Kirchhoffite
A valid IMA mineral species
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About Kirchhoffite
Formula:
Cs(BSi2O6)
Colour:
Colorless
Lustre:
Vitreous, Sub-Vitreous
Hardness:
6 - 6½
Specific Gravity:
3.622
Crystal System:
Tetragonal
Member of:
Name:
Named in 2010 by Atali A. Agakhanov, Leonid A. Pautov, Vladimir Yu. Karpenko, Elena Sokolova, and Frank C. Hawthorne in honor of Gustav Kirchhoff [b. March 12, 1824 in Königsberg, East Prussia (Germany), d. October 17, 1887 in Berlin, Germany] who was co-discoverer of cesium and who co-developed the field of chemical spectroscopy. Kirchhoff also developed, among many other discoveries, laws governing electrical circuits and proposed the fundamentals of what he termed "black body radiation."
Unique Identifiers
Mindat ID:
40071
Long-form identifier:
mindat:1:1:40071:0
IMA Classification of Kirchhoffite
Approved
IMA Formula:
CsBSi2O6
Approval year:
2009
First published:
2012
Type description reference:
Classification of Kirchhoffite
9.GB.05
9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
B : Chains of single connected 4-membered rings
9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
B : Chains of single connected 4-membered rings
77.1.1.8
77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Khf | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Kirchhoffite
Vitreous, Sub-Vitreous
Transparency:
Transparent
Colour:
Colorless
Hardness:
6 - 6½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Conchoidal
Density:
3.622 g/cm3 (Measured) 3.639 g/cm3 (Calculated)
Optical Data of Kirchhoffite
Type:
Uniaxial (+)
RI values:
nω = 1.592(2) nε = 1.600(2)
Birefringence:
0.008
Max. Birefringence:
δ = 0.008
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate
Pleochroism:
Non-pleochroic
Chemistry of Kirchhoffite
Mindat Formula:
Cs(BSi2O6)
Element Weights:
Elements listed:
Crystallography of Kirchhoffite
Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Space Group:
I41/acd
Setting:
I41/acd
Cell Parameters:
a = 13.019(2) Å, c = 12.900(2) Å
Ratio:
a:c = 1 : 0.991
Unit Cell V:
2,186.48 ų (Calculated from Unit Cell)
Z:
16
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0019219 | Kirchhoffite | Agakhanov A A, Pautov L A, Karpenko V Y, Sokolova E, Hawthorne F C (2012) Kirchhoffite, CsBSi2O6, a new mineral species from the Darai-Pioz Alkaline Massif,Tajikistan: Description and crystal structure The Canadian Mineralogist 50 523-529 | 2012 | Upper Dara-Pioz alkaline massif, Garm district, Tajikistan | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 5.32 Å | (32) |
| 3.48 Å | (82) |
| 3.26 Å | (100) |
| 2.770 Å | (67) |
| 2.373 Å | (21) |
| 2.294 Å | (41) |
| 2.109 Å | (34) |
| 1.768 Å | (22) |
Reference:
Comments:
The crystal structure of kirchhoffite was refined to an R1 index of 3.1% based on 487 observed reflections collected on a four-circle diffractometer with MoKα X-radiation. In the structure, there are two tetrahedrally coordinated sites: Si is occupied by silicon, Si–O = 1.610 Å, B is occupied by boron, B–O = 1.465 Å, and Cs is [12]-coordinated, Cs–O = 3.301 Å. Tetrahedra form a [BSi2O6] framework, the topology of which is identical to that of tetragonal pollucite, CsAlSi2O6. The [12]-coordinated Cs atoms occupy the channels along [111] formed by six-membered rings of tetrahedra. Kirchhoffite, CsBSi2O6, is a B analogue of the tetragonal modification of pollucite.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Kirchhoffite
