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Charoite

A valid IMA mineral species
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About CharoiteHide

Formula:
(K,Sr)15-16(Ca,Na)32[Si6O11(O,OH)6]2[Si12O18(O,OH)12]2[Si17O25(O,OH)18]2(OH,F)4 · ~3H2O
Colour:
Violet to deep lilac, whitish-grey to brown
Lustre:
Vitreous, Silky
Hardness:
5 - 6
Specific Gravity:
2.54
Crystal System:
Monoclinic
Name:
For the type locality, near the Chara River, Russia.
Essential component of the rock charoitite.




Unique IdentifiersHide

Mindat ID:
972
Long-form identifier:
mindat:1:1:972:4

Similar NamesHide

ChaoiteA valid IMA mineral speciesC

IMA Classification of CharoiteHide

Approved
IMA Formula:
(K,Sr,Ba,Mn2+)15-16(Ca,Na)32Si70(O,OH)180(OH,F)4·nH2O
Approval year:
1977

Classification of CharoiteHide

9.DG.92

9 : SILICATES (Germanates)
D : Inosilicates
G : Inosilicates with 3-periodic single and multiple chains
70.1.2.3

70 : INOSILICATES Column or Tube Structures
1 : Column or Tube Structures with columnar silicate units
17.1.14

17 : Silicates Containing other Anions
1 : Silicates with fluoride (not containing Al)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
ChaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CharoiteHide

Vitreous, Silky
Transparency:
Translucent
Colour:
Violet to deep lilac, whitish-grey to brown
Comment:
Material from the type locality is vivid purple, due to trace manganese. Whitish-gray to brown from Patyn Mt.
Hardness:
5 - 6 on Mohs scale
Hardness:
VHN50=412 kg/mm2 - Vickers
Cleavage:
Distinct/Good
Good in three directions.
Density:
2.54 g/cm3 (Measured)    2.77 g/cm3 (Calculated)

Optical Data of CharoiteHide

Type:
Biaxial (+)
RI values:
nα = 1.55 nβ = 1.553 nγ = 1.559
2V:
Measured: 28° to 30°, Calculated: 72°
Max. Birefringence:
δ = 0.009
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v strong
Optical Extinction:
X = b, Z ∧ c = 5°.
Pleochroism:
Weak
Comments:
X = rose
Z = colorless

Chemistry of CharoiteHide

Mindat Formula:
(K,Sr)15-16(Ca,Na)32[Si6O11(O,OH)6]2[Si12O18(O,OH)12]2[Si17O25(O,OH)18]2(OH,F)4 · ~3H2O
Element Weights:
Element% weight
O43.761 %
Si28.755 %
Ca18.758 %
K8.578 %
H0.147 %

Calculated from ideal end-member formula.
O
Si
Ca
K
H
Common Impurities:
Al,Fe,Mn,Sr,Ba

Crystallography of CharoiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Cell Parameters:
a = 32.296 Å, b = 19.651 Å, c = 7.16 Å
β = 96.3°
Ratio:
a:b:c = 1.643 : 1 : 0.364
Unit Cell V:
4517 ų
Z:
2
Morphology:
Fibrous, massive.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018568CharoiteRozhdestvenskaya I V, Mugnaioli E, Czank M, Depmeier W, Kolb U, Merlino S (2011) Essential features of the polytypic charoite-96 structure compared to charoite-90 Mineralogical Magazine 75 2833-28462011Murun massif in Yakutia, Sakha Republic, Siberia, Russia0293
0017698CharoiteRozhdestvenskaya I, Mugnaioli E, Czank M, Depmeier W, Kolb U, Reinholdt A, Weirich T (2010) The structure of charoite, (K,Sr,Ba,Mn)15-16(Ca,Na)32[(Si70(O,OH)180)](OH,F)4.0*nH2O, solved by conventional and automated electron diffraction Mineralogical Magazine 74 159-1772010Murun massif, Yakutiya, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.348 Å(100)
3.134 Å(85)
12.5 Å(70)
2.79 Å(50)
2.71 Å(35)
3.90 Å(30)
2.97 Å(30)
Comments:
Murun massif, Russia. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Geological Setting:
Potassic feldspar metasomatites

Type Occurrence of CharoiteHide

Place of Conservation of Type Material:
University of Rome, Rome, Italy, number 24352.
A.E. Fersman Mineralogical Museum, Moscow, Russia.
Geological Setting of Type Material:
K-feldspar metasomatites at the contact of nepheline- and aegirine-syenites with limestones.
Associated Minerals at Type Locality:

