Arsenudinaite
A valid IMA mineral species
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About Arsenudinaite
Formula:
NaMg4(AsO4)3
Colour:
beige, pale brownish, brownish-yellowish or greyish-brownish
Lustre:
Vitreous
Hardness:
3½
Specific Gravity:
3.816 (Calculated)
Crystal System:
Tetragonal
Name:
Named for being the arsenic analogue of udinaite.
Type Locality:
Isostructural with:
Known synthetic analogue. The As analogue of udinaite. First purely sodium-magnesium anhydrous arsenate mineral. Chemically somewhat related to badalovite, berzeliite, calciojohillerite, magnesiohatertite, and paraberzeliite. Compare also 'Unnamed (Na-Mg Arsenate Hydroxyarsenate)'.
Visually indistinguishable from udinite.
Visually indistinguishable from udinite.
Unique Identifiers
Mindat ID:
53170
Long-form identifier:
mindat:1:1:53170:0
IMA Classification of Arsenudinaite
Classification of Arsenudinaite
8.AC.50
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Audn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Arsenudinaite
Vitreous
Transparency:
Transparent
Colour:
Beige, pale brownish, brownish-yellowish or greyish-brownish
Streak:
White
Hardness:
3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
3.816 g/cm3 (Calculated)
Optical Data of Arsenudinaite
Type:
Uniaxial (-)
RI values:
nω = 1.777(10) nε = 1.820(6)
Max. Birefringence:
δ = 0.043
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Chemistry of Arsenudinaite
Mindat Formula:
NaMg4(AsO4)3
Element Weights:
Elements listed:
Crystallography of Arsenudinaite
Crystal System:
Tetragonal
Class (H-M):
42m - Scalenohedral
Space Group:
I42d
Cell Parameters:
a = 6.8022(2) Å, c = 19.1843(6) Å
Ratio:
a:c = 1 : 2.82
Unit Cell V:
887.66 ų (Calculated from Unit Cell)
Z:
4
Epitaxial Relationships of Arsenudinaite
Epitaxial Minerals:
| 'Anhydrite' | CaSO4 |
| 'Forsterite' | Mg2(SiO4) |
Epitaxy Comments:
Interesting double epitactic intergrowths were observed: “ribbed” parallel aggregates of small, flattened forsterite crystals epitactically overgrow a larger prismatic anhydrite crystal and crystals of udinaite or arsenudinaite epitactically overgrow forsterite
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.657 Å | (26) |
| 4.300 Å | (24) |
| 3.341 Å | (29) |
| 3.007 Å | (46) |
| 2.775 Å | (100) |
| 2.750 Å | (17) |
| 2.663 Å | (17) |
| 1.698 Å | (27) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 45a : [Sulfates, arsenates, selenates, antimonates] |
Type Occurrence of Arsenudinaite
General Appearance of Type Material:
Equant tetragonal prismatic–dipyramidal crystals up to 0.15 mm, aggregates up to 1 cm and interrupted crusts up to 2 × 2 cm2.
