Montgomeryite
A valid IMA mineral species - grandfathered
This page kindly sponsored by Zach Berghorst
About Montgomeryite
Formula:
Ca4MgAl4(PO4)6(OH)4 · 12H2O
Colour:
Dark green to light green, colourless, red, yellow
Lustre:
Vitreous
Hardness:
4
Specific Gravity:
2.53
Crystal System:
Monoclinic
Member of:
Name:
After Arthur Montgomery (2 December 1909, New York City, New York, USA - 31 December 1999, Albuquerque, New Mexico, USA), American mineralogist, Professor of Geology, Lafayette College, Easton, Pennsylvania, USA, who collected the first specimens.
Isostructural with:
The Mg analogue of kingsmountite and fanfaniite.
A secondary mineral in sedimentary phosphate nodules and as a late-stage mineral in highly oxidized phosphate nodules in granitic pegmatite.
A secondary mineral in sedimentary phosphate nodules and as a late-stage mineral in highly oxidized phosphate nodules in granitic pegmatite.
Unique Identifiers
Mindat ID:
2767
Long-form identifier:
mindat:1:1:2767:6
IMA Classification of Montgomeryite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca4MgAl4(PO4)6(OH)4·12H2O
Classification of Montgomeryite
8.DH.25
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
42.11.8.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.8.12
19 : Phosphates
8 : Phosphates of Al and other metals
19 : Phosphates
8 : Phosphates of Al and other metals
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Mgm | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Montgomeryite
Vitreous
Transparency:
Transparent, Translucent
Colour:
Dark green to light green, colourless, red, yellow
Comment:
Coloration may be zoned.
Hardness:
4 on Mohs scale
Cleavage:
Perfect
On {010}, perfect; on {100}, poor.
On {010}, perfect; on {100}, poor.
Density:
2.53 g/cm3 (Measured) 2.523 g/cm3 (Calculated)
Optical Data of Montgomeryite
Type:
Biaxial (-)
RI values:
nα = 1.572 nβ = 1.578 nγ = 1.582
2V:
Measured: 75° , Calculated: 78°
Max. Birefringence:
δ = 0.010
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v strong
Pleochroism:
Weak
Comments:
X = Colourless to pale green
Y = Z = Colourless
also, may exhibit:
X = Light orange-brown
Y = Pale magenta-pink
Z = Light orange-brown
Y = Z = Colourless
also, may exhibit:
X = Light orange-brown
Y = Pale magenta-pink
Z = Light orange-brown
Chemistry of Montgomeryite
Mindat Formula:
Ca4MgAl4(PO4)6(OH)4 · 12H2O
Element Weights:
Crystallography of Montgomeryite
Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
B2
Cell Parameters:
a = 10.02 Å, b = 24.12 Å, c = 6.24 Å
β = 91.55°
β = 91.55°
Ratio:
a:b:c = 0.415 : 1 : 0.259
Unit Cell V:
1,507.55 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals lathlike, flattened on {010} and elongated and striated along [001]; terminated by pyramids. {010} dominant, with many {hk0} vicinal prism forms. Commonly occur in subparallel growths in contact on {010}. Massive; as subparallel aggregates of coarse plates.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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View
CIF File Best | x | y | z | a | b | c
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Rotation
Stop | Start
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Labels
Console Off | On | Grey | Yellow
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0000486 | Montgomeryite | Fanfani L, Nunzi A, Zanazzi P F, Zanzari A R (1976) Additional data on the crystal structure of montgomeryite American Mineralogist 61 12-14 | ![]() | 1976 | 0 | 293 | |
| 0000410 | Montgomeryite | Moore P B, Araki T (1974) Montgomeryite, Ca4Mg(H2O)12[Al4(OH)4(PO4)6]:. Its crystal structure and relation to Vauxite, Fe2(H2O)4[Al4(OH)4(H2O)4(PO4)4].4H2O American Mineralogist 59 843-850 | ![]() | 1974 | 0 | 293 |
CIF Raw Data - click here to close
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 21 : Chemically precipitated carbonate, phosphate, iron formations |
Geological Setting:
Granitic pegmatites
Type Occurrence of Montgomeryite
Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, USA: #95481.
Geological Setting of Type Material:
Phosphate nodules in sedmimentary rocks.
