Bernarlottiite
A valid IMA mineral species
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About Bernarlottiite
Formula:
Pb6(As5Sb3)S18
Colour:
Lead-gray
Lustre:
Metallic
Specific Gravity:
5.601 (Calculated)
Crystal System:
Triclinic
Member of:
Name:
Named in honor of Bernardino Lotti (4 May 1847, Massa Marittima, Tuscany, Italy - 11 January 1933, Rome, Italy), geologist, for his significant contribution to the knowledge of the geology of Tuscany and to the development of the Tuscan mining industry. He also served as president of the Italian Geological Society.
Unique Identifiers
Mindat ID:
46083
Long-form identifier:
mindat:1:1:46083:7
IMA Classification of Bernarlottiite
Approved
IMA Formula:
Pb2+12(As3+10Sb3+6)S2-36
Approval year:
2013
First published:
2017
Type description reference:
Orlandi, Paolo, Biagioni, Cristian, Bonaccorsi, Elena, Moëlo, Yves, Paar, Werner H. (2017) Lead-antimony sulfosalts from Tuscany (Italy) XXI. Bernarlottiite, Pb12(As10Sb6)Σ16S36, a new N = 3.5 member of the sartorite homologous series from the Ceragiola marble quarry: occurrence and crystal structure. European Journal of Mineralogy, 29 (4) 713-726 doi:10.1127/ejm/2017/0029-2625
Classification of Bernarlottiite
2.HC.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Bl | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Bernarlottiite
Metallic
Transparency:
Opaque
Colour:
Lead-gray
Tenacity:
Brittle
Cleavage:
None Observed
Density:
5.601 g/cm3 (Calculated)
Comment:
Calculated for ideal formula
Optical Data of Bernarlottiite
Anisotropism:
Distinctly (air) to strongly (oil) anisotropic, grayish to bluish rotation tints
Bireflectance:
Distinct
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 470nm | 30.0% | 37.5% |
| 546nm | 30.3% | 37.3% |
| 589nm | 29.7% | 36.8% |
| 650nm | 29.3% | 36.2% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 37.5%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White
Internal Reflections:
Abundant, red
Pleochroism:
Weak
Comments:
Shades of gray-blue. Weak in air, distinct in oil.
Chemistry of Bernarlottiite
Mindat Formula:
Pb6(As5Sb3)S18
Element Weights:
Elements listed:
Crystallography of Bernarlottiite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Setting:
P1
Cell Parameters:
a = 23.501(8) Å, b = 8.386(2) Å, c = 23.704(8) Å
α = 89.88(1)°, β = 102.93(1)°, γ = 89.91(1)°
α = 89.88(1)°, β = 102.93(1)°, γ = 89.91(1)°
Ratio:
a:b:c = 2.802 : 1 : 2.827
Unit Cell V:
4553 ų
Z:
3
Morphology:
Acicular on [010]
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.851 Å | (s) |
| 3.794 Å | (s) |
| 3.278 Å | (s) |
| 3.075 Å | (s) |
| 2.748 Å | (vs) |
| 2.363 Å | (s) |
| 2.221 Å | (vs) |
| 1.935 Å | (s) |
Reference:
Orlandi, Paolo, Biagioni, Cristian, Bonaccorsi, Elena, Moëlo, Yves, Paar, Werner H. (2017) Lead-antimony sulfosalts from Tuscany (Italy) XXI. Bernarlottiite, Pb12(As10Sb6)Σ16S36, a new N = 3.5 member of the sartorite homologous series from the Ceragiola marble quarry: occurrence and crystal structure. European Journal of Mineralogy, 29 (4) 713-726 doi:10.1127/ejm/2017/0029-2625
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Bernarlottiite
General Appearance of Type Material:
Lead-gray acicular crystals up to 1 mm in length and few micrometers in width
Place of Conservation of Type Material:
Type material is deposited in the collections of the Museo di Storia Naturale, Universittà di Pisa, Via Roma 79, Calci (Pisa), Italy, catalogue number 19687.