Synonyms of CharoiteHide

Other Language Names for CharoiteHide

Dutch:Charoiet
German:Charoit
Italian:Charoite
Lithuanian:Čaroitas
Polish:Czaroit
Russian:Чароит
Spanish:Charoita

Common AssociatesHide

Associations Based on Photo Data:
195 photos of Charoite associated with AegirineNaFe3+Si2O6
115 photos of Charoite associated with TinaksiteK2Na(Ca,Mn2+)2TiO[Si7O18(OH)]
51 photos of Charoite associated with SteacyiteK0.3(Na,Ca)2ThSi8O20
42 photos of Charoite associated with QuartzSiO2
21 photos of Charoite associated with FrankameniteK3Na3Ca5(Si12O30)(F,OH)4 · H2O
17 photos of Charoite associated with Fedorite(Na,K)2-3(Ca4Na3)Si16O38(OH,F)2 · 3.5H2O
13 photos of Charoite associated with TokkoiteK2Ca4[Si7O18(OH)](OH,F)
12 photos of Charoite associated with MicroclineK(AlSi3O8)
12 photos of Charoite associated with PectoliteNaCa2Si3O8(OH)
11 photos of Charoite associated with GalenaPbS

Related Minerals - Strunz-mindat GroupingHide

9.DG.Barrydawsonite-(Y)Na1.5Y0.5CaSi3O8(OH)Mon. 2/m : P21/b
9.DG.ParatobermoriteCa5AlSi5O16(OH) · 5H2OMon. 2/m
9.DG.CalcinaksiteKNaCa(Si4O10) · H2OTric. 1 : P1
9.DG.AlvesiteNaKZrSi6O15 · 2H2OOrth. mmm(2/m2/m2/m)
9.DG.02SteedeiteNaMn2[Si3BO9](OH)2Tric. 1 : P1
9.DG.02NolzeiteNaMn2[Si3BO9](OH)2 · 2H2OTric. 1 : P1
9.DG.05MurakamiiteLiCa2Si3O8(OH)Tric. 1 : P1
9.DG.05SeranditeNaMn2+2Si3O8(OH)Tric. 1 : P1
9.DG.05BustamiteCaMn2+(Si2O6)Tric. 1 : P1
9.DG.05PectoliteNaCa2Si3O8(OH)Tric. 1 : P1
9.DG.05TanohataiteLiMn2Si3O8(OH)Tric. 1 : P1
9.DG.05DalnegorskiteCa5Mn2+(Si3O9)2Tric. 1 : P1
9.DG.05'Wollastonite-1A'CaSiO3Tric. 1 : P1
9.DG.05WollastoniteCa3(Si3O9)Tric. 1 : P1
9.DG.05FerrobustamiteCaFe2+(Si2O6)Tric. 1
9.DG.05SchizoliteNaCaMnSi3O8(OH)Tric. 1 : P1
9.DG.07CascanditeCaScSi3O8(OH)Tric. 1
9.DG.08PlombièriteCa5Si6O16(OH)2 · 7H2OOrth.
9.DG.10ClinotobermoriteCa5Si6O17 · 5H2OMon.
9.DG.10RiversideiteCa5Si6O16(OH)2 · 2H2O Orth.
9.DG.10TobermoriteCa5Si6O17 · 5H2OMon. 2 : P21
9.DG.12JusiteNa2Ca15Al4Si16O54 · 17H2O
9.DG.12KenotobermoriteCa4Si6O15(OH)2 · 5H2OMon.
9.DG.15FoshagiteCa4(Si3O9)(OH)2Tric. 1 : P1
9.DG.20JenniteCa9(Si3O9)2(OH)8 · 8H2OTric. 1 : P1
9.DG.20KameneviteK2TiSi3O9 · H2OOrth. 222 : P212121
9.DG.25ParaumbiteK3Zr2H(Si3O9)2 · nH2OOrth. mm2
9.DG.25UmbiteK2(Zr,Ti)Si3O9 · H2OOrth. 222 : P212121
9.DG.30SørenseniteNa4SnBe2Si6O16(OH)4Mon. 2/m : B2/b
9.DG.32Escheite Ca2NaMnTi5[Si12O34]O2(OH)3 · 12H2OOrth. mm2 : Ama2
9.DG.35XonotliteCa6(Si6O17)(OH)2Mon. 2/m : B2/m
9.DG.40HillebranditeCa2(SiO3)(OH)2Orth. mmm(2/m2/m2/m) : Cmcm
9.DG.45ZoriteNa8(Ti,Nb)5(Si6O17)2(OH,O)5 · 14H2OOrth.
9.DG.45ChivruaiiteCa4(Ti,Nb)5(Si6O17)2(OH,O)5 · 13-14H2OOrth. mmm(2/m2/m2/m) : Cmmm
9.DG.50Haineaultite(Na,Ca)5Ca(Ti,Nb)5(Si6O17)2(OH,F)8 · 5H2OOrth. 222 : C222
9.DG.55EpididymiteNa2Be2Si6O15 · H2OOrth. mmm(2/m2/m2/m) : Pnma
9.DG.60EudidymiteNa2Be2Si6O15 · H2OMon. 2/m : B2/b
9.DG.65ElpiditeNa2ZrSi6O15 · 3H2OOrth.
9.DG.65PatyniteNaKCa4[Si9O23]Tric. 1 : P1
9.DG.67WhelaniteCu2+2Ca6[Si6O17(OH)](CO3)(OH)3 · 2H2OOrth. mm2 : Pnn2
9.DG.70EnricofrancoiteKNaCaSi4O10Tric. 1 : P1
9.DG.70YusupoviteNa2Zr(Si6O15) · 2.5H2OMon. 2/m : B2/m
9.DG.70LitidioniteKNaCuSi4O10Tric. 1 : P1
9.DG.70Fenaksite(K,Na)4(Fe,Mn)2(Si4O10)2(OH,F)Tric. 1 : P1
9.DG.70ManaksiteKNaMnSi4O10Tric. 1 : P1
9.DG.75SenkevichiteCsKNaCa2TiO[Si7O18](OH)Tric. 1 : P1
9.DG.75TinaksiteK2Na(Ca,Mn2+)2TiO[Si7O18(OH)]Tric.
9.DG.75TokkoiteK2Ca4[Si7O18(OH)](OH,F)Tric.
9.DG.80FluorcanasiteK3Na3Ca5Si12O30F4 · H2OMon. m : Bm
9.DG.80CanasiteK3Na3Ca5Si12O30(OH)4Mon. m : Bm
9.DG.85MiseriteK1.5-x(Ca,Y,REE)5(Si6O15)(Si2O7)(OH,F)2 · yH2OTric.
9.DG.90FrankameniteK3Na3Ca5(Si12O30)(F,OH)4 · H2OTric. 1 : P1
9.DG.95YuksporiteK4(Ca,Na)14(Sr,Ba)2(◻,Mn,Fe)(Ti,Nb)4(O,OH)4(Si6O17)2(Si2O7)3(H2O,OH)3Mon. 2/m : P21/m
9.DG.97Eveslogite(Na,K,Ca,Sr,Ba)48 [(Ti,Nb,Mn,Fe2+)12Si48O144(OH)12](F,OH,Cl)14Mon. 2/m : P2/m

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 8.5780% 2,659 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

IR Spectrum:
The IR spectrum shows the presence of both molecular
water and hydroxyl.
Thermal Behaviour:
About 2.4% H2O is lost up to 300° and l.3% more to 600°. Small endothermic effects are noted at 440°, 760°, and 970°.
Notes:
Insoluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:
Jewelry

Charoite in petrologyHide

An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.

Internet Links for CharoiteHide

References for CharoiteHide

Reference List:

Localities for CharoiteHide

Showing 14 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
India
 
  • Tamil Nadu
    • Chengalpattu district
Deepthi et al. (2015)
Russia (TL)
 
  • Aldan Shield
    • Chara and Tokko Rivers Confluence
Konev et al. (1993) +1 other reference
Kaneva +4 other references
Solyanik et al. (2008) +3 other references
Pavel M. Kartashov (n.d.)
- (n.d.)
Pekov (1998)
Vorob'yov E.I. (2008)
Vorob'yov E.I. (2008)
Pavel M. Kartashov (n.d.)
Kaneva +3 other references
  • Irkutsk Oblast
Vladykin et al. (2008)
Kaneva et al. (2020)
  • Kemerovo Oblast
    • Tashtagolsky District
      • Synzas River
doi.org (n.d.) +1 other reference
 
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