions
8 : Silicates with niobate or tantalate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
SbkIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ShcherbakoviteHide

Vitreous, Greasy
Transparency:
Opaque
Colour:
Dark brown
Hardness:
6½ on Mohs scale
Hardness:
VHN100=731 - 845 - Vickers
Tenacity:
Brittle
Cleavage:
Poor/Indistinct
Two directions, observed microscopically, may be parting.
Fracture:
Irregular/Uneven
Density:
2.968 g/cm3 (Measured)    3.194 g/cm3 (Calculated)

Optical Data of ShcherbakoviteHide

Type:
Biaxial (-)
RI values:
nα = 1.707 nβ = 1.745 nγ = 1.776
2V:
Measured: 82° , Calculated: 82°
Max. Birefringence:
δ = 0.069
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Dispersion:
r > v
Pleochroism:
Visible
Comments:
X = pale yellow; Y = yellow; Z = brownish yellow.

Chemistry of ShcherbakoviteHide

Mindat Formula:
(K,Ba)KNa(Ti,Nb)2(Si4O12)O2
Element Weights:
Element% weight
O42.005 %
Si21.067 %
Ti17.953 %
K14.664 %
Na4.311 %

Calculated from ideal end-member formula.
Common Impurities:
Zr,Al,Fe,Ta,Mn,Mg,Ca,Cl,H2O

Crystallography of ShcherbakoviteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Imma
Setting:
Imma
Cell Parameters:
a = 10.55 Å, b = 13.92 Å, c = 8.1 Å
Ratio:
a:b:c = 0.758 : 1 : 0.582
Unit Cell V:
1,189.53 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005885ShcherbakoviteUvarova Y A, Sokolova E V, Hawthorne F C, Liferovich R P, Mitchell R H (2003) The crystal chemistry of shcherbakovite from the Khibina Massif, Kola Peninsula, Russia The Canadian Mineralogist 41 1193-12012003Khibina Massif, Kola Peninsula, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.90 Å(100)
1.081 Å(100)
2.64 Å(70)
1.688 Å(70)
1.576 Å(60)
3.39 Å(50)
2.04 Å(50)
1.538 Å(50)
Comments:
Apatitovyi Tsirk, Rasvumchorr Mine, Khibiny Massif, Russia. The data are from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
7 : Ultramafic igneous rocks
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of ShcherbakoviteHide

General Appearance of Type Material:
Crystals are long prismatic, to 6 cm; terminated crystals are uncommon.
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia; 57256.
Geological Setting of Type Material:
In a pegmatite in alkalic rocks.
Associated Minerals at Type Locality:

Synonyms of ShcherbakoviteHide

Other Language Names for ShcherbakoviteHide

Relationship of Shcherbakovite to other SpeciesHide

Member of:
Other Members of Batisite Group:
BatisiteBaNaNaTi2(Si4O12)O2Orth. mmm(2/m2/m2/m) : Imma
NoonkanbahiteBaKNaTi2(Si4O12)O2Orth. mmm(2/m2/m2/m) : Imma

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Shcherbakovite associated with AegirineNaFe3+Si2O6
1 photo of Shcherbakovite associated with NatroliteNa2Al2Si3O10 · 2H2O
1 photo of Shcherbakovite associated with CafetiteCaTi2O5 · H2O
1 photo of Shcherbakovite associated with TitaniteCaTiO(SiO4)

