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Mccrillisite

A valid IMA mineral species
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About MccrillisiteHide

Formula:
NaCs(Be,Li)Zr2(PO4)4 · 1-2H2O
Colour:
White to colorless
Lustre:
Vitreous
Hardness:
4 - 4½
Specific Gravity:
3.125
Crystal System:
Tetragonal
Member of:
Name:
In honor of the late Dean McCrillis (February 8, 1931 in Quincy, Massachusetts - January 15, 1989), mineral dealer and his son, Philip.
Unique combination of elements. The only known Cs phosphate mineral. Also the sixth non-silicate oxysalt with species-defining Cs, the other ones being cesiodymite (sulphate), caesiumpharmacosiderite (arsenate), londonite and ramanite-(Cs) (borates), and margaritasite (vanadate).


Unique IdentifiersHide

Mindat ID:
7174
Long-form identifier:
mindat:1:1:7174:7

IMA Classification of MccrillisiteHide

Approved
IMA Formula:
NaCs(Be,Li)Zr4+2(PO4)4·1-2H2O
Approval year:
1991
First published:
1994

Classification of MccrillisiteHide

8.CA.20

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
A : With small and large/medium cations
40.5.4.2

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
5 : AXO4·xH2O

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
McrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MccrillisiteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
White to colorless
Streak:
White
Hardness:
4 - 4½ on Mohs scale
Cleavage:
None Observed
Fracture:
Conchoidal
Density:
3.125(5) g/cm3 (Measured)    3.30 g/cm3 (Calculated)

Optical Data of MccrillisiteHide

Type:
Uniaxial (+)
RI values:
nω = 1.634(2) nε = 1.645(2)
Max. Birefringence:
δ = 0.011
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Comments:
Anomalously biaxial, with 2V to 5 degrees.

Chemistry of MccrillisiteHide

Mindat Formula:
NaCs(Be,Li)Zr2(PO4)4 · 1-2H2O
Element Weights:
Element% weight
O36.496 %
Zr24.481 %
Cs17.834 %
P16.625 %
Na3.085 %
Be1.209 %
H0.271 %

Calculated from ideal end-member formula.
O
Zr
Cs
P
Na
Be
H
Common Impurities:
Al,Ca,Mg,Mn,Fe,Sr,K,Zn,Hf,Rb,F

Crystallography of MccrillisiteHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Space Group:
I41/amd
Setting:
I41/amd
Cell Parameters:
a = 6.573(2) Å, c = 17.28(2) Å
Ratio:
a:c = 1 : 2.629
Unit Cell V:
746.57 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Bipyramidal. The dominant form is {111}, and the minor form is {001}.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.060 Å(100)
6.159 Å(90)
4.326 Å(80)
3.281 Å(80)
4.099 Å(40)
2.896 Å(30)
1.849 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
22 : Hydration and low-? subsurface aqueous alteration (see also #23)

Type Occurrence of MccrillisiteHide

General Appearance of Type Material:
Bipyramidal crystals as much as 1.2 mm in maximum dimension. Many crystals have a crackled appearance.
Place of Conservation of Type Material:
National Museum of Natural History (Smithsonian), Washington, D.C., USA, 170853.
Geological Setting of Type Material:
Late-staqe hydrothermal alteration of earlier-formed Zr-bearing minerals in the pegmatite.
Associated Minerals at Type Locality:

Synonyms of MccrillisiteHide

Other Language Names for MccrillisiteHide

Relationship of Mccrillisite to other SpeciesHide

Member of:
Other Members of Gainesite Group:
GainesiteNa(Na,K)(Be,Li)Zr2(PO4)4 · 1.5-2H2OTet. 4mm : I41md
SelwyniteNaK(Be,Al)Zr2(PO4)4 · 2H2OTet. 4/mmm(4/m2/m2/m) : I41/amd

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Mccrillisite associated with SideriteFeCO3

Related Minerals - Strunz-mindat GroupingHide

8.CA.ApexiteNaMg(PO4) · 9H2OTric. 1 : P1
8.CA.BrandãoiteBeAl2(PO4)2(OH)2(H2O)5Tric. 1 : P1
8.CA.DavidlloyditeZn3(AsO4)2 · 4H2OTric. 1 : P1
8.CA.05ParafransoletiteCa3Be2(PO4)2(PO3OH)2 · 4H2OTric. 1 : P1
8.CA.05FransoletiteCa3Be2(PO4)2(PO3OH)2 · 4H2OMon. 2/m : P21/b
8.CA.10EhrleiteCa4Be3Zn2(PO4)6 · 9H2OTric. 1 : P1
8.CA.15FaheyiteBe2Mn2+Fe3+2(PO4)4 · 6H2OTrig. 32 : P3121
8.CA.20GainesiteNa(Na,K)(Be,Li)Zr2(PO4)4 · 1.5-2H2OTet. 4mm : I41md
8.CA.20SelwyniteNaK(Be,Al)Zr2(PO4)4 · 2H2OTet. 4/mmm(4/m2/m2/m) : I41/amd
8.CA.25PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 23 : I23
8.CA.30NizamoffiteMn2+Zn2(PO4)2(H2O)4Orth. mmm(2/m2/m2/m) : Pbcm
8.CA.30ArsenohopeiteZn3(AsO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pnma
8.CA.30HopeiteZnZn2(PO4)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pnma
8.CA.35WarikahniteZn3(AsO4)2 · 2H2OTric. 1 : P1
8.CA.40PhosphophylliteZn2Fe 2+(PO4)2 · 4H2OMon. 2/m : P21/b
8.CA.42SteinmetziteZn2Fe3+(PO4)2(OH) · 3H2OTric. 1 : P1
8.CA.45ParascholziteCaZn2(PO4)2 · 2H2OMon.
8.CA.45ScholziteCaZn2(PO4)2 · 2H2OOrth. mmm(2/m2/m2/m) : Pbcm
8.CA.50KeyiteCu2+3Zn4Cd2(AsO4)6 · 2H2OMon. 2/m
8.CA.55PushcharovskiteK0.6Cu18[AsO2(OH)2]4[AsO3OH]10(AsO4)(OH)9.6 · 18.6H2OTric.
8.CA.60ProsperiteCa2Zn4(AsO4)4 · H2OMon.
8.CA.65GengenbachiteKFe3+3(PO3OH)4[PO2(OH)2]2 · 6H2OTrig. 3m : P31c
8.CA.70ParahopeiteZn3(PO4)2 · 4H2OTric. 1 : P1
8.CA.70ReaphookhilliteMgZn2(PO4)2 · 4H2OTric. 1 : P1
8.CA.75StergiouiteCaZn2(AsO4)2 · 4H2OMon. m : Pb
8.CA.80LimousiniteBaCa[Be4P4O16] · 6H2OMon. 2/m : P21/b
8.CA.85MinjiangiteBaBe2(PO4)2Hex. 6/mmm(6/m2/m2/m) : P6/mmm
8.CA.85Wilancookite(Ba5Li2◻)Ba6Be24P24O96 · 26H2OIso. 23 : I23

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MccrillisiteHide

References for MccrillisiteHide

Localities for MccrillisiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • Maine
    • Oxford County
      • Paris
Foord et al. (1994) +1 other reference
 
and/or  
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