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Manganostibite

A valid IMA mineral species - grandfathered
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About ManganostibiteHide

Formula:
(Mn,Fe)7SbAsO12
Colour:
Black; dark reddish brown in transmitted light
Lustre:
Greasy
Specific Gravity:
4.949
Crystal System:
Orthorhombic
Name:
In allusion to the composition, containing MANGANese and antimony (Latin = STIBium).
The Mn-enriched analogue of garpenbergite.

Chemically similar to garpenbergite and somewhat to manganoschafarzikite, melanostibite, filipstadite, and tegengrenite.


Unique IdentifiersHide

Mindat ID:
2528
Long-form identifier:
mindat:1:1:2528:3

IMA Classification of ManganostibiteHide

Classification of ManganostibiteHide

4.BB.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
B : Metal: Oxygen = 3:4 and similar
B : With only medium-sized cations
44.3.2.1

44 : ANTIMONATES
3 : Miscellaneous
24.4.2

24 : Antimonates and Antimonites
4 : Antimonates and antimonites of Mn and Fe

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MnsbIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of ManganostibiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of ManganostibiteHide

Greasy
Transparency:
Translucent, Opaque
Colour:
Black; dark reddish brown in transmitted light
Streak:
Chocolate-brown
Fracture:
Irregular/Uneven
Density:
4.949 g/cm3 (Measured)    5.00 g/cm3 (Calculated)

Optical Data of ManganostibiteHide

Type:
Biaxial (-)
RI values:
nα = 1.92(2) nβ = 1.95(2) nγ = 1.96(2)
Max. Birefringence:
δ = 0.040
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Dispersion:
r > v strong
Pleochroism:
Visible
Comments:
X = b = Reddish brown
Z ^ c = Nearly opaque
Comments:
2V(meas.) = Very small.

Chemistry of ManganostibiteHide

Mindat Formula:
(Mn,Fe)7SbAsO12
Element Weights:
Element% weight
Mn49.734 %
O24.830 %
Sb15.747 %
As9.689 %

Calculated from ideal end-member formula.

Crystallography of ManganostibiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Cell Parameters:
a = 8.727(5) Å, b = 18.847(6) Å, c = 6.062(4) Å
Ratio:
a:b:c = 0.463 : 1 : 0.322
Unit Cell V:
997.06 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Embedded grains exhibiting crystal outlines at times. Nearly opaque rods and fibers with positive elongation.
Comment:
Space Group: Ibmm.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000210ManganostibiteMoore P B (1970) Manganostibite: A novel cubic close-packed structure type American Mineralogist 55 1489-149919700293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.651 Å(10)
4.965 Å(6)
4.38 Å(6)
1.5418 Å(5)
2.180 Å(5)
9.313 Å(4)
4.694 Å(4)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits
Stage 7: Great Oxidation Event<2.4
46 : Near-surface hydrothermal alteration of minerals (see also #22)

Type Occurrence of ManganostibiteHide

General Appearance of Type Material:
subhedral prismatic grains.
Place of Conservation of Type Material:
Swedish Museum of Natural History, Stockholm, Sweden.
Geological Setting of Type Material:
late-stage hydrothermal veins in manganese deposits in limestone
Associated Minerals at Type Locality:

Other Language Names for ManganostibiteHide

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Manganostibite associated with HausmanniteMn2+Mn3+2O4
1 photo of Manganostibite associated with ManganositeMnO
1 photo of Manganostibite associated with JacobsiteMn2+Fe3+2O4
1 photo of Manganostibite associated with Katoptrite(Mn2+,Mg)13(Al,Fe3+)4Sb5+2(SiO4)2O20

