Rayite
A valid IMA mineral species
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About Rayite
Formula:
Pb8(Ag,Tl)2Sb8S21
Colour:
Lead-gray
Lustre:
Metallic
Hardness:
2½
Specific Gravity:
6.13 (Calculated)
Crystal System:
Monoclinic
Name:
Named after Professor Santosh Kumar Ray (1908–1976), Indian petrologist, President College, Calcutta, India.
Unique Identifiers
Mindat ID:
3374
Long-form identifier:
mindat:1:1:3374:5
Similar Names
| Gayite | A valid IMA mineral species | NaMn2+Fe53+(PO4)4(OH)6 · 2H2O |
| Grayite | A valid IMA mineral species - grandfathered | (Th,Pb,Ca)(PO4) · H2O |
| Raite | A valid IMA mineral species | Mn2+Mn22+Na2(◻1.75Ti0.25)Si8O20(OH)2(H2O)4 · Na(H2O)6 |
| Rajite | A valid IMA mineral species | Cu(Te24+O5) |
| Ranite | A synonym of Gonnardite | |
| Rathite | A valid IMA mineral species - grandfathered | Ag2Pb12-xTlx/2As18+x/2S40 |
IMA Classification of Rayite
Approved
IMA Formula:
(Ag1+,Tl1+)2Pb2+8Sb3+8S2-21
Approval year:
1982
First published:
1983
Classification of Rayite
2.HC.10d
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb
3.6.20.5
3 : SULFOSALTS
6 : 2 < ø < 2.49
3 : SULFOSALTS
6 : 2 < ø < 2.49
5.7.46
5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
7 : Sulpharsenites etc. of Pb and other metals
5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
7 : Sulpharsenites etc. of Pb and other metals
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ray | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Rayite
Metallic
Transparency:
Opaque
Colour:
Lead-gray
Streak:
Lead-gray
Hardness:
2½ on Mohs scale
Cleavage:
None Observed
Density:
6.13 g/cm3 (Calculated)
Optical Data of Rayite
Anisotropism:
Perceptible, dark blue to dark reddish brown
Bireflectance:
Weak
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 400nm | 38.3% | 41.8% |
| 420nm | 38.0% | 41.3% |
| 440nm | 37.8% | 40.9% |
| 460nm | 37.6% | 40.6% |
| 480nm | 37.6% | 40.4% |
| 500nm | 37.5% | 40.1% |
| 520nm | 37.5% | 39.9% |
| 540nm | 37.5% | 39.6% |
| 560nm | 37.4% | 39.4% |
| 580nm | 37.2% | 38.9% |
| 600nm | 37.0% | 38.4% |
| 620nm | 36.7% | 37.9% |
| 640nm | 36.3% | 37.5% |
| 660nm | 35.9% | 37.3% |
| 680nm | 35.6% | 37.2% |
| 700nm | 35.3% | 37.1% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 41.8%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White with greenish and blueish tints
Internal Reflections:
None
Pleochroism:
Weak
Comments:
Greenish to greenish-blue.
Chemistry of Rayite
Mindat Formula:
Pb8(Ag,Tl)2Sb8S21
Element Weights:
Common Impurities:
Cu
Crystallography of Rayite
Crystal System:
Monoclinic
Cell Parameters:
a = 13.60(2) Å, b = 11.96(3) Å, c = 24.49(5) Å
β = 103.94(12)°
β = 103.94(12)°
Ratio:
a:b:c = 1.137 : 1 : 2.048
Unit Cell V:
3,866.13 ų (Calculated from Unit Cell)
Z:
4
Comment:
Point Group: n.d. ; Space Group: n.d.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.37 Å | (100) |
| 3.26 Å | (90) |
| 2.98 Å | (50) |
| 3.90 Å | (30) |
| 3.74 Å | (30) |
| 2.06 Å | (30) |
| 2.88 Å | (20) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Rayite
General Appearance of Type Material:
Tabular 30 µm grains and 0.5 mm patches.
Place of Conservation of Type Material:
Indian Institute of Technology, Kharagpur, India.
Institute of Mineralogy and Geochemistry of Rare Elements, Moscow, Russia.