General Appearance of Type Material:
Occurs as colorless equant grains 10 to 80 μm in diameter
Place of Conservation of Type Material:
Fersman Mineralogical Museum, Moscow, russia, reg. no. 3923/1
Associated Minerals at Type Locality:
Synonyms of Kirchhoffite
Other Language Names for Kirchhoffite
Relationship of Kirchhoffite to other Species
Member of:
Other Members of Zeolite Group:
| Alflarsenite | NaCa2Be3Si4O13(OH) · 2H2O | Mon. 2 : P21 |
| Amicite | K2Na2Al4Si4O16 · 5H2O | Mon. 2 |
| Ammonioleucite | (NH4)(AlSi2O6) | Tet. 4/m : I41/a |
| Analcime | Na(AlSi2O6) · H2O | Tric. 1 : P1 |
| Arzamastsevite | K6Al5Si6O20(OH)4Cl | Tet. 42m : I42m |
| Bellbergite | (K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2O | Hex. |
| Bikitaite | LiAlSi2O6 · H2O | Tric. 1 : P1 |
| Boggsite | Ca8Na3(Si,Al)96O192 · 70H2O | Orth. mmm(2/m2/m2/m) : Imma |
| Brewsterite Subgroup | Zeolite Group. | |
| Chabazite-Levyne Subgroup | M[Al2Si4O12] · 6H2O | |
| Chiavennite | CaMnBe2Si5O13(OH)2 · 2H2O | Mon. 2/m : P21/b |
| Clinoptilolite Subgroup | (Na/Ca/K)3-6[Al6-7Si29-30O72] · 20H2O | |
| Cowlesite | CaAl2Si3O10 · 6H2O | Orth. mmm(2/m2/m2/m) |
| Dachiardite Subgroup | Zeolite Group. | |
| Direnzoite | NaK6MgCa2(Al13Si47O120) · 36H2O | Orth. mmm(2/m2/m2/m) : Pmmn |
| Edingtonite | Ba[Al2Si3O10] · 4H2O | Orth. 222 : P212121 |
| Epistilbite | CaAl2Si6O16 · 5H2O | Mon. |
| Erionite Subgroup | M2[Al4Si14O36] · 15H2O | |
| Fabrièsite | Na3Al3Si3O12 · 2H2O | Orth. mm2 : Pmm2 |
| Faujasite Subgroup | M3.5[Al7Si17O48] · 32H2O | |
| Ferrierite Subgroup | Name used for unanalysed specimens that could be either ferrierite-K, ferrierite-Mg, ... | |
| Ferrochiavennite | Ca1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2O | Mon. 2/m : P21/b |
| Flörkeite | (K3Ca2Na)[Al8Si8O32] · 12H2O | Tric. 1 : P1 |
| Garronite Subgroup | ||
| Gaultite | Na4Zn2Si7O18 · 5H2O | Orth. mm2 : Fdd2 |
| Gismondine Subgroup | Zeolite Group. | |
| Gmelinite Subgroup | In 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K. | |
| Gobbinsite | Na5(Si11Al5)O32 · 11H2O | Orth. mmm(2/m2/m2/m) : Pnma |
| Goosecreekite | Ca[Al2Si6O16] · 5H2O | Mon. 2 : P21 |
| Gottardiite | Na3Mg3Ca5Al19Si117O272 · 93H2O | Orth. mmm(2/m2/m2/m) : Cmca |
| Heulandite Subgroup | (Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O | |
| Hsianghualite | Ca3Li2(Be3Si3O12)F2 | Iso. 23 : I213 |
| Kalborsite | K6Al4BSi6O20(OH)4Cl | Tet. 42m : P421c |
| Laumontite | CaAl2Si4O12 · 4H2O | Mon. 2/m : B2/m |
| Leucite | K(AlSi2O6) | Tet. 4/m : I41/a |
| Limousinite | BaCa[Be4P4O16] · 6H2O | Mon. 2/m : P21/b |
| Lithosite | K6Al4Si8O25 · 2H2O | Mon. |
| Loomisite | Ba[Be2P2O8] · H2O | Mon. m |
| Lovdarite | K2Na6Be4Si14O36 · 9H2O | Orth. mm2 |
| Maricopaite | Pb7Ca2(Si,Al)48O100 · 32H2O | Orth. |
| Martinandresite | Ba2(Al4Si12O32) · 10H2O | Orth. mmm(2/m2/m2/m) : Pmmn |
| Mazzite Subgroup | Zeolite Group. | |
| Meierite | Ba44Si66Al30O192Cl25(OH)33 | Iso. m3m(4/m32/m) : Im3m |
| Merlinoite | K5Ca2(Si23Al9)O64 · 24H2O | Orth. mmm(2/m2/m2/m) : Immm |
| Montesommaite | (K,Na)9Al9Si23O64 · 10H2O | Orth. mm2 : Fdd2 |
| Mordenite | (Na2,Ca,K2)4(Al8Si40)O96 · 28H2O | Orth. |
| Mountainite | KNa2Ca2[Si8O19(OH)] · 6H2O | Mon. 2/m : P2/b |
| Mutinaite | Na3Ca4Si85Al11O192 · 60H2O | Orth. mmm(2/m2/m2/m) : Pnma |
