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Flaggite

A valid IMA mineral species
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About FlaggiteHide

06865080017272473387757.jpg
Arthur L. Flagg
Formula:
Pb4Cu2+4Te6+2(SO4)2O11(OH)2(H2O)
Colour:
Lime-green to yellow-green
Lustre:
Adamantine
Hardness:
3
Specific Gravity:
6.137 (Calculated)
Crystal System:
Triclinic
Name:
Named in honour of Arthur Leonard Flagg (29 June 1883, Woonsocket, Rhode Island, USA – 27 April 1961, Phoenix, Arizona, USA), mining engineer, mineral collector, and promoter of mineral collecting. He worked at various mines, especially in Arizona, founded the Mineralogical Society of Arizona, and served as president of the American Federation of Mineralogical Societies. He also wrote a number of articles, brochures, and books including Mineralogical Journeys in Arizona. The Flagg Mineral Foundation was started after his death and was named in his honor.
Structurally and chemically related to bairdite.

The layers in the structure of flaggite are very similar to those in bairdite, timroseite and paratimroseite.


Unique IdentifiersHide

Mindat ID:
55596
Long-form identifier:
mindat:1:1:55596:8

Similar NamesHide

FluckiteA valid IMA mineral speciesCaMn2+(AsO3OH)2 · 2H2O

IMA Classification of FlaggiteHide

Approved
IMA Formula:
Pb2+4Cu2+4Te6+2(S6+O4)2O11(OH)2(H2O)
Approval year:
2021
First published:
2022
Approval history:
IMA No. 2021-044

Classification of FlaggiteHide

7.DF.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
F : With large and medium-sized cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
FlgIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FlaggiteHide

Adamantine
Colour:
Lime-green to yellow-green
Streak:
Very pale green
Hardness:
Tenacity:
Brittle
Cleavage:
Very Good
One excellent cleavage {010}.
Fracture:
Irregular/Uneven
Density:
6.137 g/cm3 (Calculated)

Optical Data of FlaggiteHide

Type:
Biaxial (+)
RI values:
nα = 1.95(1) nβ = 1.96(1) nγ = 2.00(1)
2V:
Measured: 54° (2)
Max. Birefringence:
δ = 0.050
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Pleochroism:
Visible
Comments:
X = green, Y = light yellow green, Z = nearly colourless.
Comments:
Absorption: X > Y > Z.

Chemistry of FlaggiteHide

Mindat Formula:
Pb4Cu2+4Te6+2(SO4)2O11(OH)2(H2O)
Element Weights:
Element% weight
Pb47.136 %
O20.018 %
Te14.514 %
Cu14.456 %
S3.647 %
H0.229 %

Calculated from ideal end-member formula.

Crystallography of FlaggiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pedial
Space Group:
P1
Cell Parameters:
a = 9.5610(2) Å, b = 9.9755(2) Å, c = 10.4449(3) Å
α = 74.884(1)°, β = 89.994(1)°, γ = 78.219(1)°
Ratio:
a:b:c = 0.958 : 1 : 1.047
Unit Cell V:
939.97 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.41 Å(65)
4.59 Å(93)
4.34 Å(49)
3.519 Å(53)
3.070 Å(99)
3.023 Å(87)
2.724 Å(100)
2.167 Å(41)

Type Occurrence of FlaggiteHide

General Appearance of Type Material:
Lime-green to yellow-green tablets, up to 0.5 mm across.
Place of Conservation of Type Material:
Mineralogical colletions of the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue nos. 64499, 64500, and 76143.
Geological Setting of Type Material:
In cavities in quartz matrix.
Associated Minerals at Type Locality:

Synonyms of FlaggiteHide

Other Language Names for FlaggiteHide

Dutch:Flaggiet
German:Flaggit

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Flaggite associated with BackitePb2AlTeO6Cl
1 photo of Flaggite associated with SchieffelinitePb10Te6+6O20(OH)14(SO4)(H2O)5

Related Minerals - Strunz-mindat GroupingHide

7.DF.Siligiite [Pb(H2O)5(SO4)][Zn9(OH)18]Mon. 2/m : P21/b
7.DF.AlcaparrosaiteK3Ti4+Fe3+(SO4)4O(H2O)2Mon. 2/m : B2/b
7.DF.BairditePb2Cu2+4Te6+2O10(OH)2(SO4) · H2OMon. 2/m : P21/b
7.DF.TzeferisiteCaZn8(SO4)2(OH)12Cl2(H2O)9Trig. 3m(32/m) : R3c
7.DF.Cherokeeite[Pb2Zn(OH)4](SO4) · H2OMon. 2/m
7.DF.Ammoniomathesiusite(NH4)5(UO2)4(SO4)4(VO5) · 4H2OTet. 4/m : P4/n
7.DF.Sigogglinite[Pb6Zn(OH)8]2(SO4)6 · (H2O)8-xMon. 2/m : P2/m
7.DF.XBlueridgeite[Pb8Zn3Cu2+(OH)16](SO4)2(S2O3)2 · 2H2OMon. 2/m : P21/b
7.DF.ErssoniteMg7Fe3+2(OH)18[Ca(H2O)6](SO4)2 · 12H2OTrig. 3m(32/m) : P3c1
7.DF.PoellmanniteCa6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
7.DF.Carlsonite(NH4)5Fe3+3O(SO4)6 · 7H2OTric. 1 : P1
7.DF.Cuprocherokeeite[Pb8Zn3Cu2+(OH)16](SO4)4 · 4H2OMon. 2/m
7.DF.Haywoodite[Pb(H2O)10][Zn12(OH)20(H2O)(SO4)3]Tric. 1 : P1
7.DF.ChromschieffelinitePb10Te6+6O20(OH)14(CrO4)(H2O)5Orth. 222 : C2221
7.DF.05UklonskoviteNaMg(SO4)F · 2H2OMon. 2/m : P21/m
7.DF.10KainiteKMg(SO4)Cl · 3H2OMon. 2/m : B2/m
7.DF.10KaliochalciteKCu2(SO4)2[(OH)(H2O)]Mon. 2/m : B2/m
7.DF.15NatrochalciteNaCu2(SO4)2(OH) · 2H2OMon. 2/m : B2/m
7.DF.17GenplesiteCa3Sn(SO4)2(OH)6 · 3H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
7.DF.17'Unnamed (Ba-Sb Silicate-Sulphate-Hydroxide-Hydrate)'Ba3Sb5+[(Si,S)O3(OH)]2(OH,O)6 · 3H2O Trig. 3 : P3
7.DF.20SideronatriteNa2Fe(SO4)2(OH) · 3H2OOrth. 222 : P212121
7.DF.20MetasideronatriteNa2Fe(SO4)2(OH) · H2OOrth. mmm(2/m2/m2/m)
7.DF.25FleischeritePb3Ge(SO4)2(OH)6 · 3H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
7.DF.25MallestigitePb3Sb5+(SO4)(AsO4)(OH)6 · 3H2OHex. 6 : P63
7.DF.25SchaurteiteCa3Ge(SO4)2(OH)6 · 4H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
7.DF.25DespujolsiteCa3Mn4+(SO4)2(OH)6 · 3H2OHex. 6m2 : P62c
7.DF.30Slavíkite(H3O+)3Mg6Fe15(SO4)21(OH)18 · 98H2OTrig. 3 : R3
7.DF.35MetavoltineK2Na6Fe2+Fe3+6O2(SO4)12 · 18H2OTrig.
7.DF.40LannoniteMg2Ca4Al4(SO4)8F8 · 24H2OTet. 4/m : I4/m
7.DF.40VlodavetsiteAlCa2(SO4)2F2Cl · 4H2OTet. 4/m : I4/m
7.DF.45PeretaiteCa(SbO)4(SO4)2(OH)2 · 2H2OMon. 2/m : B2/b
7.DF.50GordaiteNaZn4(SO4)(OH)6Cl · 6H2OTrig. 3 : P3
7.DF.50CalamaiteNa2TiO(SO4)2 · 2H2OOrth. mmm(2/m2/m2/m) : Ibam
7.DF.52Huizingite-(Al)[(NH4)9(SO4)2][(Al,Fe3+)3(OH)2(H2O)4(SO4)6]Tric. 1 : P1
7.DF.52ScordariiteK8(Fe3+0.670.33)[Fe3+3O(SO4)6]2 · 14H2OTrig. 3 : R3
7.DF.55Clairite(NH4)2Fe3(SO4)4(OH)3 · 3H2OTric.
7.DF.55GiacovazzoiteK5Fe3+3O(SO4)6 · 10H2OMon. 2/m : P21/b
7.DF.57MagnanelliiteK3Fe3+2(SO4)4(OH)(H2O)2Mon. 2/m : B2/b
7.DF.60ArzruniteCu4Pb2(SO4)(OH)4Cl6 · 2H2O (?)Orth.
7.DF.60EvdokimoviteTl4(VO)3(SO4)5(H2O)5Mon. 2/m
7.DF.62Bridgesite-(Ce)CaCe2Cu6(SO4)4(OH)12 · 8H2OMon. 2/m : B2/m
7.DF.65ElyitePb4Cu(SO4)O2(OH)4 · H2OMon. 2/m : P21/b
7.DF.70YecoraiteFe3+3Bi5(Te6+O4)2(Te4+O3)O9 · 9H2O
7.DF.70LautenthalitePbCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DF.75RiomarinaiteBi(SO4)(OH) · H2OMon. 2/m
7.DF.80DukeiteBi3+24Cr6+8O57(OH)6 · 3H2OTrig. 3m : P31c

Other InformationHide

Notes:
The Raman spectrum exhibits bands consistent with TeO6 and SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FlaggiteHide

References for FlaggiteHide

Localities for FlaggiteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • Arizona
    • Cochise County
      • Tombstone Mining District
        • Contention-Grand Central Mine group
doi.org (n.d.) +1 other reference
        • Silver Plume Mine
Marek Chorazewicz (2022)
  • California
    • San Bernardino County
      • Silver Lake Mining District
        • Soda Mountains
          • Baker
            • Otto Mountain
Marek Chorazewicz (2026)
 
and/or  
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