Institute of Mineralogy and Geochemistry of Rare Elements, Moscow, Russia.
Geological Setting of Type Material:
Polymetallic deposit.
Associated Minerals at Type Locality:
Synonyms of Rayite
Other Language Names for Rayite
Related Minerals - Strunz-mindat Grouping
| 2.HC. | Bernarlottiite | Pb6(As5Sb3)S18 |
| 2.HC. | Huntingdonite | Pb19Sb16As6S51Cl2 |
| 2.HC. | Moiraite | Pb12Sb8As8S36 |
| 2.HC.05f | Parapierrotite | TlSb5S8 |
| 2.HC.05g | Marumoite | Pb32As40S92 |
| 2.HC.05b | Baumhauerite II | |
| 2.HC.05d | Rathite | Ag2Pb12-xTlx/2As18+x/2S40 |
| 2.HC.05e | Heptasartorite | Tl7Pb22As55S108 |
| 2.HC.05d | Dufrénoysite | Pb2As2S5 |
| 2.HC.05e | Hendekasartorite | Tl2Pb48As82S172 |
| 2.HC.05b | Argentobaumhauerite | Ag1.5Pb22As33.5S72 |
| 2.HC.05c | Argentoliveingite | Ag3+xPb36-2xAs51+xS112 |
| 2.HC.05b | Baumhauerite | Pb12As16S36 |
| 2.HC.05d | Veenite | Pb16Sb9-xAs7+xS40, x ~ 0-0.5 |
| 2.HC.05e | Dekatriasartorite | TlPb58As97S204 |
| 2.HC.05a | Hyršlite | Pb8As10Sb6S32 |
| 2.HC.05e | Incomsartorite | Tl6Pb144As246S516 |
| 2.HC.05c | Liveingite | Pb20As24S56 |
| 2.HC.05c | Johnjamborite | Pb14Sb8.5As7.5S38 |
| 2.HC.05f | Pierrotite | Tl2(Sb,As)10S16 |
| 2.HC.05d | Rathite-IV | PbAs2S4 |
| 2.HC.05d | Argentodufrénoysite | Ag3Pb26As35S80 |
| 2.HC.05e | Écrinsite | AgTl3Pb4As11Sb9S36 |
| 2.HC.05a | Sartorite | PbAs2S4 |
| 2.HC.05a | Twinnite | Pb0.8Tl0.1Sb1.3As0.8S4 |
| 2.HC.05f | Philrothite | TlAs3S5 |
| 2.HC.05h | Polloneite | AgPb46As26Sb23S120 |
| 2.HC.05a | Guettardite | Pb8(Sb0.56As0.44)16S32 |
| 2.HC.10a | Fülöppite | Pb3Sb8S15 |
| 2.HC.10d | Semseyite | Pb9Sb8S21 |
| 2.HC.10c | Heteromorphite | Pb7Sb8S19 |
| 2.HC.10b | Plagionite | Pb5Sb8S17 |
| 2.HC.15 | Falkmanite | Pb3Sb2S6 |
| 2.HC.15 | Boulangerite | Pb5Sb4S11 |
| 2.HC.20 | Robinsonite | Pb4Sb6S13 |
| 2.HC.25 | Moëloite | Pb6Sb6S14(S3) |
| 2.HC.30 | Dadsonite | Pb23Sb25S60Cl |
| 2.HC.35 | Zoubekite | AgPb4Sb4S10 |
| 2.HC.35 | Proto-owyheeite | Ag9Pb40Sb45S112 |
| 2.HC.35 | Owyheeite | Ag3Pb10Sb11S28 |
| 2.HC.40 | Parasterryite | Ag4Pb20Sb14As10S58 |
| 2.HC.50 | Lopatkaite | Pb5Sb3AsS11 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Rayite
mindat.org URL:
https://www.mindat.org/min-3374.html
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References for Rayite
Localities for Rayite
Showing 2 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
India | |
| Mukherjee et al. (1998) |
| - (1983) +1 other reference |
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The
Dariba Mine, Rajpura-Dariba mine, Rajsamand District, Udaipur Division, Rajasthan, India