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Tundrite-(Ce)

A valid IMA mineral species
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About Tundrite-(Ce)Hide

Formula:
Na2Ce2Ti(SiO4)(CO3)2O2
Colour:
Yellow-brown, green-yellow
Lustre:
Vitreous, Greasy, Silky
Hardness:
3
Specific Gravity:
3.70
Crystal System:
Triclinic
Member of:
Name:
Originally called titanorhabdophane. Named tundrite after the Lovozero tundra, by E. I. Semenov in 1963. The suffix was added in 1987, following the Levinson rule, to indicate the dominant rare earth element.
Closely related to kihlmanite-(Ce).


Unique IdentifiersHide

Mindat ID:
4048
Long-form identifier:
mindat:1:1:4048:4

Similar NamesHide

Tundrite
Tundrite-(Nd)A valid IMA mineral speciesNa2(Nd,Ce)2Ti(SiO4)(CO3)2O2

IMA Classification of Tundrite-(Ce)Hide

Approved
IMA status notes:
Renamed by the IMA
IMA Formula:
Na2Ce3+2Ti4+O2SiO4(CO3)2

Classification of Tundrite-(Ce)Hide

9.AH.10

9 : SILICATES (Germanates)
A : Nesosilicates
H : Nesosilicates with CO3, SO4, PO4, etc.
17.1.11.

17 : COMPOUND CARBONATES
1 : Miscellaneous
17.4.15

17 : Silicates Containing other Anions
4 : Silicates with carbonates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Tnd-CeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Tundrite-(Ce)Hide

Vitreous, Greasy, Silky
Colour:
Yellow-brown, green-yellow
Hardness:
Tenacity:
Brittle
Density:
3.70 g/cm3 (Measured)    

Optical Data of Tundrite-(Ce)Hide

Type:
Biaxial (+)
RI values:
nα = 1.743 nβ = 1.8 nγ = 1.88
Max. Birefringence:
δ = 0.137
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (84°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Dispersion:
r > v moderate
Optical Extinction:
Z ∧ c = 14°.
Pleochroism:
Visible
Comments:
X = pale yellow; Z = greenish yellow.

Chemistry of Tundrite-(Ce)Hide

Mindat Formula:
Na2Ce2Ti(SiO4)(CO3)2O2
Element Weights:
Element% weight
Ce45.332 %
O31.058 %
Ti7.743 %
Na7.438 %
Si4.543 %
C3.886 %

Calculated from ideal end-member formula.
Ce
O
Ti
Na
Si
C

Crystallography of Tundrite-(Ce)Hide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.5702(6) Å, b = 13.949(2) Å, c = 5.0235(5) Å
α = 100.19(1)°, β = 70.88(1)°, γ = 101.26(1)°
Ratio:
a:b:c = 0.543 : 1 : 0.36
Unit Cell V:
487.91 ų
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0006184Tundrite-(Ce)Grice J D, Rowe R, Poirier G, Wight Q (2008) Tundrite-(Ce) from Mount Saint-Hilaire, Quebec: Crystal-structure analysis and species characterization The Canadian Mineralogist 46 413-4222008Mount Saint-Hilaire, Quebec, Canada0293
0015572Tundrite-(Ce)Shumyatskaya N G, Voronkov A A, Ilyukhin V V, Belov N V (1976) Tundrite, Na2Ce2TiO2[SiO4](CO3)2 - refinement of the crystal structure and chemical formula Soviet Physics Crystallography 21 399-4051976Khibiny Massif, Kola Peninsula, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.06 Å(80)
2.78 Å(100)
2.72 Å(100)
2.50 Å(30)
2.37 Å(30)
2.02 Å(30)
1.927 Å(30)
1.881 Å(20)
1.794 Å(30)
1.709 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]

Type Occurrence of Tundrite-(Ce)Hide

General Appearance of Type Material:
Fine acicular crystals up to 5 mm long and spherulites up to 15 mm in diameter. Alters to rhabdophane.
Place of Conservation of Type Material:
Fersman Mineralogical Museum, Moscow, Russia, number 72020 (type).
Geological Setting of Type Material:
Nepheline syenite pegmatite.
Associated Minerals at Type Locality:

Synonyms of Tundrite-(Ce)Hide

Tundrite (in part)

Other Language Names for Tundrite-(Ce)Hide

Relationship of Tundrite-(Ce) to other SpeciesHide

Member of:
Other Members of Tundrite Group:
Tundrite-(Nd)Na2(Nd,Ce)2Ti(SiO4)(CO3)2O2
Structurally related to group(s):