Related Minerals - Strunz-mindat GroupingHide

9.DH.DevilliersiteCa4Ca2Fe3+10O4[(Fe3+10Si2)O36]Tric. 1 : P1
9.DH.'Gageite-2M'(Mn,Mg,Zn)42Si16O54(OH)40Mon. 2/m
9.DH.BavsiiteBa2V2O2[Si4O12]Tet. 4/m : I4/m
9.DH.YuzuxiangiteSr3Fe3+(Si2O6)2(OH) · 3H2OMon. 2/m : P21/m
9.DH.LouisfuchsiteCa2(Mg4Ti2)(Al4Si2)O20Tric. 1 : P1
9.DH.05LeucophaniteNaCaBeSi2O6FOrth. 222 : P212121
9.DH.10OhmiliteSr3(Ti,Fe3+)(Si4O12)(O,OH) · 2-3H2OMon. 2/m : P21/m
9.DH.15HaradaiteSrVSi2O7Orth. mmm(2/m2/m2/m)
9.DH.15SuzukiiteBaVSi2O7Orth.
9.DH.20BatisiteBaNaNaTi2(Si4O12)O2Orth. mmm(2/m2/m2/m) : Imma
9.DH.20NoonkanbahiteBaKNaTi2(Si4O12)O2Orth. mmm(2/m2/m2/m) : Imma
9.DH.25TaikaniteSr3BaMn2+2(Si4O12)O2Mon. 2 : B2
9.DH.30KrauskopfiteBaSi2O5 · 3H2OMon. 2/m : P21/b
9.DH.35GageiteMn21(Si4O12)2O3(OH)20Mon. 2/m
9.DH.35Balangeroite(Mg,Fe2+,Fe3+,Mn2+)42Si16O54(OH)40Mon. 2/m
9.DH.40KuratiteCa2(Fe2+5Ti)O2[Si4Al2O18]Tric. 1 : P1
9.DH.40AenigmatiteNa4[Fe2+10Ti2]O4[Si12O36]Tric. 1 : P1
9.DH.40DorriteCa4(Mg3Fe3+9)O4(Si3Al8Fe3+O36)Tric.
9.DH.40SerendibiteCa4[Mg6Al6]O4[Si6B3Al3O36]Tric. 1 : P1
9.DH.40RhöniteCa4[Mg8Fe3+2Ti2]O4[Si6Al6O36]Tric. 1 : P1
9.DH.40KhesiniteCa4(Mg3Fe3+9)O4(Fe3+9Si3)O36Tric. 1 : P1
9.DH.40'UM1991-29-SiO:FeMgNa'Na4(Mg5Fe3+7)O4[Si9Fe3+3O36]
9.DH.40HøgtuvaiteCa4[Fe2+6Fe3+6]O4[Si8Be2Al2O36]Tric. 1 : P1
9.DH.40'Leucorhönite'Ca2(Mg,Fe3+,Al)6(Si,Al)6O20Tric.
9.DH.40WelshiteCa4Mg9Sb3O4[Si6Be3AlFe2O36]Tric. 1 : P1
9.DH.40WilkinsoniteNa2Fe2+4Fe3+2(Si6O18)O2Tric. 1 : P1
9.DH.40KrinoviteNa2Mg4Cr3+2(Si6O18)O2Tric. 1 : P1
9.DH.40Makarochkinite(Ca,Na)4[Fe2+8Fe3+2Ti2]O4[Si8Be2Al2O36]Tric. 1 : P1
9.DH.45SapphirineMg4(Mg3Al9)O4[Si3Al9O36]Mon. 2/m : P21/b
9.DH.50Khmaralite(Mg,Al,Fe)16[(Al,Si,Be)12O36]O4Mon. 2/m : P21/b
9.DH.55'UM1988-26-SiO:AlMg'Mg4Al2O[Si3Al2O15]
9.DH.55Surinamite(Mg,Fe)3Al4BeSi3O16Mon. 2/m
9.DH.60DeeriteFe2+6Fe3+3(Si6O17)O3(OH)5Mon. 2/m : P21/b
9.DH.65Taneyamalite(Na,Ca)Mn2+12(Si,Al)12(O,OH)44Tric.
9.DH.65HowieiteNa(Fe2+,Fe3+,Al,Mg)12(Si6O17)2(O,OH)10Tric. 1 : P1
9.DH.70JohninnesiteNa2Mn2+9Mg7(OH)8[AsO4]2[Si6O17]2Tric.
9.DH.75AgrelliteNaCa2Si4O10FTric. 1 : P1

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 14.6640% 4,546 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Notes:
Insoluble in HNO3 and HCl, partly soluble in H2SO4 on heating.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ShcherbakoviteHide

References for ShcherbakoviteHide

Localities for ShcherbakoviteHide

Showing 28 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Derby-West Kimberley Shire
      • Noonkanbah Station
Mineralogical Magazine 1984 48 : 263-266 +2 other references
Canada
 
  • Nunavut
    • Qikiqtaaluk Region
      • Baffin Island
Hogarth (1997) +1 other reference
Russia
 
  • Murmansk Oblast
    • Carbonatite Stock in the vicinity of Tul'ilukht Bay
Mandarino (1997) +1 other reference
    • Eveslogchorr Mt
Men'shikov Yu.P. et al. (2003)
Arzamastsev et al. (2008)
    • Kandalakshsky District
Akimenko et al. (2014)
Pekov (1998)
    • Koashva Mt
Arzamastsev et al. (2008)
Arzamastsev et al. (2008)
[World of Stones 95:5-6 +2 other references
    • Kovdorsky District
      • Kovdor Massif
Moiseev et al. (2007)
Pekov (1998) +1 other reference
Pekov (1998)
Arzamastseva et al. (1999) +1 other reference
Am Min 79:1011 +1 other reference
      • Rasvumchorr Mine
World of Stones 95: 5-6 +2 other references
Pekov I.V. et al. (2010) +1 other reference
Pekov (1998)
Pavel M. Kartashov (n.d.) +2 other references
Khomyakov et al. (1983) +1 other reference
[World of Stones 12:49]
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
Dill et al. (2023)
        • Santiago del Teide
Dill et al. (2023)
USA
 
  • Montana
    • Chouteau County
      • Highwood Mountains
Kuehner et al. (2003, June)
  • Wyoming
    • Sweetwater County
Hausel et al. (2001)
Mitchell et al. (1991)
Mitchell (1990)
Mitchell (1990)
 
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