Geological Setting of Type Material:
Cavities in Early Jurassic marbles that experienced an Alpine tectonometamorphic event
Associated Minerals at Type Locality:
Reference:
Orlandi, Paolo, Biagioni, Cristian, Bonaccorsi, Elena, Moëlo, Yves, Paar, Werner H. (2017) Lead-antimony sulfosalts from Tuscany (Italy) XXI. Bernarlottiite, Pb12(As10Sb6)Σ16S36, a new N = 3.5 member of the sartorite homologous series from the Ceragiola marble quarry: occurrence and crystal structure. European Journal of Mineralogy, 29 (4) 713-726 doi:10.1127/ejm/2017/0029-2625
Synonyms of Bernarlottiite
Other Language Names for Bernarlottiite
Dutch:Bernarlottiiet
German:Bernarlottiit
Relationship of Bernarlottiite to other Species
Member of:
Other Members of Sartorite Group:
| Argentobaumhauerite | Ag1.5Pb22As33.5S72 | Tric. 1 : P1 |
| Argentodufrénoysite | Ag3Pb26As35S80 | Tric. 1 : P1 |
| Argentoliveingite | Ag3+xPb36-2xAs51+xS112 | Tric. 1 : P1 |
| Barikaite | Ag3Pb10(Sb8As11)S40 | Mon. 2/m : P21/b |
| Baumhauerite | Pb12As16S36 | Tric. 1 : P1 |
| Boscardinite | TlPb4(Sb7As2)S18 | Tric. 1 : P1 |
| Carducciite | (Ag2Sb2)Pb12(As,Sb)16S40 | Mon. 2/m : P21/b |
| Dekatriasartorite | TlPb58As97S204 | Mon. 2/m : P21/b |
| Dufrénoysite | Pb2As2S5 | Mon. 2 : P21 |
| Écrinsite | AgTl3Pb4As11Sb9S36 | Tric. 1 : P1 |
| Enneasartorite | Tl6Pb32As70S140 | Mon. 2/m : P21/b |
| Geuerite | Ag2Tl4Pb4As22S40 | Mon. 2/m : P21/b |
| Giuşcăite | Ag2Tl4Pb4As20Sb2S40 | Mon. m |
| Guettardite | Pb8(Sb0.56As0.44)16S32 | Mon. 2/m : P21/b |
| Hendekasartorite | Tl2Pb48As82S172 | Mon. 2/m : P21/b |
| Heptasartorite | Tl7Pb22As55S108 | Mon. 2/m : P21/b |
| Hyršlite | Pb8As10Sb6S32 | Mon. 2 : P21 |
| Incomsartorite | Tl6Pb144As246S516 | Mon. 2/m |
| Interliveingite | AgPb18As25S56 | Mon. 2 : P21 |
| Liveingite | Pb20As24S56 | Mon. 2 : P21 |
| Parapierrotite | TlSb5S8 | Mon. m |
| Philrothite | TlAs3S5 | Mon. 2/m : P21/b |
| Pierrotite | Tl2(Sb,As)10S16 | Orth. mm2 : Pna21 |
| Polloneite | AgPb46As26Sb23S120 | Mon. 2 : P21 |
| Rathite | Ag2Pb12-xTlx/2As18+x/2S40 | Mon. 2/m : P21/b |
| Sartorite | PbAs2S4 | Mon. 2/m : P21/m |
| Twinnite | Pb0.8Tl0.1Sb1.3As0.8S4 | Mon. 2/m |
| Veenite | Pb16Sb9-xAs7+xS40, x ~ 0-0.5 | Mon. 2 : P21 |
Related Minerals - Strunz-mindat Grouping
| 2.HC. | Huntingdonite | Pb19Sb16As6S51Cl2 |
| 2.HC. | Moiraite | Pb12Sb8As8S36 |
| 2.HC.05f | Parapierrotite | TlSb5S8 |
| 2.HC.05g | Marumoite | Pb32As40S92 |
| 2.HC.05b | Baumhauerite II | |
| 2.HC.05d | Rathite | Ag2Pb12-xTlx/2As18+x/2S40 |
| 2.HC.05e | Heptasartorite | Tl7Pb22As55S108 |
| 2.HC.05d | Dufrénoysite | Pb2As2S5 |
| 2.HC.05e | Hendekasartorite | Tl2Pb48As82S172 |
| 2.HC.05b | Argentobaumhauerite | Ag1.5Pb22As33.5S72 |
| 2.HC.05c | Argentoliveingite | Ag3+xPb36-2xAs51+xS112 |
| 2.HC.05b | Baumhauerite | Pb12As16S36 |
| 2.HC.05d | Veenite | Pb16Sb9-xAs7+xS40, x ~ 0-0.5 |
| 2.HC.05e | Dekatriasartorite | TlPb58As97S204 |
| 2.HC.05a | Hyršlite | Pb8As10Sb6S32 |
| 2.HC.05e | Incomsartorite | Tl6Pb144As246S516 |
| 2.HC.05c | Liveingite | Pb20As24S56 |
| 2.HC.05c | Johnjamborite | Pb14Sb8.5As7.5S38 |
| 2.HC.05f | Pierrotite | Tl2(Sb,As)10S16 |
| 2.HC.05d | Rathite-IV | PbAs2S4 |
| 2.HC.05d | Argentodufrénoysite | Ag3Pb26As35S80 |
| 2.HC.05e | Écrinsite | AgTl3Pb4As11Sb9S36 |
| 2.HC.05a | Sartorite | PbAs2S4 |
| 2.HC.05a | Twinnite | Pb0.8Tl0.1Sb1.3As0.8S4 |
| 2.HC.05f | Philrothite | TlAs3S5 |
| 2.HC.05h | Polloneite | AgPb46As26Sb23S120 |
| 2.HC.05a | Guettardite | Pb8(Sb0.56As0.44)16S32 |
| 2.HC.10a | Fülöppite | Pb3Sb8S15 |
| 2.HC.10d | Semseyite | Pb9Sb8S21 |
| 2.HC.10d | Rayite | Pb8(Ag,Tl)2Sb8S21 |
| 2.HC.10c | Heteromorphite | Pb7Sb8S19 |
| 2.HC.10b | Plagionite | Pb5Sb8S17 |
| 2.HC.15 | Falkmanite | Pb3Sb2S6 |
| 2.HC.15 | Boulangerite | Pb5Sb4S11 |
| 2.HC.20 | Robinsonite | Pb4Sb6S13 |
| 2.HC.25 | Moëloite | Pb6Sb6S14(S3) |
| 2.HC.30 | Dadsonite | Pb23Sb25S60Cl |
| 2.HC.35 | Zoubekite | AgPb4Sb4S10 |
| 2.HC.35 | Proto-owyheeite | Ag9Pb40Sb45S112 |
| 2.HC.35 | Owyheeite | Ag3Pb10Sb11S28 |
| 2.HC.40 | Parasterryite | Ag4Pb20Sb14As10S58 |
| 2.HC.50 | Lopatkaite | Pb5Sb3AsS11 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Bernarlottiite
mindat.org URL:
https://www.mindat.org/min-46083.html
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References for Bernarlottiite
Reference List:
Orlandi, Paolo, Del Chiaro, Lorenzo, Pagano, Renato (1996) Minerals of the Seravezza Marble, Tuscany, Italy, in January - February 1996. The Mineralogical Record, 27 (1) Tucson. 47-58(as Sb-rich baumhauerite)
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) New minerals and nomenclature modifications approved in 2014, CNMNC Newsletter No 20. Mineralogical Magazine, 78 (3) 549-558 doi:10.1180/minmag.2014.078.3.05
Orlandi, Paolo, Biagioni, Cristian, Bonaccorsi, Elena, Moëlo, Yves, Paar, Werner H. (2017) Lead-antimony sulfosalts from Tuscany (Italy) XXI. Bernarlottiite, Pb12(As10Sb6)Σ16S36, a new N = 3.5 member of the sartorite homologous series from the Ceragiola marble quarry: occurrence and crystal structure. European Journal of Mineralogy, 29 (4) 713-726 doi:10.1127/ejm/2017/0029-2625
Localities for Bernarlottiite
Showing 3 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Italy (TL) | |
| Williams et al. (2014) +2 other references |
Romania | |
| Dincă et al. (2025) |
Russia | |
| Kasatkin et al. (2021) |
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Ceragiola quarries, Seravezza quarrying basin, Seravezza, Lucca Province, Tuscany, Italy