This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.

Focus:

In focus

Chemistry of HsianghualiteHide

Mindat Formula:

Ca₃Li₂(Be₃Si₃O₁₂)F₂

Element Weights:

Element	% weight
O	40.386 %
Ca	25.291 %
Si	17.723 %
F	7.993 %
Be	5.687 %
Li	2.920 %

Calculated from ideal end-member formula.

Elements listed:

Be, Ca, F, Li, O, Si - search for minerals with similar chemistry

Common Impurities:

Al,Fe,Mg,Na,K

Crystallography of HsianghualiteHide

Crystal System:

Isometric

Class (H-M):

23 - Tetartoidal

Space Group:

I2₁3

Cell Parameters:

a = 12.897(4) Å

Unit Cell V:

2,145.19 Å³ (Calculated from Unit Cell)

Morphology:

Crystals modifed by the dodecahedron, to 1.5 cm; granular, massive.

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0015620	Hsianghualite	Rastsvetaeva R K, Rekhlova O Y, Andrianov V I, Malinovskii Y A (1991) Crystal structure of hsianghualite Soviet Physics Doklady 36 11-13		1991	China	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Hsianghualite'
loop_
_publ_author_name
'Rastsvetaeva R K'
'Rekhlova O Y'
'Andrianov V I'
'Malinovskii Y A'
_journal_name_full 'Soviet Physics Doklady'
_journal_volume 36 
_journal_year 1991
_journal_page_first 11
_journal_page_last 13
_publ_section_title
;
 Crystal structure of hsianghualite
;
_database_code_amcsd 0015620
_chemical_compound_source 'China'
_chemical_formula_sum 'Li2 Ca3 Be3 Si3 O12 F2'
_cell_length_a 12.864
_cell_length_b 12.864
_cell_length_c 12.864
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 2128.767
_exptl_crystal_density_diffrn      2.967
_symmetry_space_group_name_H-M 'I 21 3'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  '1/2-z,-x,1/2+y'
  '-z,1/2-x,+y'
  '-z,1/2+x,1/2-y'
  '1/2-z,+x,-y'
  '1/2+z,1/2-x,-y'
  '+z,-x,1/2-y'
  'z,x,y'
  '1/2+z,1/2+x,1/2+y'
  '1/2+y,1/2-z,-x'
  '+y,-z,1/2-x'
  '1/2-y,-z,1/2+x'
  '-y,1/2-z,+x'
  '-y,1/2+z,1/2-x'
  '1/2-y,+z,-x'
  'y,z,x'
  '1/2+y,1/2+z,1/2+x'
  '-x,1/2+y,1/2-z'
  '1/2-x,+y,-z'
  '1/2+x,1/2-y,-z'
  '+x,-y,1/2-z'
  '1/2-x,-y,1/2+z'
  '-x,1/2-y,+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Li1   0.47690   0.47690   0.47690   0.02406
Li2   0.22960   0.22960   0.22960   0.03293
Ca1   0.08630   0.00000   0.25000   0.02318
Ca2   0.50000   0.25000   0.34450   0.02394
Be   0.37080   0.32960   0.09350   0.02406
Si   0.12390   0.15530   0.42030   0.02115
O1   0.10340   0.39340   0.01210   0.02292
O2   0.06740   0.38240   0.20770   0.02254
O3   0.35840   0.14950   0.26200   0.02356
O4   0.36700   0.18240   0.45730   0.02406
F1   0.39540   0.39540   0.39540   0.02786
F2   0.14540   0.14540   0.14540   0.02660

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
2.746 Å	(100)
2.209 Å	(100)
2.090 Å	(90)
1.753 Å	(70)
3.443 Å	(60)
1.691 Å	(52)
1.228 Å	(45)

Comments:

Hunan Province, China.

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Near-surface Processes
22 : Hydration and low-? subsurface aqueous alteration (see also #23)

Type Occurrence of HsianghualiteHide

Type Locality:

ⓘ Xianghualing Mine, Xianghualing Sn-polymetallic ore field, Linwu Co., Chenzhou, Hunan, China

General Appearance of Type Material:

White trisoctahedral or dodecahedral crystals and granular masses.

