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Iimoriite-(Y)

A valid IMA mineral species
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About Iimoriite-(Y)Hide

04320280017271924031518.jpg
Satoyasu Iimori and Takeo Iimori
Formula:
Y2[SiO4][CO3]
Colour:
Buff-tan, light purplish gray
Lustre:
Vitreous, Resinous
Hardness:
5½ - 6
Specific Gravity:
4.47
Crystal System:
Triclinic
Name:
Named iimoriite by A. Kato and K. Nagashima in 1970 in honor of Satoyasu Iimori (飯盛里安)(19 October 1885, Kanazawa, Ishikawa Prefecture, Japan - 13 October 1982, Japan) and Takeo Iimori (飯盛武夫)( - 16 August 1942), Japanese chemists who first described many rare earth minerals from the Fusamata pegmatite district. The suffix was added in 1985.
A silico-carbonate of yttrium found in REE- and uranium-bearing granitic pegmatites and veins. Found as alteration product after thalénite-(Y) from the Suishoyama pegmatite, Japan together with tengerite-(Y) (Kato & Nagashima 1970) and at the Åskagen pegmatite, Sweden.


Unique IdentifiersHide

Mindat ID:
2006
Long-form identifier:
mindat:1:1:2006:6

IMA Classification of Iimoriite-(Y)Hide

Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
Y2(SiO4)(CO3)
Approval year:
1967
First published:
1970
Approval history:
Approved by IMA in 1967 (IMA1967-033).

Classification of Iimoriite-(Y)Hide

9.AH.05

9 : SILICATES (Germanates)
A : Nesosilicates
H : Nesosilicates with CO3, SO4, PO4, etc.
53.1.3.1

53 : NESOSILICATES Insular SiO4 Groups and Other Anions or Complex Cations
1 : Insular SiO4 Groups and Other Anions of Complex Cations with (CO3)
17.4.9

17 : Silicates Containing other Anions
4 : Silicates with carbonates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Iim-YIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Iimoriite-(Y)Hide

Vitreous, Resinous
Transparency:
Transparent
Colour:
Buff-tan, light purplish gray
Comment:
Colourless in thin section (TL)
Streak:
White with purplish gray-tint
Hardness:
5½ - 6 on Mohs scale
Cleavage:
Distinct/Good
distinct on (011)
Density:
4.47 g/cm3 (Measured)    4.91 g/cm3 (Calculated)

Optical Data of Iimoriite-(Y)Hide

Type:
Biaxial (-)
RI values:
nα = 1.753 nβ = 1.824 nγ = 1.83
2V:
Measured: 31° , Calculated: 32°
Max. Birefringence:
δ = 0.077
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
distinct to strong
Pleochroism:
Non-pleochroic

Chemistry of Iimoriite-(Y)Hide

Mindat Formula:
Y2[SiO4][CO3]
Element Weights:
Element% weight
Y53.898 %
O33.948 %
Si8.513 %
C3.641 %

Calculated from ideal end-member formula.
Y
O
Si
C

Chemical AnalysisHide

Oxide wt%:
 1
Y2O348.73 %
Yb2O37.74 %
Er2O33.16 %
Lu2O31.88 %
Dy2O34.79 %
Tb2O30.38 %
Gd2O32.64 %
CO2 calc14.12 %
SiO216.56 %
Total:100 %
Empirical formulas:
Sample IDEmpirical Formula
1(Y1.51Yb0.14Dy0.09Er0.06Gd0.05Lu0.03Tb0.01)S1.89(SiO4)(CO3)1.12

Crystallography of Iimoriite-(Y)Hide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 6.573 Å, b = 6.651 Å, c = 6.454 Å
α = 116.44°, β = 92.34°, γ = 95.63°
Ratio:
a:b:c = 0.988 : 1 : 0.97
Unit Cell V:
250.3 ų
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005503Iimoriite-(Y)Hughes J M, Foord E E, Jai-Nhuknan J, Bell J M (1996) The atomic arrangement of iimoriite-(Y), Y2(SiO4)(CO3) The Canadian Mineralogist 34 817-8201996Bokan Mountain, Prince of Wales Island, Alaska, USA0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.881 Å(100)
2.954 Å(80)
2.784 Å(40)
3.023 Å(36)
2.841 Å(35)
2.705 Å(29)
3.20 Å(27)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4a: Earth’s earliest continental crust>4.4-3.0
19 : Granitic intrusive rocks
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of Iimoriite-(Y)Hide

General Appearance of Type Material:
As masses up to 3 x 3 x 2 cm in size.
Place of Conservation of Type Material:
National Science Museum, Tokyo, Japan, M16288; National Museum of Natural History, Washington, D.C., USA, 120635.
Geological Setting of Type Material:
Quartz-microcline-pegmatite.
Associated Minerals at Type Locality:

Synonyms of Iimoriite-(Y)Hide

Other Language Names for Iimoriite-(Y)Hide

Common AssociatesHide

Associations Based on Photo Data:
11 photos of Iimoriite-(Y) associated with Allanite-(Nd)(CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH)
9 photos of Iimoriite-(Y) associated with DolomiteCaMg(CO3)2
9 photos of Iimoriite-(Y) associated with Tengerite-(Y)Y2(CO3)3 · 2-3H2O
5 photos of Iimoriite-(Y) associated with Keiviite-(Y)Y2Si2O7
4 photos of Iimoriite-(Y) associated with Thalénite-(Y)Y3Si3O10F
3 photos of Iimoriite-(Y) associated with Gadolinite-(Y)Y2Fe2+Be2Si2O10
3 photos of Iimoriite-(Y) associated with PyriteFeS2
3 photos of Iimoriite-(Y) associated with Allanite-(Y)(CaY)(AlAlFe2+)O[Si2O7][SiO4](OH)
2 photos of Iimoriite-(Y) associated with 'Yttrofluorite'(Ca1-xYx)F2+x where 0.05 < x < 0.3
2 photos of Iimoriite-(Y) associated with Allanite-(Ce)(CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH)

Related Minerals - Strunz-mindat GroupingHide

9.AH.Fluorbritholite-(Nd)Ca2Nd3(SiO4)3FHex. 6/m : P63/m
9.AH.10Tundrite-(Ce)Na2Ce2Ti(SiO4)(CO3)2O2Tric. 1 : P1
9.AH.10Tundrite-(Nd)Na2(Nd,Ce)2Ti(SiO4)(CO3)2O2
9.AH.15GaluskiniteCa7(SiO4)3(CO3) Mon. 2/m : P21/b
9.AH.15SpurriteCa5(SiO4)2(CO3)Mon. 2/m : P21/b
9.AH.20TernesiteCa5(SiO4)2(SO4)Orth. mmm(2/m2/m2/m) : Pnma
9.AH.20SilicocarnotiteCa5[(SiO4)(PO4)](PO4)Orth. mmm(2/m2/m2/m) : Pnma
9.AH.25Britholite-(Ce)(Ce,Ca)5(SiO4)3OHHex. 6/m : P63/m
9.AH.25Britholite-(Y)(Y,Ca)5(SiO4)3OHHex. 6/m : P63/m
9.AH.25MattheddleitePb5(SiO4)1.5(SO4)1.5(Cl,OH)Hex. 6/m : P63/m
9.AH.25Fluorbritholite-(Ce)(Ce,Ca)5(SiO4)3FHex. 6/m : P63/m
9.AH.25FluorellestaditeCa5(SiO4)1.5(SO4)1.5FHex. 6/m : P63/m
9.AH.25Fluorbritholite-(La)Ca2La3(SiO4)3FHex. 6/m : P63/m
9.AH.25Fluorbritholite-(Y)(Y,Ca)5(SiO4)3FHex. 6/m : P63/m
9.AH.25HydroxylellestaditeCa5(SiO4)1.5(SO4)1.5(OH)Hex. 6/mmm(6/m2/m2/m) : P63/mcm
9.AH.25'Calciobritholite'(Ca,Y)5(SiO4,PO4)3(OH)
9.AH.25'Britholite-(La)'Ca2(La,Ce,Ca)3(SiO4,PO4)3(OH,F)
9.AH.25Tritomite-(Ce)Ce5(SiO4,BO4)3(OH,O)
9.AH.25Tritomite-(Y)Y5(SiO4,BO4)3(O,OH,F)
9.AH.25Fluorcalciobritholite(Ca,REE)5(SiO4,PO4)3FHex. 6/m : P63/m
9.AH.25ChlorellestaditeCa5(SiO4)1.5(SO4)1.5ClHex. 6/m : P63/m
9.AH.35DargaiteBaCa12(SiO4)4(SO4)2O3Trig. 3m(32/m) : R3m
9.AH.35NabimusaiteKCa12(SiO4)4(SO4)2O2FTrig. 3m(32/m) : R3m
9.AH.40StracheriteBaCa6(SiO4)2[(PO4)(CO3)]FTrig. 3m(32/m) : R3m
9.AH.40ZadoviteBaCa6[(SiO4)(PO4)](PO4)2FTrig. 3m : R3m
9.AH.40GazeeviteBaCa6(SiO4)2(SO4)2OTrig. 3m(32/m) : R3m
9.AH.45FlamiteCa8-x(Na,K)x(SiO4)4-x(PO4)xOrth. mm2
9.AH.50ByzantieviteBa5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4),(SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5Trig. 3 : R3
9.AH.55Greenwoodite(Ba,V3+O)2V3+9(Fe3+,Fe2+)2Si2O22Trig. 3m(32/m) : P3m1
9.AH.60Kihlmanite-(Ce)Ce2TiO2(SiO4)(HCO3)2(H2O)Tric. 1 : P1
9.AH.65TsangpoiteCa5(PO4)2(SiO4)Hex.
9.AH.70'Enalite'(Th,REE,Al) [(PO4),(SiO4),(OH)]Tet.

Fluorescence of Iimoriite-(Y)Hide

Other InformationHide

Notes:
Slight reaction with cold HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Iimoriite-(Y)Hide

References for Iimoriite-(Y)Hide

Localities for Iimoriite-(Y)Hide

Showing 11 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Angola
 
  • Huambo Province
    • Bailundo
Beleque (2010)
France
 
  • Occitanie
    • Ariège
      • Foix
        • Luzenac
Gatel (1990)
Germany
 
  • Bavaria
    • Lower Franconia
      • Aschaffenburg District
        • Sailauf
          • Hartkoppe
Lorenz (2004)
Japan (TL)
 
  • Fukushima Prefecture
    • Date District
      • Kawamata
Kato et al. (1970)
        • Iizaka Village (Iisaka)
Kato et al. (1970) +1 other reference
Norway
 
  • Nordland
    • Hamarøy
      • Drag
Raade (2007)
Husdal (2011)
    • Narvik
Husdal (2019)
Russia
 
  • Murmansk Oblast
    • Lovozersky District
      • Keivy Mountains
        • Western Keivy Massif
Voloshin A.V. et al. (1987)
Sweden
 
  • Värmland County
    • Filipstad
      • Persberg ore district
Kristiansen (1993) +1 other reference
USA
 
  • Alaska
    • Prince of Wales-Hyder Census Area
      • Ketchikan Mining District
        • Prince of Wales Island
          • Bokan Mountain
Foord et al. (1984)
 
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