| Nabesite | Na2BeSi4O10 · 4H2O | Orth. 222 : P212121 |
| Natrolite Subgroup | A subgroup of the Zeolite Group. | |
| Offretite | KCaMg(Si13Al5)O36 · 15H2O | Hex. 6m2 : P6m2 |
| Pahasapaite | Li8(Ca,Li,K)10.5Be24(PO4)24 · 38H2O | Iso. 23 : I23 |
| Parthéite | Ca2(Si4Al4) O15 (OH)2 · 4H2O | Mon. 2/m : B2/b |
| Paulingite Subgroup | Paulingite was originally described in 1960. | |
| Perlialite | K9Na(Ca,Sr)[Al2Si4O12]6 · 15H2O | Hex. 6/mmm(6/m2/m2/m) : P6/mmm |
| Phillipsite Subgroup | (Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O | |
| Pollucite | (Cs,Na)2(Al2Si4O12) · 2H2O | Iso. m3m(4/m32/m) : Ia3d |
| Roggianite | Ca2Be(OH)2Al2Si4O13 · 2.5H2O | Tet. 4/mmm(4/m2/m2/m) : I4/mcm |
| Rongibbsite | Pb2(Si4Al)O11(OH) | Mon. 2/m : B2/m |
| Stilbite Subgroup | M6-7[Al8-9Si27-28O72] · nH2O | |
| Terranovaite | (Na,Ca)8(Si68Al12)O160 · 29H2O | Orth. |
| Thomsonite Subgroup | The large majority of "thomsonite" is thomsonite-Ca. | |
| Thornasite | Na12Th4+3(Si8O19)4 · 18H2O | Trig. 3m : R3m |
| Tschernichite | (Ca,Na2)[Al2Si4O12] · 4-8H2O | Tet. 4/mmm(4/m2/m2/m) : P4/mmm |
| Tschörtnerite | Ca4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2O | Iso. m3m(4/m32/m) : Fm3m |
| 'UM1996-38-SiO:AlCaHNa' | Na-Ca-Al-Si-O-H | |
| 'UM1999-33-SiO:AlHKNa' | K7Na5Al12Si20O64 · 24H2O | |
| 'UM2002-40-SiO:AlCaHKMgNa' | (Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2O | Tet. 422 : P4122 |
| 'Unnamed (Ca analogue of Merlinoite)' | (Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ? | |
| Wairakite | Ca(Al2Si4O12) · 2H2O | Mon. 2/m : B2/m |
| Weinebeneite | CaBe3(PO4)2(OH)2 · 4H2O | Mon. m : Bb |
| Wenkite | (Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2O | Hex. 6m2 : P62m |
| Wilancookite | (Ba5Li2◻)Ba6Be24P24O96 · 26H2O | Iso. 23 : I23 |
| Willhendersonite | KCa[Al3Si3O12] · 5H2O | Tric. 1 : P1 |
| Yugawaralite | CaAl2Si6O16 · 4H2O | Mon. m : Pb |
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 9.GB.05 | Fabrièsite | Na3Al3Si3O12 · 2H2O |
| 9.GB.05 | Lithosite | K6Al4Si8O25 · 2H2O |
| 9.GB.05 | Wairakite | Ca(Al2Si4O12) · 2H2O |
| 9.GB.05 | Hsianghualite | Ca3Li2(Be3Si3O12)F2 |
| 9.GB.05 | Leucite | K(AlSi2O6) |
| 9.GB.05 | Pollucite | (Cs,Na)2(Al2Si4O12) · 2H2O |
| 9.GB.05 | Ammonioleucite | (NH4)(AlSi2O6) |
| 9.GB.05 | Analcime | Na(AlSi2O6) · H2O |
| 9.GB.10 | Laumontite | CaAl2Si4O12 · 4H2O |
| 9.GB.15 | Yugawaralite | CaAl2Si6O16 · 4H2O |
| 9.GB.20 | Roggianite | Ca2Be(OH)2Al2Si4O13 · 2.5H2O |
| 9.GB.25 | Goosecreekite | Ca[Al2Si6O16] · 5H2O |
| 9.GB.30 | Montesommaite | (K,Na)9Al9Si23O64 · 10H2O |
| 9.GB.35 | Parthéite | Ca2(Si4Al4) O15 (OH)2 · 4H2O |
Fluorescence of Kirchhoffite
Not fluorescent
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Kirchhoffite
mindat.org URL:
https://www.mindat.org/min-40071.html
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References for Kirchhoffite
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. (2010) New minerals and nomenclature modifications approved in 2010, CNMNC Newsletter No 2. Mineralogical Magazine, 74 (2) 375-377 doi:10.1180/s0026461x00056036
Localities for Kirchhoffite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Tajikistan (TL) | |
| Williams et al. (2010) +4 other references |
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The
Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan