Riomarinaite
A valid IMA mineral species
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About Riomarinaite
Formula:
Bi(SO4)(OH) · H2O
Colour:
light beige to light grey
Lustre:
Vitreous
Hardness:
2 - 3
Specific Gravity:
4.80 (Calculated)
Crystal System:
Monoclinic
Name:
For the type locality, the Rio Marina mine, Italy.
This page provides mineralogical data about Riomarinaite.
Unique Identifiers
Mindat ID:
27210
Long-form identifier:
mindat:1:1:27210:8
IMA Classification of Riomarinaite
Approved
IMA Formula:
Bi3+S6+O4(OH)·H2O
Approval year:
2000
First published:
2005
Classification of Riomarinaite
7.DF.75
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
F : With large and medium-sized cations
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
F : With large and medium-sized cations
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Rmr | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Riomarinaite
Vitreous
Colour:
Light beige to light grey
Streak:
White to light grey
Hardness:
2 - 3 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
4.80(3) g/cm3 (Calculated)
Chemistry of Riomarinaite
Mindat Formula:
Bi(SO4)(OH) · H2O
Element Weights:
Elements listed:
Crystallography of Riomarinaite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 6.0118(3) Å, b = 13.3355(6) Å, c = 6.4854(4) Å
β = 112.906°
β = 112.906°
Ratio:
a:b:c = 0.451 : 1 : 0.486
Unit Cell V:
478.94 ų
Z:
4
Comment:
Space Group: P21/n.
Crystal Structure
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Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0009781 | Riomarinaite | Graunar M, Lazarini F (1982) Di-mu-hydroxo-bis[aquasulfatobismuth(III)] Acta Crystallographica B38 2879-2881 | ![]() | 1982 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.2598 Å | (100) |
| 5.4530 Å | (42) |
| 3.3350 Å | (42) |
| 5.1152 Å | (37) |
| 3.1127 Å | (36) |
| 5.1926 Å | (32) |
| 2.9151 Å | (22) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47b : [Sulfates and sulfites] | |
| 47f : [Uranyl (U⁶⁺) minerals] |
Type Occurrence of Riomarinaite
General Appearance of Type Material:
Cavernous masses and coatings, rarely radiated aggregates of acicular crystals.
Place of Conservation of Type Material:
Bavarian State Collection for Mineralogy, Munich, Germany (MSM 27074)
Geological Setting of Type Material:
Alteration product of bismuthinite at very low pH values.
Associated Minerals at Type Locality:
Synonyms of Riomarinaite
Other Language Names for Riomarinaite
Dutch:Riomarinaiet
German:Riomarinait
Russian:Риомаринаит
Simplified Chinese:瑞铋矾
Traditional Chinese:瑞鉍礬
Common Associates
Associations Based on Photo Data:
| 2 photos of Riomarinaite associated with Bismuthinite | Bi2S3 |
| 2 photos of Riomarinaite associated with Native Bismuth | Bi |
| 1 photo of Riomarinaite associated with Cannonite | Bi2(SO4)O(OH)2 |
| 1 photo of Riomarinaite associated with Pyrite | FeS2 |
Related Minerals - Strunz-mindat Grouping
| 7.DF. | Siligiite | [Pb(H2O)5(SO4)][Zn9(OH)18] |
| 7.DF. | Alcaparrosaite | K3Ti4+Fe3+(SO4)4O(H2O)2 |
| 7.DF. | Flaggite | Pb4Cu2+4Te6+2(SO4)2O11(OH)2(H2O) |
| 7.DF. | Bairdite | Pb2Cu2+4Te6+2O10(OH)2(SO4) · H2O |
| 7.DF. | Tzeferisite | CaZn8(SO4)2(OH)12Cl2(H2O)9 |
| 7.DF. | Cherokeeite | [Pb2Zn(OH)4](SO4) · H2O |
| 7.DF. | Ammoniomathesiusite | (NH4)5(UO2)4(SO4)4(VO5) · 4H2O |
| 7.DF. | Sigogglinite | [Pb6Zn(OH)8]2(SO4)6 · (H2O)8-x |
| 7.DF.X | Blueridgeite | [Pb8Zn3Cu2+(OH)16](SO4)2(S2O3)2 · 2H2O |
| 7.DF. | Erssonite | Mg7Fe3+2(OH)18[Ca(H2O)6](SO4)2 · 12H2O |
| 7.DF. | Poellmannite | Ca6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DF. | Carlsonite | (NH4)5Fe3+3O(SO4)6 · 7H2O |
| 7.DF. | Cuprocherokeeite | [Pb8Zn3Cu2+(OH)16](SO4)4 · 4H2O |
| 7.DF. | Haywoodite | [Pb(H2O)10][Zn12(OH)20(H2O)(SO4)3] |
| 7.DF. | Chromschieffelinite | Pb10Te6+6O20(OH)14(CrO4)(H2O)5 |
| 7.DF.05 | Uklonskovite | NaMg(SO4)F · 2H2O |
| 7.DF.10 | Kainite | KMg(SO4)Cl · 3H2O |
| 7.DF.10 | Kaliochalcite | KCu2(SO4)2[(OH)(H2O)] |
| 7.DF.15 | Natrochalcite | NaCu2(SO4)2(OH) · 2H2O |
| 7.DF.17 | Genplesite | Ca3Sn(SO4)2(OH)6 · 3H2O |
| 7.DF.17 | 'Unnamed (Ba-Sb Silicate-Sulphate-Hydroxide-Hydrate)' | Ba3Sb5+[(Si,S)O3(OH)]2(OH,O)6 · 3H2O |
| 7.DF.20 | Sideronatrite | Na2Fe(SO4)2(OH) · 3H2O |
| 7.DF.20 | Metasideronatrite | Na2Fe(SO4)2(OH) · H2O |
| 7.DF.25 | Fleischerite | Pb3Ge(SO4)2(OH)6 · 3H2O |
| 7.DF.25 | Mallestigite | Pb3Sb5+(SO4)(AsO4)(OH)6 · 3H2O |
| 7.DF.25 | Schaurteite | Ca3Ge(SO4)2(OH)6 · 4H2O |
| 7.DF.25 | Despujolsite | Ca3Mn4+(SO4)2(OH)6 · 3H2O |
| 7.DF.30 | Slavíkite | (H3O+)3Mg6Fe15(SO4)21(OH)18 · 98H2O |
| 7.DF.35 | Metavoltine | K2Na6Fe2+Fe3+6O2(SO4)12 · 18H2O |
| 7.DF.40 | Lannonite | Mg2Ca4Al4(SO4)8F8 · 24H2O |
| 7.DF.40 | Vlodavetsite | AlCa2(SO4)2F2Cl · 4H2O |
| 7.DF.45 | Peretaite | Ca(SbO)4(SO4)2(OH)2 · 2H2O |
| 7.DF.50 | Gordaite | NaZn4(SO4)(OH)6Cl · 6H2O |
| 7.DF.50 | Calamaite | Na2TiO(SO4)2 · 2H2O |
| 7.DF.52 | Huizingite-(Al) | [(NH4)9(SO4)2][(Al,Fe3+)3(OH)2(H2O)4(SO4)6] |
| 7.DF.52 | Scordariite | K8(Fe3+0.67◻0.33)[Fe3+3O(SO4)6]2 · 14H2O |
| 7.DF.55 | Clairite | (NH4)2Fe3(SO4)4(OH)3 · 3H2O |
| 7.DF.55 | Giacovazzoite | K5Fe3+3O(SO4)6 · 10H2O |
| 7.DF.57 | Magnanelliite | K3Fe3+2(SO4)4(OH)(H2O)2 |
| 7.DF.60 | Arzrunite | Cu4Pb2(SO4)(OH)4Cl6 · 2H2O (?) |
| 7.DF.60 | Evdokimovite | Tl4(VO)3(SO4)5(H2O)5 |
| 7.DF.62 | Bridgesite-(Ce) | CaCe2Cu6(SO4)4(OH)12 · 8H2O |
| 7.DF.65 | Elyite | Pb4Cu(SO4)O2(OH)4 · H2O |
| 7.DF.70 | Yecoraite | Fe3+3Bi5(Te6+O4)2(Te4+O3)O9 · 9H2O |
| 7.DF.70 | Lautenthalite | PbCu4(SO4)2(OH)6 · 3H2O |
| 7.DF.80 | Dukeite | Bi3+24Cr6+8O57(OH)6 · 3H2O |
Fluorescence of Riomarinaite
none
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Riomarinaite
mindat.org URL:
https://www.mindat.org/min-27210.html
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References for Riomarinaite
Reference List:
Graunar, M., Lazarini, F. (1982) Di-μ-hydroxo-bis[aquasulfatobismuth(III)]. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 38 (11) 2879-2881 doi:10.1107/s0567740882010188
Vrtiška, Luboš; Pauliš, Petr; Čejka, Jiří; Malíková, Radana; Dolníček, Zdeněk; Dvořák, Zdeněk; Pour, Ondřej (2020) Riomarinait z Cínovce - první výskyt velmi vzácného sulfátu bismutu v České republice [Riomarinaite from Cínovec - first occurence of very rare bismuth sulphate in the Czech Republic]. Bulletin Mineralogie Petrologie, 28 (2). 359-363 doi:10.46861/bmp.28.359
Localities for Riomarinaite
Showing 6 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| Clissold (2007) |
Czech Republic | |
| Vrtiška et al. (2020) |
Europe | |
| Vrtiška et al. (2020) |
Germany | |
| Habel (2009) |
| Dill et al. (2012) |
Italy (TL) | |
| Rögner (2005) +1 other reference |
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The
Zinnwald-Cínovec mining region, Ore Mountains, Europe