Segelerite
A valid IMA mineral species
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About Segelerite
Formula:
Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O
Colour:
Green, chartreuse, colorless, pale yellow
Lustre:
Vitreous
Hardness:
4
Specific Gravity:
2.67
Crystal System:
Orthorhombic
Member of:
Name:
Named for Curt G. Segeler (1901-1989), combustion atmosphere engineer for the America Gas Association. Curt invented the Degree Day rule of thumb used to estimate energy consumption for home heating. He was also an important amateur mineralogist, Brooklyn, New York, who specialized in phosphate minerals.
This page provides mineralogical data about Segelerite.
Unique Identifiers
Mindat ID:
3605
Long-form identifier:
mindat:1:1:3605:0
IMA Classification of Segelerite
Approved
IMA Formula:
CaMgFe3+(PO4)2(OH)·4H2O
Approval year:
1973
First published:
1974
Type description reference:
Classification of Segelerite
8.DH.20
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
42.11.1.2
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.14.21
19 : Phosphates
14 : Phosphates of Fe and other metals
19 : Phosphates
14 : Phosphates of Fe and other metals
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Sgl | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Segelerite
Vitreous
Transparency:
Transparent, Translucent
Colour:
Green, chartreuse, colorless, pale yellow
Streak:
White
Hardness:
4 on Mohs scale
Hardness Data:
Measured
Cleavage:
Perfect
Perfect on the {010}
Perfect on the {010}
Density:
2.67 g/cm3 (Measured) 2.610 g/cm3 (Calculated)
Optical Data of Segelerite
Type:
Biaxial (-)
RI values:
nα = 1.618 nβ = 1.635 nγ = 1.65
2V:
Measured: 45° to 70°, Calculated: 84°
Max. Birefringence:
δ = 0.032
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
Surface Relief:
Moderate
Dispersion:
r > v
Pleochroism:
Visible
Comments:
X = Y = colorless; Z = yellow.
Comments:
Orientation: X = b; Y = a; Z = c.
Absorption: Z > X = Y.
Absorption: Z > X = Y.
Chemistry of Segelerite
Mindat Formula:
Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O
Element Weights:
Crystallography of Segelerite
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pcca
Cell Parameters:
a = 14.826(5) Å, b = 18.751(4) Å, c = 7.307(1) Å
Ratio:
a:b:c = 0.791 : 1 : 0.39
Unit Cell V:
2,031.36 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Type material:
Long prismatic, striated parallel to the prism which is [001]. Nearly square outline, with lustrous {100}, {010}, {11O} and {121}.
Long prismatic, striated parallel to the prism which is [001]. Nearly square outline, with lustrous {100}, {010}, {11O} and {121}.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0000583 | Segelerite | Moore P B, Araki T (1977) Overite, segelerite, and jahnsite: a study in combinatorial polymorphism American Mineralogist 62 692-702 | ![]() | 1977 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.868 Å | (100) |
| 9.31 Å | (90) |
| 5.34 Å | (60) |
| 3.729 Å | (50) |
| 3.421 Å | (50) |
| 4.97 Å | (40) |
| 4.65 Å | (40) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] |
Geological Setting:
National Museum of Natural History (Smithsonian), Washington, D.C., USA, 127154.
Type Occurrence of Segelerite
General Appearance of Type Material:
Striated prisms along joint fractures in dense ferrisicklerite-rockbridgeite. Crystals to 0.5 mm in length.
Geological Setting of Type Material:
Complex zoned pegmatite. Alteration of triphylite.
Associated Minerals at Type Locality:
Synonyms of Segelerite
Other Language Names for Segelerite
Relationship of Segelerite to other Species
Member of:
Other Members of Overite Group:
| Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O | Orth. mmm(2/m2/m2/m) : Pbca |
| Overite | CaMgAl(PO4)2(OH) · 4H2O | Orth. mmm(2/m2/m2/m) : Pbca |
| Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O | Orth. mmm(2/m2/m2/m) : Pbca |
Common Associates
Associations Based on Photo Data:
| 4 photos of Segelerite associated with Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
| 3 photos of Segelerite associated with Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
| 1 photo of Segelerite associated with Natrojarosite | NaFe3(SO4)2(OH)6 |
| 1 photo of Segelerite associated with Jahnsite Subgroup | XM1M22M32(H2O)8(OH)2(PO4)4 |
| 1 photo of Segelerite associated with Montgomeryite | Ca4MgAl4(PO4)6(OH)4 · 12H2O |
| 1 photo of Segelerite associated with Heterosite | Fe3+(PO4) |
Related Minerals - Strunz-mindat Grouping
| 8.DH. | Thebaite-(NH4) | (NH4)3Al(C2O4)(PO3OH)2(H2O) |
| 8.DH. | Whiteite-(MnMnMn) | Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH. | Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) · 2H2O |
| 8.DH. | Bergbauerite | (H2O)2Mn2(Fe2Ti)(PO4)4(OH)2(H2O)10 · 4H2O |
| 8.DH. | Dendoraite-(NH4) | (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 |
| 8.DH. | Rowleyite | [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl] |
| 8.DH. | Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 · 14H2O |
| 8.DH. | Whiteite-(CaMnFe) | CaMnFe2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.05 | Minyulite | KAl2(PO4)2F · 4H2O |
| 8.DH.10 | Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
| 8.DH.10 | Tinsleyite | KAl2(PO4)2(OH) · 2H2O |
| 8.DH.10 | Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O |
| 8.DH.15 | Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(NaMnMn) | {Na}{Mn2+}{(Mn2+,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMnMg) | {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(MnMnMg) | MnMnMg2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMnZn) | {Ca}{Mn2+}{Zn2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnMg) | {Mn2+}{Mn2+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnFe) | {Mn2+}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | 'Jahnsite-(CaFeFe)' | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Rittmannite | {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O |
| 8.DH.15 | Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | 'Jahnsite-(CaMgMg)' | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnZn) | {Mn2+}{Mn2+}{Zn2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMgMg) | CaMg3Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaFeMg) | {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMnMg) | {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(MnFeMg) | {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | 'Kaluginite' | (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O |
| 8.DH.15 | Jahnsite-(CaFeMg) | {Ca}{Fe2+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMnMn) | {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(NaFeMg) | {Na}{Fe3+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.20 | Lun'okite | (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O |
| 8.DH.20 | Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O |
| 8.DH.20 | Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O |
| 8.DH.20 | Juonniite | CaMgSc(PO4)2(OH) · 4H2O |
| 8.DH.20 | Overite | CaMgAl(PO4)2(OH) · 4H2O |
| 8.DH.25 | Calcioferrite | Ca4MgFe3+4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Zodacite | Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Fanfaniite | Ca4Mn2+Al4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Kingsmountite | Ca3Mn2+FeAl4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Montgomeryite | Ca4MgAl4(PO4)6(OH)4 · 12H2O |
| 8.DH.30 | Pararobertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Arseniosiderite | Ca2Fe3+3(AsO4)3O2 · 3H2O |
| 8.DH.30 | Sailaufite | (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O |
| 8.DH.30 | Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Kolfanite | Ca2Fe3+3O2(AsO4)3 · 2H2O |
| 8.DH.35 | Mantienneite | KMg2Al2Ti(PO4)4(OH)3 · 15H2O |
| 8.DH.35 | Sperlingite | (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)] [(H2O)9(OH)] · 4H2O |
| 8.DH.35 | Paulkerrite | K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O |
| 8.DH.35 | Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O |
| 8.DH.35 | Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O |
| 8.DH.35 | Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O |
| 8.DH.35 | Fluormacraeite | [(H2O)K]Mn2(Fe2Ti)(PO4)4(OF)(H2O)10 · 4H2O |
| 8.DH.40 | Xanthoxenite | Ca4Fe3+2(PO4)4(OH)2 · 3H2O |
| 8.DH.45 | Mahnertite | NaCu3(AsO4)2Cl · 5H2O |
| 8.DH.50 | Andyrobertsite | KCdCu5(AsO4)4(H2AsO4) · 2H2O |
| 8.DH.50 | Calcioandyrobertsite | KCaCu5(AsO4)4(H2AsO4) · 2H2O |
| 8.DH.55 | Englishite | K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O |
| 8.DH.60 | Bouazzerite | Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O |
| 8.DH.65 | Galliskiite | Ca4Al2(PO4)2F8 · 5H2O |
| 8.DH.70 | Joteite | Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O |
| 8.DH.75 | Kampelite | Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O |
| 8.DH.80 | Kapundaite | NaCaFe4(PO4)4(OH)3 · 5H2O |
| 8.DH.85 | Vaniniite | Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O |
Other Information
Notes:
Soluble in dilute HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Segelerite
mindat.org URL:
https://www.mindat.org/min-3605.html
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References for Segelerite
Reference List:
Moore, Paul Brian, Ito, J. (1974) I. Jahnsite, segelerite, and robertsite, three new transition metal phosphate species. II. Redefinition of overite, an isotype of segelerite. III. Isotypy of robertsite, mitridatite, and arseniosiderite. American Mineralogist, 59 (1-2) 48-59
Localities for Segelerite
Showing 4 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| Mineralogical Magazine 39 (1974) |
Portugal | |
| Rend. Soc. It. Min. Petr. |
| Rewitzer et al. (1984) |
USA (TL) | |
| Moore et al. (1974) |
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The
Tip Top Mine, Fourmile, Custer Mining District, Custer County, South Dakota, USA