Johnsomervilleite
A valid IMA mineral species
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About Johnsomervilleite
Formula:
Na3CaFe11(PO4)9
Originally given, i.a., as
{Ca}{Na6◻2}{Ca6Na2}{(Fe2+,Mg,Mn2+)43}(PO4)36; the above IMA formula is wrong
{Ca}{Na6◻2}{Ca6Na2}{(Fe2+,Mg,Mn2+)43}(PO4)36; the above IMA formula is wrong
Colour:
Dark brown to blackish gray, pitch-black
Lustre:
Sub-Vitreous, Resinous
Hardness:
4½
Specific Gravity:
3.35
Crystal System:
Trigonal
Member of:
Name:
Named in 1980 by A. Livingstone in memory of Mr John M. Somerville (1908-1978) who presented to the Royal Scottish Museum a specimen of garnet-quartz rock, which contained the new species.
Type Locality:
Unique Identifiers
Mindat ID:
2107
Long-form identifier:
mindat:1:1:2107:0
IMA Classification of Johnsomervilleite
Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
Na3CaFe2+11(PO4)9
Approval year:
1979
First published:
1980
Approval history:
Formula redefinition: https://www.eur-j-mineral.net/32/275/2020/
Classification of Johnsomervilleite
8.AC.50
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th ed.:
38.2.9.2
38.2.5.2
38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
19.12.31
19 : Phosphates
12 : Phosphates of Mn
19 : Phosphates
12 : Phosphates of Mn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Jsv | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Jsv | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Johnsomervilleite
Sub-Vitreous, Resinous
Transparency:
Translucent
Colour:
Dark brown to blackish gray, pitch-black
Streak:
Light brown; gray-brown with an olive tint
Hardness:
4½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
Probably {0001}
Probably {0001}
Fracture:
Splintery, Sub-Conchoidal
Density:
3.35 g/cm3 (Measured) 3.41 g/cm3 (Calculated)
Optical Data of Johnsomervilleite
Type:
Uniaxial (+/-)
RI values:
nα = 1.655 nβ = 1.655
2V:
Measured: 10°
Surface Relief:
Moderate
Comments:
Anomalously biaxial: α = 1.655 β = ∼1.655 γ = n.d. 2V(meas.) = 10◦
n = 1.646(1) (metamict)
n = 1.646(1) (metamict)
Chemistry of Johnsomervilleite
Mindat Formula:
Na3CaFe11(PO4)9
Originally given, i.a., as
{Ca}{Na6◻2}{Ca6Na2}{(Fe2+,Mg,Mn2+)43}(PO4)36; the above IMA formula is wrong
Originally given, i.a., as
{Ca}{Na6◻2}{Ca6Na2}{(Fe2+,Mg,Mn2+)43}(PO4)36; the above IMA formula is wrong
Element Weights:
Crystallography of Johnsomervilleite
Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 15.00 Å, c = 42.75 Å
Ratio:
a:c = 1 : 2.85
Unit Cell V:
8,330.08 ų (Calculated from Unit Cell)
Z:
18
Morphology:
Anhedral grains
Comment:
may be metamict
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 2.764 Å | (100) |
| 3.70 Å | (70) |
| 3.55 Å | (70) |
| 2.965 Å | (70) |
| 11.20 Å | (50) |
| 2.501 Å | (40) |
| 1.852 Å | (20) |
Comments:
Loch Quoich, Scotland, UK. The data are from the type description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 2: Planetesimal differentiation and alteration | 4.566-4.550 |
| 5 : Primary asteroid phases | 4.566–4.560 |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites | |
| Stage 5: Initiation of plate tectonics | <3.5-2.5 |
| 40 : Regional metamorphism (greenschist, amphibolite, granulite facies) |
Geological Setting:
Granite pegmatite
Type Occurrence of Johnsomervilleite
General Appearance of Type Material:
Gray to pink greasy grains up to 4 mm in size.
Place of Conservation of Type Material:
Scottish Mineral Collection of the Royal Scottish Museum, Edinburgh.
Geological Setting of Type Material:
Granite pegmatite pods in kyanite-sillimanite gneiss.
Associated Minerals at Type Locality:
Synonyms of Johnsomervilleite
Other Language Names for Johnsomervilleite
Relationship of Johnsomervilleite to other Species
Member of:
Other Members of Fillowite Group:
| Chladniite | Na3CaMg11(PO4)9 | Trig. 3 : R3 |
| Fillowite | Na3CaMn2+11(PO4)9 | Trig. 3 : R3 |
| Galileiite | Na3Fe2+Fe2+11(PO4)9 | Trig. 3 : R3 |
Common Associates
Associations Based on Photo Data:
| 5 photos of Johnsomervilleite associated with Barićite | (Mg,Fe)3(PO4)2 · 8H2O |
| 4 photos of Johnsomervilleite associated with Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 3 photos of Johnsomervilleite associated with Phosphosiderite | FePO4 · 2H2O |
| 3 photos of Johnsomervilleite associated with Vivianite | Fe2+Fe2+2(PO4)2 · 8H2O |
| 1 photo of Johnsomervilleite associated with Fluorapatite | Ca5(PO4)3F |
| 1 photo of Johnsomervilleite associated with Muscovite | KAl2(AlSi3O10)(OH)2 |
Related Minerals - Strunz-mindat Grouping
| 8.AC. | 'Crocobelonite-1M' | CaFe3+2O(PO4)2 |
| 8.AC. | Magnesioqingheiite | Na2Mg(MgAl)(PO4)3 |
| 8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 |
| 8.AC. | Changesite-(Y) | (Ca8Y)◻Fe2+(PO4)7 |
| 8.AC. | Babunaite-(Nd) | NdAsO4 |
| 8.AC. | Crocobelonite | CaFe3+2O(PO4)2 |
| 8.AC. | Wopmayite | Ca6Na3◻Mn(PO4)3(PO3OH)4 |
| 8.AC. | Beershevaite | CaFe3+3(PO4)3O |
| 8.AC. | Epiebnerite | (NH4)Zn(PO4) |
| 8.AC. | Ebnerite | (NH4)Zn(PO4) |
| 8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 |
| 8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 |
| 8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O |
| 8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 |
| 8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 |
| 8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 |
| 8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 |
| 8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 |
| 8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 |
| 8.AC.02 | Ziminaite | Fe3+ 6 (VO4)6 |
| 8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 |
| 8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O |
| 8.AC.05 | 'Unnamed (Na-Mg Arsenate Hydroxyarsenate)' | NaMg3(AsO4)(AsO3OH)2 |
| 8.AC.05 | 'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)' | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 |
| 8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 |
| 8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 |
| 8.AC.05 va | 'Alluaudite-Na[]' | ◻4Na4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | 'Alluaudite-Ca[]' | ◻4Ca4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | 'Ferroalluaudite-NaNa' | Na4Na4Fe2+4Fe3+8(PO4)12 |
| 8.AC.05 | 'Hagendorfite-NaNa' | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) |
| 8.AC.05 | O'Danielite | Na(Zn,Mg)3(AsO4)(AsO3OH)2 |
| 8.AC.05 | Howardevansite | NaCuFe2(VO4)3 |
| 8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 |
| 8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 |
| 8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 |
| 8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 |
| 8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] |
| 8.AC.05 | Manganohatertite | NaNaCa(MnFe3+)(AsO4)3 |
| 8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 |
| 8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 |
| 8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 |
| 8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 |
| 8.AC.10 | 'Ferrohagendorfite' | NaCaFe2+Fe2+2(PO4)3 |
| 8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 |
| 8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 |
| 8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 |
| 8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 |
| 8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 |
| 8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 |
| 8.AC.10 | Bradaczekite | NaCu4(AsO4)3 |
| 8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 |
| 8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 |
| 8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 |
| 8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 |
| 8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 |
| 8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 |
| 8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 |
| 8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 |
| 8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 |
| 8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 |
| 8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 |
| 8.AC.18 | Manitobaite | Na16Mn2+ 25Al8(PO4)30 |
| 8.AC.20 | Marićite | NaFe2+(PO4) |
| 8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 |
| 8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 |
| 8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 |
| 8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) |
| 8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 |
| 8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 |
| 8.AC.30 | Brianite | Na2CaMg(PO4)2 |
| 8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 |
| 8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · |
| 8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 |
| 8.AC.45 | Magnesiochangesite-(Ce) | (Ca8Ce)◻Mg(PO4)7 |
| 8.AC.45 | Tuite | Ca3(PO4)2 |
| 8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 |
| 8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) |
| 8.AC.45 | Magnesiochangesite-(Y) | (Ca8Y)◻ Mg(PO4)7 |
| 8.AC.45 | Changesite-(Ce) | (Ca8Ce)◻Fe2+(PO4)7 |
| 8.AC.45 | Merrillite | Ca9NaMg(PO4)7 |
| 8.AC.45 | Whitlockite | Ca9Mg(PO4)6(PO3OH) |
| 8.AC.47 | Iwateite | Na2BaMn(PO4)2 |
| 8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 |
| 8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 |
| 8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 |
| 8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 |
| 8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 |
| 8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 |
| 8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 |
| 8.AC.50 | Udinaite | NaMg4(VO4)3 |
| 8.AC.50 | Arsenudinaite | NaMg4(AsO4)3 |
| 8.AC.50 | Chladniite | Na3CaMg11(PO4)9 |
| 8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 |
| 8.AC.55 | Pharmazincite | KZnAsO4 |
| 8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 |
| 8.AC.60 | Kosnarite | KZr2(PO4)3 |
| 8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 |
| 8.AC.70 | Stanfieldite | Ca4Mg5(PO4)6 |
| 8.AC.75 | Ronneburgite | K2MnV4O12 |
| 8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] |
| 8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 |
Fluorescence of Johnsomervilleite
Not fluorescent with LW or SW UV.
Other Information
Notes:
Soluble in 20% HCl, H2SO4, and HNO3.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Johnsomervilleite
mindat.org URL:
https://www.mindat.org/min-2107.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
Mineral Dealers:
References for Johnsomervilleite
Reference List:
Livingstone, A. (1980) Johnsomervilleite, a new transition-metal phosphate mineral from the Loch Quoich area, Scotland. Mineralogical Magazine, 43 (331) 833-836 doi:10.1180/minmag.1980.043.331.01
Nickel, Ernest H., Mandarino, Joseph A. (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature. American Mineralogist, 72 (9-10) 1031-1042
Hatert, Frédéric, Grew, Edward S., Vignola, Pietro, Rotiroti, Nicola, Nestola, Fabrizio, Keller, Paul, Baijot, Maxime, Bruni, Yannick, Fransolet, André-Mathieu, Dal Bo, Fabrice, Depret, Martin (2021) Crystal chemistry and nomenclature of fillowite-type phosphates. The Canadian Mineralogist, 59 (4) 781-796 doi:10.3749/canmin.2000043
Localities for Johnsomervilleite
Showing 13 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Abstracts of the Lunar and Planetary Science Conference et al. (1990) |
Brazil | |
| Cassedanne et al. (1999) |
Canada | |
| Černý et al. (1998) +1 other reference |
Finland | |
| Ilkka Mikkola collection |
Italy | |
| Vignola et al. (2010) |
Mexico | |
| Olsen +1 other reference |
Rwanda | |
| Fransolet et al. (1998) |
Spain | |
| Roda et al. (2001) |
| Roda et al. (2004) +1 other reference |
UK (TL) | |
| Livingstone (1980) +1 other reference |
Ukraine | |
| Lyzhachenko et al. (2019) |
USA | |
| Olsen +1 other reference |
| Olsen et al. (1993) |
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Sapucaia mine, Sapucaia do Norte, Galiléia, Minas Gerais, Brazil