Place of Conservation of Type Material:

National Museum for Geology, Beijing, China, number B00744 (type).
Musée Géologique Cantonal, Lausanne, Switzerland, number MGL 79982 (type).

Geological Setting of Type Material:

Phlogopite veins in metamorphosed Devonian limestone that was intruded by granite.

Reference:

Huang W.-H., Tu S., Wang K.-H., Chao C.-L., Yu C.-C. (1958) Hsiang-hua-shih, a new beryllium mineral. Ti-chih-yueh-k'an: 7: 35-35 (in Chinese).

Other Language Names for HsianghualiteHide

Dutch:Hsianghualiet

German:Hsianghualith
Hsianghualit

Norwegian:Hsianghualitt

Russian:Сянхуалит

Simplified Chinese:香花石

Spanish:Hsianghualita

Traditional Chinese:香花石

Relationship of Hsianghualite to other SpeciesHide

Member of:

Zeolite Group

Other Members of Zeolite Group:

Alflarsenite	NaCa₂Be₃Si₄O₁₃(OH) · 2H₂O	Mon. 2 : P2₁
Amicite	K₂Na₂Al₄Si₄O₁₆ · 5H₂O	Mon. 2
Ammonioleucite	(NH₄)(AlSi₂O₆)	Tet. 4/m : I4₁/a
Analcime	Na(AlSi₂O₆) · H₂O	Tric. 1 : P1
Arzamastsevite	K₆Al₅Si₆O₂₀(OH)₄Cl	Tet. 42m : I42m
Bellbergite	(K,Ba,Sr)₂Sr₂Ca₂(Ca,Na)₄[Al₃Si₃O₁₂]₆ · 30H₂O	Hex.
Bikitaite	LiAlSi₂O₆ · H₂O	Tric. 1 : P1
Boggsite	Ca₈Na₃(Si,Al)₉₆O₁₉₂ · 70H₂O	Orth. mmm(2/m2/m2/m) : Imma
Brewsterite Subgroup	Zeolite Group.
Chabazite-Levyne Subgroup	M[Al₂Si₄O₁₂] · 6H₂O
Chiavennite	CaMnBe₂Si₅O₁₃(OH)₂ · 2H₂O	Mon. 2/m : P2₁/b
Clinoptilolite Subgroup	(Na/Ca/K)_3-6[Al_6-7Si_29-30O₇₂] · 20H₂O
Cowlesite	CaAl₂Si₃O₁₀ · 6H₂O	Orth. mmm(2/m2/m2/m)
Dachiardite Subgroup	Zeolite Group.
Direnzoite	NaK₆MgCa₂(Al₁₃Si₄₇O₁₂₀) · 36H₂O	Orth. mmm(2/m2/m2/m) : Pmmn
Edingtonite	Ba[Al₂Si₃O₁₀] · 4H₂O	Orth. 222 : P2₁2₁2₁
Epistilbite	CaAl₂Si₆O₁₆ · 5H₂O	Mon.
Erionite Subgroup	M₂[Al₄Si₁₄O₃₆] · 15H₂O
Fabrièsite	Na₃Al₃Si₃O₁₂ · 2H₂O	Orth. mm2 : Pmm2
Faujasite Subgroup	M_3.5[Al₇Si₁₇O₄₈] · 32H₂O
Ferrierite Subgroup	Name used for unanalysed specimens that could be either ferrierite-K, ferrierite-Mg, ...
Ferrochiavennite	Ca_1-2Fe[(Si,Al,Be)₅Be₂O₁₃(OH)₂] · 2H₂O	Mon. 2/m : P2₁/b
Flörkeite	(K₃Ca₂Na)[Al₈Si₈O₃₂] · 12H₂O	Tric. 1 : P1
Garronite Subgroup
Gaultite	Na₄Zn₂Si₇O₁₈ · 5H₂O	Orth. mm2 : Fdd2
Gismondine Subgroup	Zeolite Group.
Gmelinite Subgroup	In 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
Gobbinsite	Na₅(Si₁₁Al₅)O₃₂ · 11H₂O	Orth. mmm(2/m2/m2/m) : Pnma
Goosecreekite	Ca[Al₂Si₆O₁₆] · 5H₂O	Mon. 2 : P2₁
Gottardiite	Na₃Mg₃Ca₅Al₁₉Si₁₁₇O₂₇₂ · 93H₂O	Orth. mmm(2/m2/m2/m) : Cmca
Heulandite Subgroup	(Na/Ca/K)_5-6[Al_8-9 Si_27-28 O₇₂] · nH₂O
Kalborsite	K₆Al₄BSi₆O₂₀(OH)₄Cl	Tet. 42m : P42₁c
Kirchhoffite	Cs(BSi₂O₆)	Tet. 4/mmm(4/m2/m2/m) : I4₁/acd
Laumontite	CaAl₂Si₄O₁₂ · 4H₂O	Mon. 2/m : B2/m
Leucite	K(AlSi₂O₆)	Tet. 4/m : I4₁/a
Limousinite	BaCa[Be₄P₄O₁₆] · 6H₂O	Mon. 2/m : P2₁/b
Lithosite	K₆Al₄Si₈O₂₅ · 2H₂O	Mon.
Loomisite	Ba[Be₂P₂O₈] · H₂O	Mon. m
Lovdarite	K₂Na₆Be₄Si₁₄O₃₆ · 9H₂O	Orth. mm2
Maricopaite	Pb₇Ca₂(Si,Al)₄₈O₁₀₀ · 32H₂O	Orth.
Martinandresite	Ba₂(Al₄Si₁₂O₃₂) · 10H₂O	Orth. mmm(2/m2/m2/m) : Pmmn
Mazzite Subgroup	Zeolite Group.
Meierite	Ba₄₄Si₆₆Al₃₀O₁₉₂Cl₂₅(OH)₃₃	Iso. m3m(4/m32/m) : Im3m
Merlinoite	K₅Ca₂(Si₂₃Al₉)O₆₄ · 24H₂O	Orth. mmm(2/m2/m2/m) : Immm
Montesommaite	(K,Na)₉Al₉Si₂₃O₆₄ · 10H₂O	Orth. mm2 : Fdd2
Mordenite	(Na₂,Ca,K₂)₄(Al₈Si₄₀)O₉₆ · 28H₂O	Orth.
Mountainite	KNa₂Ca₂[Si₈O₁₉(OH)] · 6H₂O	Mon. 2/m : P2/b
Mutinaite	Na₃Ca₄Si₈₅Al₁₁O₁₉₂ · 60H₂O	Orth. mmm(2/m2/m2/m) : Pnma
Nabesite	Na₂BeSi₄O₁₀ · 4H₂O	Orth. 222 : P2₁2₁2₁
Natrolite Subgroup	A subgroup of the Zeolite Group.
Offretite	KCaMg(Si₁₃Al₅)O₃₆ · 15H₂O	Hex. 6m2 : P6m2
Pahasapaite	Li₈(Ca,Li,K)_10.5Be₂₄(PO₄)₂₄ · 38H₂O	Iso. 23 : I23
Parthéite	Ca₂(Si₄Al₄) O₁₅ (OH)₂ · 4H₂O	Mon. 2/m : B2/b
Paulingite Subgroup	Paulingite was originally described in 1960.
Perlialite	K₉Na(Ca,Sr)[Al₂Si₄O₁₂]₆ · 15H₂O	Hex. 6/mmm(6/m2/m2/m) : P6/mmm
Phillipsite Subgroup	(Ca_0.5,K,Na,Ba_0.5)_4-7[Al_4-7Si_12-9O₃₂] ^. 12H₂O
Pollucite	(Cs,Na)₂(Al₂Si₄O₁₂) · 2H₂O	Iso. m3m(4/m32/m) : Ia3d
Roggianite	Ca₂Be(OH)₂Al₂Si₄O₁₃ · 2.5H₂O	Tet. 4/mmm(4/m2/m2/m) : I4/mcm
Rongibbsite	Pb₂(Si₄Al)O₁₁(OH)	Mon. 2/m : B2/m
Stilbite Subgroup	M_6-7[Al_8-9Si_27-28O₇₂] · nH₂O
Terranovaite	(Na,Ca)₈(Si₆₈Al₁₂)O₁₆₀ · 29H₂O	Orth.
Thomsonite Subgroup	The large majority of "thomsonite" is thomsonite-Ca.
Thornasite	Na₁₂Th⁴⁺₃(Si₈O₁₉)₄ · 18H₂O	Trig. 3m : R3m
Tschernichite	(Ca,Na₂)[Al₂Si₄O₁₂] · 4-8H₂O	Tet. 4/mmm(4/m2/m2/m) : P4/mmm
Tschörtnerite	Ca₄(Ca,Sr,K,Ba)₃Cu₃[Al₃Si₃O₁₂]₄(OH)₈ · nH₂O	Iso. m3m(4/m32/m) : Fm3m
'UM1996-38-SiO:AlCaHNa'	Na-Ca-Al-Si-O-H
'UM1999-33-SiO:AlHKNa'	K₇Na₅Al₁₂Si₂₀O₆₄ · 24H₂O
'UM2002-40-SiO:AlCaHKMgNa'	(Mg,Ca,Na,K)_7.5(Al_12.8Si_51.2)O₁₂₈ · 65H₂O	Tet. 422 : P4₁22
'Unnamed (Ca analogue of Merlinoite)'	(Ca,K,Na)₅(Ca,Ba)₂Al₉Si₂₃O₆₄ · 23H₂O ?
Wairakite	Ca(Al₂Si₄O₁₂) · 2H₂O	Mon. 2/m : B2/m
Weinebeneite	CaBe₃(PO₄)₂(OH)₂ · 4H₂O	Mon. m : Bb
Wenkite	(Ba,K)₄(Ca,Na)₆[(Si,Al)₂₀O₃₉(OH)₂](SO₄)₃ · 0.5H₂O	Hex. 6m2 : P62m
Wilancookite	(Ba₅Li₂◻)Ba₆Be₂₄P₂₄O₉₆ · 26H₂O	Iso. 23 : I23
Willhendersonite	KCa[Al₃Si₃O₁₂] · 5H₂O	Tric. 1 : P1
Yugawaralite	CaAl₂Si₆O₁₆ · 4H₂O	Mon. m : Pb

