Wopmayite
A valid IMA mineral species
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Formula:
Ca6Na3◻Mn(PO4)3(PO3OH)4
Colour:
Colorless to white to pale pink
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
3.027 (Calculated)
Crystal System:
Trigonal
Member of:
Name:
After Wilfrid Reid “Wop” May (March 20, 1896 – June 21, 1952) who was born in Carberry, Manitoba, Canada. “Wop” May was a pioneering aviator who created the role of the bush pilot, and opened up the Canadian North to mineral exploration and mining.
Unique Identifiers
Mindat ID:
42881
Long-form identifier:
mindat:1:1:42881:3
IMA Classification of Wopmayite
Approved
IMA Formula:
Ca6Na3◻Mn2+(PO4)3(PO3OH)4
Approval year:
2011
First published:
2013
Type description reference:
Cooper, Mark A., Hawthorne, Frank C., Abdu, Yassir A., Ball, Neil A., Ramik, Robert A., Tait, Kimberly T. (2013) Wopmayite, ideally Ca6Na3Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure. The Canadian Mineralogist, 51 (1) 93-106 doi:10.3749/canmin.51.1.93
Classification of Wopmayite
8.AC.
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Wop | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Wopmayite
Vitreous
Transparency:
Transparent
Colour:
Colorless to white to pale pink
Streak:
White
Hardness:
5 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
None observed
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
3.027 g/cm3 (Calculated)
Optical Data of Wopmayite
Type:
Uniaxial (-)
RI values:
nω = 1.617(2) nε = 1.613(2)
Max. Birefringence:
δ = 0.004
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic
(convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis
centred and vertical. The coloured rings are isochromatics, computed with the
same physics as the Michel-Lévy bar above; the dark cross is the isogyre.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Chemistry of Wopmayite
Mindat Formula:
Ca6Na3◻Mn(PO4)3(PO3OH)4
Element Weights:
Crystallography of Wopmayite
Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3c
Cell Parameters:
a = 10.3926(2) Å, c = 37.1694(9) Å
Ratio:
a:c = 1 : 3.577
Unit Cell V:
3,476.68 ų (Calculated from Unit Cell)
Z:
6
Morphology:
Rhombohedron {10-11}.
Twinning:
No visible twinning
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0019803 | Wopmayite | Cooper M A, Hawthorne F C, Abdu Y A, Ball N A, Ramik R A, Tait K T (2013) Wopmayite, ideally Ca6Na3[]Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure The Canadian Mineralogist 51 93-106 | 2013 | the Tanco Mine, Bernic Lake, Manitoba, Canada | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 8.017 Å | (31) |
| 6.421 Å | (32) |
| 5.166 Å | (33) |
| 3.425 Å | (29) |
| 3.186 Å | (88) |
| 2.858 Å | (100) |
| 2.736 Å | (27) |
| 2.589 Å | (68) |
Reference:
Cooper, Mark A., Hawthorne, Frank C., Abdu, Yassir A., Ball, Neil A., Ramik, Robert A., Tait, Kimberly T. (2013) Wopmayite, ideally Ca6Na3Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure. The Canadian Mineralogist, 51 (1) 93-106 doi:10.3749/canmin.51.1.93
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Wopmayite
General Appearance of Type Material:
Corroded rhombic crystals ~150 µm across.
Place of Conservation of Type Material:
Department of Natural History, Royal Ontario Museum, Toronto, Ontario, Canada, catalogue number M40501.
Geological Setting of Type Material:
Zoned petalite-subgroup pegmatite after dissolution of primary lithiophosphate by hydrothermal solutions.
Associated Minerals at Type Locality:
Reference:
Cooper, Mark A., Hawthorne, Frank C., Abdu, Yassir A., Ball, Neil A., Ramik, Robert A., Tait, Kimberly T. (2013) Wopmayite, ideally Ca6Na3Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure. The Canadian Mineralogist, 51 (1) 93-106 doi:10.3749/canmin.51.1.93
Synonyms of Wopmayite
Other Language Names for Wopmayite
Relationship of Wopmayite to other Species
Member of:
Other Members of Whitlockite Subgroup:
| Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
| Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
| Whitlockite | Ca9Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 8.AC. | 'Crocobelonite-1M' | CaFe3+2O(PO4)2 |
| 8.AC. | Magnesioqingheiite | Na2Mg(MgAl)(PO4)3 |
| 8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 |
| 8.AC. | Changesite-(Y) | (Ca8Y)◻Fe2+(PO4)7 |
| 8.AC. | Babunaite-(Nd) | NdAsO4 |
| 8.AC. | Crocobelonite | CaFe3+2O(PO4)2 |
| 8.AC. | Beershevaite | CaFe3+3(PO4)3O |
| 8.AC. | Epiebnerite | (NH4)Zn(PO4) |
| 8.AC. | Ebnerite | (NH4)Zn(PO4) |
| 8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 |
| 8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 |
| 8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O |
| 8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 |
| 8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 |
| 8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 |
| 8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 |
| 8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 |
| 8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 |
| 8.AC.02 | Ziminaite | Fe3+ 6 (VO4)6 |
| 8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 |
| 8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O |
| 8.AC.05 | 'Unnamed (Na-Mg Arsenate Hydroxyarsenate)' | NaMg3(AsO4)(AsO3OH)2 |
| 8.AC.05 | 'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)' | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 |
| 8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 |
| 8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 |
| 8.AC.05 va | 'Alluaudite-Na[]' | ◻4Na4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | 'Alluaudite-Ca[]' | ◻4Ca4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | 'Ferroalluaudite-NaNa' | Na4Na4Fe2+4Fe3+8(PO4)12 |
| 8.AC.05 | 'Hagendorfite-NaNa' | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) |
| 8.AC.05 | O'Danielite | Na(Zn,Mg)3(AsO4)(AsO3OH)2 |
| 8.AC.05 | Howardevansite | NaCuFe2(VO4)3 |
| 8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 |
| 8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 |
| 8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 |
| 8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 |
| 8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] |
| 8.AC.05 | Manganohatertite | NaNaCa(MnFe3+)(AsO4)3 |
| 8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 |
| 8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 |
| 8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 |
| 8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 |
| 8.AC.10 | 'Ferrohagendorfite' | NaCaFe2+Fe2+2(PO4)3 |
| 8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 |
| 8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 |
| 8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 |
| 8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 |
| 8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 |
| 8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 |
| 8.AC.10 | Bradaczekite | NaCu4(AsO4)3 |
| 8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 |
| 8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 |
| 8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 |
| 8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 |
| 8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 |
| 8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 |
| 8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 |
| 8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 |
| 8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 |
| 8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 |
| 8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 |
| 8.AC.18 | Manitobaite | Na16Mn2+ 25Al8(PO4)30 |
| 8.AC.20 | Marićite | NaFe2+(PO4) |
| 8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 |
| 8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 |
| 8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 |
| 8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) |
| 8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 |
| 8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 |
| 8.AC.30 | Brianite | Na2CaMg(PO4)2 |
| 8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 |
| 8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · |
| 8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 |
| 8.AC.45 | Magnesiochangesite-(Ce) | (Ca8Ce)◻Mg(PO4)7 |
| 8.AC.45 | Tuite | Ca3(PO4)2 |
| 8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 |
| 8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) |
| 8.AC.45 | Magnesiochangesite-(Y) | (Ca8Y)◻ Mg(PO4)7 |
| 8.AC.45 | Changesite-(Ce) | (Ca8Ce)◻Fe2+(PO4)7 |
| 8.AC.45 | Merrillite | Ca9NaMg(PO4)7 |
| 8.AC.45 | Whitlockite | Ca9Mg(PO4)6(PO3OH) |
| 8.AC.47 | Iwateite | Na2BaMn(PO4)2 |
| 8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 |
| 8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 |
| 8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 |
| 8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 |
| 8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 |
| 8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 |
| 8.AC.50 | Johnsomervilleite | Na3CaFe11(PO4)9 |
| 8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 |
| 8.AC.50 | Udinaite | NaMg4(VO4)3 |
| 8.AC.50 | Arsenudinaite | NaMg4(AsO4)3 |
| 8.AC.50 | Chladniite | Na3CaMg11(PO4)9 |
| 8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 |
| 8.AC.55 | Pharmazincite | KZnAsO4 |
| 8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 |
| 8.AC.60 | Kosnarite | KZr2(PO4)3 |
| 8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 |
| 8.AC.70 | Stanfieldite | Ca4Mg5(PO4)6 |
| 8.AC.75 | Ronneburgite | K2MnV4O12 |
| 8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] |
| 8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 |
Fluorescence of Wopmayite
Does not fluoresce
Other Information
IR Spectrum:
IR absorption bands (cm–1, s = strong, m = medium, w = weak) 2830s and 2395s (O−H stretching), 1720m and 1651m (combinations), 1345s (P−O−H bending vibration), 1185s, 1090s, 994w, and 947w (various stretching bands of the PO4 group), 870w (P–OH stretching).
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Wopmayite
mindat.org URL:
https://www.mindat.org/min-42881.html
Please feel free to link to this page.
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References for Wopmayite
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2012) New minerals and nomenclature modifications approved in 2012. CNMNC Newsletter No 12. Mineralogical Magazine, 76 (1) 151-155 doi:10.1180/minmag.2012.076.1.151
Cooper, Mark A., Hawthorne, Frank C., Abdu, Yassir A., Ball, Neil A., Ramik, Robert A., Tait, Kimberly T. (2013) Wopmayite, ideally Ca6Na3Mn(PO4)3(PO3OH)4, a new phosphate mineral from the Tanco Mine, Bernic Lake, Manitoba: description and crystal structure. The Canadian Mineralogist, 51 (1) 93-106 doi:10.3749/canmin.51.1.93
Localities for Wopmayite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Canada (TL) | |
| Williams et al. (2012) |
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