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Tundrite-(Ce) associated with AegirineNaFe3+Si2O6
2 photos of Tundrite-(Ce) associated with Ranciéite(Ca,Mn2+)0.2(Mn4+,Mn3+)O2 · 0.6H2O
2 photos of Tundrite-(Ce) associated with Rhabdophane-(Ce)Ce(PO4) · 0.6H2O
1 photo of Tundrite-(Ce) associated with AlbiteNa(AlSi3O8)
1 photo of Tundrite-(Ce) associated with Riebeckite◻Na2(Fe2+3Fe3+2)Si8O22(OH)2
1 photo of Tundrite-(Ce) associated with OrthoclaseK(AlSi3O8)
1 photo of Tundrite-(Ce) associated with Cerite-(CeCa)(Ce7Ca2)◻Mg(SiO4)3(SiO3OH)4(OH)3

Related Minerals - Strunz-mindat GroupingHide

9.AH.Fluorbritholite-(Nd)Ca2Nd3(SiO4)3FHex. 6/m : P63/m
9.AH.05Iimoriite-(Y)Y2[SiO4][CO3]Tric. 1 : P1
9.AH.10Tundrite-(Nd)Na2(Nd,Ce)2Ti(SiO4)(CO3)2O2
9.AH.15GaluskiniteCa7(SiO4)3(CO3) Mon. 2/m : P21/b
9.AH.15SpurriteCa5(SiO4)2(CO3)Mon. 2/m : P21/b
9.AH.20TernesiteCa5(SiO4)2(SO4)Orth. mmm(2/m2/m2/m) : Pnma
9.AH.20SilicocarnotiteCa5[(SiO4)(PO4)](PO4)Orth. mmm(2/m2/m2/m) : Pnma
9.AH.25Britholite-(Ce)(Ce,Ca)5(SiO4)3OHHex. 6/m : P63/m
9.AH.25Britholite-(Y)(Y,Ca)5(SiO4)3OHHex. 6/m : P63/m
9.AH.25MattheddleitePb5(SiO4)1.5(SO4)1.5(Cl,OH)Hex. 6/m : P63/m
9.AH.25Fluorbritholite-(Ce)(Ce,Ca)5(SiO4)3FHex. 6/m : P63/m
9.AH.25FluorellestaditeCa5(SiO4)1.5(SO4)1.5FHex. 6/m : P63/m
9.AH.25Fluorbritholite-(La)Ca2La3(SiO4)3FHex. 6/m : P63/m
9.AH.25Fluorbritholite-(Y)(Y,Ca)5(SiO4)3FHex. 6/m : P63/m
9.AH.25HydroxylellestaditeCa5(SiO4)1.5(SO4)1.5(OH)Hex. 6/mmm(6/m2/m2/m) : P63/mcm
9.AH.25'Calciobritholite'(Ca,Y)5(SiO4,PO4)3(OH)
9.AH.25'Britholite-(La)'Ca2(La,Ce,Ca)3(SiO4,PO4)3(OH,F)
9.AH.25Tritomite-(Ce)Ce5(SiO4,BO4)3(OH,O)
9.AH.25Tritomite-(Y)Y5(SiO4,BO4)3(O,OH,F)
9.AH.25Fluorcalciobritholite(Ca,REE)5(SiO4,PO4)3FHex. 6/m : P63/m
9.AH.25ChlorellestaditeCa5(SiO4)1.5(SO4)1.5ClHex. 6/m : P63/m
9.AH.35DargaiteBaCa12(SiO4)4(SO4)2O3Trig. 3m(32/m) : R3m
9.AH.35NabimusaiteKCa12(SiO4)4(SO4)2O2FTrig. 3m(32/m) : R3m
9.AH.40StracheriteBaCa6(SiO4)2[(PO4)(CO3)]FTrig. 3m(32/m) : R3m
9.AH.40ZadoviteBaCa6[(SiO4)(PO4)](PO4)2FTrig. 3m : R3m
9.AH.40GazeeviteBaCa6(SiO4)2(SO4)2OTrig. 3m(32/m) : R3m
9.AH.45FlamiteCa8-x(Na,K)x(SiO4)4-x(PO4)xOrth. mm2
9.AH.50ByzantieviteBa5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4),(SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5Trig. 3 : R3
9.AH.55Greenwoodite(Ba,V3+O)2V3+9(Fe3+,Fe2+)2Si2O22Trig. 3m(32/m) : P3m1
9.AH.60Kihlmanite-(Ce)Ce2TiO2(SiO4)(HCO3)2(H2O)Tric. 1 : P1
9.AH.65TsangpoiteCa5(PO4)2(SiO4)Hex.
9.AH.70'Enalite'(Th,REE,Al) [(PO4),(SiO4),(OH)]Tet.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Tundrite-(Ce)Hide

References for Tundrite-(Ce)Hide

Reference List:

Localities for Tundrite-(Ce)Hide

Showing 7 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Grice (1989) +1 other reference
Greenland
 
  • Kujalleq
Semenov et al. (5 1.del) +1 other reference
Karup-Møller (1982)
Karup-Møller (1982)
Russia
 
  • Murmansk Oblast
    • Kihlman Mountain
Pavel M. Kartashov (n.d.) +3 other references
    • Lovozersky District
      • Seidozero Lake
        • Lepkhe-Nel'm Mt
Semenov E.I. (1972)
 
and/or  
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