Associated Minerals at Type Locality:
Other Language Names for Montgomeryite
Relationship of Montgomeryite to other Species
Member of:
Other Members of Montgomeryite Subgroup:
| Fanfaniite | Ca4Mn2+Al4(PO4)6(OH)4 · 12H2O | Mon. 2/m : B2/b |
| Kingsmountite | Ca3Mn2+FeAl4(PO4)6(OH)4 · 12H2O | Tric. 1 : P1 |
Common Associates
Associations Based on Photo Data:
| 51 photos of Montgomeryite associated with Whitlockite | Ca9Mg(PO4)6(PO3OH) |
| 44 photos of Montgomeryite associated with Variscite | AlPO4 · 2H2O |
| 42 photos of Montgomeryite associated with Englishite | K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O |
| 40 photos of Montgomeryite associated with Roscherite | Ca2Mn2+5Be4(PO4)6(OH)4 · 6H2O |
| 38 photos of Montgomeryite associated with Tiptopite | K2(Na,Ca)2Li3Be6(PO4)6(OH)2 · H2O |
| 35 photos of Montgomeryite associated with Wardite | NaAl3(PO4)2(OH)4 · 2H2O |
| 35 photos of Montgomeryite associated with Crandallite | CaAl3(PO4)(PO3OH)(OH)6 |
| 30 photos of Montgomeryite associated with Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
| 18 photos of Montgomeryite associated with Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O |
| 15 photos of Montgomeryite associated with Fairfieldite | Ca2Mn2+(PO4)2 · 2H2O |
Related Minerals - Strunz-mindat Grouping
| 8.DH. | Thebaite-(NH4) | (NH4)3Al(C2O4)(PO3OH)2(H2O) |
| 8.DH. | Whiteite-(MnMnMn) | Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH. | Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) · 2H2O |
| 8.DH. | Bergbauerite | (H2O)2Mn2(Fe2Ti)(PO4)4(OH)2(H2O)10 · 4H2O |
| 8.DH. | Dendoraite-(NH4) | (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 |
| 8.DH. | Rowleyite | [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl] |
| 8.DH. | Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 · 14H2O |
| 8.DH. | Whiteite-(CaMnFe) | CaMnFe2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.05 | Minyulite | KAl2(PO4)2F · 4H2O |
| 8.DH.10 | Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
| 8.DH.10 | Tinsleyite | KAl2(PO4)2(OH) · 2H2O |
| 8.DH.10 | Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O |
| 8.DH.15 | Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(NaMnMn) | {Na}{Mn2+}{(Mn2+,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMnMg) | {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(MnMnMg) | MnMnMg2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMnZn) | {Ca}{Mn2+}{Zn2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnMg) | {Mn2+}{Mn2+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnFe) | {Mn2+}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | 'Jahnsite-(CaFeFe)' | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Rittmannite | {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O |
| 8.DH.15 | Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | 'Jahnsite-(CaMgMg)' | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnZn) | {Mn2+}{Mn2+}{Zn2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMgMg) | CaMg3Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaFeMg) | {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMnMg) | {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(MnFeMg) | {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | 'Kaluginite' | (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O |
| 8.DH.15 | Jahnsite-(CaFeMg) | {Ca}{Fe2+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMnMn) | {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(NaFeMg) | {Na}{Fe3+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.20 | Segelerite | Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O |
| 8.DH.20 | Lun'okite | (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O |
| 8.DH.20 | Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O |
| 8.DH.20 | Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O |
| 8.DH.20 | Juonniite | CaMgSc(PO4)2(OH) · 4H2O |
| 8.DH.20 | Overite | CaMgAl(PO4)2(OH) · 4H2O |
| 8.DH.25 | Calcioferrite | Ca4MgFe3+4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Zodacite | Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Fanfaniite | Ca4Mn2+Al4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Kingsmountite | Ca3Mn2+FeAl4(PO4)6(OH)4 · 12H2O |