Related Minerals - Strunz-mindat GroupingHide

4.BB.ChenmingiteFeCr2O4Orth. mmm(2/m2/m2/m) : Pnma
4.BB.ThermaerogeniteCuAl2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.ChukocheniteLiAl5O8Orth. mmm(2/m2/m2/m) : Imma
4.BB.Elgoresyite(Mg5Si2)O9Mon. 2/m : B2/m
4.BB.JianmuiteZrTi4+Ti3+5Al3O16Tet. 4 : I4
4.BB.DellagiustaiteV2+Al2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.GarpenbergiteMn6◻AsSbO10(OH)2Orth. mmm(2/m2/m2/m)
4.BB.MagnéliiteTi3+2Ti4+2O7Tric. 1 : P1
4.BB.05Qandilite(Mg,Fe3+)2(Ti,Fe3+,Al)O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05ChromiteFe2+Cr3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05Filipstadite(Fe3+0.5Sb5+0.5)Mn2O4Iso.
4.BB.05JacobsiteMn2+Fe3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05WernerkrauseiteCa(Fe3+,Mn3+)2Mn4+O6Orth. mmm(2/m2/m2/m) : Pnma
4.BB.05HarmuniteCaFe2O4Orth. mmm(2/m2/m2/m) : Pbcm
4.BB.05ZincochromiteZnCr2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05Deltalumite(Al0.670.33)Al2O4Tet. 42m : P4m2
4.BB.05FrankliniteZn2+Fe3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05CochromiteCoCr2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05'Nichromite'(Ni,Co,Fe)(Cr,Fe,Al)2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05HercyniteFe2+Al2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05GahniteZnAl2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05GalaxiteMn2+Al2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05GuiteCo2+Co3+2O4Iso.
4.BB.05CoulsoniteFe2+V3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05VuorelaineniteMn2+V3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05SpinelMgAl2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05CuprospinelCu2+Fe3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05ManganochromiteMn2+Cr2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05MagnesiocoulsoniteMgV2O4Iso. m3m(4/m32/m)
4.BB.05TrevoriteNi2+Fe3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05MagnesiochromiteMgCr2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05MagnesioferriteMgFe3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05MagnetiteFe2+Fe3+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.05UlvöspinelTiFe2+2O4Iso. m3m(4/m32/m) : Fd3m
4.BB.10HausmanniteMn2+Mn3+2O4Tet. 4/mmm(4/m2/m2/m) : I41/amd
4.BB.10HetaeroliteZnMn2O4Tet. 4/mmm(4/m2/m2/m) : I41/amd
4.BB.15Titanomaghemite(Ti4+0.50.5)Fe3+2O4Iso. 432 : P4332
4.BB.15Maghemite(Fe3+0.670.33)Fe3+2O4Iso. 432 : P4132
4.BB.20Tegengrenite(Mn3+0.5Sb5+0.5)Mg2O4Trig. 3 : R3
4.BB.25XieiteFe2+Cr2O4Orth. mmm(2/m2/m2/m)
4.BB.30CarmeltaziteZrAl2Ti4O11Orth. mmm(2/m2/m2/m) : Pnma
4.BB.35FeiiteFe2+2(Fe2+Ti4+)O5Orth. mmm(2/m2/m2/m) : Cmcm
4.BB.40MaohokiteMgFe2O4Orth. mmm(2/m2/m2/m) : Pnma
4.BB.45Tschaunerite (Fe2+)(Fe2+Ti4+)O4Orth. mmm(2/m2/m2/m) : Cmcm

Other InformationHide

Notes:
Totally soluble in HCl; partly soluble in HNO3.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ManganostibiteHide

References for ManganostibiteHide

Reference List:

Localities for ManganostibiteHide

Showing 10 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Romania
 
  • Maramureș County
    • Târgu Lăpuș
HÎRTOPANU et al. (2025)
Russia
 
  • Khakassia (Republic of Khakassia)
    • Askizsky Rayon
      • Askiz ore district
Kassandrov et al. (2009)
Kassandrov et al. (2009)
Sweden
 
  • Värmland County
    • Filipstad
      • Långban Ore District
Gatedal (n.d.)
Holtstam et al. (1999) +2 other references
      • Nordmark mining district
        • Jakobsberg ore field
Mineralogical Magazine: 62: 395
Gatedal (2003)
Igelström (1884) +1 other reference
Holtstam et al. (1998)
Magnusson (1929) +1 other reference
 
and/or  
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