Common AssociatesHide

Associations Based on Photo Data:

10 photos of Hsianghualite associated with Eucryptite	LiAlSiO₄
6 photos of Hsianghualite associated with Calcite	CaCO₃
6 photos of Hsianghualite associated with Scheelite	Ca(WO₄)
5 photos of Hsianghualite associated with Liberite	Li₂BeSiO₄
4 photos of Hsianghualite associated with Biotite	K(Fe²⁺/Mg)₂(Al/Fe³⁺/Mg/Ti)([Si/Al/Fe]₂Si₂O₁₀)(OH/F)₂
4 photos of Hsianghualite associated with Albite	Na(AlSi₃O₈)
4 photos of Hsianghualite associated with Fluorite	CaF₂
2 photos of Hsianghualite associated with Phlogopite	KMg₃(AlSi₃O₁₀)(OH)₂

Related Minerals - Strunz-mindat Grouping Hide

9.GB.05	Fabrièsite	Na₃Al₃Si₃O₁₂ · 2H₂O	Orth. mm2 : Pmm2
9.GB.05	Lithosite	K₆Al₄Si₈O₂₅ · 2H₂O	Mon.
9.GB.05	Wairakite	Ca(Al₂Si₄O₁₂) · 2H₂O	Mon. 2/m : B2/m
9.GB.05	Kirchhoffite	Cs(BSi₂O₆)	Tet. 4/mmm(4/m2/m2/m) : I4₁/acd
9.GB.05	Leucite	K(AlSi₂O₆)	Tet. 4/m : I4₁/a
9.GB.05	Pollucite	(Cs,Na)₂(Al₂Si₄O₁₂) · 2H₂O	Iso. m3m(4/m32/m) : Ia3d
9.GB.05	Ammonioleucite	(NH₄)(AlSi₂O₆)	Tet. 4/m : I4₁/a
9.GB.05	Analcime	Na(AlSi₂O₆) · H₂O	Tric. 1 : P1
9.GB.10	Laumontite	CaAl₂Si₄O₁₂ · 4H₂O	Mon. 2/m : B2/m
9.GB.15	Yugawaralite	CaAl₂Si₆O₁₆ · 4H₂O	Mon. m : Pb
9.GB.20	Roggianite	Ca₂Be(OH)₂Al₂Si₄O₁₃ · 2.5H₂O	Tet. 4/mmm(4/m2/m2/m) : I4/mcm
9.GB.25	Goosecreekite	Ca[Al₂Si₆O₁₆] · 5H₂O	Mon. 2 : P2₁
9.GB.30	Montesommaite	(K,Na)₉Al₉Si₂₃O₆₄ · 10H₂O	Orth. mm2 : Fdd2
9.GB.35	Parthéite	Ca₂(Si₄Al₄) O₁₅ (OH)₂ · 4H₂O	Mon. 2/m : B2/b

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HsianghualiteHide

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https://www.mindat.org/min-1937.html
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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

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References for HsianghualiteHide

Reference List:

Huang W.-H., Tu S., Wang K.-H., Chao C.-L., Yu C.-C. (1958) Hsiang-hua-shih, a new beryllium mineral. Ti-chih-yueh-k'an: 7: 35-35 (in Chinese).

Fleischer, M. (1959) New Mineral Names. American Mineralogist, 44 (11-12). 1321-1329 p.1327

Beus, A.A. (1960) Geochemistry of beryllium and the genetic types of beryllium deposits. Akad. Nauk SSSR Inst. mineral., geokhim., i kristallokhim redkikh elementov: 1960: l-329. (in Russian)

Fleischer, M. (1961) New mineral names. American Mineralogist, 46 (1-2). 241-244

Section of Crystal Structure Analysis of the Academy of Geological Sciences (1973) The crystal structure of hsianghualite. Acta Geologica Sinica: 47(2): 235-242.

Rastsvetaeva, R.K., Rekhlova, O.Y., Andrianov, V.I., Malinovskii, Y.A. (1991) Crystal structure of hsianghualite. Soviet Physics - Doklady: 36: 11-13.

Rastsvetaeva, R.K., Rekhlova, O.Y., Andrianov, V.I., Malinovskii, Y.A. (1991) Crystal structure of hsianghualite (in Russian). Doklady Akademii Nauk SSSR: 316: 624-628.

Coombs, Douglas S., Alberti, Alberto, Armbruster, Thomas, Artioli, Gilberto, Colella, Carmine, Galli, Ermanno, Grice, Joel D., Liebau, Friedrich, Mandarino, Joseph A., Minato, Hideo, et al. (1997) Recommended nomenclature for zeolite minerals; report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. The Canadian Mineralogist, 35 (6). 1571-1606

(2001) Hsianghualite. Handbook of Mineralogy. Mineralogical Society of America

Localities for HsianghualiteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

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Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


China
Hunan Chenzhou Linwu Co. ⓘ Xianghualing Sn-polymetallic ore field	Li et al. (2023)
ⓘ Xianghualing Mine (TL)	[Ti-chih-yueh-k'an +3 other references
ⓘ Xianghuapu Mine	Yuzhou Li (1990)

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Hsianghualite

About HsianghualiteHide

Unique IdentifiersHide

IMA Classification of HsianghualiteHide

Classification of HsianghualiteHide

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Physical Properties of HsianghualiteHide

Optical Data of HsianghualiteHide