| 8.DH.30 | Pararobertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Arseniosiderite | Ca2Fe3+3(AsO4)3O2 · 3H2O |
| 8.DH.30 | Sailaufite | (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O |
| 8.DH.30 | Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Kolfanite | Ca2Fe3+3O2(AsO4)3 · 2H2O |
| 8.DH.35 | Mantienneite | KMg2Al2Ti(PO4)4(OH)3 · 15H2O |
| 8.DH.35 | Sperlingite | (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)] [(H2O)9(OH)] · 4H2O |
| 8.DH.35 | Paulkerrite | K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O |
| 8.DH.35 | Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O |
| 8.DH.35 | Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O |
| 8.DH.35 | Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O |
| 8.DH.35 | Fluormacraeite | [(H2O)K]Mn2(Fe2Ti)(PO4)4(OF)(H2O)10 · 4H2O |
| 8.DH.40 | Xanthoxenite | Ca4Fe3+2(PO4)4(OH)2 · 3H2O |
| 8.DH.45 | Mahnertite | NaCu3(AsO4)2Cl · 5H2O |
| 8.DH.50 | Andyrobertsite | KCdCu5(AsO4)4(H2AsO4) · 2H2O |
| 8.DH.50 | Calcioandyrobertsite | KCaCu5(AsO4)4(H2AsO4) · 2H2O |
| 8.DH.55 | Englishite | K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O |
| 8.DH.60 | Bouazzerite | Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O |
| 8.DH.65 | Galliskiite | Ca4Al2(PO4)2F8 · 5H2O |
| 8.DH.70 | Joteite | Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O |
| 8.DH.75 | Kampelite | Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O |
| 8.DH.80 | Kapundaite | NaCaFe4(PO4)4(OH)3 · 5H2O |
| 8.DH.85 | Vaniniite | Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Montgomeryite
mindat.org URL:
https://www.mindat.org/min-2767.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
Mineral Dealers:
References for Montgomeryite
Reference List:
Larsen, Esper S. 3rd (1940) Overite and montgomeryite: two new minerals from Fairfield, Utah. American Mineralogist, 25 (5). p.315-326.
Moore, Paul Brian, Araki, Takaharu (1974) Montgomeryite, Ca4Mg(H2O)12[Al4(OH)4(PO4)6]: Its crystal structure and relation to vauxite, Fe2+2(H2O)4[Al4(OH)4(H2O)4(PO4)4]·4H2O. American Mineralogist, 59 (7-8) 843-850
Localities for Montgomeryite
Showing 61 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| Trueman (1965) | |
| Podgson RE +1 other reference |
| |
| Pilkington et al. (1979) |
| Birch et al. (1993) |
| Mineralogical Magazine 39 (1974) +1 other reference |
| Nickel (2008) |
Austria | |
| Walter et al. (1998) |
Brazil | |
| Cassedanne et al. (1973) |
Cape Verde | |
| Figueiredo +3 other references |
France | |
| Karkanas et al. (2002) |
| Lacroix (1910) |
| Quattropani et al. (1999) +1 other reference | |
Germany | |
| Weiß (1990) |
| Wittern (2001) |
| Liesegang et al. (2022) |
| SEM-EDS and Raman Spectroscopy by Joy ... |
Israel | |
| Goldberg et al. (1975) |
| Weiner et al. (1993) | |
Italy | |
| Orlandi (2011) |
| Vattano M. et al. (2013) +1 other reference |
Kazakhstan | |
| Bernard et al. (2004) |
Mexico | |
| Forti (2006) |
Morocco | |
| Fransolet et al. (1987) |
| Favreau (2012) |
Namibia | |
| von Bezing (2007) |
| Keller (1985) | |
Portugal | |
| Schnorrer-Köhler (1991) |
| |
South Africa | |
| Martini et al. (1978) |
| Martini et al. (1978) |
| Miller et al. (2013) |
Spain | |
| Christian Rewitzer collection |
| Camprubí et al. (4) |
| Melgarejo et al. (1988) | |
| Joan Rosell. RosellMinerals | |
| Bareche (2005) | |
| Díaz-Acha et al. (2022) | |
| Mineralogistes de Catalunya (1997) |
| Calvo Rebollar (2015) |
Sweden | |
| Lorin (2022) |
Thailand | |
| Lenoble et al. (2006, September) |
USA | |
| Castor et al. (2004) |
| Collected by Dick Thomssen. |
| Silver Coin Mine. Compact Disc. Paul ... |
| Rocks & Minerals. Nov. 1999. +2 other references |
| Newmont Mining Corporation | |
| Min News (1999) | |
| Kampf et al. (2016) |
| Collected by Paul Adams. EDS and XRD ... |
| Castor et al. (2004) |
| Castor et al. (2004) |
| Czaja (2025) |
| Rocks & Minerals: 60: 117. +1 other reference |
| Smith et al. (2000) |
| Loomis (2011) |
| Rocks & Minerals: 57: 160 &/or 60: 110 ... |
| Don Howard (1999) |
| Palache et al. (1951) +1 other reference |
| Wilson (2010) |
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Tip Top Mine, Fourmile, Custer Mining District, Custer County, South Dakota, USA