Place of Conservation of Type Material:
Collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5238/1
Geological Setting of Type Material:
The hottest zone of the Arsenatnaya fumarole. The temperatures in this area measured, using a chromel–alumel thermocouple,during collecting were 450–470 ◦C
Associated Minerals at Type Locality:
Synonyms of Arsenudinaite
Other Language Names for Arsenudinaite
Relationship of Arsenudinaite to other Species
Forms a series with:
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 8.AC. | 'Crocobelonite-1M' | CaFe3+2O(PO4)2 |
| 8.AC. | Magnesioqingheiite | Na2Mg(MgAl)(PO4)3 |
| 8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 |
| 8.AC. | Changesite-(Y) | (Ca8Y)◻Fe2+(PO4)7 |
| 8.AC. | Babunaite-(Nd) | NdAsO4 |
| 8.AC. | Crocobelonite | CaFe3+2O(PO4)2 |
| 8.AC. | Wopmayite | Ca6Na3◻Mn(PO4)3(PO3OH)4 |
| 8.AC. | Beershevaite | CaFe3+3(PO4)3O |
| 8.AC. | Epiebnerite | (NH4)Zn(PO4) |
| 8.AC. | Ebnerite | (NH4)Zn(PO4) |
| 8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 |
| 8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 |
| 8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O |
| 8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 |
| 8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 |
| 8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 |
| 8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 |
| 8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 |
| 8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 |
| 8.AC.02 | Ziminaite | Fe3+ 6 (VO4)6 |
| 8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 |
| 8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O |
| 8.AC.05 | 'Unnamed (Na-Mg Arsenate Hydroxyarsenate)' | NaMg3(AsO4)(AsO3OH)2 |
| 8.AC.05 | 'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)' | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 |
| 8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 |
| 8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 |
| 8.AC.05 va | 'Alluaudite-Na[]' | ◻4Na4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | 'Alluaudite-Ca[]' | ◻4Ca4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | 'Ferroalluaudite-NaNa' | Na4Na4Fe2+4Fe3+8(PO4)12 |
| 8.AC.05 | 'Hagendorfite-NaNa' | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) |
| 8.AC.05 | O'Danielite | Na(Zn,Mg)3(AsO4)(AsO3OH)2 |
| 8.AC.05 | Howardevansite | NaCuFe2(VO4)3 |
| 8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 |
| 8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 |
| 8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 |
| 8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 |
| 8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] |
| 8.AC.05 | Manganohatertite | NaNaCa(MnFe3+)(AsO4)3 |
| 8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 |
| 8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 |
| 8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 |
| 8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 |
| 8.AC.10 | 'Ferrohagendorfite' | NaCaFe2+Fe2+2(PO4)3 |
| 8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 |
| 8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 |
| 8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 |
| 8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 |
| 8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 |
| 8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 |
| 8.AC.10 | Bradaczekite | NaCu4(AsO4)3 |
| 8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 |
| 8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 |
| 8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 |
| 8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 |
| 8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 |
| 8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 |
| 8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 |
| 8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 |
| 8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 |
| 8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 |
| 8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 |
| 8.AC.18 | Manitobaite | Na16Mn2+ 25Al8(PO4)30 |
| 8.AC.20 | Marićite | NaFe2+(PO4) |
| 8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 |
| 8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 |
| 8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 |
| 8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) |
| 8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 |
| 8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 |
| 8.AC.30 | Brianite | Na2CaMg(PO4)2 |
| 8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 |
| 8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · |
| 8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 |
| 8.AC.45 | Magnesiochangesite-(Ce) | (Ca8Ce)◻Mg(PO4)7 |
| 8.AC.45 | Tuite | Ca3(PO4)2 |
| 8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 |
| 8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) |
| 8.AC.45 | Magnesiochangesite-(Y) | (Ca8Y)◻ Mg(PO4)7 |
| 8.AC.45 | Changesite-(Ce) | (Ca8Ce)◻Fe2+(PO4)7 |
| 8.AC.45 | Merrillite | Ca9NaMg(PO4)7 |
| 8.AC.45 | Whitlockite | Ca9Mg(PO4)6(PO3OH) |
| 8.AC.47 | Iwateite | Na2BaMn(PO4)2 |
| 8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 |
| 8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 |
| 8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 |
| 8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 |
| 8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 |
| 8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 |
| 8.AC.50 | Johnsomervilleite | Na3CaFe11(PO4)9 |
| 8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 |
| 8.AC.50 | Udinaite | NaMg4(VO4)3 |
| 8.AC.50 | Chladniite | Na3CaMg11(PO4)9 |
| 8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 |
| 8.AC.55 | Pharmazincite | KZnAsO4 |
| 8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 |
| 8.AC.60 | Kosnarite | KZr2(PO4)3 |
| 8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 |
| 8.AC.70 | Stanfieldite | Ca4Mg5(PO4)6 |
| 8.AC.75 | Ronneburgite | K2MnV4O12 |
| 8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] |
| 8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Arsenudinaite
mindat.org URL:
https://www.mindat.org/min-53170.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Arsenudinaite
Reference List:
Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter 45, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (5) 1225-1232 doi:10.1180/mgm.2018.160
Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850
Localities for Arsenudinaite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
| Hålenius et al. (2018) +1 other reference |
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The
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia