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Scordariite

A valid IMA mineral species
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About ScordariiteHide

Formula:
K8(Fe3+0.670.33)[Fe3+3O(SO4)6]2 · 14H2O
Colour:
Yellowish to brownish
Lustre:
Vitreous
Hardness:
2 - 2½
Specific Gravity:
2.432 (Calculated)
Crystal System:
Trigonal
Name:
Named in honor of Fernando Scordari (b. 1944), professor of Mineralogy at the University of Bari. He was the president of the Società Italiana di Mineralogia e Petrologia (SIMP) in 1998–2000 and a vice-president of the European Mineralogical Union (2000–2004). He is an expert on crystallography and mass spectrometry with special interest in silicates and sulfates. He also made important contributions to the crystal chemistry of metavoltine and its related compounds.
Structurally related to metavoltine and carlsonite. Chemically especially related to giacovazzoite - another K-Fe oxysulfate.


Unique IdentifiersHide

Mindat ID:
53674
Long-form identifier:
mindat:1:1:53674:1

IMA Classification of ScordariiteHide

Classification of ScordariiteHide

7.DF.52

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
F : With large and medium-sized cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
SdaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ScordariiteHide

Vitreous
Transparency:
Transparent
Colour:
Yellowish to brownish
Streak:
Yellowish
Hardness:
2 - 2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{0001}
Fracture:
Irregular/Uneven
Density:
2.432 g/cm3 (Calculated)

Optical Data of ScordariiteHide

Type:
Uniaxial (-)
Pleochroism:
Visible
Comments:
pale yellow to yellow
Comments:
Mean refractive index is 1.573.

Chemistry of ScordariiteHide

Mindat Formula:
K8(Fe3+0.670.33)[Fe3+3O(SO4)6]2 · 14H2O
Element Weights:
Element% weight
O48.249 %
S18.131 %
Fe17.552 %
K14.739 %
H1.330 %

Calculated from ideal end-member formula.
O
S
Fe
K
H

Crystallography of ScordariiteHide

Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 9.7509(4) Å, c = 53.525(2) Å
Ratio:
a:c = 1 : 5.489
Unit Cell V:
4,407.34 ų (Calculated from Unit Cell)
Z:
3

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of ScordariiteHide

General Appearance of Type Material:
Pseudo-hexagonal {0001} tabular crystals up to 0.5 mm in size
Place of Conservation of Type Material:
Mineralogical collections of the Museo di Storia Naturale, Università di Pisa, Via Roma 79, Calci (Pisa, Italy), catalogue number 19893
Geological Setting of Type Material:
Oxidation of pyrite in old stopes.
Associated Minerals at Type Locality:

Synonyms of ScordariiteHide

Other Language Names for ScordariiteHide

Common AssociatesHide

Associations Based on Photo Data:
7 photos of Scordariite associated with GiacovazzoiteK5Fe3+3O(SO4)6 · 10H2O

Related Minerals - Strunz-mindat GroupingHide

7.DF.Siligiite [Pb(H2O)5(SO4)][Zn9(OH)18]Mon. 2/m : P21/b
7.DF.AlcaparrosaiteK3Ti4+Fe3+(SO4)4O(H2O)2Mon. 2/m : B2/b
7.DF.FlaggitePb4Cu2+4Te6+2(SO4)2O11(OH)2(H2O)Tric. 1 : P1
7.DF.BairditePb2Cu2+4Te6+2O10(OH)2(SO4) · H2OMon. 2/m : P21/b
7.DF.TzeferisiteCaZn8(SO4)2(OH)12Cl2(H2O)9Trig. 3m(32/m) : R3c
7.DF.Cherokeeite[Pb2Zn(OH)4](SO4) · H2OMon. 2/m
7.DF.Ammoniomathesiusite(NH4)5(UO2)4(SO4)4(VO5) · 4H2OTet. 4/m : P4/n
7.DF.Sigogglinite[Pb6Zn(OH)8]2(SO4)6 · (H2O)8-xMon. 2/m : P2/m
7.DF.XBlueridgeite[Pb8Zn3Cu2+(OH)16](SO4)2(S2O3)2 · 2H2OMon. 2/m : P21/b
7.DF.ErssoniteMg7Fe3+2(OH)18[Ca(H2O)6](SO4)2 · 12H2OTrig. 3m(32/m) : P3c1
7.DF.PoellmanniteCa6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
7.DF.Carlsonite(NH4)5Fe3+3O(SO4)6 · 7H2OTric. 1 : P1
7.DF.Cuprocherokeeite[Pb8Zn3Cu2+(OH)16](SO4)4 · 4H2OMon. 2/m
7.DF.Haywoodite[Pb(H2O)10][Zn12(OH)20(H2O)(SO4)3]Tric. 1 : P1
7.DF.ChromschieffelinitePb10Te6+6O20(OH)14(CrO4)(H2O)5Orth. 222 : C2221
7.DF.05UklonskoviteNaMg(SO4)F · 2H2OMon. 2/m : P21/m
7.DF.10KainiteKMg(SO4)Cl · 3H2OMon. 2/m : B2/m
7.DF.10KaliochalciteKCu2(SO4)2[(OH)(H2O)]Mon. 2/m : B2/m
7.DF.15NatrochalciteNaCu2(SO4)2(OH) · 2H2OMon. 2/m : B2/m
7.DF.17GenplesiteCa3Sn(SO4)2(OH)6 · 3H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
7.DF.17'Unnamed (Ba-Sb Silicate-Sulphate-Hydroxide-Hydrate)'Ba3Sb5+[(Si,S)O3(OH)]2(OH,O)6 · 3H2O Trig. 3 : P3
7.DF.20SideronatriteNa2Fe(SO4)2(OH) · 3H2OOrth. 222 : P212121
7.DF.20MetasideronatriteNa2Fe(SO4)2(OH) · H2OOrth. mmm(2/m2/m2/m)
7.DF.25FleischeritePb3Ge(SO4)2(OH)6 · 3H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
7.DF.25MallestigitePb3Sb5+(SO4)(AsO4)(OH)6 · 3H2OHex. 6 : P63
7.DF.25SchaurteiteCa3Ge(SO4)2(OH)6 · 4H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
7.DF.25DespujolsiteCa3Mn4+(SO4)2(OH)6 · 3H2OHex. 6m2 : P62c
7.DF.30Slavíkite(H3O+)3Mg6Fe15(SO4)21(OH)18 · 98H2OTrig. 3 : R3
7.DF.35MetavoltineK2Na6Fe2+Fe3+6O2(SO4)12 · 18H2OTrig.
7.DF.40LannoniteMg2Ca4Al4(SO4)8F8 · 24H2OTet. 4/m : I4/m
7.DF.40VlodavetsiteAlCa2(SO4)2F2Cl · 4H2OTet. 4/m : I4/m
7.DF.45PeretaiteCa(SbO)4(SO4)2(OH)2 · 2H2OMon. 2/m : B2/b
7.DF.50GordaiteNaZn4(SO4)(OH)6Cl · 6H2OTrig. 3 : P3
7.DF.50CalamaiteNa2TiO(SO4)2 · 2H2OOrth. mmm(2/m2/m2/m) : Ibam
7.DF.52Huizingite-(Al)[(NH4)9(SO4)2][(Al,Fe3+)3(OH)2(H2O)4(SO4)6]Tric. 1 : P1
7.DF.55Clairite(NH4)2Fe3(SO4)4(OH)3 · 3H2OTric.
7.DF.55GiacovazzoiteK5Fe3+3O(SO4)6 · 10H2OMon. 2/m : P21/b
7.DF.57MagnanelliiteK3Fe3+2(SO4)4(OH)(H2O)2Mon. 2/m : B2/b
7.DF.60ArzruniteCu4Pb2(SO4)(OH)4Cl6 · 2H2O (?)Orth.
7.DF.60EvdokimoviteTl4(VO)3(SO4)5(H2O)5Mon. 2/m
7.DF.62Bridgesite-(Ce)CaCe2Cu6(SO4)4(OH)12 · 8H2OMon. 2/m : B2/m
7.DF.65ElyitePb4Cu(SO4)O2(OH)4 · H2OMon. 2/m : P21/b
7.DF.70YecoraiteFe3+3Bi5(Te6+O4)2(Te4+O3)O9 · 9H2O
7.DF.70LautenthalitePbCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DF.75RiomarinaiteBi(SO4)(OH) · H2OMon. 2/m
7.DF.80DukeiteBi3+24Cr6+8O57(OH)6 · 3H2OTrig. 3m : P31c

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 14.7385% 4,569 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Fluorescence of ScordariiteHide

Other InformationHide

Notes:
Readily soluble in water at room temperature
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ScordariiteHide

References for ScordariiteHide

Localities for ScordariiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Tuscany
    • Lucca Province
      • Stazzema
        • Sant'Anna di Stazzema
Miyawaki et al. (2019) +2 other references
 
and/or  
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